新一代高强塑性钢的开发与应用
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摘要
为满足汽车、建筑、能源等工业对材料强度级别和使用性能不断提高的要求,世界钢铁业正在开发新一代高强塑性钢。基于先进高强度钢AHSS汽车板、高强度抗震建筑用钢和高等级管线钢的开发,讨论了新一代高强塑性钢的主要技术特征,包括使用性能(成形性、抗冲撞能力、抗震性能、抗皱能力、超载下的形变能力)对塑性指标(均匀延伸率、n值、屈强比)的要求、复相组织与残余奥氏体的强塑化机理、关键工艺技术以及新产品新技术的发展方向。同时考虑到对强韧性和焊接性能的要求,讨论了热变形奥氏体动力学模型、高韧性焊接热影响区HAZ的细化韧化以及硫含量的影响与控制。
To meet the increasing requirement of automotive,construction and energy industry on high strength and high performance of structural materials,a new generation of high strength-plasticity(HSP) steels has been developed by the steel industry in the world.Based on the development of advanced high strength steels AHSS,high strength steels for construction and high grade pipeline steels,the main features of HSP steels are discussed,including the requirement of performance(formability,crashworthiness,aseismic ability,buckling resistance and deformability) on plasticity index(uniform elongation,n-value,yield ratio),the strengthening-plasticizing mechanism with multiphase structure and retained austenite,key process and technology as well as the promised new products and new techniques.For the necessary toughness and weldability,the dynamic model for austenite recrystallization,high toughness welding HAZ refinement and toughening and the effect of sulfur content are also discussed.
To meet the increasing requirement of automotive,construction and energy industry on high strength and high performance of structural materials,a new generation of high strength-plasticity(HSP) steels has been developed by the steel industry in the world.Based on the development of advanced high strength steels AHSS,high strength steels for construction and high grade pipeline steels,the main features of HSP steels are discussed,including the requirement of performance(formability,crashworthiness,aseismic ability,buckling resistance and deformability) on plasticity index(uniform elongation,n-value,yield ratio),the strengthening-plasticizing mechanism with multiphase structure and retained austenite,key process and technology as well as the promised new products and new techniques.For the necessary toughness and weldability,the dynamic model for austenite recrystallization,high toughness welding HAZ refinement and toughening and the effect of sulfur content are also discussed.
引文
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[49]王国栋.TMCP技术的新进展——柔性化在线热处理技术与装备[J].轧钢,2010,27(2):1-6.
[50]Naoshi Ayukawa,Yoshio Terada.Design Concept of High Strength UOE Linepipes[A].The International Symposium Proceedings on X80 Steel Grade Pipelines[C].Beijing: CSM,2004,320- 350.
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[3]Yoshiyuki Watanabe,Kiyoshi Ishibashi.Development of 590N/mm~2 Steel with Good Weldability for Building Struct ures[J].Nippon Steel Technical Report,2004,90(7):21 - 25.
[4]Alan Glover.X80 Design,Construction and Operation[A]. The International Symposium Proceedings on X80 Steel Grade Pipelines[C].Beijing:CSM,2004.
[S]Dieter Ameling.Steel-Competing for the Future[A].METEC in Steel Conference[C].D(u|¨)sseldorf:German Steel Federa tion,2007.
[6]IISI-AutoCo.Advanced High Strength Steel(AHSS)Application Guideline[R].Germany:International Iron＆Steel Institute, Committee on Automotive Applications,2006.
[7]Michel Babbit.Some Highlights on New Steel Products for Automotive Use[J].Steel Research Int.,2006,77(9-10): 620-626.
[8]Thomas Heller.New Steel Solutions for the Worldwide Car Industry[A].China-Germany Symposium on New Steel Materials [C].Beijing:CSM,2006.
[9]Eric Lamm.Advanced Steel Solutions for Automotive Lightweighting [R].Japan:USINOR Auto,Windsor Workshop Nippon Steel Corporation,2001.
[10]Stephen Denner.Advanced High Strength Steels for Automotives Weightlightening[A].DOE Expo4[C].Washington DC:DOE,2001.
[11]Manabu Takahashi.Development of High Strength Steels for Automobiles[J].Nippon Steel Technical Report,2003, 88(7):2-7.
[12]Ponge D.Structural Materials-Steels[R].H(u|¨)rtgenwald: Max-Planck-Institut fur Eisenforschung GmbH,2006.
[13]Tomasz Wierzbicki.New Research Program on Fracture of Advanced High Strength Steels(AHSS)[R].Massachusetts: Impact and Crashworthiness Lab,Massachusetts Institute of Technology,2006.
[14]David K Matlock.Micro-structural Aspects of Advanced High-Strength Sheet Steels[R].Arlington Virginia:AHSS Workshop,NSF-ASP,2006.
[15]ThyssenKrupp Stahl-Service-Center.Steel Needs a Concept-Services and Product Range[R].Germany:ThyssenKrupp Stahl-Service-Center GmbH,2007.
[16]李光瀛.汽车构件与零部件新材料及其热处理新技术的发展与应用[J].金属热处理,2010,(12):1-13.
[17]Shogo Tomita.Advanced Technologies in Strip/Plate Rolling and On-line Heat-treatment at JFE Steel of Recent Years[A].ICSR 2010[C].Beijing:CSM,2010.
[18]Ishikawa Nobuyuki,Endo Shigeru,Kondo Joe.High Performance UOE Linepipes[J].JFE Technical Report,2006,7 (1):20-26.
[19]Zackay V F,Parker E R,Fahr D,et al.[J].Trans.of ASM,1967,60:252-259.
[20]Sakuma Y,Matsumura O,Akisue O.Influence of Annealing Temperature on Microstructure and Mechanical Properties of 400℃Transformed Steel Containing Retained Austenite [J].ISIJ International,1991,31(11):1348-1353.
[21]Koh-ichi Sugimoto,Noboru Usui.Effects of Volume Fraction and Stability of Retained Austenite on Ductility of TRIP-aided Dual-phase Steels[J].ISIJ International,1992, 32(12):1311-1318.
[22]Nakajima K,Urabe T,Hosoya Y.Influence of Microstructural Morphology and Prestraining on Short Fatigue Crack Propagation in Dual-phase Steels[J].ISIJ,International, ??2001,41(3):298-304.
[23]Mesplont C,Vandeputte S,De Cooman B C.Microstructure -Properties Relationships in Complex Phase Cold-Rolled High Strength Steels[J].ISS,2001,XXXIX:359- 371.
[24]Pichler A,Traint S,Pauli H.Processing and Properties of Cold-Rolled Trip Steels[J].ISS,2001,XXXIX:411- 424.
[25]Jacques P J,Harlet Ph,Delannay F.Critical Assessment of the Phase Transformations Occurring During the Heat-Treatment of TRIP Assisted Multiphase Steels[A].Int. Conf.on TRIP-Aided High Strength Ferrous Alloys[C]. GRIPS,Ghent:Ed BC De Cooman,2002.
[26]Georg Frommeyer,Udo Brux,Peter Neumann.Supra-Ductile and High-Strength Manganese-TRIP/TWIP Steels for High Energy Absorption Purposes[J].ISIJ International. 2003,43(3):438 - 446.
[27]Shunichi Hashimoto,Shushi Ikeda,Koh-ichi Sugimoto,et al.Effectsof Nb and Mo Addition to0.2%C 1.5%Si-1. 5%Mn Steel on Mechanical Properties of Hot Rolled TRIPaided Steel Sheets[J].ISIJ International,2004,44(9): 1590 -1598.
[28]Bandyopadhyay N R,Datta S.Effect of Manganese Partitioning on Transformation Induced Plasticity Characteristics in Microalloyed Dual Phase Steels[J].ISIJ International, 2004,44(5):927-934.
[29]陆匠心,王利,应白桦,等.高强度汽车钢板的特性及应用[J].汽车工艺与材料,2004,(6):13-15.
[30]Wang Li,Jin lei,Xia Qi,et al.Application of TRIP Steel to Replace Mild Steel in Automotive Parts[A].AHSSS 2004 Proceedings[C].Beijing:CSM,2004.
[31]John G Speer,Fernando C Rizzo Assun?? o,David K Matlock, et al.The“Quenching and Partitioning”Process: Background and Recent Progress[J].Materials Research, 2005,8(4):417- 423.
[32]De Cooman B C,Speer J G.Quench and Partitioning Steel:a New AHSS Concept for Automotive Anti Intrusion Applications [J].Steel Research Int.,2006,77(9 -10):634 -640.
[33]Sandra Traint,Andreas Pichler,Robert Sierlinger,et al. Low-alloyed TRIP-Steels with Optimized Strength,Form ing and Welding Properties[J].Steel Research int.,2006, 77(9-10):641-649.
[34]李光瀛.北京市科委重大项目技术研究报告冷轧TRIP600钢的研究与开发[R].北京:钢铁研究总院,2007.
[35]李光瀛,史秉华.超轻钢汽车用TRIP钢的川发[R].北京:钢铁研究总院,2007.
[36]Koh-ichi Sugimoto,Muneo Murata.Formability of C-Si-Mn-Al -Nb-Mo Ultra High strength TRIP-aided Sheet Steels [J].ISIJ International,2007,47(9):1357- 1362.
[37]张峰,宋仁伯,刘雅政.1000MPa级冷轧双相钢的热处理工艺与性能研究[J].材料热处理技术,2008,(2):42-45.
[38]Hulka K.High Strength Steel for Construction Enginnering [R].Germany:NPC GmbH,1999.
[39]Kazuo Omata,Hiroshi Yoshimura,Sadahiro Yamamoto. Leading High Performance Steel Plates with Advanced Manufacturing Technologies[J].NKK Technical Review, 2003,88:73-80.
[40]Yoshiyuki Watanabe,Kiyoshi Ishibashi.Development of 590N/mm2 Steel with Good Weldability for Building Structures [J].Nippon Steel Technical Report,2004,90(7 ):53 - 58.
[41]龚士弘,盛光敏.地震区建筑用钢的开发[A].2001中国钢铁年会论文集[C].北京:中国金属学会,2001.
[42]李光瀛,刘浏.现代钢结构用高强度钢板的开发[A].全国钢结构技术标准及建筑钢结构技术、设备、配套产品应用研讨会论文集[C].北京:中国工程建设标准化协会,2003.
[43]Kim Y M,Kim S K,Lim Y J,et al.Effect of Microstructure on the Yield Ratio and Low Temperature Toughness of Linepipe Steels[J],ISIJ International,2002,42(12):1571 1577.
[44]李光瀛,刘浏,于桂玲,等.抗震建筑结构用高强度钢的开发—低镍铬红土矿资源利用之一[A].第十届中国科协年会论文集[C].北京:中国科学技术协会,2008.
[45]Hoffmann Jacques,Donnay Boris.TMCP Application in Sections, Bars and Rails[A].TMCP TMP 2004[C].Luxembourg: Profilarbed Research,2004.
[46]Franchil A,Crespil P.Some Recent Results of the Research on Steel Rebars[R].Italy:Department of Structural Engineering, Politecnico of Milano,2001.
[47]Bimal Kumar Panigrahi,Surendra Kumar Jain.Impact Toughness of High Strength Low Alloy TMT Reinforce ment Ribbed Bar[J].Bull.Mater.Sci.,2002,25(4):319 -324.
[48]Ishikawa Nobuguki,Endo Shigeru,Kondo Joe.High Performance UOE Linepipes[J].JFE Technical Report,2006,7 (1):20-26.
[49]王国栋.TMCP技术的新进展——柔性化在线热处理技术与装备[J].轧钢,2010,27(2):1-6.
[50]Naoshi Ayukawa,Yoshio Terada.Design Concept of High Strength UOE Linepipes[A].The International Symposium Proceedings on X80 Steel Grade Pipelines[C].Beijing: CSM,2004,320- 350.
[51]Jang-Yong Yoo,Jin Ho Bae.Mechanical Properties and Microstructure of API X80 Grade Hot-Rolled Strips and Plates [A].The International Symposium Proceedings on X80 Steel Grade Pipelines[C].Beijing:CSM,2004.
[52]Guang-ying Li,Shao-kang Pu,Ping-he Li,et al.Production, Microstructure and Properties of Microalloyed High strength 385 MN/mm~2 Grade Ship Plate[A].Proceedings of HSLA Steels'85 Beijing[C].Beijing:CSM,1985,605 - 611.
[53]Ohjoon kwon.A Technology for the Prediction and Control of Microstructure Changes and Mechanical Properties in Steel[J].ISIJ International,1992,32(3):350- 358.
[54]Yoshie A,Fujioka M,Watanabe Y,et al.Modelling of Mi- ??crostructural Evolution and Mechanical Properties of Steel Plates Produced by Thermo-Mechanical Control Process [J].ISIJ International,1992,32(3):395-404.
[55]Pietrzyk M,Roucoules C,Hodgson P D.Modelling the During Rolling Thermomechanical of a Nb HSLASteel and Microstructural Evo[ution[J].ISIJ International,1995,35 (5):531-541.
[56]Bai D O,Yuet Maccagn S,Jonas O J.Static Recrystallization of Nband Cooling Conditions Nb-B Steels under Continuous [J].ISIJ Internationai,1996,36(8):1084-1093.
[57]Medina S F,Mancillal J E.Static Recrysta IIization Modelling of Hot Deformed Steels Containing Several Alloying Elements [J].ISIJ International,1996,36(8):1070-1076.
[58]Panigrahi B K.Processing of Low Carbon Steel Plate and HotStrip an Overview[J].Bull.Mater.Sci.,2001,24 (4):361 - 371.
[59]Shigeaki Ogibayashi.Advances in Technology of Oxide Metallurgy [J].Nippon Steel Technical Report,1994,61(4):70 -76.
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