Single aligned submicron fibers composed of hole- and electron-transport materials and an organic dye were fabricated. The fibers demonstrated optical waveguiding with the loss coefficient of 1.2 × 10−3–3.9 × 10−3 μm−1 at 540-nm wavelength. The loss coefficient was lower than those previously reported for optically active polymer submicron fibers. A method to couple the fibers with counter electrodes was presented using phase segregation of an insulating polymer.