长余辉发光材料及其在水泥基材料中的应用研究进展
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摘要
长余辉发光材料是一类重要的光致发光材料,具有环保节能的特点。目前,以环保节能、安全经济为前提的蓄光型长余辉发光材料已广泛用于工艺美术、军事航空、医学放射学图像、电器、交通安全及建筑等诸多领域。从基质选择的角度出发,综述了长余辉发光材料的类型(主要为硫化物型、铝酸盐型、硅酸盐型及其他基质型)、发展历程、发光机理及常见制备方法。发光材料在合成过程中基质晶格中产生了结构缺陷和杂质缺陷,这些缺陷的存在局部地破坏了晶体内部的规则排列,当外部光源对发光材料进行照射时,电子可在各级能级间跃迁,从而产生发光现象。概述了其在新型建筑材料——发光水泥基材料中的最新研究进展,最后对长余辉发光材料及其在水泥基材料中的应用研究趋势进行了展望。
Long persistence luminescent materials is a type of important photoluminescence materials with the characteristics of environmental protection and energy saving.At present,the long afterglow luminescent materials with the premise of environmental protection and energy saving,safety and economy have been widely used in many fields such as arts and crafts,military aviation,medical radiology images,electrical appliances,traffic safety and architecture.In this paper,the types,development,luminescent mechanism and common preparation methods of long persistence luminescent materials,including sulfite,aluminate,silicate luminescent materials etc,were summarized.The structure defects and impurity defects are generated in the parent lattice of luminescent materials during the synthesis process,these defects partially have destroyed the crystal internal rules,when the external light source of luminous materials are irradiated,electrons can jump among all energy levels,thereby producing luminous phenomenon.Then,the latest research progress of luminescent cementitious materials were reviewed.Finally,the research trends of long persistence luminescent materials and its utilization in cementitious materials were prospected.
Long persistence luminescent materials is a type of important photoluminescence materials with the characteristics of environmental protection and energy saving.At present,the long afterglow luminescent materials with the premise of environmental protection and energy saving,safety and economy have been widely used in many fields such as arts and crafts,military aviation,medical radiology images,electrical appliances,traffic safety and architecture.In this paper,the types,development,luminescent mechanism and common preparation methods of long persistence luminescent materials,including sulfite,aluminate,silicate luminescent materials etc,were summarized.The structure defects and impurity defects are generated in the parent lattice of luminescent materials during the synthesis process,these defects partially have destroyed the crystal internal rules,when the external light source of luminous materials are irradiated,electrons can jump among all energy levels,thereby producing luminous phenomenon.Then,the latest research progress of luminescent cementitious materials were reviewed.Finally,the research trends of long persistence luminescent materials and its utilization in cementitious materials were prospected.
引文
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[25]廉世勋,李秀英,尹笃林,等.固溶体结构对Ca2-x Srx Zn4Ti15O36∶Pr3+发光性质的影响[J].无机化学学报,2006,22(2):336-340.
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[31]李友芬,秦奕鸿,刘莉莉.助溶剂对固相微波法合成MgAl2O4∶Eu发光性能的影响[J].硅酸盐通报,2014,33(5):23-27.
[32]李松坤,王小平,王丽君,等.长余辉发光材料的研究进展[J].材料导报A:综述篇,2014,28(3):63-67.
[33]WAN J X,YAO Y W,TANG G Y,et al.Hydrothermal synthesis and size-enhanced chromaticity of Sr2ZnSi2O7∶Eu3+nanoparticles[J].J Nanosci Nanotechno,2008,8(3):1449-1453.
[34]王林生,李敏,赖华生,等.喷雾热解法制备球形SrAl2O4∶Eu,Dy长余辉发光材料[J].中国稀土学报,2011,29(4):455-462.
[35]张金安.聚合物水泥长余辉蓄能发光涂料的制备[J].齐齐哈尔大学学报,2004,20(1):25-30.
[36]潘英豪.发光反光混凝土地面砖及其生产方法[P].中国专利:CN1587162A,2005-03-02.
[37]高炳申.蓄能发光的混凝土或树脂建材制品[P].中国专利:CN201588336U,2010-09-22.
[38]黄利辉.用建筑垃圾和生活垃圾的炉渣制成的发光混凝土砖[P].中国专利:CN102296742A,2011-12-28.
[39]刘华章.混凝土发光砖面层配合比的试验研究[J].混凝土和水泥制品,2008(3):55-57.
[40]王信刚,宋固全,胡明玉.发光透光水泥基材料[P].中国专利:CN101805608A,2010-08-18.
[41]王信刚,陈方斌,章未琴,等.发光透光水泥基材料的力学性能与光学特性[J].中国矿业大学学报,2013,42(2):195-199.
[42]王倩.发光混凝土的制备及性能研究[D].沈阳:沈阳建筑大学,2012.
[43]徐芬莲,陈景,赵晚群,等.一种非放射性的环保蓄能发光透水混凝土路面及其施工方法[P].中国专利:CN103437259A,2013-12-11.
[44]陈景,王晶晶,徐芬莲,等.环保节能型发光透水混凝土的制备及应用[J].混凝土,2015(6):106-109.
[2]TROJAN-PIEGZA J,NIITTYKOSKI J,HLS J,et al.Thermoluminescence and kinetics of persistent luminescence of vacuum-sintered Tb3+-doped and Tb3+,Ca2+codoped Lu2O3materials[J].Chemistry of Materials,2008(20):2252-2261.
[3]肖志国,罗昔贤.蓄光型发光材料及其制品[M].北京:化学工业出版社,2005.
[4]HAPPEK U,BASUN S,CHOI J,et al.Electron transfer processes in rare earth doped insulators[J].Journal of Alloys and Compounds,2000(303):198-206.
[5]李建宇.稀土发光材料及其应用[M].北京:化学工业出版社,2003.
[6]TENG X M,ZHUANG W D,HU Y S,et al.Effect of flux on the properties of CaAl2O4∶Eu2+,Nd3+long afterglow phosphor[J].Journal of Alloys and Compounds,2008(458):446-449.
[7]林元华,张中太,张枫.铝酸盐长余辉光致发光材料的制备及其发光机制的研究[J].材料导报,2000,14(1):35-37.
[8]肖志国.《新型光致发光材料及涂料》专家评审委员会资料[Z].大连:大连市科委,1993.
[9]袁剑辉,袁红辉,张振华.蓝色长余辉材料Sr4Al4O7∶Eu2+,Dy3+的合成及其发光特性[J].光电子激光,2006,17(4):44-49.
[10]王育华,王雷,张水合.蓝色长余辉材料CaAl2O4∶Eu2+,Nd3+的合成及其发光特性[J].高等学校化学学报,2005,26(11):1990-1993.
[11]QIU T,JI Z G,KONG Z,et al.Preparation and optimization of long persistent luminescent Sr4Al14O25∶(Eu,Dy)phosphor materials[J].Journal of Inorganic Materials,2012,27(12):1-5.
[12]CLABAU F,ROCQUEFELTE X,LE MERCIER T,et al.Formulation of phosphorescence mechanisms in inorganic solids based on a new model of defect conglomeration[J].Chemistry of Materials,2006(18):3212-3220.
[13]DORENBOS P,BOS A.Lanthanide level location and related thermoluminescence phenomena[J].Radiation Measurements,2008(43):139-145.
[14]龚宇.几种典型硅酸盐长余辉材料的制备及其光学性能的研究[D].兰州:兰州大学,2012.
[15]肖志国,肖志强.硅酸盐长余辉发光材料及其制造方法[P].中国专利:ZL98105078,1998-09-30.
[16]WANG X J,JIA D D,YEN W M.Mn2+activated green,yellow,and red long persistent phosphors[J].Journal of Luminescence,2003(34):102-103.
[17]LEI B F,LIU Y L,LIU J,et al.Pink light emitting long-lasting phosphorescence in Sm3+-doped CdSiO3[J].Journal of Solid State Chemistry,2004(177):1333-1337.
[18]LEI B F,LIU Y L,YE Z R,et al.Luminescence properties of CdSiO3∶Mn2+phosphor[J].Journal of Luminescence,2004(109):215-219.
[19]AITASALO T,HRENIAK D,HOELSA J,et al.Persistent luminescence of Ba2MgSi2O7∶Eu2+[J].Journal of Luminescence,2007(122-123):110-112.
[20]JIANG L,CHANG C,MAO D,et al.Luminescent properties of CaMgSi2O6-based phosphors co-doped with different rare earth ions[J].Journal of Alloys and Compounds,2004,377(1-2):211-215.
[21]LEI B F,LIU Y L,YE Z R,et al.A novel white light emitting long-lasting phosphor[J].Chinese Chemical Letters,2004,15(3):335-338.
[22]DOTSENKO V P,BEREZOVSKAYA I V,ERRYUSHINA N P,et al.Luminesce-nce properties and electronic structure of Sm3+-doped YAl3B4O12[J].Journal of Materials Science,2010,45(6):1469-1472.
[23]HE M,HUANG G L,TAO H L,et al.Synthesis and luminescence properties of europium doped YBa3B9O18[J].Physica B:Condensed Matter,2012,407(14):2725-2728.
[24]李灿涛,袁剑辉,张万锴,等.掺杂Gd3+对Y2O2S∶Eu3+发光特性的影响[J].发光学报,1999,20(4):316-319.
[25]廉世勋,李秀英,尹笃林,等.固溶体结构对Ca2-x Srx Zn4Ti15O36∶Pr3+发光性质的影响[J].无机化学学报,2006,22(2):336-340.
[26]刘应亮,雷炳富,邝金勇,等.长余辉发光材料研究进展[J].无机化学学报,2009,25(8):1323-1329.
[27]张中太,张俊英.无机光致发光材料及应用[M].北京:化学工业出版社,2005.
[28]XIAO L,SUN M,ZHANG J Y,et al.Effect of mixing process on the luminescent properties of SrAl2O4∶Eu2+,Dy3+long afterglow phosphors[J].Journal of Rare Earths,2010(28):150-152.
[29]张俊文,谭宁会,刘应亮,等.沉淀法合成纳米晶上转换发光材料Y2O2S∶Yb,Er[J].无机化学学报,2010,26(2):229-232.
[30]GALCERAN M,PUJOL M C,MENDEZ C,et al.Synthesis of monoclinic KGd(WO4)2nanocrystals by two preparation methods[J].JNanopart Research,2009(11):717-721.
[31]李友芬,秦奕鸿,刘莉莉.助溶剂对固相微波法合成MgAl2O4∶Eu发光性能的影响[J].硅酸盐通报,2014,33(5):23-27.
[32]李松坤,王小平,王丽君,等.长余辉发光材料的研究进展[J].材料导报A:综述篇,2014,28(3):63-67.
[33]WAN J X,YAO Y W,TANG G Y,et al.Hydrothermal synthesis and size-enhanced chromaticity of Sr2ZnSi2O7∶Eu3+nanoparticles[J].J Nanosci Nanotechno,2008,8(3):1449-1453.
[34]王林生,李敏,赖华生,等.喷雾热解法制备球形SrAl2O4∶Eu,Dy长余辉发光材料[J].中国稀土学报,2011,29(4):455-462.
[35]张金安.聚合物水泥长余辉蓄能发光涂料的制备[J].齐齐哈尔大学学报,2004,20(1):25-30.
[36]潘英豪.发光反光混凝土地面砖及其生产方法[P].中国专利:CN1587162A,2005-03-02.
[37]高炳申.蓄能发光的混凝土或树脂建材制品[P].中国专利:CN201588336U,2010-09-22.
[38]黄利辉.用建筑垃圾和生活垃圾的炉渣制成的发光混凝土砖[P].中国专利:CN102296742A,2011-12-28.
[39]刘华章.混凝土发光砖面层配合比的试验研究[J].混凝土和水泥制品,2008(3):55-57.
[40]王信刚,宋固全,胡明玉.发光透光水泥基材料[P].中国专利:CN101805608A,2010-08-18.
[41]王信刚,陈方斌,章未琴,等.发光透光水泥基材料的力学性能与光学特性[J].中国矿业大学学报,2013,42(2):195-199.
[42]王倩.发光混凝土的制备及性能研究[D].沈阳:沈阳建筑大学,2012.
[43]徐芬莲,陈景,赵晚群,等.一种非放射性的环保蓄能发光透水混凝土路面及其施工方法[P].中国专利:CN103437259A,2013-12-11.
[44]陈景,王晶晶,徐芬莲,等.环保节能型发光透水混凝土的制备及应用[J].混凝土,2015(6):106-109.
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