纺织品抗紫外整理剂的开发与应用研究
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摘要
随着工业的发展,各种废气对大气的污染曰益加剧,导致地球臭氧层遭到破坏,地表太阳光的紫外线辐射量逐渐增强,对人们的健康造成了损害。因此,国际上非常重视抗紫外功能性织物的开发和研究,纺织品的抗紫外整理成为纺织行业的重要课题之一。
本文针对提高涤、棉织物紫外线防护性能这一目标,选用合适的非离子及阴离子表面活性剂,分别通过乳化、分散的方法复配出了适合于纺织整理加工的新型紫外整理剂(UVS),并对其应用进行了系统的研究。本文选取了空隙率较小的涤纶织物以及棉织物,通过与目前整理效果较好的Rayosan P、Rayosan C、Tinofast PEX、Tinofast CEL等紫外吸收剂的一系列相关对比实验,筛选出了对涤纶整理效果较好的S-61和对棉整理效果较好的S-81。
在研究涤用抗紫外整理剂应用工艺时,通过抗紫外效果对比试验得出了合适的整理工艺,并且做了一系列上染率测试和耐久性试验;将整理剂与分散染料对涤纶同浴染色后,通过测定织物UPF值、K/S值、L、a~*、b~*值以及日晒牢度等指标,讨论了整理剂对涤纶的处理效果和对分散染料的影响。结果表明S-61在合适的工艺条件下对涤纶上染率很高,提升性很好,类似于分散染料对涤纶的上染,可以与分散染料同浴上染涤纶。此外,将整理剂与荧光增白剂对涤纶同浴处理
With the development of industry, pollution for atmosphere has become increasingly serious and ozone layer has been destroyed. Because the increased amount of radiation of ultraviolet in the sunlight is harmful to people's health, the research of ultraviolet protective textile attracts more and more worldwide attention.This research is focused on improving ultraviolet protective ability of polyester and cotton. The surfactants which have good ability of dispersion and emulsification have been selected to compound several different kinds of ultraviolet absorbers. The attempt is made to study the new kinds of UV absorbers (UVS) and to select out S-61(a better UV absorbers on polyester fiber) and S-81(a preferred UV absorbers on cotton) from several newly absorbers together with Rayosan P, Rayosan C, Tinofast PEX, Tinofast CEL, which perform outstandingly in UV protection being used now through a series of comparison experiments.
In the study of application of UV absorbers for Polyester fiber, the absorbers are applied to polyester dyeing together with disperse dyes by one-bath dyeing methods. The influence on polyester treatment and dispersed dyes used is discussed on the data of UPF, K/S, L, a~*, b~* and light fastness. The result shows that S-61 is best applied on polyester and with no adverse effects on dispersed dyes. In this paper, the treatment of UV absorbers and fluorescent whitening agents is applied simultaneously in one bath. UPF and whiteness show that all the used absorbers have some slightly influence on whitening treatment.In the study of application of cotton UV protection treatment, the best padding and curing process of S-81 is attained by controlling pH, temperature, bath-rate and agents. The result is that S-81 can react with cellulose fiber in 100℃ and the bath-rate of 1:10. At the same time, it is also suitable for pad-bake process. Its influence on the degree of white is fairly low. The application of S-61 and S-81 may have promising future.Jianning Wang(Textile Chemistry and Dyeing&Finishing Engineering)Supervised by professor Quan Zhu and professor Xiaoli Chen
本文针对提高涤、棉织物紫外线防护性能这一目标,选用合适的非离子及阴离子表面活性剂,分别通过乳化、分散的方法复配出了适合于纺织整理加工的新型紫外整理剂(UVS),并对其应用进行了系统的研究。本文选取了空隙率较小的涤纶织物以及棉织物,通过与目前整理效果较好的Rayosan P、Rayosan C、Tinofast PEX、Tinofast CEL等紫外吸收剂的一系列相关对比实验,筛选出了对涤纶整理效果较好的S-61和对棉整理效果较好的S-81。
在研究涤用抗紫外整理剂应用工艺时,通过抗紫外效果对比试验得出了合适的整理工艺,并且做了一系列上染率测试和耐久性试验;将整理剂与分散染料对涤纶同浴染色后,通过测定织物UPF值、K/S值、L、a~*、b~*值以及日晒牢度等指标,讨论了整理剂对涤纶的处理效果和对分散染料的影响。结果表明S-61在合适的工艺条件下对涤纶上染率很高,提升性很好,类似于分散染料对涤纶的上染,可以与分散染料同浴上染涤纶。此外,将整理剂与荧光增白剂对涤纶同浴处理
With the development of industry, pollution for atmosphere has become increasingly serious and ozone layer has been destroyed. Because the increased amount of radiation of ultraviolet in the sunlight is harmful to people's health, the research of ultraviolet protective textile attracts more and more worldwide attention.This research is focused on improving ultraviolet protective ability of polyester and cotton. The surfactants which have good ability of dispersion and emulsification have been selected to compound several different kinds of ultraviolet absorbers. The attempt is made to study the new kinds of UV absorbers (UVS) and to select out S-61(a better UV absorbers on polyester fiber) and S-81(a preferred UV absorbers on cotton) from several newly absorbers together with Rayosan P, Rayosan C, Tinofast PEX, Tinofast CEL, which perform outstandingly in UV protection being used now through a series of comparison experiments.
In the study of application of UV absorbers for Polyester fiber, the absorbers are applied to polyester dyeing together with disperse dyes by one-bath dyeing methods. The influence on polyester treatment and dispersed dyes used is discussed on the data of UPF, K/S, L, a~*, b~* and light fastness. The result shows that S-61 is best applied on polyester and with no adverse effects on dispersed dyes. In this paper, the treatment of UV absorbers and fluorescent whitening agents is applied simultaneously in one bath. UPF and whiteness show that all the used absorbers have some slightly influence on whitening treatment.In the study of application of cotton UV protection treatment, the best padding and curing process of S-81 is attained by controlling pH, temperature, bath-rate and agents. The result is that S-81 can react with cellulose fiber in 100℃ and the bath-rate of 1:10. At the same time, it is also suitable for pad-bake process. Its influence on the degree of white is fairly low. The application of S-61 and S-81 may have promising future.Jianning Wang(Textile Chemistry and Dyeing&Finishing Engineering)Supervised by professor Quan Zhu and professor Xiaoli Chen
引文
[1] 金芳.涤/棉织物的防紫外整理 [D] ,2002.1
[2] I.Holme著.徐鹏译.紫外吸收剂的防护性能[J].国外纺织技术,2003,(9):31-33.
[3] Rupp J., Bohringer A., Yonenaga A., Hilden J. Textiles for Protection against Harmful Ultraviolet Radiation [J]. International Textile Bulletin, 2001, 47(6): 8-14.
[4] Palacin F. Textile Finish Protects Against UV Radiation [J]. Melliand Textilberichte/International Textile Reports (German Edition), 1997, 78(7/8): 519-522;E113-E115.
[5] 杨栋梁.紫外线屏蔽整理的近况 [J].印染,2002,(3):28-44.
[6] Haerri H. P, Haenzi D. Ultraviolet Absorbers for Sun-Protective Cotton[J]. International Dyer, 2002, 187(9): 35-36.
[7] Haerri H. P., Haenzi D., Donze J.-J. Application of UV Absorbers for Sun Protective Fabrics [J]. Melliand Textilberichte/International Textile Reports (German Edition), 2001, 82 (1/2): 59-62;E16-E19.
[8] 马明洁等.有效阻断紫外线透过衣物对人体的伤害 [J].日用化学工业,1999,(10) 5:46-48.
[9] Cantrell-M. Sun-screen with style [J]. Textile-Month, 2000, 2: 36-38.
[10] Algaba I., Riva A. In Vitro Measurement of the Ultraviolet Protection Factor of Apparel Textiles [J]. Coloration Technology, 2002, 188(2): 52-58.
[11] Thiry M. C. Here Comes the Sun. AATCCReview [J], 2002, 2(6): 13-16.
[12] 徐路等.纺织品防紫外线性能评定标准的研究[J].新纺织:32-35.
[13] 吴雄英.纺织品抗紫外线辐射性能的测试方法比较[J].印染,2001,(2):38-43.
[14] 金芳 许海育.纺织品的防紫外整理[J].中国纺织:35-37.
[15] 杨栋梁.纺织品的紫外线评比整理(二) [J].印染,21 (6):35-39.
[16] 冯亚青等.助剂化学及工艺学[M].化学工业出版社,1997,(6).
[17] 汉斯·莫利特等著,杨光译.乳液、悬浮液、固体配合技术与应用[M].化学工业出版社,2004,(1).
[18] Sharma D. K., Singh M. Effect of Dyeing and Finishing Treatments on Sun Protection of Woven Fabrics—A Study [J]. Colourage, 2001, 49 (annual): 69-74.
[19] Bohringer B., Schindling G., Schon U., Hanke D., Hoffmann K., Altmeyer P., Klotz M. L. UV Protection by Textiles [J]. Melliand Textilberichte/International Textile Reports (German Edition), 1997, 78(7/8): 522-525;E115-E117.
[20] 谭娴.抗紫外线辐射效果与纺织品特性的关系[J].纺织科学研究:23-26.
[21] 刘晓艳等.防紫外线辐射织物的开发现状[J].中国个体防护装备,2003,(6):21-23.
[22] Hanke-D, Hoffmann-K, Altmeyer-P, Bohringer-B, Schindler-G, Schon-U, Klotz-ML. UV protection by textiles [J]. Chemical-Fibers-International, 47 (2): 130-131.
[23] 沈国先等.紫外线防护及其纺织品[J].现代纺织技技术,2001,9(2):53-55.
[24] Veatch K. D. Gatewood B. M. Influence of Light Exposure on the UV Protection of Direct, Reactive, Acid, and Disperse Dyes on Cotton and Nylon Fabrics [J]. AATCC Review, 2002, 2(2): 47-51.
[25] 荆忠胜.表面活性剂概论[M].中国轻工业出版社,1999,(5).
[26] 罗巨涛.染整助剂及其应用[M].中国纺织出版社,2003,(9).
[27] 李全明等.防紫外线织物的研究 [J].高科技纤维与应用,2002,27(6):19-21.
[28] 徐英莲等.纺织品的紫外线防护性能研究 [J].丝绸,2002,(4):14-16.
[29] 有防护性能的紫外线吸收剂[J].现代纺织技术,2004,(2):51-52.
[30] 唐增荣等.抗紫外线整理剂DP—UV的研制和应用 [J] ,印染,2000.(5):30-33.
[31] 严玉蓉等。紫外吸收剂及紫外屏蔽纤维/织物的发展[J].产业用纺织品,2001,(8):5-8.
[32] 徐步斌.苯并三唑类紫外线吸收剂的台成[J].华东理工大学学报,1997,23(2):58-62.
[33] Bajaj P., Kothari V. K., Ghosh S. B. Some Innovations in UV Protective Clothing [J].Indian Journal of Fibre & Textile Research, 2000, 25(4): 315-329.
[34] 王锦成等.纳米材料在化学纤维中的应用[J].印染,2004,(7):45-48.
[35] 常涛.抗紫外线纺织品[J].陕西纺织,2002,(4):35-38.
[36] 李昕.纺织品的防紫外线辐射整理[J].染整科技,2003,(4):4—11.
[2] I.Holme著.徐鹏译.紫外吸收剂的防护性能[J].国外纺织技术,2003,(9):31-33.
[3] Rupp J., Bohringer A., Yonenaga A., Hilden J. Textiles for Protection against Harmful Ultraviolet Radiation [J]. International Textile Bulletin, 2001, 47(6): 8-14.
[4] Palacin F. Textile Finish Protects Against UV Radiation [J]. Melliand Textilberichte/International Textile Reports (German Edition), 1997, 78(7/8): 519-522;E113-E115.
[5] 杨栋梁.紫外线屏蔽整理的近况 [J].印染,2002,(3):28-44.
[6] Haerri H. P, Haenzi D. Ultraviolet Absorbers for Sun-Protective Cotton[J]. International Dyer, 2002, 187(9): 35-36.
[7] Haerri H. P., Haenzi D., Donze J.-J. Application of UV Absorbers for Sun Protective Fabrics [J]. Melliand Textilberichte/International Textile Reports (German Edition), 2001, 82 (1/2): 59-62;E16-E19.
[8] 马明洁等.有效阻断紫外线透过衣物对人体的伤害 [J].日用化学工业,1999,(10) 5:46-48.
[9] Cantrell-M. Sun-screen with style [J]. Textile-Month, 2000, 2: 36-38.
[10] Algaba I., Riva A. In Vitro Measurement of the Ultraviolet Protection Factor of Apparel Textiles [J]. Coloration Technology, 2002, 188(2): 52-58.
[11] Thiry M. C. Here Comes the Sun. AATCCReview [J], 2002, 2(6): 13-16.
[12] 徐路等.纺织品防紫外线性能评定标准的研究[J].新纺织:32-35.
[13] 吴雄英.纺织品抗紫外线辐射性能的测试方法比较[J].印染,2001,(2):38-43.
[14] 金芳 许海育.纺织品的防紫外整理[J].中国纺织:35-37.
[15] 杨栋梁.纺织品的紫外线评比整理(二) [J].印染,21 (6):35-39.
[16] 冯亚青等.助剂化学及工艺学[M].化学工业出版社,1997,(6).
[17] 汉斯·莫利特等著,杨光译.乳液、悬浮液、固体配合技术与应用[M].化学工业出版社,2004,(1).
[18] Sharma D. K., Singh M. Effect of Dyeing and Finishing Treatments on Sun Protection of Woven Fabrics—A Study [J]. Colourage, 2001, 49 (annual): 69-74.
[19] Bohringer B., Schindling G., Schon U., Hanke D., Hoffmann K., Altmeyer P., Klotz M. L. UV Protection by Textiles [J]. Melliand Textilberichte/International Textile Reports (German Edition), 1997, 78(7/8): 522-525;E115-E117.
[20] 谭娴.抗紫外线辐射效果与纺织品特性的关系[J].纺织科学研究:23-26.
[21] 刘晓艳等.防紫外线辐射织物的开发现状[J].中国个体防护装备,2003,(6):21-23.
[22] Hanke-D, Hoffmann-K, Altmeyer-P, Bohringer-B, Schindler-G, Schon-U, Klotz-ML. UV protection by textiles [J]. Chemical-Fibers-International, 47 (2): 130-131.
[23] 沈国先等.紫外线防护及其纺织品[J].现代纺织技技术,2001,9(2):53-55.
[24] Veatch K. D. Gatewood B. M. Influence of Light Exposure on the UV Protection of Direct, Reactive, Acid, and Disperse Dyes on Cotton and Nylon Fabrics [J]. AATCC Review, 2002, 2(2): 47-51.
[25] 荆忠胜.表面活性剂概论[M].中国轻工业出版社,1999,(5).
[26] 罗巨涛.染整助剂及其应用[M].中国纺织出版社,2003,(9).
[27] 李全明等.防紫外线织物的研究 [J].高科技纤维与应用,2002,27(6):19-21.
[28] 徐英莲等.纺织品的紫外线防护性能研究 [J].丝绸,2002,(4):14-16.
[29] 有防护性能的紫外线吸收剂[J].现代纺织技术,2004,(2):51-52.
[30] 唐增荣等.抗紫外线整理剂DP—UV的研制和应用 [J] ,印染,2000.(5):30-33.
[31] 严玉蓉等。紫外吸收剂及紫外屏蔽纤维/织物的发展[J].产业用纺织品,2001,(8):5-8.
[32] 徐步斌.苯并三唑类紫外线吸收剂的台成[J].华东理工大学学报,1997,23(2):58-62.
[33] Bajaj P., Kothari V. K., Ghosh S. B. Some Innovations in UV Protective Clothing [J].Indian Journal of Fibre & Textile Research, 2000, 25(4): 315-329.
[34] 王锦成等.纳米材料在化学纤维中的应用[J].印染,2004,(7):45-48.
[35] 常涛.抗紫外线纺织品[J].陕西纺织,2002,(4):35-38.
[36] 李昕.纺织品的防紫外线辐射整理[J].染整科技,2003,(4):4—11.
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