粉煤灰资源化技术开发与利用研究进展
|
摘要
针对我国粉煤灰堆积造成的日益突出的土地和环境污染问题,论文综述了我国粉煤灰资源开发与应用现状;简要介绍了粉煤灰在大掺杂量方面的应用,如建材领域、农业领域、矿山领域和环保领域;详细介绍了粉煤灰在高附加值领域的应用现状,如粉煤灰的深度分离、氧化铝提取、稀有金属提取和高附加值产品合成等方面。最后,探讨了粉煤灰资源化利用存在的问题,并提出了未来粉煤灰资源化开发利用的发展趋势。
With the increasingly outstanding problems of land and environmental pollution caused by the accumulation of fly ash in China. This paper summarizes the present situation of development and application of fly ash resources. This paper briefly introduces the application of fly ash in large amount of doping,such as building materials,agriculture,mining and environmental protection. Moreover,the application status of fly ash in high value-added field is introduced in detail,such as deep separation of fly ash,extraction of alumina,extraction of rare metals and synthesis of high value-added products. Finally,the paper proposes the existing problems and the development trend of fly ash resource utilization in future.
With the increasingly outstanding problems of land and environmental pollution caused by the accumulation of fly ash in China. This paper summarizes the present situation of development and application of fly ash resources. This paper briefly introduces the application of fly ash in large amount of doping,such as building materials,agriculture,mining and environmental protection. Moreover,the application status of fly ash in high value-added field is introduced in detail,such as deep separation of fly ash,extraction of alumina,extraction of rare metals and synthesis of high value-added products. Finally,the paper proposes the existing problems and the development trend of fly ash resource utilization in future.
引文
[1]王建新,李晶,赵仕宝,等.中国粉煤灰的资源化利用研究进展与前景[J].硅酸盐通报,2018(12):3833-3841.
[2]郭新亮.燃煤电厂粉煤灰综合利用技术研究[D].西安:长安大学,2009.
[3]张灿强.不同种类粉煤灰特性的实验研究[D].南京:东南大学,2017.
[4]Selic E,Herbell J D. Utilization of fly ash from coal-fired power plants in China[J]. Journal of Zhejiang University-Science A(Applied Physics&Engineering),2008,9(5):681-687.
[5]孙俊民,王秉军,张占军.高铝粉煤灰资源化利用与循环经济[J].轻金属,2012(10):1-5.
[6]Yang Q C,Ma S H,Zheng S L,et al. Recovery of alumina from eir-culating fluidized bed combustion Al-rich fly ash using mild hydro-chemical process[J]. Transactions of nonferrous metals society of China,2014,24(4):1187-1195.
[7]Xu H,Li Q,Shen L F,et al. Low-reactive eirculating fluidized bed combustion(CFBC)fly ashes as source material for geopolymersyn-thesis[J]. Waste management,2010,30(1):57-62.
[8]Ahmaruzzaman M. A review on the utilization of fly ash[J]. Progress in energy and combustion science,2010,36(3):327-363.
[9]Wang S. Application of solid ash based catalysts in heterogeneous catalysis[J]. Environmental science&technology,2008,42:7055-7063.
[10]Vassilev S V,Vassileva C G. A new approach for the classification of coal fly ashes based on their origin,composition,properties and behavior[J]. Fuel,2007,86:1490-1512.
[11]Li J,Zhuang X,Querol X,et al. A review on the applications of coal combustion products in China[J]. International geology review,2018,60(5-6):671-716.
[12]佚名.内蒙古首条利用粉煤灰制作的绿色“生态板”下线[J].粉煤灰综合利用,2018(5):139.
[13]Manisha Basua,b,Manish Pandea,et al. Potential fly-ash utilization in agriculture:A global review[J]. Progress in natural science,2009,(10):1173-1186.
[14]Banerjee S S. Removal of nickel(II)and zinc(II)from waste water using fly ash and impregnated fly ash[J]. Separation science and technology,2003,38(5):1015-1032.
[15]曾经,刘春华.火电厂粉煤灰改性物对Cu(Ⅱ)的吸附性能及应用研究[J].材料保护,2007(6):55-57.
[16]Tomasz K,Anna K,Ryszard C. Effective adsorption of lead ions using fly ash obtained in the novel circulating fluidized bed combustion technology[J]. Microchemical journal,2019,145:1011-1025.
[17]Hermassi M,Valderrama C,Moreno N. Fly ash as reactive sorbent for phosphate removal from treated waste water as a potential slow release fertilizer[J]. Journal of environmental chemical engineering,2017,5(1):160-169.
[18]彭喜花,马喜君,刘雪梅,等.改性粉煤灰处理低浓度含磷废水的研究[J].环境污染与防治,2012(1):52-55.
[19]邹鹏,郁海华.采用改性粉煤灰对电厂脱硫废水中Cl-的去除[J].工业水处理,2019,39(3):50-53.
[20]张罡,熊青山.金属盐改性粉煤灰处理含氟废水及吸附热力学研究[J].当代化工,2018,47(12):2588-2597.
[21]Rubel A,Andrews R,Gonzalez R,et al. Adsorption of Hg and NOxon coal by-products[J]. Fuel,2005,84(7-8):911-916.
[22]Rathnayake M,Julnipitawong P,Tangtermsirikul S,et al. Utilization of coal fly ash and bottom ash as solid sorbents for sulfur dioxide reduction from coal fired power plant:Life cycle assessment and applications[J]. Journal of cleaner production,2018,202(20):934-945.
[23]Ji L,Yu H,Wang X l. CO2sequestration by direct mineralisation using fly ash from Chinese Shenfu coal[J]. Fuel processing technology,2017,156:429-437.
[24]宋晓睿,杨辉.空心玻璃微球制备技术研究进展[J].硅酸盐学报,2012,40(3):450-457.
[25]LIANG J Z. Toughening and reinforcing in rigid inorganic particulate filled poly(propylene):A review[J]. J Appl Polym Sci,2002,8(3):1547-1555.
[26]郭新亮.基于粉煤灰磁珠的磁性吸附剂制备及铜吸附研究[D].合肥:安徽理工大学,2016.
[27]李超,王丽萍,郭昭华,等.粉煤灰中锂提取技术研究进展[J].有色金属:冶炼部分. 2018(4):46-50.
[28]郭昭华.粉煤灰“一步酸溶法”提取氧化铝工艺技术及工业化发展研究[J].煤炭工程,2015(7):5-8.
[29]孙培梅,童军武,徐红艳,等.从粉煤灰中提取氧化铝熟料溶出过程工艺研究[J].中南大学学报:自然科学版,2010(5):1698-1702.
[30]王腾飞,张金山,李侠.碱法提取高铝粉煤灰中氧化铝的研究进展[J].矿产综合利用,2019(1):16-20.
[31]唐云,陈福林,刘安荣.燃煤电厂粉煤灰提取氧化铝研究[J].煤炭学报. 2009(1):105-110.
[32]代世峰,任徳贻,周义平,等.煤型稀有金属矿床:成因类型、赋存状态和利用评价[J].煤炭学报,2014(8):1707-1715.
[33]李超,王丽萍,郭昭华,等.盐酸体系下镓的提取技术研究进展[J].稀有金属与硬质合金,2019(1):6-10.
[34] Taggart R K,Hower J C,Hsu-Kim H. Effects of roasting additives and leaching parameters on the extraction of rare earth elements from coal fly ash[J]. International Journal of coal geology,2018,196:106-114.
[35]Li C X,Zhou Y,Tian Y M. Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash,https://doi. org/10. 1016/j. ceramint. 2018. 12. 021.
[36]Luo Y,Zheng S l,Preparation of sintered foamed ceramics derived entirely from coal fly ash[J]. Construction and building materials,2018,163:529-538.
[37]Zou D,Xu J R,Chen X F,A novel thermal spraying technique to fabricate fly ash/alumina composite membranes for oily emulsion and spent tin wastewater treatment[J]. Separation and purification technology,https://doi. org/10. 1016/j.seppur. 2019. 02. 051.
[38]施云芬,陈媛,张益维,等.粉煤灰负载钒氧化物低温SCR催化剂脱硝性能研究[J].东北电力大学学报,2015(3):59-63.
[39]Jain D,Mishra M,Synthesis and characterization of novel aminopropylated fly ash catalyst and its beneficial application in base catalyzed Knoevenagel condensation reaction[J]. Fuel Processing Technology,2012,95:119-126.
[40]Yang S Y,Liang P,Hua K H. Preparation of carboxylated nitrile butadiene rubber/fly ash composites by in-situ carboxylate reaction[J]. Composites science and technology,2018,167:294-300.
[41]Yang S Y,Liang P,Peng X K. Improvement in mechanical properties of SBR/fly ash composites by in-situ graftingneutralization reaction[J]. Chemical engineering journal,2018,354:849-855.
[42]冯泽平,高钙粉煤灰地质聚合物的制备及耐久性研究[J].矿产保护与利用,2018(2):107-110.
[43]Wang Y C,Zhao J P,Facile preparation of slag or fly ash geopolymer composite coatings with flame resistance[J]. Construction and building materials,2019,203:655-661.
[44]贾敏,池君洲,王永旺,等.粉煤灰酸法提取氧化铝的残渣制备4A分子筛[J].矿产保护与利用. 2017(1):77-83.
[45]李超,王丽萍,郭昭华,等.粉煤灰提铝后尾渣合成13X分子筛及其对Pb2+吸附性能的研究[J].矿产保护与利用,2018(6):98-102.
[46]Hyland M. Preparation of zeolite 4A by using high-alumina coal fly ash[M]. John Wiley&Sons,Inc,2015,119-126.
[47]谢建忠.利用粉煤灰制备泡沫玻璃[J].矿产保护与利用,1999(3):53-54.
[48]Bai J G,Yang X H,Xu S C. Preparation of foam glass from waste glass and fly ash[J]. Materials Letters,2014,136:52-54.
[2]郭新亮.燃煤电厂粉煤灰综合利用技术研究[D].西安:长安大学,2009.
[3]张灿强.不同种类粉煤灰特性的实验研究[D].南京:东南大学,2017.
[4]Selic E,Herbell J D. Utilization of fly ash from coal-fired power plants in China[J]. Journal of Zhejiang University-Science A(Applied Physics&Engineering),2008,9(5):681-687.
[5]孙俊民,王秉军,张占军.高铝粉煤灰资源化利用与循环经济[J].轻金属,2012(10):1-5.
[6]Yang Q C,Ma S H,Zheng S L,et al. Recovery of alumina from eir-culating fluidized bed combustion Al-rich fly ash using mild hydro-chemical process[J]. Transactions of nonferrous metals society of China,2014,24(4):1187-1195.
[7]Xu H,Li Q,Shen L F,et al. Low-reactive eirculating fluidized bed combustion(CFBC)fly ashes as source material for geopolymersyn-thesis[J]. Waste management,2010,30(1):57-62.
[8]Ahmaruzzaman M. A review on the utilization of fly ash[J]. Progress in energy and combustion science,2010,36(3):327-363.
[9]Wang S. Application of solid ash based catalysts in heterogeneous catalysis[J]. Environmental science&technology,2008,42:7055-7063.
[10]Vassilev S V,Vassileva C G. A new approach for the classification of coal fly ashes based on their origin,composition,properties and behavior[J]. Fuel,2007,86:1490-1512.
[11]Li J,Zhuang X,Querol X,et al. A review on the applications of coal combustion products in China[J]. International geology review,2018,60(5-6):671-716.
[12]佚名.内蒙古首条利用粉煤灰制作的绿色“生态板”下线[J].粉煤灰综合利用,2018(5):139.
[13]Manisha Basua,b,Manish Pandea,et al. Potential fly-ash utilization in agriculture:A global review[J]. Progress in natural science,2009,(10):1173-1186.
[14]Banerjee S S. Removal of nickel(II)and zinc(II)from waste water using fly ash and impregnated fly ash[J]. Separation science and technology,2003,38(5):1015-1032.
[15]曾经,刘春华.火电厂粉煤灰改性物对Cu(Ⅱ)的吸附性能及应用研究[J].材料保护,2007(6):55-57.
[16]Tomasz K,Anna K,Ryszard C. Effective adsorption of lead ions using fly ash obtained in the novel circulating fluidized bed combustion technology[J]. Microchemical journal,2019,145:1011-1025.
[17]Hermassi M,Valderrama C,Moreno N. Fly ash as reactive sorbent for phosphate removal from treated waste water as a potential slow release fertilizer[J]. Journal of environmental chemical engineering,2017,5(1):160-169.
[18]彭喜花,马喜君,刘雪梅,等.改性粉煤灰处理低浓度含磷废水的研究[J].环境污染与防治,2012(1):52-55.
[19]邹鹏,郁海华.采用改性粉煤灰对电厂脱硫废水中Cl-的去除[J].工业水处理,2019,39(3):50-53.
[20]张罡,熊青山.金属盐改性粉煤灰处理含氟废水及吸附热力学研究[J].当代化工,2018,47(12):2588-2597.
[21]Rubel A,Andrews R,Gonzalez R,et al. Adsorption of Hg and NOxon coal by-products[J]. Fuel,2005,84(7-8):911-916.
[22]Rathnayake M,Julnipitawong P,Tangtermsirikul S,et al. Utilization of coal fly ash and bottom ash as solid sorbents for sulfur dioxide reduction from coal fired power plant:Life cycle assessment and applications[J]. Journal of cleaner production,2018,202(20):934-945.
[23]Ji L,Yu H,Wang X l. CO2sequestration by direct mineralisation using fly ash from Chinese Shenfu coal[J]. Fuel processing technology,2017,156:429-437.
[24]宋晓睿,杨辉.空心玻璃微球制备技术研究进展[J].硅酸盐学报,2012,40(3):450-457.
[25]LIANG J Z. Toughening and reinforcing in rigid inorganic particulate filled poly(propylene):A review[J]. J Appl Polym Sci,2002,8(3):1547-1555.
[26]郭新亮.基于粉煤灰磁珠的磁性吸附剂制备及铜吸附研究[D].合肥:安徽理工大学,2016.
[27]李超,王丽萍,郭昭华,等.粉煤灰中锂提取技术研究进展[J].有色金属:冶炼部分. 2018(4):46-50.
[28]郭昭华.粉煤灰“一步酸溶法”提取氧化铝工艺技术及工业化发展研究[J].煤炭工程,2015(7):5-8.
[29]孙培梅,童军武,徐红艳,等.从粉煤灰中提取氧化铝熟料溶出过程工艺研究[J].中南大学学报:自然科学版,2010(5):1698-1702.
[30]王腾飞,张金山,李侠.碱法提取高铝粉煤灰中氧化铝的研究进展[J].矿产综合利用,2019(1):16-20.
[31]唐云,陈福林,刘安荣.燃煤电厂粉煤灰提取氧化铝研究[J].煤炭学报. 2009(1):105-110.
[32]代世峰,任徳贻,周义平,等.煤型稀有金属矿床:成因类型、赋存状态和利用评价[J].煤炭学报,2014(8):1707-1715.
[33]李超,王丽萍,郭昭华,等.盐酸体系下镓的提取技术研究进展[J].稀有金属与硬质合金,2019(1):6-10.
[34] Taggart R K,Hower J C,Hsu-Kim H. Effects of roasting additives and leaching parameters on the extraction of rare earth elements from coal fly ash[J]. International Journal of coal geology,2018,196:106-114.
[35]Li C X,Zhou Y,Tian Y M. Preparation and characterization of mullite whisker reinforced ceramics made from coal fly ash,https://doi. org/10. 1016/j. ceramint. 2018. 12. 021.
[36]Luo Y,Zheng S l,Preparation of sintered foamed ceramics derived entirely from coal fly ash[J]. Construction and building materials,2018,163:529-538.
[37]Zou D,Xu J R,Chen X F,A novel thermal spraying technique to fabricate fly ash/alumina composite membranes for oily emulsion and spent tin wastewater treatment[J]. Separation and purification technology,https://doi. org/10. 1016/j.seppur. 2019. 02. 051.
[38]施云芬,陈媛,张益维,等.粉煤灰负载钒氧化物低温SCR催化剂脱硝性能研究[J].东北电力大学学报,2015(3):59-63.
[39]Jain D,Mishra M,Synthesis and characterization of novel aminopropylated fly ash catalyst and its beneficial application in base catalyzed Knoevenagel condensation reaction[J]. Fuel Processing Technology,2012,95:119-126.
[40]Yang S Y,Liang P,Hua K H. Preparation of carboxylated nitrile butadiene rubber/fly ash composites by in-situ carboxylate reaction[J]. Composites science and technology,2018,167:294-300.
[41]Yang S Y,Liang P,Peng X K. Improvement in mechanical properties of SBR/fly ash composites by in-situ graftingneutralization reaction[J]. Chemical engineering journal,2018,354:849-855.
[42]冯泽平,高钙粉煤灰地质聚合物的制备及耐久性研究[J].矿产保护与利用,2018(2):107-110.
[43]Wang Y C,Zhao J P,Facile preparation of slag or fly ash geopolymer composite coatings with flame resistance[J]. Construction and building materials,2019,203:655-661.
[44]贾敏,池君洲,王永旺,等.粉煤灰酸法提取氧化铝的残渣制备4A分子筛[J].矿产保护与利用. 2017(1):77-83.
[45]李超,王丽萍,郭昭华,等.粉煤灰提铝后尾渣合成13X分子筛及其对Pb2+吸附性能的研究[J].矿产保护与利用,2018(6):98-102.
[46]Hyland M. Preparation of zeolite 4A by using high-alumina coal fly ash[M]. John Wiley&Sons,Inc,2015,119-126.
[47]谢建忠.利用粉煤灰制备泡沫玻璃[J].矿产保护与利用,1999(3):53-54.
[48]Bai J G,Yang X H,Xu S C. Preparation of foam glass from waste glass and fly ash[J]. Materials Letters,2014,136:52-54.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |