吸氮除磷材料的研究和应用现状
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摘要
人类的超强度活动导致水体中氮磷超标,是造成水体富营养化、发黑发臭、生态功能失衡的主要原因。目前去除氮磷的方法主要有生物法(短程硝化反硝化和好氧反硝化)、化学法(投加药剂法)和物理法(吹脱法和材料吸附法)。其中物理吸附法相比于其他方法,具有价格低廉、材料来源广泛、无二次污染、适用于大面积城市污水的特点。综述了近年来国内外吸氮除磷材料的研究和应用现状,着重阐述了矿物型和非矿物型吸氮除磷材料的应用效果,并对其应用前景进行展望。
The excessive nitrogen and phosphorus in water caused by human activities are the main causes of water eutrophication,blackening and the imbalance of ecological functions.Current methods to remove nitrogen and phosphorus mainly include biological methods(short range nitrification denitrification and aerobic denitrification),physical method(blow off treatment and material adsorption),chemical method(dosing reagent).Compared with other methods,the physical adsorption method has the characteristics of low price,wide material source,no secondary pollution,suitable for large area of urban sewage.the recent research and application of nitrogen and phosphorus removal materials at home and abroad were reviewed.The application effects of mineral and non mineral type nitrogen and phosphorus removal materials were emphatically expounded,and prospects for its application were expected.
The excessive nitrogen and phosphorus in water caused by human activities are the main causes of water eutrophication,blackening and the imbalance of ecological functions.Current methods to remove nitrogen and phosphorus mainly include biological methods(short range nitrification denitrification and aerobic denitrification),physical method(blow off treatment and material adsorption),chemical method(dosing reagent).Compared with other methods,the physical adsorption method has the characteristics of low price,wide material source,no secondary pollution,suitable for large area of urban sewage.the recent research and application of nitrogen and phosphorus removal materials at home and abroad were reviewed.The application effects of mineral and non mineral type nitrogen and phosphorus removal materials were emphatically expounded,and prospects for its application were expected.
引文
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[3]鲍祥,张艳,贺学周,等.改性凹凸棒土负载铝盐吸附剂去除水中总磷研究[J].安徽农学通报,2016,22(19):28-31.
[4]Kim S,Lee T.A study for the removal of phosphorous using coated exfoliated vermiculite[J].Korea Institute of Geoscience and Mineral Resources,2014,15(12):5-13.
[5]郑易安,王爱勤.不同方式处理蛭石对磷吸附性能研究[J].应用化工,2010,39(2):204-208.
[6]陈小燕,刘键熙,苏玉萍,等.两种锁磷剂锁磷效果对比研究[J].福建师范大学学报:自然科学版,2016,32(4):56-60.
[7]韩博涛,李晓玲,李彦鹏,等.污泥发酵液中氨氮和磷的去除方法研究[J].中国给水排水,2017,33(5):112-115.
[8]范军辉,郝瑞霞,李萌,等.基于反硝化脱氮的硫铁复合填料除磷机制[J].环境科学,2016,37(11):4275-4281.
[9]王趁义,袁晖,韩志萍,等.原位柱撑改性膨润土在微污染饮用水除磷中的应用研究[J].环境工程学报,2009,3(8):92-94.
[10]翟由涛,杭小帅,干方群.改性高岭土对废水中磷的吸附性能及机理研究[J].土壤,2012,44(1):55-61.
[11]Cui Y,Li J,Du Z.Comparative study of performance and mechanism of lanthanum and cerium modified zeolite on phosphorus removal in wastewater[J].Journal of the Chinese Society of Rare Earths,2016,34(4):460-468.
[12]林丽丹,王哲,顾伟,等.沸石/水合氧化锆吸附水中的磷[J].环境工程学报,2017,11(2):702-708.
[13]Liu S J,Li J,Yang Y K.Influence of environmental factors on the phosphorus adsorption of lanthanum-modified bentonite in eutrophic water and sediment[J].Environmental Science and Pollution Research,2016,23(3):2487-2494.
[14]Zheng Y,Zhang J,Wang A.Fast removal of ammonium nitrogen from aqueous solution using chitosan-g-poly(acrylic acid)/attapulgite composite[J].Chemical Engineering Journal,2009,155(1-2):215-222.
[15]Wang M,Liao L,Zhang X,et al.Adsorption of low-concentration ammonium onto vermiculite from Hebei province,China[J].Clays&Clay Minerals,2011,59(5):459-465.
[16]金诗迪.环境矿物材料对养殖水质的调控[D].杭州:浙江大学,2014.
[17]Sun Z,Qu X,Wang G,et al.Frost RL removal characteristics of ammonium nitrogen from wastewater by modified Ca-bentonites[J].Applied Clay Science,2015,107:46-51.
[18]王雅萍,刘云,董元华,等.改性膨润土对氨氮废水吸附性能的研究[J].应用化工,2011,40(7):1148-1152.
[19]Liu Q Q,Tan X,Zhao L.Experimental study on the ammonium ion-exchange material and its removal of ammonia nitrogen from water[J].Advanced Materials Research,2011,183-185:1558-1562.
[20]李晶,邓昭平,李霞.氧化钙改性高岭土对垃圾渗滤液中氨氮的去除研究[J].化学通报,2017,80(1):99-103.
[21]崔凯.改性沸石处理废水中氨氮的研究[D].沈阳:沈阳工业大学,2016.
[22]肖利萍,耿莘惠,裴格,等.环境矿物改性及对污水中氨氮的吸附试验研究[J].非金属矿,2015,38(4):59-62.
[23]Huang T,Cao X,Zhang Q.Catalytic oxidation of high-concentration ammonia in groundwater by a naturally formed co-oxide filter film[J].Desalination&Water Treatment,2014,52(7-9):1615-1623.
[24]张芙蓉,雷行,常冰,等.铝锰复合氧化物负载沸石对氨氮和磷的同步吸附特性[J].环境工程学报,2017,11(4):2163-2169.
[25]Sun E,Qian Y,Jin H,et al.Structure of straw biochar/amino resin doping nano SiO2and its phosphorus removal characteristic[J].Transactions of the Chinese Society of Agricultural Engineering,2017,33(8):211-218.
[26]赵娟,李远文,杨耐德,等.改性牡蛎壳对废水中磷吸附性能的研究[J].化工新型材料,2014,42(3):154-156.
[27]Chen Y,Luo X,Xiong C,et al.The mechanism of ion-exchange and adsorption coexist on medium-low concentration ammonium-nitrogen removal by ion-exchange resin[J].Environmental Technology,2015,36(18):2349-2356.
[28]熊昌狮,代振鹏,朱清江,等.离子交换树脂对模拟氨氮废水的吸附研究[J].江西理工大学学报,2016,37(1):10-14.
[2]Yin H,Yan X,Gu X.Evaluation of thermally-modified calcium-rich attapulgite as a low-cost substrate for rapid phosphorus removal in constructed wetlands[J].Water Research,2017,115:329-338.
[3]鲍祥,张艳,贺学周,等.改性凹凸棒土负载铝盐吸附剂去除水中总磷研究[J].安徽农学通报,2016,22(19):28-31.
[4]Kim S,Lee T.A study for the removal of phosphorous using coated exfoliated vermiculite[J].Korea Institute of Geoscience and Mineral Resources,2014,15(12):5-13.
[5]郑易安,王爱勤.不同方式处理蛭石对磷吸附性能研究[J].应用化工,2010,39(2):204-208.
[6]陈小燕,刘键熙,苏玉萍,等.两种锁磷剂锁磷效果对比研究[J].福建师范大学学报:自然科学版,2016,32(4):56-60.
[7]韩博涛,李晓玲,李彦鹏,等.污泥发酵液中氨氮和磷的去除方法研究[J].中国给水排水,2017,33(5):112-115.
[8]范军辉,郝瑞霞,李萌,等.基于反硝化脱氮的硫铁复合填料除磷机制[J].环境科学,2016,37(11):4275-4281.
[9]王趁义,袁晖,韩志萍,等.原位柱撑改性膨润土在微污染饮用水除磷中的应用研究[J].环境工程学报,2009,3(8):92-94.
[10]翟由涛,杭小帅,干方群.改性高岭土对废水中磷的吸附性能及机理研究[J].土壤,2012,44(1):55-61.
[11]Cui Y,Li J,Du Z.Comparative study of performance and mechanism of lanthanum and cerium modified zeolite on phosphorus removal in wastewater[J].Journal of the Chinese Society of Rare Earths,2016,34(4):460-468.
[12]林丽丹,王哲,顾伟,等.沸石/水合氧化锆吸附水中的磷[J].环境工程学报,2017,11(2):702-708.
[13]Liu S J,Li J,Yang Y K.Influence of environmental factors on the phosphorus adsorption of lanthanum-modified bentonite in eutrophic water and sediment[J].Environmental Science and Pollution Research,2016,23(3):2487-2494.
[14]Zheng Y,Zhang J,Wang A.Fast removal of ammonium nitrogen from aqueous solution using chitosan-g-poly(acrylic acid)/attapulgite composite[J].Chemical Engineering Journal,2009,155(1-2):215-222.
[15]Wang M,Liao L,Zhang X,et al.Adsorption of low-concentration ammonium onto vermiculite from Hebei province,China[J].Clays&Clay Minerals,2011,59(5):459-465.
[16]金诗迪.环境矿物材料对养殖水质的调控[D].杭州:浙江大学,2014.
[17]Sun Z,Qu X,Wang G,et al.Frost RL removal characteristics of ammonium nitrogen from wastewater by modified Ca-bentonites[J].Applied Clay Science,2015,107:46-51.
[18]王雅萍,刘云,董元华,等.改性膨润土对氨氮废水吸附性能的研究[J].应用化工,2011,40(7):1148-1152.
[19]Liu Q Q,Tan X,Zhao L.Experimental study on the ammonium ion-exchange material and its removal of ammonia nitrogen from water[J].Advanced Materials Research,2011,183-185:1558-1562.
[20]李晶,邓昭平,李霞.氧化钙改性高岭土对垃圾渗滤液中氨氮的去除研究[J].化学通报,2017,80(1):99-103.
[21]崔凯.改性沸石处理废水中氨氮的研究[D].沈阳:沈阳工业大学,2016.
[22]肖利萍,耿莘惠,裴格,等.环境矿物改性及对污水中氨氮的吸附试验研究[J].非金属矿,2015,38(4):59-62.
[23]Huang T,Cao X,Zhang Q.Catalytic oxidation of high-concentration ammonia in groundwater by a naturally formed co-oxide filter film[J].Desalination&Water Treatment,2014,52(7-9):1615-1623.
[24]张芙蓉,雷行,常冰,等.铝锰复合氧化物负载沸石对氨氮和磷的同步吸附特性[J].环境工程学报,2017,11(4):2163-2169.
[25]Sun E,Qian Y,Jin H,et al.Structure of straw biochar/amino resin doping nano SiO2and its phosphorus removal characteristic[J].Transactions of the Chinese Society of Agricultural Engineering,2017,33(8):211-218.
[26]赵娟,李远文,杨耐德,等.改性牡蛎壳对废水中磷吸附性能的研究[J].化工新型材料,2014,42(3):154-156.
[27]Chen Y,Luo X,Xiong C,et al.The mechanism of ion-exchange and adsorption coexist on medium-low concentration ammonium-nitrogen removal by ion-exchange resin[J].Environmental Technology,2015,36(18):2349-2356.
[28]熊昌狮,代振鹏,朱清江,等.离子交换树脂对模拟氨氮废水的吸附研究[J].江西理工大学学报,2016,37(1):10-14.
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