土壤镉和砷污染钝化修复材料及科学计量研究
|
摘要
使用Web of Science(WOS)核心合集数据库统计了5年内(2014—2018年)关于土壤镉(Cd)和砷(As)单一污染的情况,发现土壤Cd和As污染依然受到人们的广泛关注,且我国在该领域发文最多。利用CiteSpace软件分析发现施用钝化修复材料是土壤Cd和As污染治理的热点修复技术之一。基于此,本文综述了常见的钝化修复材料及其钝化机理,并分别对钝化修复材料的室内研究和修复实践进行总结,发现无机类钝化修复材料中石灰类主要通过调节土壤pH值改变重金属有效性;磷酸盐类分别通过共沉淀和点位竞争机制钝化重金属;金属及其氧化物类通过表面络合和还原作用对重金属的钝化效果更好;黏土矿物中海泡石和坡缕石廉价绿色且具有较大的比表面积,对重金属的钝化效果较好。有机类钝化剂中生物炭类为研究热点材料之一,因表面拥有丰富的官能团和较大的比表面积,其对重金属表现出良好的钝化修复效果;有机废弃物含高度腐殖化的有机质和微生物,对重金属钝化效果较好。此外,对国内外典型的Cd和As污染实践修复工程进行介绍,发现金属及其氧化物、堆肥、生物炭以及廉价易获得的石灰和黏土矿物施用较广。最后,讨论了钝化修复材料施用中亟需解决的问题。
This paper used the Web of Science(WOS)core collection database to gather statistics on soil cadmium and arsenic single contamination during 2014 to 2018. It was found that cadmium and arsenic contamination in soil were still widely concerned, and China published the most articles in this field. By using CiteSpace software, we found that application of immobilization materials was one of the most popular technologies for soil cadmium and arsenic remediation. Based on this, this paper summarized the common immobilization materials and mechanism, and the indoor research and remediation practice related to immobilization materials were summarized, respectively. For inorganic immobilization materials, lime changes the effectiveness of heavy metals mainly by regulating soil pH; phosphates immobilize heavy metal through co-precipitation and site competition mechanism; metal oxides showed a good remediation effect on heavy metal by surface complexation and reduction; sepiolite and palygorskite were cheap and green, and had large specific surface areas, and showed significant amendment effect on heavy metal. For organic immobilization materials, biochar shows significant immobilization effect on heavy metal due to its rich functional group and high surface area. Organic waste contained large quantity of humic substances, organic matter,and microorganisms, and showed significant effect on heavy metal immobilization. In addition, the typical field remediation projects of cadmium/arsenic contaminated soil in China and other areas of the world were introduced. Overall, it is found that the metal and its oxides,compost, biochar, lime and clay minerals are applied widely in the world. To provide the guidance for cadmium and arsenic contaminated soil remediation, we finally discussed the urgent problems that need to be solved in the application of immobilization materials.
This paper used the Web of Science(WOS)core collection database to gather statistics on soil cadmium and arsenic single contamination during 2014 to 2018. It was found that cadmium and arsenic contamination in soil were still widely concerned, and China published the most articles in this field. By using CiteSpace software, we found that application of immobilization materials was one of the most popular technologies for soil cadmium and arsenic remediation. Based on this, this paper summarized the common immobilization materials and mechanism, and the indoor research and remediation practice related to immobilization materials were summarized, respectively. For inorganic immobilization materials, lime changes the effectiveness of heavy metals mainly by regulating soil pH; phosphates immobilize heavy metal through co-precipitation and site competition mechanism; metal oxides showed a good remediation effect on heavy metal by surface complexation and reduction; sepiolite and palygorskite were cheap and green, and had large specific surface areas, and showed significant amendment effect on heavy metal. For organic immobilization materials, biochar shows significant immobilization effect on heavy metal due to its rich functional group and high surface area. Organic waste contained large quantity of humic substances, organic matter,and microorganisms, and showed significant effect on heavy metal immobilization. In addition, the typical field remediation projects of cadmium/arsenic contaminated soil in China and other areas of the world were introduced. Overall, it is found that the metal and its oxides,compost, biochar, lime and clay minerals are applied widely in the world. To provide the guidance for cadmium and arsenic contaminated soil remediation, we finally discussed the urgent problems that need to be solved in the application of immobilization materials.
引文
[1]Mirlean N,Roisenberg A.The effect of emissions of fertilizer production on the environment contamination by cadmium and arsenic in southern Brazil[J].Environmental Pollution,2006,143(2):335-340.
[2]Khalid S,Shahid M,Niazi N K,et al.A comparison of technologies for remediation of heavy metal contaminated soils[J].Journal of Geochemical Exploration,2017,182:247-268.
[3]陈能场,郑煜基,何晓峰,等.《全国土壤污染状况调查公报》探析[J].农业环境科学学报,2017,36(9):1689-1692.CHEN Neng-chang,ZHENG Yu-ji,HE Xiao-feng,et al.Analysis of the Report on the national general survey of soil contamination[J].Journal of Agro-Environment Sciences,2017,36(9):1689-1692.
[4]Jarup L.Hazards of heavy metal contamination[J].British Medical Bulletin,2003,68(1):167-182.
[5]Michael K,Ale?V,Vojtěch E.Chemical stabilization of metals and arsenic in contaminated soils using oxides:A review[J].Environmental Pollution,2013,172:9-22.
[6]施培俊,王冠华,陈亚华,等.原位化学钝化技术在重金属污染土壤修复中的研究进展[J].环境科学导刊,2016,35（增刊1):121-124.SHI Pei-jun,WANG Guan-hua,CHEN Ya-hua,et al.A review of in situ chemical immobilization remediation of heavy metals in contaminated soils[J].Environmental Science Survey,2016,35(Suppl1):121-124.
[7]Shao X,Huang B,Zhao Y,et al.Impacts of human activities and sampling strategies on soil heavy metal distribution in a rapidly developing region of China[J].Ecotoxicology Environmental Safety,2014,104(1):1-8.
[8]Alam M G,Tokunaga S,Maekawa T.Extraction of arsenic in a synthetic arsenic-contaminated soil using phosphate[J].Chemosphere,2001,43(8):1035-1041.
[9]Tessier A.Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical Chemistry,1979,51(7):844-851.
[10]武玉,徐刚,吕迎春,等.生物炭对土壤理化性质影响的研究进展[J].地球科学进展,2014,29(1):68-79.WU Yu,XU Gang,LüYing-chun,et al.Effects of biochar amendment on soil physical and chemical properties[J].Advances in Earth Science,2014,29(1):68-79.
[11]Guo G,Zhou Q,Ma L Q.Availability and assessment of fixing additives for the in situ remediation of heavy metal contaminated soils:Areview[J].Environmental Monitoring and Assessment,2006,116(1/2/3):513-528.
[12]陈悦.引文空间分析原理与应用[M].北京：科学出版社,2014.CHEN Yue.Principles and applications of citation space analysis[M].Beijing:Science Press,2014.
[13]陈远其,张煜,陈国梁.石灰对土壤重金属污染修复研究进展[J].生态环境学报,2016,25(8):1419-1424.CHEN Yuan-qi,ZHANG Yu,CHEN Guo-liang.Remediation of heavy metal contaminated soils by lime:A review[J].Ecology and Environmental Sciences,2016,25(8):1419-1424.
[14]熊礼明.石灰对土壤吸附镉的行为及有效性的影响[J].环境科学研究,1994,7(1):35-38.XIONG Li-ming.Cadium adsorption and availability as affected by soil liming[J].Research of Environmental Science,1994,7(1):35-38.
[15]Woldetsadik D,Drechsel P,Keraita B,et al.Effects of biochar and alkaline amendments on cadmium immobilization,selected nutrient and cadmium concentrations of lettuce(Lactuca sativa)in two contrasting soils[J].SpringerPlus,2016,5(1):397.
[16]朱奇宏,黄道友,刘国胜,等.石灰和海泡石对镉污染土壤的修复效应与机理研究[J].水土保持学报,2009,23(1):111-116.ZHU Qi-hong,HUANG Dao-you,LIU Guo-sheng,et al.Effect and mechanism of lime and sepiolite on remediation of cadmium contaminated soils[J].Journal of Soil and Water Conservation,2009,23(1):111-116.
[17]刘维涛,周启星.不同土壤改良剂及其组合对降低大白菜镉和铅含量的作用[J].环境科学学报,2010,30(9):1846-1853.LIU Wei-tao,ZHOU Qi-xing.Effectiveness of different soil ameliorants in reducing concentrations of Cd and Pb in Chinese cabbage[J].Acta Scientiae Circumstantiae,2010,30(9):1846-1853.
[18]Wang X,Liang C H,Yin Y.Distribution and transformation of cadmium formations amended with serpentine and lime in contaminated meadow soil[J].Journal of Soils and Sediments,2015,15(7):1531-1537.
[19]Chen Y,Xie T,Liang Q,et al.Effectiveness of lime and peat applications on cadmium availability in a paddy soil under various moisture regimes[J].Environmental Science and Pollution Research,2016,23(8):7757-7766.
[20]吴宝麟.铅镉砷复合污染土壤钝化修复研究[D].长沙：中南大学,2014.WU Bao-lin.The immobilization remediation study on cadmium,lead and arsenic in contaminated soils[D].Changsha:Central South University,2014.
[21]殷飞,王海娟,李燕燕,等.不同钝化剂对重金属复合污染土壤的修复效应研究[J].农业环境科学学报,2015,34(3):438-448.YIN Fei,WANG Hai-juan,LI Yan-yan,et al.Remediation of multiple heavy metal contaminated soil using different immobilization agents[J].Journal of Agro-Environment Sciences,2015,34(3):438-448.
[22]Hartley W,Lepp N W.Remediation of arsenic contaminated soils by389iron-oxide application,evaluated in terms of plant productivity,arsenic and phytotoxic metal uptake[J].Science of the Total Environment,2008,390(1):35-44.
[23]Lombi E,Zhao F J,Zhang G,et al.In situ fixation of metals in soils using bauxite residue:Chemical assessment[J].Environmental Pollution,2002,118(3):445-452.
[24]王立群,罗磊,马义兵,等.不同钝化剂和培养时间对Cd污染土壤中可交换态Cd的影响[J].农业环境科学学报,2009,28(6):1098-1105.WANG Li-qun,LUO Lei,MA Yi-bing,et al.Effects of different amendments and incubation times on exchangeable Cd in contaminated soils[J].Journal of Agro-Environment Sciences,2009,28(6):1098-1105.
[25]田杰,罗琳,范美蓉,等.赤泥对污染土壤中Cd、Pb和Zn形态及水稻生长的影响[J].土壤通报,2012,43(1):195-199.TIAN Jie,LUO Lin,FAN Mei-rong,et al.Effects of red mud addition fractions on Cd,Pb and Zn and rice growth in contaminated soil[J].Chinese Journal of Soil Science,2012,43(1):195-199.
[26]黄蔼霞,许超,吴启堂,等.赤泥对重金属污染红壤修复效果及其评价[J].水土保持学报,2012,26(1):267-272.HUANG Ai-xia,XU Chao,WU Qi-tang,et al.The remediation effect and evaluation of red mud on heavy metal contaminated red soil[J].Journal of Soil and Water Conservation,2012,26(1):267-272.
[27]黄崇玲.不同铁氧化物对土壤镉有效性及水稻累积镉的影响[D].南宁：广西大学,2013.HUANG Chong-ling.Effects of different iron oxides on the bioavailability of soil cadmium and cadmium accumulation in rice[D].Nanning:Guangxi University,2013.
[28]官迪,纪雄辉.镉污染土壤钝化修复机制及研究进展[J].湖南农业科学,2016(4):119-122.GUAN Di,JI Xiong-hui.Mechanism and research progress of immobilization remediation of cadmium contaminated soil[J].Hunan Agricultural Sciences,2016(4):119-122.
[29]Gonzalez V,Garcia I,Moral F D,et al.Effectiveness of amendments on the spread and phytotoxicity of contaminants in metal-arsenic polluted soil[J].Journal of Hazardous Materials,2012,205/206:72-80.
[30]林志灵,曾希柏,张杨珠,等.人工合成铁、铝矿物和镁铝双金属氧化物对土壤砷的钝化效应[J].环境科学学报,2013,33(7):1953-1959.LIN Zhi-lin,ZENG Xi-bai,ZHANG Yang-zhu,et al.Immobilization effects of synthetic Fe/Al minerals and Mg/Al layered double oxides additions on arsenic in soil[J].Acta Scientiae Circumstantiae,2013,33(7):1953-1959.
[31]Xu Y,Liang X,Xu Y,et al.Remediation of heavy metal-polluted agricultural soils using clay minerals:A review[J].Pedosphere,2017,27(2):193-204.
[32]孙约兵,徐应明,史新,等.海泡石对镉污染红壤的钝化修复效应研究[J].环境科学学报,2012,32(6):1465-1472.SUN Yue-bing,XU Ying-ming,SHI Xin,et al.The effects of sepiolite on immobilization remediation of cadmium contaminated red soil[J].Acta Scientiae Circumstantiae,2012,32(6):1465-1472.20199
[33]王林,徐应明,孙扬,等.海泡石及其复配材料钝化修复镉污染土壤[J].环境工程学报,2010,4(9):2093-2098.WANG Lin,XU Ying-ming,SUN Yang,et al.Immobilization of cadmium contaminated soils using sepiolite and its compound materials[J].Chinese Journal of Environmental Engineering,2010,4(9):2093-2098.
[34]谭科艳.凹凸棒石用于修复铜锌镉重金属污染土壤的研究[J].岩矿测试,2011,30(4):451-456.TAN Ke-yan.Application of attapulgite in the remediation experiments of attapulgite clay to copper,zinc and cadmium contaminated soil[J].Rock and Mineral Analysis,2011,30(4):451-456.
[35]Sun Y,Ye L,Xu Y,et al.In situ stabilization remediation of cadmium(Cd)and lead(Pb)co-contaminated paddy soil using bentonite[J].Applied Clay Science,2015,105/106:200-206.
[36]高瑞丽,唐茂,付庆灵,等.生物炭、蒙脱石及其混合添加对复合污染土壤中重金属形态的影响[J].环境科学,2017,38(1):361-367.GAO Rui-li,TANG Mao,FU Qing-ling,et al.Fractions transformation of heavy metals in compound contaminated soil treated with biochar,montmorillonite and mixed addition[J].Environmental Science,2017,38(1):361-367.
[37]Mia S,Dijkstra F A,Singh B.Chapter one-long-term aging of biochar:A molecular understanding with agricultural and environmental implications[J].Advances in Agronomy,2017,141:1-51.
[38]徐楠楠,林大松,徐应明,等.生物炭在土壤改良和重金属污染治理中的应用[J].农业环境与发展,2013,30(4):29-34.XU Nan-nan,LIN Da-song,XU Ying-ming,et al.Application of biochar on soil improvement and heavy metal pollution abatement[J].Agro-Environment&Development,2013,30(4):29-34.
[39]祝凌.表面改性对生物炭性能的影响及其对2,4-D和镉的吸附特性研究[D].北京：中国农业大学,2018.ZHU Ling.Effect of surface modification on biochar properties and its adsorption properties to 2,4-D and cadmium[D].Beijing:China Agricultural University,2018.
[40]Mendez A,Gomez A,Pazferreiro J,et al.Effects of sewage sludge biochar on plant metal availability after application to a Mediterranean soil[J].Chemosphere,2012,89(11):1354-1359.
[41]郑瑞伦.生物炭对污染和设施退化土壤的修复研究[D].北京：中国科学院生态环境研究中心,2012.ZHENG Rui-lun.Remediation research of biochar on contaminated and degraded facility soils[D].Beijing:Center for Ecological Environment Research,Chinese Academy of Sciences,2012.
[42]杨惟薇,张超兰,曹美珠,等.4种生物炭对镉污染潮土钝化修复效果研究[J].水土保持学报,2015,29(1):239-243.YANG Wei-wei,ZHANG Chao-lan,CAO Mei-zhu,et al.Immobilization and remediation of cadmium contaminated soil with four kinds of biochars[J].Journal of Soil and Water Conservation,2015,29(1):239-243.
[43]杨晓庆,侯仔尧,常梦婷,等.生物炭对镉污染土壤的修复研究[J].江苏农业科学,2015,43(6):335-337.YANG Xiao-qing,HOU Zai-yao,CHANG Meng-ting,et al.Remediation research of biochar on cadmium contaminated soil[J].Jiangsu Agricultural Sciences,2015,43(6):335-337.
[44]王丹丹,林静雯,张岩,等.牛粪生物炭对Cd2+的吸附影响因素及特性[J].环境工程学报,2015,9(7):3197-3203.WANG Dan-dan,LIN Jing-wen,ZHANG Yan,et al.Cd2+adsorption influential factors and performance of dairy dung biochar[J].Chinese Journal of Environmental Engineering,2015,9(7):3197-3203.
[45]Trakal L,Veselska V,Safarik I,et al.Lead and cadmium sorption mechanisms on magnetically modified biochars[J].Bioresource Technology,2016,203:318-324.
[46]汪玉瑛,计海洋,吕豪豪,等.羊栖菜生物炭对镉污染土壤性质及镉形态的影响[J].农业环境科学学报,2018,37(6):1132-1140.WANG YU-ying,JI Hai-yang,LüHao-hao,et al.Effects of biochar derived from Sargassum fusiforme on the properties and cadmium forms of cadmium contaminated soil[J].Journal of Agro-Environment Sciences,2018,37(6):1132-1140.
[47]关连珠,周景景,张昀,等.不同来源生物炭对砷在土壤中吸附与解吸的影响[J].应用生态学报,2013,24(10):2941-2946.GUAN Lian-zhu,ZHOU Jing-jing,ZHOU Yun,et al.Effects of biochar produced from different sources on arsenic adsorption and desorption in soil[J].Chinese Journal of Applied Ecology,2013,24(10):2941-2946.
[48]Zhang M,Gao B.Removal of arsenic,methylene blue,and phosphate by biochar/AlOOH nanocomposite[J].Chemical Engineering Journal,2013,226(24):286-292.
[49]Wang S,Gao B,Li Y.Enhanced arsenic removal by biochar modified with nickel(Ni)and manganese(Mn)oxyhydroxides[J].Journal of Industrial and Engineering Chemistry,2016,37:361-365.
[50]朱司航,赵晶晶,尹英杰,等.针铁矿改性生物炭对砷吸附性能[J].环境科学,2019,40(6):2773-2782.ZHU Si-hang,ZHAO Jing-jing,YIN Ying-jie,et al.Application of goethite modified biochar for arsenic removal from aqueous solution[J].Environmental Science,2019,40(6):2773-2782.
[51]孙翠平,李彦,张英鹏,等.农田重金属钝化剂研究进展[J].山东农业科学,2016,48(8):147-153.SUN Cui-ping,LI Yan,ZHANG Ying-peng,et al.Research progress of farmland heavy metal immobilization[J].Shandong Agricultural Sciences,2016,48(8):147-153.
[52]王立群.镉污染土壤原位修复剂及其机理研究[D].北京：首都师范大学,2009.WANG Li-qun.Mechanism research and in situ remediation agent of cadmium contaminated soil[D].Beijing:Capital Normal University,2009.
[53]李扬,乔玉辉,莫晓辉,等.蚯蚓粪作为土壤重金属污染修复剂的潜力分析[J].农业环境科学学报,2010,29（增刊）：250-255.LI Yang,QIAO Yu-hui,MO Xiao-hui,et al.Analysis for earthworm feces as one of potential remediation agent of heavy metal contaminated in soil[J].Journal of Agro-Environment Sciences,2010,29(Suppl):250-255.
[54]陈春霞,卢瑛,尹伟,等.骨粉和沸石对污染土壤中铅和镉生物有效性的影响[J].广东农业科学,2011,38(14):60-62.CHEN Chun-xia,LU Ying,YIN Wei,et al.Effect of bonemeal and zeolite on bioavailability of lead and cadmium in contaminated soils[J].Guangdong Agricultural Science,2011,38(14):60-62.
[55]黎大荣,吴丽香,宁晓君,等.不同钝化剂对土壤有效态铅和镉含量的影响[J].环境保护科学,2013,39(3):46-49.LI Da-rong,WU Li-xiang,NING Xiao-jun,et al.Effects of different immobilization agents on contens of available lead and cadmium in soil[J].Environmental Protection Science,2013,39(3):46-49.
[56]刘秀珍,马志宏,赵兴杰.不同有机肥对镉污染土壤镉形态及小麦抗性的影响[J].水土保持学报,2014,28(3):243-247.LIU Xiu-zhen,MA Zhi-hong,ZHAO Xing-jie.Effects of different organic manure on cadmium form of soil and resistance of wheat in cadmium contaminated soil[J].Journal of Soil and Water Conservation,2014,28(3):243-247.
[57]Kwiatkowska M J.Functions of organic matter in polluted soils:The effect of organic amendments on phytoavailability of heavy metals[J].Applied Soil Ecology,2018,123:542-545.
[58]梁彦秋,潘伟,刘婷婷,等.有机酸在修复Cd污染土壤中的作用研究[J].环境科学与管理,2006,31(8):76-78.LIANG Yan-qiu,PAN Wei,LIU Ting-ting,et al.Study on effect of organic acid on Cd contaminated soil remediation[J].Environmental Science and Management,2006,31(8):76-78.
[59]陈英旭,林琦,陆芳,等.有机酸对铅、镉植株危害的解毒作用研究[J].环境科学学报,2000,20(4):467-472.CHEN Ying-xu,LIN Qi,LU Fang,et al.Study on detoxification of organic acids to raddish under the stress of lead and cadmium[J].Acta Scientiae Crcumstantiae,2000,20(4):467-472.
[60]杨海琳,廖柏寒.低分子有机酸去除土壤中重金属条件的研究[J].农业环境科学学报,2010,29(12):2330-2337.YANG Hai-lin,LIAO Bo-han.Extraction conditions for heavy metals from contaminated soil by using low molecular organic acids[J].Journal of Agro-Environment Sciences,2010,29(12):2330-2337.
[61]Bolan N,Kunhikrishnan A,Thangarajan R,et al.Remediation of heavy metal(loid)s contaminated soils to mobilize or to immobilize?[J].Journal of Hazardous Materials,2014,266(4):141-166.
[62]Ebrahimian E,Bybordi A.Effect of organic acids on heavy-metal uptake and growth of canola grown in contaminated soil[J].Communications in Soil Science and Plant Analysis,2014,45(13):1715-1725.
[63]Qiao J,Li X,Li F,et al.Humic substances facilitate arsenic reduction and release in flooded paddy soil[J].Environmental Science&Technology,2019,53(9):5034-5042.
[64]Chen S,Sun L,Chao L,et al.Influence of organic acid and amino acid on cadmium and lead desorption from soil[J].Soil Research,2007,45(7):554-558.
[65]Wang S,Mulligan C N.Effects of three low-molecular-weight organic acids(LMWOAs)and pH on the mobilization of arsenic and heavy metals(Cu,Pb,and Zn)from mine tailings[J].Environmental Geochemistry and Health,2013,35(1):111-118.
[66]Boechat C L,Pistoia V C,Ludtke A C,et al.Solubility of heavy metals/metalloid on multi-metal contaminated soil samples from a gold ore processing area:Effects of humic substances[J].Revista Brasileira389De Ciencia Do Solo,2016,40:e0150383.
[67]Alozie N,Heaney N,Lin C,et al.Biochar immobilizes soil-borne arsenic but not cationic metals in the presence of low-molecular-weight organic acids[J].Science of the Total Environment,2018,630:1188-1194.
[68]Taghipour M,Jalali M.Heavy metal release from some industrial wastes:Influence of organic and inorganic acids,clay minerals,and nanoparticles[J].Pedosphere,2018,28(1):70-83.
[69]徐应明,李军幸,孙国红,等.新型功能膜材料对污染土壤铅汞镉钝化作用研究[J].农业环境科学学报,2003,22(1):86-89.XU Ying-ming,LI Jun-xing,SUN Guo-hong,et al.Inactivation of lead,mercury and cadmium in-situ in contaminated soil by a functionalized monolayer materials[J].Journal of Agro-Environment Sciences,2003,22(1):86-89.
[70]林大松,徐应明,孙国红,等.应用介孔分子筛材料（MCM-41）对土壤重金属污染的改良[J].农业环境科学学报,2006,25(2):331-335.LIN Da-song,XU Ying-ming,SUN Guo-hong,et al.Amendment of heavy metal in contaminated soil by(MCM-41)[J].Journal of AgroEnvironment Sciences,2006,25(2):331-335.
[71]李剑睿,徐应明,林大松,等.农田重金属污染原位钝化修复研究进展[J].生态环境学报,2014,23(4):721-728.LI Jian-rui,XU Ying-ming,LIN Da-song,et al.In situ immobilization remediation of heavy metals in contaminated soils:A review[J].Ecology and Environmental Sciences,2014,23(4):721-728.
[72]Markovic M,Kumar A,Andjelkovic I,et al.Ecotoxicology of manufactured graphene oxide nanomaterials and derivation of preliminary guideline values for freshwater environments[J].Environmental Toxicology and Chemistry,2018,37(5):1340-1348.
[73]段立杰,谷蕾.生物炭减轻土壤重金属污染研究进展[J].低碳世界,2017(7):14-15.DUAN Li-jie,GU Lei.Research progress of biochar to reduce heavy metal contaminated soil[J].Low Carbon World,2017(7):14-15.
[74]熊仕娟,黄兴成.沸石在镉污染土壤修复中的研究进展[J].现代园艺,2017(15):8-9.XIAONG Shi-juan,HUANG Xing-cheng.Research progress of zeolite in the remediation of cadmium contaminated soil[J].Xiandai Horticulture,2017(15):8-9.
[75]Harter R D,Naidu R.Role of metal organic complexation in metal sorption by soils[J].Advances in Agronomy,1995,55(8):219-263.
[76]Karlsson T,Elgh-Dalgren K,Bj?rn E,et al.Complexation of cadmium to sulfur and oxygen functional groups in an organic soil[J].Geochimica et Cosmochimica Acta,2007,71(3):604-614.
[77]Wang R Z,Huang D L,Liu Y G,et al.Investigating the adsorption behavior and the relative distribution of Cd2+,sorption mechanisms on biochars by different feedstock[J].Bioresource Technology,2018,26:265-271.
[78]周婷,周根娣,和苗苗.生物炭对土壤重金属吸附机理研究进展[J].杭州师范大学学报（自然科学版）,2018,17(4):404-410.ZHOU Ting,ZHOU Gen-di,HE Miao-miao.Absorption mechanism of biochar on soil heavy metals[J].Journal of Hangzhou Normal Uni-20199versity(Natural Science Edition),2018,17(4):404-410.
[79]Chen S,Xu M,Ma Y,et al.Evaluation of different phosphate amendments on availability of metals in contaminated soil[J].Ecotoxicology and Environmental Safety,2007,67(2):278-285.
[80]Gray C W,Dunham S J,Dennis P G,et al.Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and redmud[J].Environmental Pollution,2006,142:530-539.
[81]王晨,王海燕,赵琨,等.硅对镉、锌、铅复合污染土壤中黑麦草生理生化性质的影响[J].生态环境,2008,17(6):2240-2245.WANG Chen,WANG Hai-yan,ZHAO Kun,et al.Effects of silicon on physiological and biochemical properties of ryegrass under the compound pollution of Cd,Zn and Pb[J].Ecology and Environment,2008,17(6):2240-2245.
[82]Cho H H,Wepasnick K,Smith B A,et al.Sorption of aqueous Zn（Ⅱ）and Cd（Ⅱ）by multiwall carbon nanotubes:The relative roles of oxygen-containing functional groups and graphenic carbon[J].Langmuir,2010,26(2):967-981.
[83]王怡璇,刘杰,唐云舒,等.硅对水稻镉转运的抑制效应研究[J].生态环境学报,2016,25(11):1822-1827.WANG Yi-xuan,LIU Jie,TANG Yun-shu,et al.Inhibition effect of silicon on cadmium accumulation and transport in rice[J].Ecology and Environmental Sciences,2016,25(11):1822-1827.
[84]傅友强,于智卫,蔡昆争,等.水稻根表铁膜形成机制及其生态环境效应[J].植物营养与肥料学报,2010,16(6):1527-1534.FU You-qiang,YU Zhi-wei,CAI Kun-zheng,et al.Mechanisms of iron plaque formation on root surface of rice plants and their ecological and environmental effects:A review[J].Plant Nutrition and Fertilizer Science,2010,16(6):1527-1534.
[85]何春娥,刘学军,张福锁.植物根表铁膜的形成及其营养与生态环境效应[J].应用生态学报,2004,15(6):1069-1073.HE Chun-er,LIU Xue-jun,ZHANG Fu-suo.Formation of iron plaque on root surface and its effect on plant nutritional and ecological environmental[J].Chinese Journal of Applied Ecology,2004,15(6):1069-1073.
[86]Luo L,Zhang S,Shan X,et al.Arsenate sorption on two Chinese red soils evaluated with macroscopic measurements and extended X-ray absorption fine-structure spectroscopy[J].Environmental Toxicology and Chemistry,2010,25(12):3118-3124.
[87]Fu D,He Z,Su S,et al.Fabrication ofα-FeOOH decorated graphene oxide-carbon nanotubes aerogel and its application in adsorption of arsenic species[J].Journal of Colloid and Interface Science,2017,505:105-114.
[88]Ko M S,Kim J Y,Park H S,et al.Field assessment of arsenic immobilization in soil amended with iron rich acid mine drainage sludge[J].Journal of Cleaner Production,2015,108:1073-1080.
[89]Thayer J S,Brinckman F E.The biological methylation of metals and metalloids[J].Advances in Organometallic Chemistry,1982,20(45):313-356.
[90]?erňanskyS,Kolen?ík M,?evc J,et al.Fungal volatilization of trivalent and pentavalent arsenic under laboratory conditions[J].Bioresource Technology,2009,99(2):1037-1040.
[91]Hong C O,Gutierrez J,Yun S,et al.Heavy metal contamination of arable soil and corn plant in the vicinity of a zinc smelting factory and stabilization by liming[J].Archives of Environmental Contamination and Toxicology,2009,56(2):190-200.
[92]Basta N T,Mcgowen S L.Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil[J].Environmental Pollution,2004,127(1):73-82.
[93]Qayyum M F,Rehman M Z,Ali S,et al.Residual effects of monoammonium phosphate,gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field[J].Chemosphere,2017,174:515-523.
[94]Placek A,Grobelak A,Kacprzak M,et al.Improving the phytoremediation of heavy metals contaminated soil by use of sewage sludge[J].International Journal of Phytoremediation,2016,18(6):605-618.
[95]Gruter R,Costerousse B,Mayer J,et al.Long-term organic matter application reduces cadmium but not zinc concentrations in wheat[J].Science of the Total Environment,2019,669:608-620.
[96]Zotiadis V,Argyraki A,Theologou E,et al.Pilot-scale application of attapulgitic clay for stabilization of toxic elements in contaminated soil[J].Journal of Geotechnical and Geoenvironmental Engineering,2012,138(5):633-637.
[97]Hartley W,Dickinson N M,Riby P,et al.Arsenic mobility and speciation in a contaminated urban soil are affected by different methods of green waste compost application[J].Environmental Pollution,2010,158(12):3560-3570.
[98]Xie X,Pi K,Liu Y,et al.In-situ arsenic remediation by aquifer iron coating:Field trial in the Datong basin,China[J].Journal of Hazardous Materials,2015,302:19-26.
[99]Ko M S,Kim J Y,Park H S,et al.Field assessment of arsenic immobilization in soil amended with iron rich acid mine drainage sludge[J].Journal of Cleaner Production,2015,108:1073-1080.
[100]Ko M S,Kim J Y,Bang S,et al.Stabilization of the As-contaminated soil from the metal mining areas in Korea[J].Environmental Geochemistry and Health,2012,34(Suppl):143-149.
[101]黄益宗,郝晓伟,雷鸣,等.重金属污染土壤修复技术及其修复实践[J].农业环境科学学报,2013,32(3):409-417.HUANG Yi-zong,HAO Xiao-wei,LEI Ming,et al.The remediation technology and remediation practice of heavy metals-contaminated soil[J].Journal of Agro-Environment Sciences,2013,32(3):409-417.
[102]韩君,梁学峰,徐应明,等.黏土矿物原位修复镉污染稻田及其对土壤氮磷和酶活性的影响[J].环境科学学报,2014,34(11):2853-2860.HAN Jun,LIANG Xue-feng,XU Ying-ming,et al.In-situ remediation of cadmium contaminated paddy soil by clay minerals and their effects on nitrogen,phosphorus and enzyme activities[J].Acta Scientiae Circumstantiae,2014,34(11):2853-2860.
[103]Yin X,Xu Y,Huang R,et al.Remediation mechanisms for Cd-contaminated soil using natural sepiolite at the field scale[J].Environmental Science Processes&Impacts,2017,19(12):1563-1570.
[104]Liang X,Xu Y,Xu Y,et al.Two-year stability of immobilization effect of sepiolite on Cd contaminants in paddy soil[J].Environmental Science and Pollution Research International,2016,23(13):12922-12931.
[105]Wu Y J,Zhou H,Zou Z J,et al.A three-year in-situ study on the persistence of a combined amendment(limestone sepiolite)for remedying paddy soil polluted with heavy metals[J].Ecotoxicology and Environmental Safety,2016,130:163-170.
[106]Zhu Q H,Huang D Y,Zhu G X,et al.Sepiolite is recommended for the remediation of Cd-contaminated paddy soil[J].Acta Agriculturae Scandinavica,Section B-Plant Soil Science,2010,60(2):110-116.
[107]Sun Y,Xu Y,Xu Y,et al.Reliability and stability of immobilization remediation of Cd polluted soils using sepiolite under pot and field trials[J].Environmental Pollution,2015,208:739-746.
[108]Zhou H,Zhou X,Zeng M,et al.Effects of combined amendments on heavy metal accumulation in rice(Oryza sativa L.)planted on contaminated paddy soil[J].Ecotoxicology and Environmental Safety,2014,101:226-232.
[109]Wang B,Xie Z,Chen J,et al.Effects of field application of phosphate fertilizers on the availability and uptake of lead,zinc and cadmium by cabbage(Brassica chinensis L.)in a mining tailing contaminated soil[J].Journal of Environmental Sciences,2008,20(9):1109-1117.
[110]Li M,Mohamed I,Raleve D,et al.Field evaluation of intensive compost application on Cd fractionation and phytoavailability in a mining-contaminated soil[J].Environmental Geochemistry and Health,3892016,38(5):1193-1201.
[111]Bian R,Chen D,Liu X,et al.Biochar soil amendment as a solution to prevent Cd-tainted rice from China:Results from a cross-site field experiment[J].Ecological Engineering,2013,58:378-383.
[112]Bian R,Joseph S,Cui L,et al.A three-year experiment confirms continuous immobilization of cadmium and lead in contaminated paddy field with biochar amendment[J].Journal of Hazardous Materials,2014,272:121-128.
[113]Zhang Y,Chen T,Liao Y,et al.Modest amendment of sewage sludge biochar to reduce the accumulation of cadmium into rice(Oryza sativa L.):A field study[J].Environmental Pollution,2016,216:819-825.
[114]Yan X L,Lin L Y,Liao X Y,et al.Arsenic stabilization by zero-valent iron,bauxite residue,and zeolite at a contaminated site planting Panax notoginseng[J].Chemosphere,2013,93(4):661-667.
[115]吴晓云,李秋蓉,欧阳通,等.改性废弃稀土抛光粉应急修复砷污染土壤研究[J].环境卫生工程,2010,18(6):42-44.WU Xiao-yun,LI Qiu-rong,OUYANG Tong,et al.Emergency restoration of arsenic contaminated soil using modified waste rare earth polishing powder[J].Environmental Sanitation Engineering,2010,18(6):42-44.
[116]赵宁亚.硫酸根离子和砷污染土壤的稳定化处理技术研究[D].上海：华东师范大学,2013.ZHAO Ning-ya.Study on stabilization technology of soils contaminated by sulfate ions and arsenic[D].Shanghai:East China Normal University,2013.
[2]Khalid S,Shahid M,Niazi N K,et al.A comparison of technologies for remediation of heavy metal contaminated soils[J].Journal of Geochemical Exploration,2017,182:247-268.
[3]陈能场,郑煜基,何晓峰,等.《全国土壤污染状况调查公报》探析[J].农业环境科学学报,2017,36(9):1689-1692.CHEN Neng-chang,ZHENG Yu-ji,HE Xiao-feng,et al.Analysis of the Report on the national general survey of soil contamination[J].Journal of Agro-Environment Sciences,2017,36(9):1689-1692.
[4]Jarup L.Hazards of heavy metal contamination[J].British Medical Bulletin,2003,68(1):167-182.
[5]Michael K,Ale?V,Vojtěch E.Chemical stabilization of metals and arsenic in contaminated soils using oxides:A review[J].Environmental Pollution,2013,172:9-22.
[6]施培俊,王冠华,陈亚华,等.原位化学钝化技术在重金属污染土壤修复中的研究进展[J].环境科学导刊,2016,35（增刊1):121-124.SHI Pei-jun,WANG Guan-hua,CHEN Ya-hua,et al.A review of in situ chemical immobilization remediation of heavy metals in contaminated soils[J].Environmental Science Survey,2016,35(Suppl1):121-124.
[7]Shao X,Huang B,Zhao Y,et al.Impacts of human activities and sampling strategies on soil heavy metal distribution in a rapidly developing region of China[J].Ecotoxicology Environmental Safety,2014,104(1):1-8.
[8]Alam M G,Tokunaga S,Maekawa T.Extraction of arsenic in a synthetic arsenic-contaminated soil using phosphate[J].Chemosphere,2001,43(8):1035-1041.
[9]Tessier A.Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical Chemistry,1979,51(7):844-851.
[10]武玉,徐刚,吕迎春,等.生物炭对土壤理化性质影响的研究进展[J].地球科学进展,2014,29(1):68-79.WU Yu,XU Gang,LüYing-chun,et al.Effects of biochar amendment on soil physical and chemical properties[J].Advances in Earth Science,2014,29(1):68-79.
[11]Guo G,Zhou Q,Ma L Q.Availability and assessment of fixing additives for the in situ remediation of heavy metal contaminated soils:Areview[J].Environmental Monitoring and Assessment,2006,116(1/2/3):513-528.
[12]陈悦.引文空间分析原理与应用[M].北京：科学出版社,2014.CHEN Yue.Principles and applications of citation space analysis[M].Beijing:Science Press,2014.
[13]陈远其,张煜,陈国梁.石灰对土壤重金属污染修复研究进展[J].生态环境学报,2016,25(8):1419-1424.CHEN Yuan-qi,ZHANG Yu,CHEN Guo-liang.Remediation of heavy metal contaminated soils by lime:A review[J].Ecology and Environmental Sciences,2016,25(8):1419-1424.
[14]熊礼明.石灰对土壤吸附镉的行为及有效性的影响[J].环境科学研究,1994,7(1):35-38.XIONG Li-ming.Cadium adsorption and availability as affected by soil liming[J].Research of Environmental Science,1994,7(1):35-38.
[15]Woldetsadik D,Drechsel P,Keraita B,et al.Effects of biochar and alkaline amendments on cadmium immobilization,selected nutrient and cadmium concentrations of lettuce(Lactuca sativa)in two contrasting soils[J].SpringerPlus,2016,5(1):397.
[16]朱奇宏,黄道友,刘国胜,等.石灰和海泡石对镉污染土壤的修复效应与机理研究[J].水土保持学报,2009,23(1):111-116.ZHU Qi-hong,HUANG Dao-you,LIU Guo-sheng,et al.Effect and mechanism of lime and sepiolite on remediation of cadmium contaminated soils[J].Journal of Soil and Water Conservation,2009,23(1):111-116.
[17]刘维涛,周启星.不同土壤改良剂及其组合对降低大白菜镉和铅含量的作用[J].环境科学学报,2010,30(9):1846-1853.LIU Wei-tao,ZHOU Qi-xing.Effectiveness of different soil ameliorants in reducing concentrations of Cd and Pb in Chinese cabbage[J].Acta Scientiae Circumstantiae,2010,30(9):1846-1853.
[18]Wang X,Liang C H,Yin Y.Distribution and transformation of cadmium formations amended with serpentine and lime in contaminated meadow soil[J].Journal of Soils and Sediments,2015,15(7):1531-1537.
[19]Chen Y,Xie T,Liang Q,et al.Effectiveness of lime and peat applications on cadmium availability in a paddy soil under various moisture regimes[J].Environmental Science and Pollution Research,2016,23(8):7757-7766.
[20]吴宝麟.铅镉砷复合污染土壤钝化修复研究[D].长沙：中南大学,2014.WU Bao-lin.The immobilization remediation study on cadmium,lead and arsenic in contaminated soils[D].Changsha:Central South University,2014.
[21]殷飞,王海娟,李燕燕,等.不同钝化剂对重金属复合污染土壤的修复效应研究[J].农业环境科学学报,2015,34(3):438-448.YIN Fei,WANG Hai-juan,LI Yan-yan,et al.Remediation of multiple heavy metal contaminated soil using different immobilization agents[J].Journal of Agro-Environment Sciences,2015,34(3):438-448.
[22]Hartley W,Lepp N W.Remediation of arsenic contaminated soils by389iron-oxide application,evaluated in terms of plant productivity,arsenic and phytotoxic metal uptake[J].Science of the Total Environment,2008,390(1):35-44.
[23]Lombi E,Zhao F J,Zhang G,et al.In situ fixation of metals in soils using bauxite residue:Chemical assessment[J].Environmental Pollution,2002,118(3):445-452.
[24]王立群,罗磊,马义兵,等.不同钝化剂和培养时间对Cd污染土壤中可交换态Cd的影响[J].农业环境科学学报,2009,28(6):1098-1105.WANG Li-qun,LUO Lei,MA Yi-bing,et al.Effects of different amendments and incubation times on exchangeable Cd in contaminated soils[J].Journal of Agro-Environment Sciences,2009,28(6):1098-1105.
[25]田杰,罗琳,范美蓉,等.赤泥对污染土壤中Cd、Pb和Zn形态及水稻生长的影响[J].土壤通报,2012,43(1):195-199.TIAN Jie,LUO Lin,FAN Mei-rong,et al.Effects of red mud addition fractions on Cd,Pb and Zn and rice growth in contaminated soil[J].Chinese Journal of Soil Science,2012,43(1):195-199.
[26]黄蔼霞,许超,吴启堂,等.赤泥对重金属污染红壤修复效果及其评价[J].水土保持学报,2012,26(1):267-272.HUANG Ai-xia,XU Chao,WU Qi-tang,et al.The remediation effect and evaluation of red mud on heavy metal contaminated red soil[J].Journal of Soil and Water Conservation,2012,26(1):267-272.
[27]黄崇玲.不同铁氧化物对土壤镉有效性及水稻累积镉的影响[D].南宁：广西大学,2013.HUANG Chong-ling.Effects of different iron oxides on the bioavailability of soil cadmium and cadmium accumulation in rice[D].Nanning:Guangxi University,2013.
[28]官迪,纪雄辉.镉污染土壤钝化修复机制及研究进展[J].湖南农业科学,2016(4):119-122.GUAN Di,JI Xiong-hui.Mechanism and research progress of immobilization remediation of cadmium contaminated soil[J].Hunan Agricultural Sciences,2016(4):119-122.
[29]Gonzalez V,Garcia I,Moral F D,et al.Effectiveness of amendments on the spread and phytotoxicity of contaminants in metal-arsenic polluted soil[J].Journal of Hazardous Materials,2012,205/206:72-80.
[30]林志灵,曾希柏,张杨珠,等.人工合成铁、铝矿物和镁铝双金属氧化物对土壤砷的钝化效应[J].环境科学学报,2013,33(7):1953-1959.LIN Zhi-lin,ZENG Xi-bai,ZHANG Yang-zhu,et al.Immobilization effects of synthetic Fe/Al minerals and Mg/Al layered double oxides additions on arsenic in soil[J].Acta Scientiae Circumstantiae,2013,33(7):1953-1959.
[31]Xu Y,Liang X,Xu Y,et al.Remediation of heavy metal-polluted agricultural soils using clay minerals:A review[J].Pedosphere,2017,27(2):193-204.
[32]孙约兵,徐应明,史新,等.海泡石对镉污染红壤的钝化修复效应研究[J].环境科学学报,2012,32(6):1465-1472.SUN Yue-bing,XU Ying-ming,SHI Xin,et al.The effects of sepiolite on immobilization remediation of cadmium contaminated red soil[J].Acta Scientiae Circumstantiae,2012,32(6):1465-1472.20199
[33]王林,徐应明,孙扬,等.海泡石及其复配材料钝化修复镉污染土壤[J].环境工程学报,2010,4(9):2093-2098.WANG Lin,XU Ying-ming,SUN Yang,et al.Immobilization of cadmium contaminated soils using sepiolite and its compound materials[J].Chinese Journal of Environmental Engineering,2010,4(9):2093-2098.
[34]谭科艳.凹凸棒石用于修复铜锌镉重金属污染土壤的研究[J].岩矿测试,2011,30(4):451-456.TAN Ke-yan.Application of attapulgite in the remediation experiments of attapulgite clay to copper,zinc and cadmium contaminated soil[J].Rock and Mineral Analysis,2011,30(4):451-456.
[35]Sun Y,Ye L,Xu Y,et al.In situ stabilization remediation of cadmium(Cd)and lead(Pb)co-contaminated paddy soil using bentonite[J].Applied Clay Science,2015,105/106:200-206.
[36]高瑞丽,唐茂,付庆灵,等.生物炭、蒙脱石及其混合添加对复合污染土壤中重金属形态的影响[J].环境科学,2017,38(1):361-367.GAO Rui-li,TANG Mao,FU Qing-ling,et al.Fractions transformation of heavy metals in compound contaminated soil treated with biochar,montmorillonite and mixed addition[J].Environmental Science,2017,38(1):361-367.
[37]Mia S,Dijkstra F A,Singh B.Chapter one-long-term aging of biochar:A molecular understanding with agricultural and environmental implications[J].Advances in Agronomy,2017,141:1-51.
[38]徐楠楠,林大松,徐应明,等.生物炭在土壤改良和重金属污染治理中的应用[J].农业环境与发展,2013,30(4):29-34.XU Nan-nan,LIN Da-song,XU Ying-ming,et al.Application of biochar on soil improvement and heavy metal pollution abatement[J].Agro-Environment&Development,2013,30(4):29-34.
[39]祝凌.表面改性对生物炭性能的影响及其对2,4-D和镉的吸附特性研究[D].北京：中国农业大学,2018.ZHU Ling.Effect of surface modification on biochar properties and its adsorption properties to 2,4-D and cadmium[D].Beijing:China Agricultural University,2018.
[40]Mendez A,Gomez A,Pazferreiro J,et al.Effects of sewage sludge biochar on plant metal availability after application to a Mediterranean soil[J].Chemosphere,2012,89(11):1354-1359.
[41]郑瑞伦.生物炭对污染和设施退化土壤的修复研究[D].北京：中国科学院生态环境研究中心,2012.ZHENG Rui-lun.Remediation research of biochar on contaminated and degraded facility soils[D].Beijing:Center for Ecological Environment Research,Chinese Academy of Sciences,2012.
[42]杨惟薇,张超兰,曹美珠,等.4种生物炭对镉污染潮土钝化修复效果研究[J].水土保持学报,2015,29(1):239-243.YANG Wei-wei,ZHANG Chao-lan,CAO Mei-zhu,et al.Immobilization and remediation of cadmium contaminated soil with four kinds of biochars[J].Journal of Soil and Water Conservation,2015,29(1):239-243.
[43]杨晓庆,侯仔尧,常梦婷,等.生物炭对镉污染土壤的修复研究[J].江苏农业科学,2015,43(6):335-337.YANG Xiao-qing,HOU Zai-yao,CHANG Meng-ting,et al.Remediation research of biochar on cadmium contaminated soil[J].Jiangsu Agricultural Sciences,2015,43(6):335-337.
[44]王丹丹,林静雯,张岩,等.牛粪生物炭对Cd2+的吸附影响因素及特性[J].环境工程学报,2015,9(7):3197-3203.WANG Dan-dan,LIN Jing-wen,ZHANG Yan,et al.Cd2+adsorption influential factors and performance of dairy dung biochar[J].Chinese Journal of Environmental Engineering,2015,9(7):3197-3203.
[45]Trakal L,Veselska V,Safarik I,et al.Lead and cadmium sorption mechanisms on magnetically modified biochars[J].Bioresource Technology,2016,203:318-324.
[46]汪玉瑛,计海洋,吕豪豪,等.羊栖菜生物炭对镉污染土壤性质及镉形态的影响[J].农业环境科学学报,2018,37(6):1132-1140.WANG YU-ying,JI Hai-yang,LüHao-hao,et al.Effects of biochar derived from Sargassum fusiforme on the properties and cadmium forms of cadmium contaminated soil[J].Journal of Agro-Environment Sciences,2018,37(6):1132-1140.
[47]关连珠,周景景,张昀,等.不同来源生物炭对砷在土壤中吸附与解吸的影响[J].应用生态学报,2013,24(10):2941-2946.GUAN Lian-zhu,ZHOU Jing-jing,ZHOU Yun,et al.Effects of biochar produced from different sources on arsenic adsorption and desorption in soil[J].Chinese Journal of Applied Ecology,2013,24(10):2941-2946.
[48]Zhang M,Gao B.Removal of arsenic,methylene blue,and phosphate by biochar/AlOOH nanocomposite[J].Chemical Engineering Journal,2013,226(24):286-292.
[49]Wang S,Gao B,Li Y.Enhanced arsenic removal by biochar modified with nickel(Ni)and manganese(Mn)oxyhydroxides[J].Journal of Industrial and Engineering Chemistry,2016,37:361-365.
[50]朱司航,赵晶晶,尹英杰,等.针铁矿改性生物炭对砷吸附性能[J].环境科学,2019,40(6):2773-2782.ZHU Si-hang,ZHAO Jing-jing,YIN Ying-jie,et al.Application of goethite modified biochar for arsenic removal from aqueous solution[J].Environmental Science,2019,40(6):2773-2782.
[51]孙翠平,李彦,张英鹏,等.农田重金属钝化剂研究进展[J].山东农业科学,2016,48(8):147-153.SUN Cui-ping,LI Yan,ZHANG Ying-peng,et al.Research progress of farmland heavy metal immobilization[J].Shandong Agricultural Sciences,2016,48(8):147-153.
[52]王立群.镉污染土壤原位修复剂及其机理研究[D].北京：首都师范大学,2009.WANG Li-qun.Mechanism research and in situ remediation agent of cadmium contaminated soil[D].Beijing:Capital Normal University,2009.
[53]李扬,乔玉辉,莫晓辉,等.蚯蚓粪作为土壤重金属污染修复剂的潜力分析[J].农业环境科学学报,2010,29（增刊）：250-255.LI Yang,QIAO Yu-hui,MO Xiao-hui,et al.Analysis for earthworm feces as one of potential remediation agent of heavy metal contaminated in soil[J].Journal of Agro-Environment Sciences,2010,29(Suppl):250-255.
[54]陈春霞,卢瑛,尹伟,等.骨粉和沸石对污染土壤中铅和镉生物有效性的影响[J].广东农业科学,2011,38(14):60-62.CHEN Chun-xia,LU Ying,YIN Wei,et al.Effect of bonemeal and zeolite on bioavailability of lead and cadmium in contaminated soils[J].Guangdong Agricultural Science,2011,38(14):60-62.
[55]黎大荣,吴丽香,宁晓君,等.不同钝化剂对土壤有效态铅和镉含量的影响[J].环境保护科学,2013,39(3):46-49.LI Da-rong,WU Li-xiang,NING Xiao-jun,et al.Effects of different immobilization agents on contens of available lead and cadmium in soil[J].Environmental Protection Science,2013,39(3):46-49.
[56]刘秀珍,马志宏,赵兴杰.不同有机肥对镉污染土壤镉形态及小麦抗性的影响[J].水土保持学报,2014,28(3):243-247.LIU Xiu-zhen,MA Zhi-hong,ZHAO Xing-jie.Effects of different organic manure on cadmium form of soil and resistance of wheat in cadmium contaminated soil[J].Journal of Soil and Water Conservation,2014,28(3):243-247.
[57]Kwiatkowska M J.Functions of organic matter in polluted soils:The effect of organic amendments on phytoavailability of heavy metals[J].Applied Soil Ecology,2018,123:542-545.
[58]梁彦秋,潘伟,刘婷婷,等.有机酸在修复Cd污染土壤中的作用研究[J].环境科学与管理,2006,31(8):76-78.LIANG Yan-qiu,PAN Wei,LIU Ting-ting,et al.Study on effect of organic acid on Cd contaminated soil remediation[J].Environmental Science and Management,2006,31(8):76-78.
[59]陈英旭,林琦,陆芳,等.有机酸对铅、镉植株危害的解毒作用研究[J].环境科学学报,2000,20(4):467-472.CHEN Ying-xu,LIN Qi,LU Fang,et al.Study on detoxification of organic acids to raddish under the stress of lead and cadmium[J].Acta Scientiae Crcumstantiae,2000,20(4):467-472.
[60]杨海琳,廖柏寒.低分子有机酸去除土壤中重金属条件的研究[J].农业环境科学学报,2010,29(12):2330-2337.YANG Hai-lin,LIAO Bo-han.Extraction conditions for heavy metals from contaminated soil by using low molecular organic acids[J].Journal of Agro-Environment Sciences,2010,29(12):2330-2337.
[61]Bolan N,Kunhikrishnan A,Thangarajan R,et al.Remediation of heavy metal(loid)s contaminated soils to mobilize or to immobilize?[J].Journal of Hazardous Materials,2014,266(4):141-166.
[62]Ebrahimian E,Bybordi A.Effect of organic acids on heavy-metal uptake and growth of canola grown in contaminated soil[J].Communications in Soil Science and Plant Analysis,2014,45(13):1715-1725.
[63]Qiao J,Li X,Li F,et al.Humic substances facilitate arsenic reduction and release in flooded paddy soil[J].Environmental Science&Technology,2019,53(9):5034-5042.
[64]Chen S,Sun L,Chao L,et al.Influence of organic acid and amino acid on cadmium and lead desorption from soil[J].Soil Research,2007,45(7):554-558.
[65]Wang S,Mulligan C N.Effects of three low-molecular-weight organic acids(LMWOAs)and pH on the mobilization of arsenic and heavy metals(Cu,Pb,and Zn)from mine tailings[J].Environmental Geochemistry and Health,2013,35(1):111-118.
[66]Boechat C L,Pistoia V C,Ludtke A C,et al.Solubility of heavy metals/metalloid on multi-metal contaminated soil samples from a gold ore processing area:Effects of humic substances[J].Revista Brasileira389De Ciencia Do Solo,2016,40:e0150383.
[67]Alozie N,Heaney N,Lin C,et al.Biochar immobilizes soil-borne arsenic but not cationic metals in the presence of low-molecular-weight organic acids[J].Science of the Total Environment,2018,630:1188-1194.
[68]Taghipour M,Jalali M.Heavy metal release from some industrial wastes:Influence of organic and inorganic acids,clay minerals,and nanoparticles[J].Pedosphere,2018,28(1):70-83.
[69]徐应明,李军幸,孙国红,等.新型功能膜材料对污染土壤铅汞镉钝化作用研究[J].农业环境科学学报,2003,22(1):86-89.XU Ying-ming,LI Jun-xing,SUN Guo-hong,et al.Inactivation of lead,mercury and cadmium in-situ in contaminated soil by a functionalized monolayer materials[J].Journal of Agro-Environment Sciences,2003,22(1):86-89.
[70]林大松,徐应明,孙国红,等.应用介孔分子筛材料（MCM-41）对土壤重金属污染的改良[J].农业环境科学学报,2006,25(2):331-335.LIN Da-song,XU Ying-ming,SUN Guo-hong,et al.Amendment of heavy metal in contaminated soil by(MCM-41)[J].Journal of AgroEnvironment Sciences,2006,25(2):331-335.
[71]李剑睿,徐应明,林大松,等.农田重金属污染原位钝化修复研究进展[J].生态环境学报,2014,23(4):721-728.LI Jian-rui,XU Ying-ming,LIN Da-song,et al.In situ immobilization remediation of heavy metals in contaminated soils:A review[J].Ecology and Environmental Sciences,2014,23(4):721-728.
[72]Markovic M,Kumar A,Andjelkovic I,et al.Ecotoxicology of manufactured graphene oxide nanomaterials and derivation of preliminary guideline values for freshwater environments[J].Environmental Toxicology and Chemistry,2018,37(5):1340-1348.
[73]段立杰,谷蕾.生物炭减轻土壤重金属污染研究进展[J].低碳世界,2017(7):14-15.DUAN Li-jie,GU Lei.Research progress of biochar to reduce heavy metal contaminated soil[J].Low Carbon World,2017(7):14-15.
[74]熊仕娟,黄兴成.沸石在镉污染土壤修复中的研究进展[J].现代园艺,2017(15):8-9.XIAONG Shi-juan,HUANG Xing-cheng.Research progress of zeolite in the remediation of cadmium contaminated soil[J].Xiandai Horticulture,2017(15):8-9.
[75]Harter R D,Naidu R.Role of metal organic complexation in metal sorption by soils[J].Advances in Agronomy,1995,55(8):219-263.
[76]Karlsson T,Elgh-Dalgren K,Bj?rn E,et al.Complexation of cadmium to sulfur and oxygen functional groups in an organic soil[J].Geochimica et Cosmochimica Acta,2007,71(3):604-614.
[77]Wang R Z,Huang D L,Liu Y G,et al.Investigating the adsorption behavior and the relative distribution of Cd2+,sorption mechanisms on biochars by different feedstock[J].Bioresource Technology,2018,26:265-271.
[78]周婷,周根娣,和苗苗.生物炭对土壤重金属吸附机理研究进展[J].杭州师范大学学报（自然科学版）,2018,17(4):404-410.ZHOU Ting,ZHOU Gen-di,HE Miao-miao.Absorption mechanism of biochar on soil heavy metals[J].Journal of Hangzhou Normal Uni-20199versity(Natural Science Edition),2018,17(4):404-410.
[79]Chen S,Xu M,Ma Y,et al.Evaluation of different phosphate amendments on availability of metals in contaminated soil[J].Ecotoxicology and Environmental Safety,2007,67(2):278-285.
[80]Gray C W,Dunham S J,Dennis P G,et al.Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and redmud[J].Environmental Pollution,2006,142:530-539.
[81]王晨,王海燕,赵琨,等.硅对镉、锌、铅复合污染土壤中黑麦草生理生化性质的影响[J].生态环境,2008,17(6):2240-2245.WANG Chen,WANG Hai-yan,ZHAO Kun,et al.Effects of silicon on physiological and biochemical properties of ryegrass under the compound pollution of Cd,Zn and Pb[J].Ecology and Environment,2008,17(6):2240-2245.
[82]Cho H H,Wepasnick K,Smith B A,et al.Sorption of aqueous Zn（Ⅱ）and Cd（Ⅱ）by multiwall carbon nanotubes:The relative roles of oxygen-containing functional groups and graphenic carbon[J].Langmuir,2010,26(2):967-981.
[83]王怡璇,刘杰,唐云舒,等.硅对水稻镉转运的抑制效应研究[J].生态环境学报,2016,25(11):1822-1827.WANG Yi-xuan,LIU Jie,TANG Yun-shu,et al.Inhibition effect of silicon on cadmium accumulation and transport in rice[J].Ecology and Environmental Sciences,2016,25(11):1822-1827.
[84]傅友强,于智卫,蔡昆争,等.水稻根表铁膜形成机制及其生态环境效应[J].植物营养与肥料学报,2010,16(6):1527-1534.FU You-qiang,YU Zhi-wei,CAI Kun-zheng,et al.Mechanisms of iron plaque formation on root surface of rice plants and their ecological and environmental effects:A review[J].Plant Nutrition and Fertilizer Science,2010,16(6):1527-1534.
[85]何春娥,刘学军,张福锁.植物根表铁膜的形成及其营养与生态环境效应[J].应用生态学报,2004,15(6):1069-1073.HE Chun-er,LIU Xue-jun,ZHANG Fu-suo.Formation of iron plaque on root surface and its effect on plant nutritional and ecological environmental[J].Chinese Journal of Applied Ecology,2004,15(6):1069-1073.
[86]Luo L,Zhang S,Shan X,et al.Arsenate sorption on two Chinese red soils evaluated with macroscopic measurements and extended X-ray absorption fine-structure spectroscopy[J].Environmental Toxicology and Chemistry,2010,25(12):3118-3124.
[87]Fu D,He Z,Su S,et al.Fabrication ofα-FeOOH decorated graphene oxide-carbon nanotubes aerogel and its application in adsorption of arsenic species[J].Journal of Colloid and Interface Science,2017,505:105-114.
[88]Ko M S,Kim J Y,Park H S,et al.Field assessment of arsenic immobilization in soil amended with iron rich acid mine drainage sludge[J].Journal of Cleaner Production,2015,108:1073-1080.
[89]Thayer J S,Brinckman F E.The biological methylation of metals and metalloids[J].Advances in Organometallic Chemistry,1982,20(45):313-356.
[90]?erňanskyS,Kolen?ík M,?evc J,et al.Fungal volatilization of trivalent and pentavalent arsenic under laboratory conditions[J].Bioresource Technology,2009,99(2):1037-1040.
[91]Hong C O,Gutierrez J,Yun S,et al.Heavy metal contamination of arable soil and corn plant in the vicinity of a zinc smelting factory and stabilization by liming[J].Archives of Environmental Contamination and Toxicology,2009,56(2):190-200.
[92]Basta N T,Mcgowen S L.Evaluation of chemical immobilization treatments for reducing heavy metal transport in a smelter-contaminated soil[J].Environmental Pollution,2004,127(1):73-82.
[93]Qayyum M F,Rehman M Z,Ali S,et al.Residual effects of monoammonium phosphate,gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field[J].Chemosphere,2017,174:515-523.
[94]Placek A,Grobelak A,Kacprzak M,et al.Improving the phytoremediation of heavy metals contaminated soil by use of sewage sludge[J].International Journal of Phytoremediation,2016,18(6):605-618.
[95]Gruter R,Costerousse B,Mayer J,et al.Long-term organic matter application reduces cadmium but not zinc concentrations in wheat[J].Science of the Total Environment,2019,669:608-620.
[96]Zotiadis V,Argyraki A,Theologou E,et al.Pilot-scale application of attapulgitic clay for stabilization of toxic elements in contaminated soil[J].Journal of Geotechnical and Geoenvironmental Engineering,2012,138(5):633-637.
[97]Hartley W,Dickinson N M,Riby P,et al.Arsenic mobility and speciation in a contaminated urban soil are affected by different methods of green waste compost application[J].Environmental Pollution,2010,158(12):3560-3570.
[98]Xie X,Pi K,Liu Y,et al.In-situ arsenic remediation by aquifer iron coating:Field trial in the Datong basin,China[J].Journal of Hazardous Materials,2015,302:19-26.
[99]Ko M S,Kim J Y,Park H S,et al.Field assessment of arsenic immobilization in soil amended with iron rich acid mine drainage sludge[J].Journal of Cleaner Production,2015,108:1073-1080.
[100]Ko M S,Kim J Y,Bang S,et al.Stabilization of the As-contaminated soil from the metal mining areas in Korea[J].Environmental Geochemistry and Health,2012,34(Suppl):143-149.
[101]黄益宗,郝晓伟,雷鸣,等.重金属污染土壤修复技术及其修复实践[J].农业环境科学学报,2013,32(3):409-417.HUANG Yi-zong,HAO Xiao-wei,LEI Ming,et al.The remediation technology and remediation practice of heavy metals-contaminated soil[J].Journal of Agro-Environment Sciences,2013,32(3):409-417.
[102]韩君,梁学峰,徐应明,等.黏土矿物原位修复镉污染稻田及其对土壤氮磷和酶活性的影响[J].环境科学学报,2014,34(11):2853-2860.HAN Jun,LIANG Xue-feng,XU Ying-ming,et al.In-situ remediation of cadmium contaminated paddy soil by clay minerals and their effects on nitrogen,phosphorus and enzyme activities[J].Acta Scientiae Circumstantiae,2014,34(11):2853-2860.
[103]Yin X,Xu Y,Huang R,et al.Remediation mechanisms for Cd-contaminated soil using natural sepiolite at the field scale[J].Environmental Science Processes&Impacts,2017,19(12):1563-1570.
[104]Liang X,Xu Y,Xu Y,et al.Two-year stability of immobilization effect of sepiolite on Cd contaminants in paddy soil[J].Environmental Science and Pollution Research International,2016,23(13):12922-12931.
[105]Wu Y J,Zhou H,Zou Z J,et al.A three-year in-situ study on the persistence of a combined amendment(limestone sepiolite)for remedying paddy soil polluted with heavy metals[J].Ecotoxicology and Environmental Safety,2016,130:163-170.
[106]Zhu Q H,Huang D Y,Zhu G X,et al.Sepiolite is recommended for the remediation of Cd-contaminated paddy soil[J].Acta Agriculturae Scandinavica,Section B-Plant Soil Science,2010,60(2):110-116.
[107]Sun Y,Xu Y,Xu Y,et al.Reliability and stability of immobilization remediation of Cd polluted soils using sepiolite under pot and field trials[J].Environmental Pollution,2015,208:739-746.
[108]Zhou H,Zhou X,Zeng M,et al.Effects of combined amendments on heavy metal accumulation in rice(Oryza sativa L.)planted on contaminated paddy soil[J].Ecotoxicology and Environmental Safety,2014,101:226-232.
[109]Wang B,Xie Z,Chen J,et al.Effects of field application of phosphate fertilizers on the availability and uptake of lead,zinc and cadmium by cabbage(Brassica chinensis L.)in a mining tailing contaminated soil[J].Journal of Environmental Sciences,2008,20(9):1109-1117.
[110]Li M,Mohamed I,Raleve D,et al.Field evaluation of intensive compost application on Cd fractionation and phytoavailability in a mining-contaminated soil[J].Environmental Geochemistry and Health,3892016,38(5):1193-1201.
[111]Bian R,Chen D,Liu X,et al.Biochar soil amendment as a solution to prevent Cd-tainted rice from China:Results from a cross-site field experiment[J].Ecological Engineering,2013,58:378-383.
[112]Bian R,Joseph S,Cui L,et al.A three-year experiment confirms continuous immobilization of cadmium and lead in contaminated paddy field with biochar amendment[J].Journal of Hazardous Materials,2014,272:121-128.
[113]Zhang Y,Chen T,Liao Y,et al.Modest amendment of sewage sludge biochar to reduce the accumulation of cadmium into rice(Oryza sativa L.):A field study[J].Environmental Pollution,2016,216:819-825.
[114]Yan X L,Lin L Y,Liao X Y,et al.Arsenic stabilization by zero-valent iron,bauxite residue,and zeolite at a contaminated site planting Panax notoginseng[J].Chemosphere,2013,93(4):661-667.
[115]吴晓云,李秋蓉,欧阳通,等.改性废弃稀土抛光粉应急修复砷污染土壤研究[J].环境卫生工程,2010,18(6):42-44.WU Xiao-yun,LI Qiu-rong,OUYANG Tong,et al.Emergency restoration of arsenic contaminated soil using modified waste rare earth polishing powder[J].Environmental Sanitation Engineering,2010,18(6):42-44.
[116]赵宁亚.硫酸根离子和砷污染土壤的稳定化处理技术研究[D].上海：华东师范大学,2013.ZHAO Ning-ya.Study on stabilization technology of soils contaminated by sulfate ions and arsenic[D].Shanghai:East China Normal University,2013.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |