Non-catalytic conversion of glycerol to syngas at intermediate temperatures: Numerical methods with detailed chemistry

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• 作者：Mohsen Ayoobi^a ; ^{mohsen.ayoobi@wayne.edu} ; Ingmar Schoegl^b ; ¹ ; ^{ischoegl@lsu.edu}
• 关键词：Non-catalytic glycerol reforming ; Syngas production ; Numerical methods ; Detailed chemistry ; Partial oxidation ; Pyrolysis
• 刊名：Fuel
• 出版年：2017
• 出版时间：1 May 2017
• 年：2017
• 卷：195
• 期：Complete
• 页码：190-200
• 全文大小：1572 K
• 卷排序：195

文摘

Non-catalytic glycerol reforming is studied numerically with detailed chemistry. Various numerical models are presented, verified and validated by experiments. The optimum model is applied for extensive simulations of glycerol reforming. Impacts of temperature, mixture stoichiometry and methanol impurity are studied. Ideal operating conditions for glycerol conversion to quality syngas are proposed.