Electronic Structure of Ni Complexes by X-ray Resonance Raman Spectroscopy (Resonant Inelastic X-ray Scattering)
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- 作者：Pieter Glatzel ; Uwe Bergmann ; Weiwei Gu ; Hongxin Wang ; Sergey Stepanov ; Beaven S. Mandimutsira ; Charles Riordan ; Colin P. Horwitz ; Terry Collins ; and Stephen P. Cramer
- 刊名：Journal of the American Chemical Society
- 出版年：2002
- 出版时间：August 21, 2002
- 年：2002
- 卷：124
- 期：33
- 页码：9668 - 9669
- 全文大小：182K
- 年卷期：v.124,no.33(August 21, 2002)
- ISSN：1520-5126
文摘
The potential of 1s2p resonant inelastic (Raman) X-ray scattering (RIXS) is demonstrated for a series of Ni coordination complexes. In this technique, incident and scattered photon energies lie in the hard X-ray range (>5 keV). The 1s2p RIXS contour plots provide information that is complementary to K-edge and L-edge spectroscopy. RIXS spectroscopy promises to be a valuable probe of electronic structure