Decoding catalytic activity of platinum carbene hydrosilylation catalysts
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- 作者：Teresa K. Meistera ; b ; Jens W. Kü ; cka ; Korbinian Rienerb ; c ; Alexander Pö ; thigd ; Wolfgang A. Herrmannc ; Fritz E. Kü ; hna ; c ; d ; fritz.kuehn@ch.tum.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：DFT ; Homogeneous catalysis ; Hydrosilylation ; Karstedt&rsquo ; s catalyst ; Markó ; &rsquo ; s catalyst ; N-heterocyclic carbenes ; Platinum ; Silanes
- 刊名：Journal of Catalysis
- 出版年：2016
- 出版时间：May 2016
- 年：2016
- 卷：337
- 期：Complete
- 页码：157-166
- 全文大小：1280 K
文摘
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Seven novel imidazo[1,5-a]pyridine-3-ylidene Pt(0) complexes are reported.
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The complexes are efficient and selective hydrosilylation catalysts.
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A correlation of HOMO energy levels, oxidation potentials and TOFs is revealed.