新疆哈图金矿成矿流体组分与同位素地球化学特征分析
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摘要
哈图金矿床位于新疆西准噶尔地区南部,是哈图金矿带中重要的金矿床之一。通过对金矿石英脉样品中的石英开展流体包裹体成分分析,结合矿石样品中的毒砂和黄铁矿的硫同位素以及方解石中的碳、氧同位素特征,分析可知:包裹体气相成分以H_2O为主,CO_2和N_2含量次之。液相成分中阳离子以Na~+、Ca~(2+)为主,阴离子以Cl~-和SO_4~(2-)为主,成矿流体属SO_4~(2-)-Cl~--Na~+-Ca~(2+)型。从早阶段至晚阶段,H_2O含量增加,CO_2及Na~+、Cl~-等离子含量降低。硫化物中硫同位素组成为-2.9‰～+0.8‰,集中在0±3‰范围,成矿物质的硫来自岩浆流体或赋矿围岩。方解石中的碳、氧同位素组成中δ13 CPDB值为-11.4‰～-9.2‰,δ18 OSMOW值为+8.5‰～+17.4‰,认为成矿流体属大气降水和岩浆水混合流体。哈图金矿与穆龙套型金矿有相似的含矿地层和成矿时间,因此可以考虑哈图地区寻找穆龙套型金矿的可能性。
The Hatu gold mine,located in the south of the western Junggar region of Xinjiang,is one of the important gold mines in the Hatu gold belt.In this paper,fluid inclusion composition analysis of quartz in quartz vein samples of gold mine is carried out,and the characteristics of sulfur isotopes of the arsenopyrite and pyrite as well as carbon and oxygen isotopes in calcite were analyzed.The analysis shows that the gas phase composition of inclusion is mainly H_2 O,followed by CO_2 and N_2.The cations in the liquid phase are mainly Na~+and Ca~(2+),while the anions are mainly Cl~-and SO_4~(2-),and the ore-forming fluid is SO_4~(2-)-Cl~--Na~+-Ca~(2+).From the early stage to the late stage,the H_2 O content increased while the CO_2,Na+,and Cl-plasma content decreased.The sulfur isotope composition of the sulfide is-2.9‰ – +0.8‰,concentrated in the range of 0‰±3‰,and the sulfur of ore-forming material is derived from magmatic fluid or ore-bearing surrounding rock.The carbon and oxygen isotopic composition of the calcite isδ13 CPDB=-11.4‰ –-9.2‰,andδ18 OSMOW= +8.5‰ – +17.4 ‰.The ore-forming fluid is considered to be a mixture of meteoric precipitation and magmatic water.The Hatu gold mine has similar ore-bearing strata and metallogenic time to Muruntau gold deposit,so the possibility of finding Muruntau gold deposit in Hatu area can be considered.
The Hatu gold mine,located in the south of the western Junggar region of Xinjiang,is one of the important gold mines in the Hatu gold belt.In this paper,fluid inclusion composition analysis of quartz in quartz vein samples of gold mine is carried out,and the characteristics of sulfur isotopes of the arsenopyrite and pyrite as well as carbon and oxygen isotopes in calcite were analyzed.The analysis shows that the gas phase composition of inclusion is mainly H_2 O,followed by CO_2 and N_2.The cations in the liquid phase are mainly Na~+and Ca~(2+),while the anions are mainly Cl~-and SO_4~(2-),and the ore-forming fluid is SO_4~(2-)-Cl~--Na~+-Ca~(2+).From the early stage to the late stage,the H_2 O content increased while the CO_2,Na+,and Cl-plasma content decreased.The sulfur isotope composition of the sulfide is-2.9‰ – +0.8‰,concentrated in the range of 0‰±3‰,and the sulfur of ore-forming material is derived from magmatic fluid or ore-bearing surrounding rock.The carbon and oxygen isotopic composition of the calcite isδ13 CPDB=-11.4‰ –-9.2‰,andδ18 OSMOW= +8.5‰ – +17.4 ‰.The ore-forming fluid is considered to be a mixture of meteoric precipitation and magmatic water.The Hatu gold mine has similar ore-bearing strata and metallogenic time to Muruntau gold deposit,so the possibility of finding Muruntau gold deposit in Hatu area can be considered.
引文
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[3]朱永峰，安芳，徐存元，等．新疆哈图及其周边金铜成矿规律和深部找矿预测[M]．北京：地质出版社，2013:1-161.ZHU Yongfeng, AN Fang, XU Cunyuan,et al.Metallogenic regularity and deep prospecting prediction of gold and copper in Hatu and its surrounding areas,Xinjiang[M].Beijing:Geological Press,2013:1-161.
[4]肖飞，徐存元，张凤军，等．西准噶尔哈图金矿床勘查新成果[J]．新疆地质，2010,28(4):409-412.XIAO Fei,XU Cunyuan,ZHANG Fengjun,et al.New achievements in the exploration of Hatu gold deposit in West Junggar[J].Geology of Xinjiang,2010,28(4):409-412.
[5]王莉娟，王玉往．新疆准噶尔盆地哈图金矿成矿流体的某些物理化学特征及与成矿关系[J]．地质与勘探，2005,41(6):24-29.WANG Lijuan,WANG Yuwang.Some physicochemical characteristics of ore-forming fluids of Hatu gold deposit in Junggar Basin,Xinjiang and their relationship with ore-forming[J].Geology and Exploration,2005,41(6):24-29.
[6]王莉娟，朱和平．新疆准噶尔盆地西缘哈图金矿成矿流体[J]．中国地质，2006,33(3):666-671.WANG Lijuan,ZHU Heping. Metallogenic Fluid of Hatu Gold Deposit in the Western Margin of Junggar Basin,Xinjiang[J].Geology of China,2006,33(3):666-671.
[7]SHEN P,PAN H D,ZHU H P.Two fluid sources and genetic implications for the Hatu gold deposit,Xinjiang,China[J].Ore Geology Reviews,2015a,73:298-312.
[8]李晶，许英霞，申萍，等．哈图金矿带成矿流体组分、硫同位素分析及矿床成因[J]．地质与勘探，2016,52(2):199-208.LI Jing,XU Yingxia,SHEN Ping,et al.Composition of ore-forming fluids,sulfur isotope analysis and genesis of the Hatu gold deposit[J].Geology and Exploration,2016,52(2):199-208.
[9]沈远超，金成伟．西准噶尔地区岩浆活动与金矿化作用[M]．北京：科学出版社，1993:1-239.SHEN Yuanchao,JIN Chengwei.Magmatic activity and gold mineralization in West Junggar[M]. Beijing:Science Press,1993:1-239.
[10]张雷，王国灿，高睿，等．新疆西准噶尔石炭系碎屑锆石U-Pb年代学及其他地质意义[J]．大地构造与成矿学，2015(4):707-717.ZHANG Lei, WANG Guocan, GAO Rui,et al.Carboniferous detrital zircon U-Pb geochronology and other geological significance[J]. Geotectonics and Metallogeny,2015(4):707-717.
[11]吴浩若，潘正莆．“构造杂岩”及其地质意义———以西准噶尔为例[J]．地质科学，1991(1):1-8.WU Haoruo,PAN Zhengpu."Tectonic Complex"and Its Geological Significance:A Case Study of West Junggar[J].Geological Science,1991(1):1-8.
[12]苏玉平，唐红峰，侯广顺，等．新疆西准噶尔达拉布特构造带铝质A型花岗岩的地球化学研究[J]．地球化学，2006,35(1):55-66.SU Yuping,TANG Hongfeng,HOU Guangshun,et al.Geochemical study of aluminous A-type granites in the Dalabut structural belt,western Junggar,Xinjiang[J].Geochemistry,2006,35(1):55-66.
[13]高山林，何志亮，周祖翼．西准噶尔克拉玛依花岗岩体地球化学特征及其意义[J]．新疆地质，2006,24(2):125-130.GAO Shanlin,HE Zhiliang,ZHOU Zuyi.Geochemical characteristics and significance of the Karamay granite body in West Junggar[J].Geology of Xinjiang,2006,24(2):125-130.
[14]韩宝福，季建清，宋彪，等．新疆准噶尔晚古生代陆壳垂向生长———后碰撞深成岩浆活动的时限[J]．岩石学报，2006,22(5):1077-1086.HAN Baofu,JI Jianqing,SONG Biao,et al. Late Paleozoic continental crust vertical growth-time limit of post-collision plutonic magmatism in Junggar,Xinjiang[J].Journal of Petrology,2006,22(5):1077-1086.
[15]王京彬，徐新．新疆北部后碰撞构造演化与成矿[J]．地质学报，2006,80(1):23-31.WANG Jingbin, XU Xin. Post-collision tectonic evolution and mineralization in northern Xinjiang[J].Journal of Geology,2006,80(1):23-31.
[16]潘鸿迪，申萍．新疆包古图斑岩铜矿中性复式岩体的同化混染作用[J]．地球科学与环境学报，2014,36(1):80-97.PAN Hongdi,SHEN Ping.Assimilation and Mixing of Neutral Compound Rocks in Baogutu Porphyry Copper Deposit,Xinjiang[J].Journal of Geosciences and Environment,2014,36(1):80-97.
[17]AUDETAT A, GUNTHER D, HEINRICH C A.Formation of a magmatic-hydrothermal ore deposit:Insights with LA-ICP-MS analysis of fluid inclusions[J].Science,1998,279(5359):2091-2094.
[18]HEINRICH C A,GUNTHER D,AUDETAT A.Metal fractionation between magmatic brine and vapor,determined by microanlysis of fluid inclusion[J].Geology,1999,27(8):755-758.
[19]WILKINSON J J,STOFFELL B,WILKINSON C C.Anomalously metal-rich fluids from hydrothermal ore deposit[J].Science,2009,323(5915):764-767.
[20]刘汉彬，金贵善，李军杰，等．铀矿地质样品的稳定同位素组成测试方法[J]．世界核地质科学，2013,30(3):174-179.LIU Hanbin,JIN Guishan,LI Junjie,et al.Test method for stable isotope composition of uranium geological samples[J]. World Nuclear Geology Science,2013,30(3):174-179.
[21]HOEFS J.Stable Isotope Geochemistry[M].Sixth Edition.Springer,2009:1-283.
[22]TAYLOR B E.Magmatic volatiles:Isotope variation of C,H and Sreviews in mineralogy[C]//Stable isotopes in high temperature geological process.Mineralogical Society of America,1986,16:185-226.
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