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云南某铅锌矿浮选工艺优化研究
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摘要
云南某铅锌矿,原矿含铅1.46%、铅的氧化率为51.28%,含锌4.38%、锌的氧化率为11.75%。由于原矿性质变化,出现了铅精矿品位不高,仅38.38%,铅精矿含锌6.84%,含锌较高的问题,所以要对原有的工艺流程进行优化研究。
     探索性试验表明,原矿中方铅矿的可浮性较好,铅回收率低,有20%左右的易浮闪锌矿,这部分闪锌矿可能会使铅锌分离困难,铅精矿品位不高,铅精矿含锌高。
     由于通常情况下,混合浮选具有节省浮选机、回水利用方便、节省浮选药剂等优点,因此首先进行了混合浮选工艺研究。试验发现,混合精矿铅锌分离效果不好,铅锌互含严重。针对混合精矿不经脱药处理,不能有效进行铅锌分离的问题,进行了混合精矿脱药再磨铅锌分离、硫化钠脱药活性炭吸附铅锌分离试验,所做试验效果均不理想。通过常规的脱药方法,铅锌分离仍不理想。
     为了得到合格的铅精矿和锌精矿,进行了优先浮选工艺优化研究。优先浮选试验发现,铅精矿品位及回收率低、铅精矿含锌高。在分析了可能原因的基础上进行了抑制剂对比、抑制剂加药地点对比、提高铅精矿品位、阶段磨矿阶段选别等工艺优化研究,铅精矿的指标有所改善,但是存在的问题并未根本解决。提高铅回收率的试验研究中,通过在浮选前加入适量的硫化钠,使易浮的氧化铅随硫化铅一起浮出,以提高铅的回收率。硫化钠加在磨机中,不仅铅品位与回收率明显提高,而且铅精矿含锌量也有下降的趋势。进一步试验表明,随着硫化钠用量的增加,铅的回收率变化不大,但是铅品位提高了2个百分点以上,而且含锌量有了大幅度的降低。
     推荐流程为优先浮选工艺,采取的优化措施是向磨机中添加碳酸钠、硫化钠各2000克/吨,以及在铅精选过程中添加闪锌矿的抑制。闭路试验获得了品位41.56%、回收率45.80%、含锌3.86%的铅精矿和品位55.65%、回收率83.73%、含铅1.47%的锌精矿。铅精矿的指标不够理想,锌精矿的指标较好。与原工艺流程相比,铅精矿品位提高了3个百分点以上,铅精矿含锌降低了近3个百分点,缓解了铅精矿含锌偏高的问题,但是铅精矿的品位、铅的回收率仍然不高,有待于进一步的研究。
The lead-zinc ore locates in a certain place of Yunnan province, of which the crude ore includes 1.46% of lead,51.28% oxidation rate of the zinc,4.38% of zinc, and 11.75% oxidation rate of zinc. Because of the problems of the low grde of lead concentrate,only 38.38% , and the high grade of zinc,6.84% hapenning due to the characteristic of the crude ore changed, so it is necessary to improve the old process flowsheet.
     The exploring tests prove that the galena of the crude ore is floatable comparatively, the recovery of lead is low, and the low grade concentrate of lead includes quite a little zinc since the difficulty of separating lead and zinc due to about 20% easy floatable sphalerite in crude ore.
     Firstly, the study of collective flotation is carried out because of many advantages for using collective flotation, such as reducing the numbers of floatation machine, convenience of recycling water and saving reagent and so on. By the tests, it is found that the results of separating lead and zinc is not very satisfactory, and lead-zinc includes each other seriously. For the problems of Inefficient lead-zinc separating without dereagent,the lead-zinc separating tests by regrinding the collective concentrate, and by reagent removal with Na2S, adsorption with carbon.But the results are not good. The separation of lead and zinc is still difficult by using conventional way of reagent removal.
     For reaching regular concentration of lead and zinc, we had a preferential flotation test for optimization of process.Through the experiment on selective flotation, we found that the grade and recovery of lead concentrate is low, and the grade of zinc is high in lead concentrate. On the base of analyzing the possibility, the experiments on technology optimum that is the comparisons of inhibitors and its locations, raising the quality of the lead concentrate, and stage grinding and stage separation are carried out. Tough the index of lead concentrate is enhanced, the radical solution is still unsolved. In the experimental study of raising the recovery of lead, optimum Na2s is added before the flotation, and easily floatated plumbous oxide and plumbous sulfide is flotated together. When sodium sulfide is fed in the milling pit, not only the grade and recovery of lead is graduated up remarkably, but also the zinc contents of lead concentrate is lower. Further investigate shows that recovery of lead varies a little, while grade of that raises more than 2% and zinc contents are lower markedly along with increase of sodium sulfide.
     The flow recommended is selective flotation,It is reached that the lead grade of 41.56%,recovery of 45.80%,and contents 3.86% of zinc in lead concentrate,and that of zinc concentrate is the zinc grade of 55.65%,recovery of 83.73%,and contents 1.74% of lead by the test of closed ciruit. The former is not sastisfactory enough, but the latter is better.by means of which the grade of lead is raised above 3% and that of zinc reduced about 3% respectively compared with the old one, and the solution of high grade of zinc in lead concentrate is improved. But more research is still need to be carried out because the grade and recovery of lead concentrate are low.
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