Exploring the role of pendant amines in transition metal complexes for the reduction of N₂ to hydrazine and ammonia

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• 作者：Papri Bhattacharya ; Demyan E. Prokopchuk ; Michael T. Mock ; ^{michael.mock@pnnl.gov}
• 关键词：Dinitrogen ; Ammonia ; Hydrazine ; Phosphines ; Pendant amine ; Chromium ; Molybdenum ; Tungsten ; Iron ; Vanadium
• 刊名：Coordination Chemistry Reviews
• 出版年：2017
• 出版时间：1 March 2017
• 年：2017
• 卷：334
• 期：Complete
• 页码：67-83
• 全文大小：2127 K
• 卷排序：334

文摘

Preparation of group 6 and FeN2 complexes bearing phosphine ligands with pendant amine groups are reviewed. Examined the effects of pendant amine bases on MN2 reactivity with protons. Acid addition formed hydrazine, ammonia, MNxHy intermediates, and M-hydrides. Acid reactivity patterns of rare phosphine-supported CrN2 complexes are described.