Synthesis of fluorine-containing 1,10-phenanthrolines using mild versions of Skraup and Doebner-von Miller reactions

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• 作者：Carsten Lü ; dtke^a ; Axel Haupt^a ; Martin Wozniak^a ; ^b ; Nora Kulak^a ; ^{nora.kulak@fu-berlin.de}
• 关键词：Phenanthroline ; Quinoline ; Skraup reaction ; Doebner-von Miller reaction
• 刊名：Journal of Fluorine Chemistry
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：193
• 期：Complete
• 页码：98-105
• 全文大小：653 K
• 卷排序：193

文摘

Fluorinated 1,10-phenanthroline and 2-methyl-1,10-phenanthroline derivatives have been synthesized and characterized. Skraup and Doebner-von Miller reactions allowed access to ten new derivatives. One of them had been reported previously as being impossible to synthesize. F, CF3, SCF3, OCF3 and SF5 were attached at position 5 of the phenanthroline moiety as well as F at positions 5 and 6.