聚合原位合成含螺吡喃组装体及其光响应研究
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摘要
具有光响应性的采用乙醇相分散共聚的方法将螺吡喃基团引入聚合原位自组装体系,合成了具有光响应性的聚甲基丙烯酸N,N-二甲基氨基乙酯-b-聚(甲基丙烯酸苄酯-co-甲基丙烯酸螺吡喃酯)(PDMA-b-P(BzMA-co-SPMA))共聚物组装体.通过调节BzMA、SPMA和PDMA的投料比,制备了球形胶束、蠕虫状胶束、"章鱼"状组装体、囊泡、实心粒子等不同形貌的组装体.所得组装体分散液具备良好的紫外响应显色性:在交替的UV(紫外)/可见光照射下,组装体分散液发生无色-蓝色的可逆转变.使用光响应组装体墨水绘制的文字和图案可以实现在UV/可见光照射(或升温)下的可逆显示与隐藏.这种方法可拓展应用于文字和图案的打印,实现精细图案的大批量快速制备.二维光响应图案具备良好的稳定性,且光响应过程具备良好的可循环性.
A series of spiropyrane-containing copolymer assemblies—p o ly(N,N-dimethylaminoethyl methacrylate)-b-poly{(benzyl methacrylate)-co-[1'-(2-methacryloxyethyl)-3',3'-dimethyl-6-nitro-spiro(2 H-1-benzopyran-2,2'-indoline)]}(PDMA-b-P(BzMA-co-SPMA)) were prepared by reversible addition-fragmentation chain transfer(RAFT) polymerization-induced self-assembly(PISA), where SPMA units act as the photo-responsive moieties, P(BzMA-co-SPMA) chains as the core-forming blocks, and PDMA chains as shell-forming blocks. First,PDMA was prepared by RAFT polymerization in ethanol at 80 °C. With PDMA as macro chain transfer agent, the RAFT PISA of BzMA and SPMA in ethanol at 70 °C were completed. By changing the feed ratios of BzMA,SPMA, and PDMA, diverse morphologies, such as spheres, worms, "octopus"-like structures, vesicles, and solid particles, were readily prepared. During UV irradiation, the absorbance maximum at 585 nm increased successively, suggesting the spiropyrane structure gradually isomerized into merocyanine structure. As a result,copolymer assembly dispersion underwent a colorless-to-colorful transformation. Subsequently, the colorful copolymer assembly dispersion was exposed to visible light. The results suggested that the absorbance maximum at 585 nm gradually decreased and the colorful copolymer assembly dispersion transformed into colorless. Using the copolymer assembly dispersion as ink, the characters and patterns were drawn on papers. Since the copolymer assembly dispersion was colorless, the characters and patterns were invisible. Upon UV irradiation, with spiropyrane isomerized into merocyanine, the characters and patterns changed to blue and visible, while upon visible light irradiation or heating, merocyanine structure isomerized into spiropyrane, which induced the characters and patterns to become colorless and invisible. Taking advantage of ink-jet printing, fine-patterned patterns and two-dimensional materials could be rapidly and massively produced, which also underwent reversible invisible-to-visible transformation, upon alternative UV irradiation and visible light irradiation/heating.
A series of spiropyrane-containing copolymer assemblies—p o ly(N,N-dimethylaminoethyl methacrylate)-b-poly{(benzyl methacrylate)-co-[1'-(2-methacryloxyethyl)-3',3'-dimethyl-6-nitro-spiro(2 H-1-benzopyran-2,2'-indoline)]}(PDMA-b-P(BzMA-co-SPMA)) were prepared by reversible addition-fragmentation chain transfer(RAFT) polymerization-induced self-assembly(PISA), where SPMA units act as the photo-responsive moieties, P(BzMA-co-SPMA) chains as the core-forming blocks, and PDMA chains as shell-forming blocks. First,PDMA was prepared by RAFT polymerization in ethanol at 80 °C. With PDMA as macro chain transfer agent, the RAFT PISA of BzMA and SPMA in ethanol at 70 °C were completed. By changing the feed ratios of BzMA,SPMA, and PDMA, diverse morphologies, such as spheres, worms, "octopus"-like structures, vesicles, and solid particles, were readily prepared. During UV irradiation, the absorbance maximum at 585 nm increased successively, suggesting the spiropyrane structure gradually isomerized into merocyanine structure. As a result,copolymer assembly dispersion underwent a colorless-to-colorful transformation. Subsequently, the colorful copolymer assembly dispersion was exposed to visible light. The results suggested that the absorbance maximum at 585 nm gradually decreased and the colorful copolymer assembly dispersion transformed into colorless. Using the copolymer assembly dispersion as ink, the characters and patterns were drawn on papers. Since the copolymer assembly dispersion was colorless, the characters and patterns were invisible. Upon UV irradiation, with spiropyrane isomerized into merocyanine, the characters and patterns changed to blue and visible, while upon visible light irradiation or heating, merocyanine structure isomerized into spiropyrane, which induced the characters and patterns to become colorless and invisible. Taking advantage of ink-jet printing, fine-patterned patterns and two-dimensional materials could be rapidly and massively produced, which also underwent reversible invisible-to-visible transformation, upon alternative UV irradiation and visible light irradiation/heating.
引文
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63Huo M,Ye Q,Che H,Wang X,Wei Y,Yuan J.Macromolecules,2017,50:1126-1133
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2Tu Y,Peng F,Adawy A,Men Y,Abdelmohsen L K E A,Wilson D A.Chem Rev,2016,116:2023-2078
3Lu A,O’Reilly R K.Curr Opin Biotechnol,2013,24:639-645
4Che H,van Hest J C M.J Mater Chem B,2016,4:4632-4647
5Stuart M A C,Huck W T S,Genzer J,Müller M,Ober C,Stamm M,Sukhorukov G B,Szleifer I,Tsukruk V V,Urban M,Winnik F,Zauscher S,Luzinov I,Minko S.Nat Mater,2010,9:101-113
6Zhang J,Li X,Li X.Prog Polym Sci,2012,37:1130-1176
7Palivan C G,Goers R,Najer A,Zhang X,Car A,Meier W.Chem Soc Rev,2016,45:377-411
8He C,Zhuang X,Tang Z,Tian H,Chen X.Adv Healthcare Mater,2012,1:48-78
9Meng F,Zhong Z,Feijen J.Biomacromolecules,2009,10:197-209
10Alarcon C d l H,Pennadam S,Alexander C.Chem Soc Rev,2005,34:276-285
11Hoffman A S.Adv Drug Deliv Rev,2013,65:10-16
12Qing Xin(卿鑫),Lv Jiuan(吕久安),Yu Yanlei(俞燕蕾).Acta Polymerica Sinica(高分子学报),2017,(11):1679-1705
13Sun J T,Hong C Y,Pan C Y.Polym Chem,2013,4:873-881
14Canning S L,Smith G N,Armes S P.Macromolecules,2016,49:1985-2001
15Derry M J,Fielding L A,Armes S P.Prog Polym Sci,2016,52:1-18
16Charleux B,Delaittre G,Rieger J,D’Agosto F.Macromolecules,2012,45:6753-6765
17Sun J T,Hong C Y,Pan C Y.Soft Matter,2012,8:7753-7767
18Wang X,Shen L,An Z.Prog Polym Sci,2018,83:1-27
19Zhang W J,Hong C Y,Pan C Y.Macromol Rapid Commun,2015,36:1428-1436
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41Zhang Q,Wang C,Fu M,Wang J,Zhu S.Polym Chem,2017,8:5474-5480
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43Chen X,Liu L,Huo M,Zeng M,Peng L,Feng A,Wang X,Yuan J.Angew Chem Int Ed,2017,56:16541-16545
44Chen S,Shi P,Zhang W.Chinese J Polym Sci,2016,35:455-479
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47Tan J,Zhang X,Liu D,Bai Y,Huang C,Li X,Zhang L.Macromol Rapid Commun,2017,38:1600508
48Ye Q,Huo M,Zeng M,Liu L,Peng L,Wang X,Yuan J.Macromolecules,2018,51:3308-3314
49Raymo F M,Giordani S.J Am Chem Soc,2001,123:4651-4652
50Klajn R.Chem Soc Rev,2014,43:148-184
51Li M,Zhang Q,Zhou Y N,Zhu S.Prog Polym Sci,2018,79:26-39
52Zhu M Q,Zhu L,Han J J,Wu W,Hurst J K,Li A D Q.J Am Chem Soc,2006,128:4303-4309
53Yan J,Zhao L X,Li C,Hu Z,Zhang G F,Chen Z Q,Chen T,Huang Z L,Zhu J,Zhu M Q.J Am Chem Soc,2015,137:2436-2439
54Zhu M Q,Zhang G-F,Hu Z,Aldred M P,Li C,Gong W L,Chen T,Huang Z L,Liu S.Macromolecules,2014,47:1543-1552
55Chang Yanhong(常艳红),Kang Hongliang(康宏亮),Li Guanghua(李光华),Han Haiwei(韩海威),Liu Ruigang(刘瑞刚).Acta Polymerica Sinica(高分子学报),2016,(10):1669-1677
56Wojtyk J T C,Buncel E,Kazmaier P M.Chem Commun,1998:1703-1704
57Zhang Q M,Wang W,Su Y Q,Hensen E J M,Serpe M J.Chem Mater,2016,28:259-265
58Park I S,Jung Y S,Lee K J,Kim J M.Chem Commun,2010,46:2859-2861
59Davis D A,Hamilton A,Yang J,Cremar L D,van Gough D,Potisek S L,Ong M T,Braun P V,Martínez T J,White S R,Moore J S,Sottos N R.Nature,2009,459:68
60Hu J,Liu S.Macromolecules,2010,43:8315-8330
61Mitsukami Y,Donovan M S,Lowe A B,McCormick C L.Macromolecules,2001,34:2248-2256
62Su T,Cheng F R,Cao J,Yan J Q,Peng X Y,He B.J Mater Chem B,2017,5:3107-3110
63Huo M,Ye Q,Che H,Wang X,Wei Y,Yuan J.Macromolecules,2017,50:1126-1133
64Zhang Y,Cao M,Yuan B,Guo T,Zhang W.Polym Chem,2017,8:7325-7332
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