镍基非晶态合金纳米颗粒材料的制备、结构与电催化性能研究
|
摘要
本文研究基于增强Ni-B非晶态合金纳米颗粒的抗氧化性、热稳定性,抑制晶化和团聚,及拓展Ni-B非晶态合金纳米颗粒的应用新领域。主要研究内容及结果如下:
1.在水溶液体系中以化学还原法制得平均粒径约10nm的Ni-B和Ni-Mo-B非晶态合金团聚态纳米颗粒。Ni-Mo-B非晶态合金的晶化温度及热稳定性明显高于Ni-B非晶态合金。XPS分析结果表明Ni-Mo-B非晶态合金具有优异的抗氧化性能。
2.应用循环伏安法首次研究了碱性介质中Ni-B非晶态合金纳米粉末微电极上甲醇、乙醇及正丙醇的电催化氧化。结果表明,Ni-B非晶态合金纳米粉末微电极对甲醇、乙醇及正丙醇的电催化氧化活性显著优于镍纳米线电极、高择优取向(220)镍电极。在含伯醇的1 mol·L~(-1)KOH溶液中,Ni-B非晶态合金纳米粉末微电极上Ni(Ⅱ)氧化起始电位较高择优取向(220)镍电极负移了0.04V,其氧化峰电位也明显负移,氧化电流密度高出高择优取向(220)镍电极约2个数量级。通过测定稳态极化曲线计算出Ni-B非晶态合金纳米粉末微电极上甲醇、乙醇及正丙醇的电氧化动力学参数。与高择优取向(220)镍电极比较,Ni(Ⅲ)与甲醇、乙醇及正丙醇反应的速率常数、Ni(Ⅱ)氧化为Ni(Ⅲ)及其逆反应的速率常数依次约大2个、3个和2-3个数量级。
Ni-B非晶态合金纳米粉末微电极上Ni(Ⅱ)氧化起始电位和氧化峰电位明显低于Ni-B纳米晶粉末微电极和化学镀Ni-B非晶态合金微盘电极,表明Ni-B非晶态合金纳米粉末微电极具有较高的电催化活性与其特有的非晶特性和纳米特性有关。
3.将反相微乳液法引人非晶态合金的制备中,获得了基本呈单分散、尺度在10-15nm且分布较均匀的Ni-B和Ni-La-B非晶态合金团簇,这是迄今为止单分散尺寸最小的非负载型非晶态合金团簇。Ni-B和Ni-La-B非晶态合金的晶化均存在2个相变过程:Ni-La-B非晶态合金晶化成Ni-La-B晶态合金和Ni-La-B晶态合金转化成纳米晶Ni-La和单质B,通过测定相转变活化能表明后1个步骤的反应速率比前1个快。
4.Ni-B非晶态合金纳米粉末微电极的吸氢能力、析氢活性及对环已酮的电催化加氢活性显著高于高比表面镍微电极,电催化加氢反应在弱吸附氢和环已酮之间进行,而不可还原的β-Ni(OH)_2的生成会抑制Ni-B非晶态合金纳米微电极的电催化加氢活性。
The research objectives of this dissertation are to increase antioxidation ability and thermal stability of the Ni-B amorphous alloy nanoclusters,to inhibit its crystallization and agglomeration,and to expand its application field.The main research contents and results are summarized as below:
1.The Ni-B and Ni-Mo-B amorphous alloys powders with a size of around 10nm were prepared by chemical reduction with KBH_4 in aqueous solution.The Ni-Mo-B alloy exhibits better thermal stability and stronger antioxidation ability than the Ni-B alloy.
2.Electrocatalytic oxidation of methanol,ethanol and propanol on the nanosize Ni-B amorphous alloy powdermicroelectrode in alkaline media was studied with cyclic voltammetry.It is shown that the nanosize Ni-B amorphous alloy powdermicroelectrode has stronger electrocatalytic activities for the oxidation of methanol,ethanol and propanol than Ni nanowire electrode,highly preferred orientation(220)nickel electrode.Compared to highly preferred orientation(220)nickel electrode,in 1 mol·L~(-1)KOH solution containing primary alcohols,the onset potential of Ni(Ⅱ)oxidation on the nanosize Ni-B amorphous alloy powdermicroelectrode is negatively shifted about 0.04V with peak potential showing a considerable decrease,and the current densities of Ni(Ⅱ)oxidation are increased approximately by the 2 orders of magnitude.The kinetic parameters were determined with the steady polarization curves.The results show that the rate constants for the oxidation of methanol,ethanol and propanol by Ni(Ⅲ),the rate constants for the oxidation of Ni(Ⅱ)to Ni(Ⅲ)and the rate constants for the reduction of Ni(Ⅲ)to Ni(Ⅱ)on the nanosize Ni-B amorphous alloy powdermicroelectrode are increased by about 2,3,2-3 orders of magnitude,respectively,in comparison with those on the highly preferred orientation(220)nickel electrode.
The onset potential and peak potential of Ni(Ⅱ)oxidation on the nanosize Ni-B amorphous alloy powdermicroelectrode are lower than those on the Ni-B nanocrystalline powdermicroelectrode and the electroless Ni-B amorphous alloy microdisk electrode.Thus,the strong electrocatalytic activity of the nanosize Ni-B amorphous alloy powdermicroelectrode is concerned with its nanometer properties and amorphous properties.
3.The nearly monodispersed Ni-B and Ni-La-B amorphous alloys nanoclusters with a size of around 10-15nm and an even size distribution,that is the smallest monodispersed size of the unsupported amorphous alloy nanoclusters so far,were prepared in W/O microemulsion.The crystallization process of Ni-La-B amorphous alloy nanoclusters includes the two steps:one is the transformation of Ni-La-B amorphous alloy into Ni-La-B crystalline alloy,the other is the decomposition of Ni-La-B crystalline alloy into Ni-La nanocrystalline and free B.It is found that the rate of the latter is higher than the former through determining phase transition activation energy.
4.The activities of hydrogen adsorption and evolution of the nanosize Ni-B amorphous alloy powdermicroelectrode and its activity of electrocatalytic hydrogenation(ECH)for cyclohexanone are stronger than high surface area nickel microelectrode.The ECH reaction occurs between the weakly chemisorbed H atoms and cyclohexanone.The activity of ECH is depressed by the formation of irreducibleβ-Ni(OH)_2.
1.在水溶液体系中以化学还原法制得平均粒径约10nm的Ni-B和Ni-Mo-B非晶态合金团聚态纳米颗粒。Ni-Mo-B非晶态合金的晶化温度及热稳定性明显高于Ni-B非晶态合金。XPS分析结果表明Ni-Mo-B非晶态合金具有优异的抗氧化性能。
2.应用循环伏安法首次研究了碱性介质中Ni-B非晶态合金纳米粉末微电极上甲醇、乙醇及正丙醇的电催化氧化。结果表明,Ni-B非晶态合金纳米粉末微电极对甲醇、乙醇及正丙醇的电催化氧化活性显著优于镍纳米线电极、高择优取向(220)镍电极。在含伯醇的1 mol·L~(-1)KOH溶液中,Ni-B非晶态合金纳米粉末微电极上Ni(Ⅱ)氧化起始电位较高择优取向(220)镍电极负移了0.04V,其氧化峰电位也明显负移,氧化电流密度高出高择优取向(220)镍电极约2个数量级。通过测定稳态极化曲线计算出Ni-B非晶态合金纳米粉末微电极上甲醇、乙醇及正丙醇的电氧化动力学参数。与高择优取向(220)镍电极比较,Ni(Ⅲ)与甲醇、乙醇及正丙醇反应的速率常数、Ni(Ⅱ)氧化为Ni(Ⅲ)及其逆反应的速率常数依次约大2个、3个和2-3个数量级。
Ni-B非晶态合金纳米粉末微电极上Ni(Ⅱ)氧化起始电位和氧化峰电位明显低于Ni-B纳米晶粉末微电极和化学镀Ni-B非晶态合金微盘电极,表明Ni-B非晶态合金纳米粉末微电极具有较高的电催化活性与其特有的非晶特性和纳米特性有关。
3.将反相微乳液法引人非晶态合金的制备中,获得了基本呈单分散、尺度在10-15nm且分布较均匀的Ni-B和Ni-La-B非晶态合金团簇,这是迄今为止单分散尺寸最小的非负载型非晶态合金团簇。Ni-B和Ni-La-B非晶态合金的晶化均存在2个相变过程:Ni-La-B非晶态合金晶化成Ni-La-B晶态合金和Ni-La-B晶态合金转化成纳米晶Ni-La和单质B,通过测定相转变活化能表明后1个步骤的反应速率比前1个快。
4.Ni-B非晶态合金纳米粉末微电极的吸氢能力、析氢活性及对环已酮的电催化加氢活性显著高于高比表面镍微电极,电催化加氢反应在弱吸附氢和环已酮之间进行,而不可还原的β-Ni(OH)_2的生成会抑制Ni-B非晶态合金纳米微电极的电催化加氢活性。
The research objectives of this dissertation are to increase antioxidation ability and thermal stability of the Ni-B amorphous alloy nanoclusters,to inhibit its crystallization and agglomeration,and to expand its application field.The main research contents and results are summarized as below:
1.The Ni-B and Ni-Mo-B amorphous alloys powders with a size of around 10nm were prepared by chemical reduction with KBH_4 in aqueous solution.The Ni-Mo-B alloy exhibits better thermal stability and stronger antioxidation ability than the Ni-B alloy.
2.Electrocatalytic oxidation of methanol,ethanol and propanol on the nanosize Ni-B amorphous alloy powdermicroelectrode in alkaline media was studied with cyclic voltammetry.It is shown that the nanosize Ni-B amorphous alloy powdermicroelectrode has stronger electrocatalytic activities for the oxidation of methanol,ethanol and propanol than Ni nanowire electrode,highly preferred orientation(220)nickel electrode.Compared to highly preferred orientation(220)nickel electrode,in 1 mol·L~(-1)KOH solution containing primary alcohols,the onset potential of Ni(Ⅱ)oxidation on the nanosize Ni-B amorphous alloy powdermicroelectrode is negatively shifted about 0.04V with peak potential showing a considerable decrease,and the current densities of Ni(Ⅱ)oxidation are increased approximately by the 2 orders of magnitude.The kinetic parameters were determined with the steady polarization curves.The results show that the rate constants for the oxidation of methanol,ethanol and propanol by Ni(Ⅲ),the rate constants for the oxidation of Ni(Ⅱ)to Ni(Ⅲ)and the rate constants for the reduction of Ni(Ⅲ)to Ni(Ⅱ)on the nanosize Ni-B amorphous alloy powdermicroelectrode are increased by about 2,3,2-3 orders of magnitude,respectively,in comparison with those on the highly preferred orientation(220)nickel electrode.
The onset potential and peak potential of Ni(Ⅱ)oxidation on the nanosize Ni-B amorphous alloy powdermicroelectrode are lower than those on the Ni-B nanocrystalline powdermicroelectrode and the electroless Ni-B amorphous alloy microdisk electrode.Thus,the strong electrocatalytic activity of the nanosize Ni-B amorphous alloy powdermicroelectrode is concerned with its nanometer properties and amorphous properties.
3.The nearly monodispersed Ni-B and Ni-La-B amorphous alloys nanoclusters with a size of around 10-15nm and an even size distribution,that is the smallest monodispersed size of the unsupported amorphous alloy nanoclusters so far,were prepared in W/O microemulsion.The crystallization process of Ni-La-B amorphous alloy nanoclusters includes the two steps:one is the transformation of Ni-La-B amorphous alloy into Ni-La-B crystalline alloy,the other is the decomposition of Ni-La-B crystalline alloy into Ni-La nanocrystalline and free B.It is found that the rate of the latter is higher than the former through determining phase transition activation energy.
4.The activities of hydrogen adsorption and evolution of the nanosize Ni-B amorphous alloy powdermicroelectrode and its activity of electrocatalytic hydrogenation(ECH)for cyclohexanone are stronger than high surface area nickel microelectrode.The ECH reaction occurs between the weakly chemisorbed H atoms and cyclohexanone.The activity of ECH is depressed by the formation of irreducibleβ-Ni(OH)_2.
引文
[1]Luborsky F.E.Amorphous metallic allays[M].London:Butterworth,1983.
[2]Makino A.,Inoue A.,Mizushima T.Soft magnetic properties of Fe-based bulk amorphous alloys[J].Materials Transactions,2000,41(11):1471-1477.
[3]Lu Z.P.,Liu C.T.,Carmichael C.A..Bulk glass formation in an Fe-based Fe-Y-Zr-M(M =Cr,Co,Al)-Mo-B system[J].Journal of Materials Research,2004,19(3):921-929.
[4]Inoue A,Takeuchi A..Recent progress in bulk glassy alloys[J].Materials Transactions,2002,43(8):1892-1906.
[5]张程煜,姚可夫.Cu64Zr36非晶合金的晶化动力学[J].稀有金属材料与工程,2006,35(1):158-160.
[6]熊中强,米镇涛,张香文.非晶态合金催化剂研究[J].化学进展,2005,17(4):614-621.
[7]Jacgues V.W.,Steen M.,Christian J.W.K.,et al.Formation of ultra-fine amorphous alloy patricles by reduction in aqueous solution[J].Nature,1986,322:622-623.
[8]闵思泽,李成岳.绿色石化技术的科学与工程基础[M].北京:中国石化出版社,2002
[9]陆关兴,陈绯,奕英豪.非晶态合金带力学性能的评价[J].玻璃钢/复合材料,1995,(3):28-31.
[10]Osaka T.,Kaoki N.,Koiwa I..A Preparation of perpendicular magnetic recording media by an electroless plating method[J].J.Electrochem.Sot.,1983,130(3):568-571.
[11]姜晓霞,沈伟.化学镀理论及实践[M].北京:国际工业出版社,2000.
[12]王森林.多元合金的化学沉积及镀层结构与性能研究[D].厦门大学化学系,2005.
[13]Ruggeri S.,Cyril Lenain,et al.Mechanically driven crystallization of amorphous MgNi..alloy during prolonged milling:applications in Ni-MH batteries[J].J Alloys Comp.,2002,339:195-201.
[14]Lei Y.Q.,Wu Y.M.,et al..Electrochemical behaviour of some mechanically alloyed Mg-Ni based amorphous hydrogen storage alloys[J].Z Phys.Chem.,1994,183:1419.
[15]Orimo S.,Fujii H..Material science of Mg-Ni-based new hydrides[J].Appl.Phys.A,2001,72:167-186.
[16]Varga M.,Mulas G.,Cocco G.,et al.Binary and ternary amorphous palladium alloys:Characterization,activity and selectivity in hydrogenation of dienes[J].Materials Science and Engineering A,2001,304-306:462-466.
[17]黄令.功能性电沉积层的形成、结构与性能研究[D].厦门大学化学系,1997.
[18]李庆伟等.非晶态合金催化剂的研究[J].化工生产与技术,2001,8(6):30-33.
[19]Coteron A.,Haghurst A.N.Synthesis by Amorphous Coppper-based Catalysts Prepared by Spark-erosion[J].Appl.Catal.A,1993,101:151-165.
[20]Wang W.J.,Qiao M.H.,Yang J.,et al.Slective Hydrogenation of Cyclopentadiene to cyclopentene over an Amorphous Ni-B/SiO2 Catalysts[J].Applied Catalysis A:General,1997,163(1/2):101-107.
[21]马爱增,陆婉珍,闵恩泽.含金属添加剂的负载型NiB非晶态合金催化剂的结构及催化性能[J].石油化工,2000,29(3):179-183.
[22]李江,乔明华,邓景发.前驱体干燥法对非晶态Ni—B/γ—A 1203催化剂性能的影响[J].高等学校化学学报,2001,22(6):1022-1024.
[23]Takahashi T.,Kai T.Hydrogenation Catalysts Prepared from Amorphous Alloys with Zirconium[J].Materials Science and Engineering A,1999,267:207-213.
[24]王明辉,李和兴,邓景发.超细Co-B非晶态合金的制备及其催化乙腈加氢性能[J].催化学报,1999,20:548-552.
[25]Li H.,Xu Y.,Deng J.F..Selective hydrogenation of adiponitrile over a Raney Ni-P amorphous catalyst[J].New J chem.,1999,23(1):1059-1061.
[26]Yu X.,Li H.,Deng J.F..Selective hydrgenation of adiponitrile over a skeletal Ni-P amorphous catalyst(Raney Ni-P)at atom pressure[J].Appl.Catal.A,2000,199:191-198.
[27]Li M.,Wang W.,Li M.,et al..Crystallization deactivation of Ni-P/SiO_2 amorphous catalyst and the stabilizing effect of silica support on th Ni-P amorphous structure.J Catal.,2000,194:211-221.
[28]Li H.,Li H.,Wang W.,et al.Excellent activity of ultrafine Co-B amorphous alloy catalyst in glucose hydrogenation.Chem.Lett.,1999,7:629-630.
[29]Inoue A..Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta Materialia,2000,48:279-306.
[30]Takeuchi A.,Inoue A.Calculations of mixing enthalpy and mismatch entropy for ternary [J].Materials Transactions,2000,41(11)1372-1378.
[31]Egami T..Universal Criteriom for Metallic Glass Formation[J].Material Science and Engineering,1997,A226-228:261-267.
[32]Egami T.Atomistic mechanism of bulk metallic glass formation[J].J.Non-tryst.Solids,2003,317:30-33.
[33]Miracle D.B.,Senkov O.N..Topological criterion for metallic glass formatiom [J].Materials Science and Engineering,2003,A 347:50-58.
[34]Senkov O.N.,Scott J.M.Specific criteria for selection of alloy composition for bulk metallic glasses[J].Scripta Materiallia,2004,50:449-452.
[35]董闯,王英敏,恙建兵等.大块非晶合金成分设计方法.中国专利,No.01128027.1,2001.
[36]王玲玲,黄维清,彭军等.机械合金化多元非晶态合金形成规律研究[J].稀有金属材料与工程,2005,34(1):17-21.
[37]王玲玲,黄维清,李小凡等.化学镀多元非晶态合金形成规律探讨[J].金属学报,2002,38(1):84-90.
[38]王玲玲,彭军,唐黎明等.电沉积制备多元非晶合金形成规律研究[J].稀有金属材料与工程,2004,33(2):113-119.
[39]王一禾,杨膺善.非晶态合金[M].北京:冶金工业出版社,1989:2-26.
[40]Li Y.,Ng S.N.,Ong C.K.,et al.Glass forming ability of bulk glass forming alloys[J].Scripta Material,1997,36(7):783-787.
[41]Davies H.A..Amorphous metallic alloys[M].London:Metal Society,1978,312-356.
[42]Lu Z.P.,Liu C.T..A new glass-forming ability criterion for bulk metallic glasses [J].Acta Mater.,2002,50:3501-3512.
[43]Senkov O.N.,Miracle D.B..A topological model for metallic glass formation[J].Journal of Non-Crystalline Solids,2003,317:34-39.
[44]阎子峰.纳米催化技术[M].北京,化学工业出版社,2003.
[45]张立德,牟季美,纳米材料和纳米结构[M].北京,科学出版社,2001.
[46]徐滨士.纳米表面工程[M].北京,化学工业出版社,2004.
[47]张锡凤,殷恒波,程晓农等.纳米镍的制备方法及在催化领域的应用[J].化学与生物工程,2005,(10):8-10.
[48]张志煜,崔作林.纳米技术与纳米材料[M].北京,国际工业出版社,2000.
[49]屈子梅.羰基法生产纳米镍粉[J].粉末冶金工业,2003,13(5):16-19.
[50]Tepper F..Nanosize powders procluced by electro-explosion of wire and their potential application[J].Power Metal,2000,43(4).
[51]Teng M.H.,Host J.J.,Hwang J.-H.,Elliott B.R.,Weertman J.R.,Mason T.O.,Dravid V.P.,Johnson D.L..Nanophase Ni particles produced by a blown arc method[J].Journal of Materials Research,1995,10(2):233-236.
[52]Chou K.S.,Huang K.C..Studies on the chemical synthesis of nanosized nickel powder and its stability[J].Joumal of Nanoparticle Research,2001,(3):127-132.
[53]张楠,翟秀静,翟玉春.纳米Ni-Co合金粉末的溶液还原法制备与表征[J].中国有色金属学报,1998,8(2):39-42.
[54]Lee S.P.,Chen Y.W..Selective hydrogenation offurfural on N-P,Ni-B,and Ni-P-B ultrafinematerials[J].Ind.Eng.Chem.Res.,1999,38(7):2548-2556.
[55]Lee S.P.,Chen Y.W..Effects of preparation on the catalytic properties of Ni-P-B ultrafine materials[J].Ind.Eng.Chem.Res.,2001,40(6):1495-1499.
[56]Fievet F.,Logier J.P..Homogeneous and heterogeneous nucleations in the polyol process for the preparation of micron and submicron size metal particles[J].Solid State Ionics,1989,32/33:98-103.
[57]Ayyappan S.,Subbanna G.N.,Gopalan R.,et al.Nanoparticles of nickel and Silver Produced by the polyol reduction of the metal salts intercalated in montmorillonite[J].Solid State Ionics,1996,84(3-4):271-281.
[58]Hegde M.S.,Laicher D..Synthesis and chemical reactivity of polyol prepared monodisperse nickel poders[J].Solid State Ionics,1997,93:33-50.
[59]齐艳妮,殷德宏,王秀平等.乙二醇溶剂中纳米镍的制备研究[J].材料科学与工程学报,2005,23(3):416-421.
[60]Anne Duteil,Gunter Schmid,Wolfgang Meyer-Zaika.Ligand stabilized nickel colloids[J].Journal of the Chemical Society,Chemical Communications,1995,(1):31.
[61]徐菊,喻克宁,梁焕珍等.用Ni(OH)_2浆化氢还原法制备纳米金属镍粉的反应机制[J].材料研究学报,2002,16(2):158.
[62]Wada Y.,Sakata T.,Mori H.,Sumida T.,Kitamura T.,Yanagida S.,Kuramoto H..Preparation of nano-sized nickel metal particles by microwave irradiation[J].Chemistry Letters,1999,28(7):607-608.
[63]Capek I..Preparation of metal nanoparticles in water-in-oil(W/O)microemulsion [J].Advances in Colloid and Interface Science,2004,110:49-74.
[64]Martin J.E.,Wilcoxon J.P.,Odinek J.,et al..Control of the Interparticle spacing in Gold Nanoparticle superlattics[J].J.Phys.Chem.B,2000,104(40):9475-9486.
[65]Martin J.E.,Wilcoxon J.P.,Odinek J.,et al..Superlattics of Platinum and Palladium Nanopartices[J].J.Phys.Chem.B,2002,106(5):971-978.
[66]Wilcoxon J.P.,Provencio P.P..Use of surfactant micelles to Control the structural phase of nanosize iron clusters[J].J.Phy.Chem.B,1999,103(45):9809-9812.
[67]Taleb A.,Petit C.,Pileni M.P.Optical Properties of Self-Assembled 2D and 3D Superlattices of Silver Nanoparticles[J].J.Phys.Chem.B.,1998,102(12):2214-2220.
[68]Petit C.,Taleb A.,Pileni M.P.Cobalt Nanosized Particles Organized in a 2D Superlattice:Synthesis,Characterization,and Magnetic Properties[J].J.Phys.Chem.B,1999,103:1805-1810.
[69]Legrand J.,Petit C.,Pileni M.P.Domain Shapes and Superlattices Made of 8 nm Cobalt Nanocrystals:Fabrication and Magnetic Properties[J].J.Phys.Chem.B,2001,105:5643-5646.
[70]Martino A.,Stokel M.,Hicks M.,et al.The synthesis and characterization of iron colloid catalysts in inverse micelle solutions[J].Appl.Catal.A:General,1997,161:235.
[71]Chen D.H.,Wu S.H..Synthesis of nickel nanoporticles in water-in-oil microemulsions[J].Chem.Mater.,2000,12(5):1354-1360.
[72]Ni X.M.,Su X.B.,Yang Z.P.,et al..The Preparation of Nickel nanorods in water-in-oil microemulsion[J].Joumal of Crystal Grouth,2003,252:612-617.
[73]M.Arturo Lopez-Quintela,Jose Rivas.Chemical Reactions in Microemulsions:A Powerful Method to Obtain Ultrafine Particles[J].Journal of Colloid and Interface Science,1993,158:446-451.
[74]张朝平,邓伟,胡林等.微乳液法制备超细Ni-Fe复合物微粒[J].无机材料学报,2001,16(3):481-485.
[75]胡林,张朝平.镍/铁复合纳米微粒中与粒径相关的控制参数及磁性能分析[J].化学物理学报,2001,14(5):518-522.
[76]Legrand J.,Taleb A.,Gota S.,et al.Synthesis and XPS Characterization of Nickel Boride Nanoparticles[J].Langmuir,2002,18(10):4131-4137.
[77]Chatterjee A.,Chakravorty D.[J].J.Mater.Sci.,1992,50:566.
[78]Kapoor S.,Salunke H.G.,Tripathil A.K.,et al..Radiolytic preparation and catalytic properties of nanophase nickel metal Particles[J].Materials Research Bulletin,2000,35:143-148.
[79]陈祖耀,陈畋,朱英杰等.γ-射线辐射从溶液环境中制得金属镍超细粉的晶粒度和磁学性质[J].化学物理学报,1997,10(1):26-30.
[80]Wang F.,Zhang Z.C.,Chang Z.Q..Effects of magnetic field on the morphology of nickel nanocrystals prepared by gamma-irradiation in aqueous solution[J].Materials Letters,2002,55(1-2):27-29.
[81]何峰,汪武祥,韩雅芳等.制备超细金属粉末的新型电解法[J].粉末冶金技术,2001, 19(2):80-82.
[82]Mishra R.S.,Valiev R.Z.,Mcfadden S.X.,et al..Severe plastic deformation processing and high strain rate superplasticity in an aluminum matix composite[J].Scripta Materialia,1990,40(1):1151-1155.
[83]王文平,高燕,薛群基等.电沉积镍纳米晶材料制备及性能[J].电镀与涂饰,2004,23(3):1-2.
[84]Delplancke J.L.,Dille J.,Reisse J.,et al..Magnetic nanopowders:ultrasound-assisted electrochemical preparation and properties[J].Chem.Mater.,2000,12(4):946-955.
[85]Xia B.,Lenggoro I.W.,Okuyama K..Preparation of Ni particles by ultrasonic spray pyrolysis of NiCl_2·6H_2O precursor containing ammonia[J].J.Mater.Sci.,2001,30:1701-1705.
[86]张晟卯,张春丽,吴志申等.室温离子液体介质中尺寸、结构可控Ni纳米微粒的制备及结构表征[J].化学学报,2004,62(15):1443-1446.
[87]Eckert J.,Holzer J.C.,et al..Synthesis and characterization of ball milled nanocrystallie fcc metals[J].Mater.Res.Soc.Symp.Proc.,1992,238:745.
[88]李宇农,何建军,龙小军.纳米金属粉末研究进展[J].粉末冶金工业,2004,14(1):34-39.
[89]Deng J.F.,Li H.X.,Wang W.J..Progress in design of new amorphous alloy catalysts[J].CatalysisToday,1999,51:113-125.
[90]Wong S.T.,Lee J.F.,Chen J.M.Preparation and characterization of MCM-41 and silica supported nickel boride catalysts[J].J.Mol.Catal.A:Chem.,2001,165(1-2):159-167.
[91]Deng J.F.,Zhang X.P.,Min E.Z.Amorphous Nickel-Phosphorus Alloy Deposited on a Support and Its Hydrogenation Activity[J].Appl.Catal.,1988,37:339-343.
[92]沈俭一,李智渝,陈懿.Ni-B超细非晶合金的化学制备,反应机理及性质研究[J].无机化学学报,1995,11(1):1-7.
[93]Shen J.Y.,Li Z.Y.,Yan Q.J.,Chen Y..Reaction of bivalent metal ions with borohydride in aqueous solution for the preparation of ultrafine amorphous alloy particles[J].J.Phys.Chem.,1993,97(32):8504-8511.
[94]李同信,张秀峰,李合秋等.非晶态超微粒子镍合金催化剂的研究I.Ni-B合金的制备及表征[J].催化学报,1995,16(4):299-303.
[95]Li H.X.,Li H.,Dai W.L.,Qiao M.H..Preparation of the Ni-B amorphous alloys with Variable boron content and its correlation to the hydrogenation activity[J].Applied Catalysis A..General,2003,238:119-130.
[96]He Y.G.,Qiao M.H.,HuH.R.,et al..Preparation of amorphousNi-B alloy:the effete of feeding order,Precursor salt,PH and adding rate[J].Materials Letters,2002,56:952-957.
[97]马爱增.负载型Ni—B非晶态合金催化剂的表征及催化性能[J].催化学报,1999,20(6):603-607.
[98].杨建明,吕剑,安忠维.非晶合金镍系催化剂研究进展[J].工业催化,2000,8(5):18-24.
[99].徐长青,朱大建,李光兴.Ni-B非晶态催化材料研究进展[J].功能材料,2004增刊,35:1974-1982.
[100]张迪倡,宗保宁,金泽明等.稀土(Y、Ce、Sm)对Ni-P非晶态合金热稳定性的影响 [J].物理化学学报,1993,9(3):325-330.
[101]Hou Y.J.,Wang Y.Q.,Mi W.L.,et al..Effects of Lanthanum addition on Ni-B amorphous alloy catalysts used in anthraquinone hydrogenation[J].React.Kinet.Catal.Lett.,2003,80(2):233-239.
[102]Hou Y.J.,Wang Y.Q.,He F.,et al..Effeets of Lanthanum addition on Ni-B/γ-Al_2O_3amorphous alloy catalysts used in anthraquinone hydrogenation[J].Applied Catalysis A:General,2004,259:35-40.
[103]李风仪,张荣斌,石秋杰,罗来涛.稀土在负载型非晶态Ni-B/Al_2O_3合金上作用研究[J].稀土,2000,21(4):38-42.
[104]王晓光,闫文胜,钟文杰.EXAFS研究Ni-B和Ni-Le-B超细非晶态合金的退火晶化[J].高等学校化学学报,2001,22(3):349-354.
[105]王晓光,张新夷,李忠瑞.Ni-B和Ni-Le-B超细非晶态合金的退火晶化及其催化性能[J].催化学报,2001,22(4):397-401.
[106]石秋杰,张雪红,李凤仪.钐对非晶态NiB合金催化剂性能及表面性质的影响[J].催化学报,1998,19(4):295-299.
[107]Qiujie Shi,Fengyi Li,Laitao Luo。Modification of the Properties of an Amorphous NiB Alloy Catalyst by Samarium[J].Reaction Kinetics and Catalysis Letters,2001,74(1):171-176.
[108]王鹏,仇立干,邢蓉.钐对Ni-B/SiO_2非晶态合金催化剂的催化性能及表面性质的影响[J].稀土,1999,20(1):45-49.
[109]王明辉,李和兴.Ni-B/SiO_2非晶态催化剂应用硝基苯液相加氢制苯胺[J].催化学报,2001,22(3):287-290.
[110]程庆彦,李伟,吴仪隽等.TiO_2负载非晶态NiB催化剂的制备、表征及HDS动力学研究[J].燃料化学学报,2000,28(3):249-252.
[111]王来军,李伟,张明慧等.非晶态合金催化剂NiB(P)/TiO_2的粉末化学镀法制备及其加氢催化性能的研究[J].南开大学学报(自然科学版),2004,37(1):1-6.
[112]Cheng Q Y,Li W,Zhou Y,Zhang M H,Guan N J,Tao K J.Ni-B/TiO_2 Amorphous Catalyst Used in Heavy Arenes of Petrochemicals Hydrogenation[J].Chinese Chemical Letters,2001,12(12):1123-1126.
[113]He Y.G.,Qiao M.H.,Hu H.R.,et al.Characterization and catalytic behavior of amorphous Ni-B/AC catalysts prepared in different impregnation sequences[J].Appl.Catal.A:General,2002,228:29-37.
[114]张荣斌,李凤仪.钕对非晶态Ni-B/膨润土催化剂性能的影响[J].稀土,2004,25(3):42-45.
[115]石秋杰,陈昭萍,罗来涛等.海泡石对非晶态NiB合金催化剂的改性研究[J].物理化学学报,2000,16(6):501-505.
[116]刘波,陈雪莹,庄继华等.负载型Ni-B非晶态合金的制备及其催化加氢活性研究[J].复旦学报(自然科学版),2002,41(4):424-428.
[117]韦世强,李忠瑞,张新夷等.超细Ni-B非晶态合金的退火晶化及其催化性能[J].科学通报,2000,45(18):1941-1944.
[118]Dai W.L.,Li H.X.,Cao Y.,et al..Evidence for the antioxidation effect of Boron on the ultrafine amorphous Ni-B alloy catalyst[J].Langmuir,2002,18(24):9605-9608.
[119]Okamoto Y.,Nitta Y.,Imanaka T.,Teranishi S..Surface Characterization of nickel boride and nickel phosphide catalysts by X-ray photoelectron spectroscopy [J].J.Chem.Soc.FaradayTrans.I,1979,15..2027-2039.
[120]杨军,邓景发.超细Ni-B非晶态合金表面的AES研究[J].化学物理学报,1994,7(2):136-140.
[121]戴维林,曹勇,范康平,邓景发.纳米Ni-Co-B非晶态合金抗氧化行为的原位XPS 研究[J].高等校化学学报,2003,24(3):473-476.
[122]张菊,郑小明,吴念慈,丁云杰.NiCoB超细非晶合金的化学制备和热稳定性研究[J].物理化学学报,1995,11(2):113-17.
[123]马延风,张明慧,李伟等.NiB、NiP与NiPB非晶态合金的物性与催化性能研究[J].南开大学学报(自然科学版),2004,37(3):61-72.
[124]沈俭一,张庆红,李智渝等.超细非晶镍合金的化学制备及类金属元素对性质的影响[J].化学学报,1995,53:1168-1172.
[125]Wang W.J.,Li H.X.,Xie S.H.,et al..Regeneration at room temperature for amorphous NiB/SiO_2 Catalyst deactivaled in cyclopentadiene hydrogenation[J].Appl.Catal.A,1999,184:33-39.
[126]唐忠,张帆,陶庭树等.Ni-Cu-B非晶态合金催化剂对双烯选择性加氢性能的研究[J].石油化工,2000,29(10):754-756.
[127]唐博合金,吕仁庆,项寿鹤.负载型Ni-B非晶态合金在裂解汽油加氢反应中的应用研究[J].石油学报(石油化工),2004,20(2):63-68.
[128]陈海鹰,邓景发,盛世善.非晶态金属合金作催化材料的研究:V.Ni—W—P非晶态合金微粉催化加氢活性研究[J].化学学报,1994,52:877-882.
[129]马爱增,陆婉珍,闵恩泽.非晶态合金催化剂对乙烯中微量乙炔的选择加氢[J].石油学报,1996,12(2):29-37.
[130]Moular A.,Smith G.V.,Mihaly B.,et al..Selective hydrogenation of enthylene ever amorphousNi-SiO_2[J].J.Catal.,1986,101:67.
[131]李同信,张秀峰,李合秋.非晶态超微粒子镍合金催化剂的研究[J].催化学报,1995,16(5):399-402.
[132]Zhang R.B.,Li F.G.,Zhang N.,et al..Benzene hydrogenation over amorphous NiB/bentonite catalyst and promoting effect ofNd[J].Appl.Catal.A,2003,239:17-23.
[133]Li J.,Qiao M.H.,Deng J.F..Amorphous Ni-B/γ-Al_2O_3 Catalyst Prepared in modified drying approach and its excellent activity in benzene hydrogenation[J].Journal of Molecular Catalysis A:Chemical,2001,169:295-301.
[134]Lee S.P.,Chen Y..Nitrobenzene hydrogenation on Ni-P,Ni-B,and Ni-P-B materials [J].J.Mol.Catal.A,2000,152:213-223.
[135]Lee S.P.,Chen Y..Catalytic properties of Ni-B and Ni-P ultrafine materials[J].Joumal of Chemical Technology and Biotechnology,2000,75:1073-1079.
[136]Li H.X.,Xu Y.P.,Li H.,et al..Gas-Phase hydrogenation of adiponitrile with selectivity to primary amineover supported Ni-B amorphous catalysts[J].Appl.Catal.A,2001,216:51-58.
[137]王鹏,李辉,曹勇等.负载型非晶合金催化剂(Ni-B/SiO_2)与已晴气固相常压加氢的研究[J].复旦学报(自然科学版),1999,38(1):2-6.
[138]Wang M.H.,Li H.X.,Wu Y.D.,Zhang J..Comparative studies on the catalytic behaviors between the Ni-B amorphous alloy and other Ni-Based catalysts during liquid phase hydrogenation of acetonitrile to ethylamine[J].Materials Letters,2003,57:2954-2964.
[139]徐长青,朱大建,李光兴.Ni-B/SiO_2非晶态催化剂对苯乙酮的催化加氢研究[J].分子催化,2004,18(4):281-285.
[140]乔明华,谢颂海,戴维林.超细非晶态NiWB合金的制备及葡萄糖加氢性能的研究[J].化学学报,2000,58(7):904-908.
[141]梁薇,负载型非晶态合金的结构及催化加氢性能[J].工业催化,2005,13(9):56-60.
[142]张菊,郑小明.超细Ni-(Co)-B非晶态合金的XPS研究[J].科技通报,13(1):26-28.
[143]贺岩峰,齐晓周,廖巧丽等.离子交换树脂负载Ni-B催化剂上异丙醇的液相脱氢[J].石油化工,1998,27(5):329-332.
[144]曲微丽,邬冰,孙芸等.乙二醇在Pt-WO3/C上的电催化氧化[J].物理化学学报,2005,21(7):804-807.
[145]Chu D.,Jiang R..Novel electrocatalysts for direct methanol fuel cells[J].Solid state Ionics,2002,148(3):591-599.
[146]Choon Choi W.,IhL Woo S..Bimetallic Pt-Ru nanowire network for anode material in a direct-methanol fuel cell[J].J.Power Sources,2003,124(2):420-425.
[147]Kim J.W.,Park S.M..Electrochemical Oxidation of Ethanol at Thermally Prepared RuO_2-Modifified Electrodes in Alkaline Media[J].Journal of the Electrochemical Society,1999,146(3):1075-1080.
[148]Nakagawa K.,Konaka R.,Nakata T.Oxidation with Nickel Peroxide.I.Oxidation of Alcohols[J].J.Org.Chem.,1962,27(5):1597-1601.
[149]George M.V.,Balachandran K.S._Nickel-peroxide oxidation of organic compounds [J].Chem.Rev.,1975,75(4):491-519.
[150]Chen Y.L.,Chou T.C.Kinetics and Mechanism of Anodic Oxidation of n-Butanol by Nickel Peroxide[J].Ind.Eng.Chem.Res.,1996,35:2172-2176.
[151]Christoskova St.G.,Danova N.,Georgieva M.,et al.Investigation of a nickel oxide system for heterogeneous oxidation of organic compounds[J].Appl.Catal.,A,1995,12:219-229.
[152]Amjad M.,Pletcher D.,Smith C.The oxidation of at a nickel anode in alkaline t-butanol/water mixtures[J].Journal of the Electrochemical Society,1977,124(2):203-206.
[153]Yoshihito Kunugi,Tsutomu Nonaka,Yong-Bo Chong and Nobuatsu Watanabe.Electroorganic reactions on organic electrodes—part 15:Electrolysis using composite-plated electrodes—part Ⅳ.Polarization study on a hydrophobic Ni/PTFE composite-plated nickel electrode[J].Electroehim.Acta,1992,37(2):353-355.
[154]Manandhar K.,Plecther D.The preparation of high surface area nickel oxide electrodes for synthesis[J].J.Appl.Electrochem.,1979,9:707-713.
[155]黄令,许书楷,汤皎宁,杨防祖,周绍民.Ni-Mo-PTFE复合电极的制备及其对甲醇电氧化的催化性能[J].应用化学,1997,14(8):21-24.
[156]Zeng Y.,Yu S.C.,Li Z.L.,Chen K.,Zhou S.M..Kinetic Model of ethanol oxidation on Ni-Mo alloyelectrode[J].ActaPhysico-Chimica Sinica,2000,16(11):1013-1021.
[157]黄令,杨防祖,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上乙醇的电氧化[J].应用化学,2005,22(6):590-594.
[158]黄令,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上丙醇的电氧化[J]. 高等学校化学学报,1997,18(6):932-937.
[159]孔景临,薛宽宏,何春建等.镍纳米线电极的电化学氧化还原行为及其对乙醇的电化学氧化催化作用[J].应用化学,2001,18(6):462-465.
[160]孔景临,薛宽宏,邵颖等.镍纳米线电极对乙醇的电催化氧化动力学参数的测定[J].物理化学学报,2002,18(3):268-271.
[161]Lo Yi Ling;Hwang Bing Joe.Kinetics of ethanol oxidation on electroless Ni-P/SnO_2/Ti electrodes in KOH solutions[J].J.Electrochem.Soc.,1995,142(2):445-450.
[162]Berchmans S,Gomathi H,Rao G P.Electrooxidation of alcohols and sugars catalysed on a nickel oxide modified glassy carbon electrode[J].J.Electroanal.Chem..,1995,394(1-2):267-270.
[163]Schrebler Guzman R S,Vilche J R,Arvia A J.The potentiodynamic behaviour of nickel in potassium hydroxide solutions[J].J.Appl.Electrochem.,1978,8:67-70.
[164]Robertson P M.On the oxidation of alcohols and amines at nickel oxide electrodes:Mechanistic aspects[J].J.Electroanal.Chem.,1980,111(1):97-104.
[165]俞守耕.低温燃料电池电催化剂的研究近况[J].电源技术,2004,28(12):798-802.
[166]刘昌见,李德平,鲍晓军.蒽的电化学加氢[J].化工学报,2004,55(11):1809-1814.
[167]Ramesh Raju R.,Damodar J.,Jayarama Reddy S..The electrocatalytic hydrogenation of α-aryl acrylic acids[J].Electrochemistry Communication,2002,4:115-117.
[168]Chambrion P.,Roger L.,Lessard J.,etal..The influence of surfactants on the electrocatalytic hydrogenation of organic compounds in micellar,emulsified,and hydroorganic solutions at Raney nickel electrodes[J].Can.J.Chem.,1995,73:804-818.
[169]Itoh N.,Xu W.C.,Hara S.,et al..Electrochemical coupling of benzene hydrogenation and water electrolysis[J].Catalysis Today,2000,56:307-314.
[170]Santana D.D.,Melo G.O.,Lima M.V..Electrocatalytic hydrogenation of organic compounds using nickel sacrificial anode[J].Journal of Electroanalytical Chemistry,2004,569:71-78.
[171]Hu X E,Yang H W,Wang X J,Bai R S.Electrohydrogenation of 4-amino-5-nitrosodimethyluracil with a foamed nickel cathode[J].Journal of Applied Electrochemistry,2002,32:321-328.
[172]Robin D,Comtois M,Martel A.The electrocatalytic hydrogenation of fused polycyclic aromatic compounds at Raney nickel electrodes:in influence of catalyst activation and electrolysis conditions[J].Can.J,Chem.,1990,68:1218-1227.
[173]Mahdavi B,Chambrion P,Binette J..Electrocatalytic hydrogenation of conjugated enones on nickel boride,nickel,and Raney nickel electrodes[J].Can.J.Chem.,1995,73:846-852.
[174]Doherty A P,Christensen P A,Hammntt A.[J].Journal of Electroanalytical Chemistry,1995,386:39-44.
[175]肖秀峰,刘榕芳,朱则善.以Zn-PTFE复合电极电合成频那醇[J].化学通报,2001,10:651-654.
[176]鲁战光,文丽蓉,张积树等.阴极电还原葡萄糖合成山梨醇的研究[J].精细化工中间体,2001,31(5):30-32.
[177]Polcaro A.M.,Demini M.S.,Palmas S.,Electrodeposition of catalysts for hydrogenation of organic molecules:hydrogenation of benzaldehyde[J].Electrochimica Acta,1992, 37(2):365-367.
[178]Quiroz M.A.,Cordova F.,Lamy-Pitara E.,Barbier J..Electrocatalytic hydrogenation of m-xylene on platinized-Platinum electrodes[J].ElectrochimicaActa,2000,45:4291-4298.
[179]Cleghorn S.J.C.,Pletcher D..The mechanism of electrocatalytic hydrogenation of organic molecules at palladium black cathodes[J].Electrochimica Acta,1993,38(213):425-430.
[180]Byran A.,Grimshaw J..Electrochemical conversion of 4-phenylbuten-2-one into 4-phenylbutan-2-ones.Electrocatalytic hydrogenation at a nickel surface[J].Electrochimica Acta,1997,42(13-14):2101-2107.
[181]Zouaoui A.,Stephan O.,Ourari A.,et al..Electrocatalytic hydrogena-tion of ketones and enones at nickel microparticles dispersed into poly(pyrrole-alkylammonium)films [J].Electrochimica Acta,2000,46:49-58.
[182]Martel A.,Mahdavi B.,Lessard J.,etal..Electrocatalytic hydrogenation of phenol on various electrode materials[J].Can.J.Chem.,1997,75:1862-1867.
[183]Ilikti H.,Rekik N.,Thomalla M..Electrocatalytic hydrogenation of phenol in aqueous solutions at a Raney nickel electrode in the presence of cationic surfactants[J].Journal of Applied Electrochemistry,2002,32:603-609.
[184]Ilikti H.,Rekik N.,Thomalla M..Electrocatalytic hydrogenation of alkyl-substitued phenols in aqueous solutions at a Raney nickel electrode in the presence of a non-micelle-forming cationic surfactant[J].Journal of Applied Electrochemistry,2004,34:127-136.
[185]Mahdavi B.,Lafrance A.,Martel A.,et al..Electrocatalytic hydrogeno- lysis oflignin model dimers at Raney nickel electrodes[J].Joumal of Applied Electrochemistry,1997,27:605-611.
[186]Menini R.,Martel A.,Menard H.,et al..The electrocatalytic hydrogenation of phenanthrene at Raney nickel electrodes:the influence of an inert gas pressure[J].Electrochimica Acta,1998,43(12-13):1697-1730.
[187]Coche L.,Ehui B.,Limosin D.,Moutet J.C..Electrocatalytic hydrogenation using precious metal microparticle in redox-active polymer films[J].J.Org.Chem,1990,55(23):5905-5910.
[188]Zouaoui A.,Stephan O.,Carrier M.,Moutet J.C..Electrodeposition of copper into functionalized polypyrrole films[J].Journal of Electroanalytical Chemistry,1999,474:113-122.
[189]Horanyi G..In Horiuti's footsteps:links between catalysis and electrocatalysis [J].Journal of Molecular Catalysis A:Chemical,2003,199:7-17.
[190]Lamy-Pitara E.,Belegridi I.,Barbier J..Liquid phase catalytic hydrogenation under potential control of the catalyst[J].Catalysis Today,1995,24:151-156.
[191]张丽芳.陈赤阳,项志军.环已烷氧化法制备环已酮工艺研究进展[J].北京石油化工学院,2004,12(2).
[192]Amouzegar K.,Savadogo O..Electrocatalytic hydrogenation of phenol on dispersed Pt:reaction mechanism and support effect[J].Electrochimica Acta,1998,43(5-6):503-508.
[193] Amouzegar K., Savadogo O..Electrocatalytic hydrogenation of phenol on dispersed Pt: effect of metal electrochemically active surface area and electrode material [J]. Journal of Applied Electrochemistry, 1991, 27: 539-542.
[194] Dube P., Kerdouss F., Laplante F., et al..Electrocatalytic hydrogenation of cyclohexanone: Simple dynamic cell design[J]. Journal of Applied Electrochemistry, 2003, 33: 541-547.
[1]范雄.X射线金属学[M].北京:机械工业出版社,1981
[2]常铁军,祁欣等.材料近代分析测试方法[M].哈尔滨:哈尔滨工业大学出版社,1999
[3]陈镜泓,李传儒.热分析及其应用[M].北京:科学出版社,1985
[4]熊兆贤等.无机材料研究方法[M].厦门:厦门大学出版社,2001
[5]陆家和,陈长彦.现代分析技术[M].北京:清华大学出版社,1995
[6]张立德,牟季美.纳米材料和纳米结构[M].北京:科学出版社,2001
[7]辛勤.固体催化剂研究方法(上册)[M].北京:科学出版社,2004
[8]黄惠忠.纳米材料分析[M].北京:化学工业出版社,2003
[9]刘世宏,王当憨,潘承璜.X射线光电子能谱分析[M].北京:科学出版社,1988
[10]范康年.谱学导论[M].北京:高等教育出版社,2001
[11]辛勤.固体催化剂研究方法(下册)[M].北京:科学出版社,2004
[12]王典芬.X射线光电子能谱在非金属材料研究中的应用[M].武汉:武汉工业大学出版社,1994
[13]Briggs D.,Seah M.P.,Practical Surface analysis by Auger and X-ray photoelectron spectroscopy[M].New York:John Wiley & Sons,1984
[1]Deng Jingfa,Li Hexing,Wang Weijiang.Progress in design of new amorphous alloy catalysts[J].Catal Today,1999,51:113-125.
[2]Wong S T,Lee J F,Chen J M.Preparation and characterization of MCM-41 and silica supported nickel boride catalysts[J].J Mol Catal A:Chem,2001,165:159-167.
[3]Tony S,Vesselina R.Hydriding properties of Ni-B alloy studied by DSC and thermorgravimetry[J].Thermochimica,1999,326:69-73.
[4]Legrand J.,Taleb A.,Gota S.,et al.Synthesis and XPS Characterization of Nickel Boride Nanoparticles[J].Langmuir,2002,18(10):4131-4137.
[5]Corrias A,Ennas G,Musinu A,Marongiu G,Paschina G.amorphous transition metal-boron ultrafine particles prepared by chemical methods[J].Chem.Mater.,1993,5(12):1722-1726
[6]Wang M H,Li H X,Wu Y D,Zhang J.Comparative studies on the catalytic behaviors between the Ni-B amorphous alloy and other Ni-Based catalysts during liquid phase hydrogenation of acetonitrile to ethylamine[J].Materials Letters,2003,57:2954-2964.
[7]Brooks A R,Clayton C R,Doss k,Lu Y C.On the role of Cr in the passivity of stainless steel[J].J.Electrochem.Soc.,1986,133:2459-2464
[8]Clayton C R,Lu Y C.A bipolar model of the passivity of stainless steels—Ⅲ.The mechanism of MoO_4~(2-)formation and incorporation[J].Corrosion Science,1989,29(7):881-898
[9]Lu Y C,Clayton C R.An XPS study of the passive and transpassive behavior of molybdenum in deaerated 0.1 M HCl[J].Corrosion Science,1989,29(8):927-937
[10]Yousif,K.M.;Smish,B.E.;Jeynes,C.J..[J].Mater.Sci.,1996,31:185
[11]Glavee,G.N.;Klabunde,K.J.;Sorensen,C.M.;Hadjipanayis,G.C.Borohydride reduction of nickel and copper ions in aqueous and nonaqueous media.Controllable chemistry leading to nanoscale metal and metal boride particles[J].Langmuir,1994,10(12):4726-4730
[12]Dai W L,Li H X,Cao Y,et al..Evidence for the antioxidation effect of Boron on the ultrafine amorphous Ni-B alloy catalyst[J].Langmuir,2002,18(24):9605-9608.
[13]Wagner,C.D.;Riggs,W.M.;Davis,L.E.;Moulder,J.F.Handbook of X-ray photoelectron Spectroscopy,Perkin-Elmer Corporation,Physical Electronics Division,Eden Prairie,MN,1978
[14]Petit C,Taleb A,Pileni M P.Self-organization of magnetic nanosized cobalt particles[J]. Advanced Materials, 1998, 10: 259-261.
[15] Beccaria, A.M.;Wang, Y.Z.;Poggi, G. Surf.Interface Anal., 1994, 21: 442
[16] Davidson A, Tempere J F, Che M, Roulet H, Dufour GSpectroscopic Studies of Nickel(II) and Nickel(III) Species Generated upon Thermal Treatments of Nickel/Ceria-Supported Materials [J].J.Phys.Chem., 1996, 100(12): 4919-4929.
[1]Manandlhar K,Plecther D.The preperation of high surface area nickel oxide electrode for synthesis[J].J.Appl.Electrochem.,1979,9:707-713.
[2]Kim J W,Park S M.Electrochemical oxidation of ethanol at thermally prepared RuO_2-Modifified electrodes in alkaline media[J].J.Electrochem.Soc.,1999,146(3):1075-1080.
[3]Cao D,Bergens S H A direct 2-propanol polymer electrolyle fuel cell[J].J.Power Sources,2003,124(1):12-17.
[4]ZENG Yue,YU Shang-Ci,LI Ze-Lin,et al.Kinetic model of ethanol oxidation on Ni-Mo alloy electrode[J].Acta Phys.-chim.Sin.,2000,16(11):1013-1021.
[5]孔景临,薛宽宏,邵颖.镍纳米线电极对乙醇的电催化氧化动力学参数的测定[J].物理化学学报,2002,18(3):268-271.
[6]黄令.功能性电沉积层的形成、结构与性能研究)[D].厦门,厦门大学,1997.
[7]查全性等.电极过程动力学导论[M].北京:科学出版社,2002,368-376.
[8]Cha C S,Li C M.,Yang H X,et al..Powder microelectrodes[J].J.Electroanal.Chem.,1994,47:368-374.
[9]胡蓉晖,杨汉西,刘金成等.微电极定量方法评价贮氢合金的电化学性质[J].电化学,1996,(4):391-396.
[10]Hu X H,Ai X,P,Yang H X,et al..A study of LiMn_2O_4 synthesized from Li_2CO_3 and MnCO_3[J].J.Power Sources,1998,74:240-243.
[11]胡晓宏,艾新平,杨汉西等.锂离子蓄电池正极材料的快速评价[J].电源技术,2003,27(3):281-283.
[12]Burke L D,Twomey T A M.Voltammetric behaviour of nickel in base with particular reference to thick oxide growth[J].J.Electroanal.Chem.,1984,162(1-2):101-119.
[13]Schrebler Guzman R S.Non-equilibrium effects in the nickel hydroxide electrode [J].J.Appl.Electrochem.,1979,9:183-189.
[14]Schrebler Guzman R S,Vilche J R,Arvia A J.The potentiodynamic behaviour of nickel in potassium hydroxide solutions[J].J.Appl.Electrochem.,1978,8:67-70.
[15]黄令,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上丙醇的电氧化[J].高等学校化学学报,1997,18(6):932-937.
[16]马淳安.有机电化学合成导论[M].北京:科学出版社,2002.
[17]孔景临,薛宽宏,何春建.镍纳米线电极的电化学氧化还原行为及其对乙醇的电化学氧化催化作用[J].应用化学,2001,18(6):462-465.
[18]刘建华,杨敬武,唐致远.掺杂球形氢氧化镍的循环伏安特性[J].天津大学学报,2000,33(1):118-121.
[19]周震,阎杰,林进,张允什.纳米Ni(OH)_2的质子扩散行为研究[J].电源技术,1999,23(6):319-321.
[20]王志兴,李新海,陈启元.微电极在Ni(OH)_2使用寿命测定中的应用[J].中南工业大学学报,1997,28(6):551-554.
[21]Wang X Y,Yan J.,Zhang Y S,et al.Cycle voltammetic studies of pasted nickel hydroxide electrode microencapsulated by cobalt[J].J.Appl.Electrochem,1998,28: 1377-1382.
[22]Berchmans S,Gomathi H,Rao G P.Electrooxidation of alcohols and sugars catalysed on a nickel oxide modified glassy carbon electrode[J].J.Electroanal.Chem.,1995,394(1-2):267-270.
[23]Lo Yi Ling;Hwang Bing Joe.Kinetics of ethanol oxidation on electroless Ni-P/SnO_2/Ti electrodes in KOH solutions[J].J.Electrochem.Soc.,1995,142(2):445-450.
[24]查全性等.电极过程动力学导论[M].北京:科学出版社,2002,183-189.
[25]马淳安.有机电化学合成导论[M].北京:科学出版社,2002,47-55.
[26]黄令,杨防祖,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上乙醇的电氧化[J].应用化学,2005,22(6):590-594.
[1]Deng Jingfa,Li Hexing,Wang Weijiang.Progress in design of new amorphous alloy catalysts[J].Catal Today,1999,51:113-125.
[2]Lee S P,Chen Y W.Effects of preparation on the catalytic properties of Ni-P-B ultrafine materials[J].Ind.Eng.Chem.Res.,2001,40(6):1495-1499.
[3]Ivanov M V,Lubin E N,Drovosekov A B.X-Ray Photoelectron Spectroscopy of Chemically Deposited Amorphous and Crystalline Ni-B Coatings[J].Protection of Metals,2003,39(2):133-141
[4]Dai Weilin,Li Hexing,Cao Yong,et al.Evidence for the antioxidation effect of boron on the ultrafine amorphous Ni-B alloy catalyst[J].Langmuir,2002,18:9605-9608.
[5]马延风,张明慧,李伟,张宝贵,陶克毅.高比表面NiP非晶态合金的制备及其催化性能[J].催化学报,2004,25(12):973-978
[6]王晓光,闫文胜,钟文杰.EXAFS研究Ni-B和Ni-Le-B超细非晶态合金的退火晶化[J].高等学校化学学报,2001,22(3):349-354.
[7]郑一雄,姚士冰,周绍民.Ni-Mo-B非晶态合金纳米颗粒的抗氧化性能研究[J].物理化学学报,2004,20(11)::1352-1356.
[8]Zysler R D,Ramos C A.Chemical synthesis and characterization of amorphous Fe-Ni-B magnetic nanoparticles[J].J.Materials Science,2001,36:2291-2294.
[9]戴维林,曹勇,范康平,邓景发.纳米Ni-Co-B非晶态合金抗氧化行为的原位XPS 研究[J].高等校化学学报,2003,24(3):473-476.
[10]Capek I.Preparation of metal nanoparticles in water-in-oil(w/o)microemulsion[J].Advances in Colleid and Interface Science[J],2004,110:49-74.
[11]Mandal M,Kundu S,Ghosh S K.etal.Wet chemical method for synthesis of superparamagnetic alloyed Ni-Pd and Ni-Pt nanomagnets in micelles[J].J.Colloid and Interface Science,2003,265:23-28.
[12]Lin X M,Sorensen C M.Temperature Dependence of Morphology and Magnetic Properties of Cobalt Nanoparticles Prepared by an Inverse Micelle Technique[J].Langmuir[J],1998,14:7140-7146.
[13]Khiew P S,Huang N M,Radiman S.etal.Synthesis of NiS nanoparticles using a sugar-ester nonionic water-in-oil microemulsion[J].Materials Letters,2004,58:762-767
[14]Janos B Nagy,Isabelle Bodart-Ravet,Eric G Derouane.Faraday Discussions of the Chemical Society[J],1989,87:189-198.
[15]Legrand J,Taleb A,Gota S,et al.Synthesis and XPS Characterization of Nickel Boride Nanoparticles[J].Langmuir,2002,18(10):4131-4137.
[16]Lufimpadio N,Nagy J B,Derouane E G.Surfactants Solution[J],1984,3:1483-1485.
[17]张朝平,邓伟,胡林等.微乳液法制备超细Ni-Fe复合物微粒[J].无机材料学报,2001,16(3):481-485.
[18]方鲲,李守平,崔陇兰.超微镍粒子/聚苯胺纳米复合材料制备及其表征[J].化学物理学报),2003,16(3):163-165
[19]郭建华,张蕴珊.电镀镍硼合金镀层结构与性能[J].东北大学学报(自然科学版), 1995,94(1):41-45
[20]韦世强,李忠瑞,张新夷等.超细Ni-B非晶态合金的退火晶化及其催化性能[J].科学通报,2000,45(18):1941-1944
[21]Moulder J F,Stickle W F,Sobol P E.etal..Handbook of x-ray Photoelectron Spectroscopy[M],Minnesota:Physical Electronics,Inc.,1995
[22]Okamoto Y,Nitta Y,Imanaka T,Teranishi S.Surface Characterization of nickel boride and nickel phosphide catalysts by X-ray photoelectron spectroscopy[J].J.Chem.Soc.Faraday Trans.I,1979,15:2027-2039.
[23]沈俭一,李智渝,陈懿.Ni-B超细非晶合金的化学制备,反应机理及性质研究[J].无机化学学报,1995,11(1):1-7.
[24]Krasteva N,Forty V,Armyanov S J.Thermal stability of Ni-P and Ni-Cu-P amorphous alloys[J].Electrochem.Soc.,1994,141:2864-2867.
[1]刘永辉.电化学测试技术[M].北京:北京航空学院出版社,1987
[2]陈体衔.实验电化学[M].厦门:厦门大学出版社,1993
[3]Nichols R J,Bewick A.Spectroscopic identification of the adsorbed intermediate in hydrogen evolution on platinum[J].J.Electroanal.Chem.,1988,243(2):445-453.
[4]Noritoshi Nanbu,Fusao Kitamura,Takeo Ohsaka.Adsorption of atomic hydrogen on a polycrystalline Pt electrode surface studied by FT-IRAS:the influence of adsorbed carbon monoxide on the spectral feature[J].J.Electroanal.Chem.,2000,485(2):128-134.
[5]Martins M E,Zinola C F,Andreasen G,SalvarezzaA C,ArviaA J.Possible existence of subsurface H-atom adsorbates and H_2 electrochemical evolution reaction intermediates on platinum in acid solutions[J].J.Electroanal.Chem.,1998,445:135-154.
[6]Clavilier J,Faure R,Guinet G,Durand R.Preparation of monocrystalline Pt microelectrodes and electrochemical study of the plane surfaces cut in the direction of the 111 and 110 planes[J].J.Electroanal.Chem.,1980,107(1):205-209.
[7]Clavilier J,Armand D,Wu B L.Electrochemical study of the initial surface condition of platinum surfaces with(100)and(111)orientations[J].J.Electroanal.Chem.,1982,135(1):159-166.
[8]Yoshio Takasu,Yuichi Fujii,Kozo Yasuda,Yukinori Iwanaga,Yoshiharu Matsuda.Electrocatalytic properties of ultrafine platinum particles for hydrogen electrode reaction in an aqueous solution of sulfuric acid[J].Electrochim.Acta,1989,34(3-4):453-458.
[9]Masae P Sumino,Shigeo Shibata.Specific adsorption of hydrogen on polycrystalline platinum electrode[J].Electrochim.Acta,1992,37(14):2629-2635.
[10]Hu C C,Wen T C.Effects of the nickel oxide on the hydrogen evolution and para-nitroaniline reduction at Ni-deposited graphite electrodes in NaOH[J].Electrochimica Acta,1998,43(12-13):1747-1756.
[11]De Giz M J,Machcado S A S,Avaca L A,Gonzalez E R.High area Ni-Zn and Ni-Co-Zn codeposits as hydrogen electrodes in alkaline solutions[J].J.Appl.Electrochem.,1992,22:973-977.
[12]Beden B,Bewick A.The anodic layer on nickel in alkaline solution:an investigation using in situ IR spectroscopy [J].Electrochimica.Acta, 1988, 33(11): 1695-1698.
[13] Hahn F, Floner D, Beden B, Lamy C. In situ investigation of the behaviour of a nickel electrode in alkaline solution by uv-vis and ir reflectance spectroscopies[J]. Electrochimica Acta, 1987, 32(11): 1631-1636.
[14] Burchardt T, Hansen V, Valand T.Microstructure and catalytic activity towards the hydrogen evolutiou reaction of electro-deposited NiP_x alloys[J]. Electrochimica Acta, 2001, 46: 2761-2706.
[15] Vandenborre H, Vermeiren P H, Leysen R.Hydrogen evolution at nickel sulphide cathodes in alkaline medium[J].Electrochim.Acta, 1984, 29(3): 297-301.
[2]Makino A.,Inoue A.,Mizushima T.Soft magnetic properties of Fe-based bulk amorphous alloys[J].Materials Transactions,2000,41(11):1471-1477.
[3]Lu Z.P.,Liu C.T.,Carmichael C.A..Bulk glass formation in an Fe-based Fe-Y-Zr-M(M =Cr,Co,Al)-Mo-B system[J].Journal of Materials Research,2004,19(3):921-929.
[4]Inoue A,Takeuchi A..Recent progress in bulk glassy alloys[J].Materials Transactions,2002,43(8):1892-1906.
[5]张程煜,姚可夫.Cu64Zr36非晶合金的晶化动力学[J].稀有金属材料与工程,2006,35(1):158-160.
[6]熊中强,米镇涛,张香文.非晶态合金催化剂研究[J].化学进展,2005,17(4):614-621.
[7]Jacgues V.W.,Steen M.,Christian J.W.K.,et al.Formation of ultra-fine amorphous alloy patricles by reduction in aqueous solution[J].Nature,1986,322:622-623.
[8]闵思泽,李成岳.绿色石化技术的科学与工程基础[M].北京:中国石化出版社,2002
[9]陆关兴,陈绯,奕英豪.非晶态合金带力学性能的评价[J].玻璃钢/复合材料,1995,(3):28-31.
[10]Osaka T.,Kaoki N.,Koiwa I..A Preparation of perpendicular magnetic recording media by an electroless plating method[J].J.Electrochem.Sot.,1983,130(3):568-571.
[11]姜晓霞,沈伟.化学镀理论及实践[M].北京:国际工业出版社,2000.
[12]王森林.多元合金的化学沉积及镀层结构与性能研究[D].厦门大学化学系,2005.
[13]Ruggeri S.,Cyril Lenain,et al.Mechanically driven crystallization of amorphous MgNi..alloy during prolonged milling:applications in Ni-MH batteries[J].J Alloys Comp.,2002,339:195-201.
[14]Lei Y.Q.,Wu Y.M.,et al..Electrochemical behaviour of some mechanically alloyed Mg-Ni based amorphous hydrogen storage alloys[J].Z Phys.Chem.,1994,183:1419.
[15]Orimo S.,Fujii H..Material science of Mg-Ni-based new hydrides[J].Appl.Phys.A,2001,72:167-186.
[16]Varga M.,Mulas G.,Cocco G.,et al.Binary and ternary amorphous palladium alloys:Characterization,activity and selectivity in hydrogenation of dienes[J].Materials Science and Engineering A,2001,304-306:462-466.
[17]黄令.功能性电沉积层的形成、结构与性能研究[D].厦门大学化学系,1997.
[18]李庆伟等.非晶态合金催化剂的研究[J].化工生产与技术,2001,8(6):30-33.
[19]Coteron A.,Haghurst A.N.Synthesis by Amorphous Coppper-based Catalysts Prepared by Spark-erosion[J].Appl.Catal.A,1993,101:151-165.
[20]Wang W.J.,Qiao M.H.,Yang J.,et al.Slective Hydrogenation of Cyclopentadiene to cyclopentene over an Amorphous Ni-B/SiO2 Catalysts[J].Applied Catalysis A:General,1997,163(1/2):101-107.
[21]马爱增,陆婉珍,闵恩泽.含金属添加剂的负载型NiB非晶态合金催化剂的结构及催化性能[J].石油化工,2000,29(3):179-183.
[22]李江,乔明华,邓景发.前驱体干燥法对非晶态Ni—B/γ—A 1203催化剂性能的影响[J].高等学校化学学报,2001,22(6):1022-1024.
[23]Takahashi T.,Kai T.Hydrogenation Catalysts Prepared from Amorphous Alloys with Zirconium[J].Materials Science and Engineering A,1999,267:207-213.
[24]王明辉,李和兴,邓景发.超细Co-B非晶态合金的制备及其催化乙腈加氢性能[J].催化学报,1999,20:548-552.
[25]Li H.,Xu Y.,Deng J.F..Selective hydrogenation of adiponitrile over a Raney Ni-P amorphous catalyst[J].New J chem.,1999,23(1):1059-1061.
[26]Yu X.,Li H.,Deng J.F..Selective hydrgenation of adiponitrile over a skeletal Ni-P amorphous catalyst(Raney Ni-P)at atom pressure[J].Appl.Catal.A,2000,199:191-198.
[27]Li M.,Wang W.,Li M.,et al..Crystallization deactivation of Ni-P/SiO_2 amorphous catalyst and the stabilizing effect of silica support on th Ni-P amorphous structure.J Catal.,2000,194:211-221.
[28]Li H.,Li H.,Wang W.,et al.Excellent activity of ultrafine Co-B amorphous alloy catalyst in glucose hydrogenation.Chem.Lett.,1999,7:629-630.
[29]Inoue A..Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta Materialia,2000,48:279-306.
[30]Takeuchi A.,Inoue A.Calculations of mixing enthalpy and mismatch entropy for ternary [J].Materials Transactions,2000,41(11)1372-1378.
[31]Egami T..Universal Criteriom for Metallic Glass Formation[J].Material Science and Engineering,1997,A226-228:261-267.
[32]Egami T.Atomistic mechanism of bulk metallic glass formation[J].J.Non-tryst.Solids,2003,317:30-33.
[33]Miracle D.B.,Senkov O.N..Topological criterion for metallic glass formatiom [J].Materials Science and Engineering,2003,A 347:50-58.
[34]Senkov O.N.,Scott J.M.Specific criteria for selection of alloy composition for bulk metallic glasses[J].Scripta Materiallia,2004,50:449-452.
[35]董闯,王英敏,恙建兵等.大块非晶合金成分设计方法.中国专利,No.01128027.1,2001.
[36]王玲玲,黄维清,彭军等.机械合金化多元非晶态合金形成规律研究[J].稀有金属材料与工程,2005,34(1):17-21.
[37]王玲玲,黄维清,李小凡等.化学镀多元非晶态合金形成规律探讨[J].金属学报,2002,38(1):84-90.
[38]王玲玲,彭军,唐黎明等.电沉积制备多元非晶合金形成规律研究[J].稀有金属材料与工程,2004,33(2):113-119.
[39]王一禾,杨膺善.非晶态合金[M].北京:冶金工业出版社,1989:2-26.
[40]Li Y.,Ng S.N.,Ong C.K.,et al.Glass forming ability of bulk glass forming alloys[J].Scripta Material,1997,36(7):783-787.
[41]Davies H.A..Amorphous metallic alloys[M].London:Metal Society,1978,312-356.
[42]Lu Z.P.,Liu C.T..A new glass-forming ability criterion for bulk metallic glasses [J].Acta Mater.,2002,50:3501-3512.
[43]Senkov O.N.,Miracle D.B..A topological model for metallic glass formation[J].Journal of Non-Crystalline Solids,2003,317:34-39.
[44]阎子峰.纳米催化技术[M].北京,化学工业出版社,2003.
[45]张立德,牟季美,纳米材料和纳米结构[M].北京,科学出版社,2001.
[46]徐滨士.纳米表面工程[M].北京,化学工业出版社,2004.
[47]张锡凤,殷恒波,程晓农等.纳米镍的制备方法及在催化领域的应用[J].化学与生物工程,2005,(10):8-10.
[48]张志煜,崔作林.纳米技术与纳米材料[M].北京,国际工业出版社,2000.
[49]屈子梅.羰基法生产纳米镍粉[J].粉末冶金工业,2003,13(5):16-19.
[50]Tepper F..Nanosize powders procluced by electro-explosion of wire and their potential application[J].Power Metal,2000,43(4).
[51]Teng M.H.,Host J.J.,Hwang J.-H.,Elliott B.R.,Weertman J.R.,Mason T.O.,Dravid V.P.,Johnson D.L..Nanophase Ni particles produced by a blown arc method[J].Journal of Materials Research,1995,10(2):233-236.
[52]Chou K.S.,Huang K.C..Studies on the chemical synthesis of nanosized nickel powder and its stability[J].Joumal of Nanoparticle Research,2001,(3):127-132.
[53]张楠,翟秀静,翟玉春.纳米Ni-Co合金粉末的溶液还原法制备与表征[J].中国有色金属学报,1998,8(2):39-42.
[54]Lee S.P.,Chen Y.W..Selective hydrogenation offurfural on N-P,Ni-B,and Ni-P-B ultrafinematerials[J].Ind.Eng.Chem.Res.,1999,38(7):2548-2556.
[55]Lee S.P.,Chen Y.W..Effects of preparation on the catalytic properties of Ni-P-B ultrafine materials[J].Ind.Eng.Chem.Res.,2001,40(6):1495-1499.
[56]Fievet F.,Logier J.P..Homogeneous and heterogeneous nucleations in the polyol process for the preparation of micron and submicron size metal particles[J].Solid State Ionics,1989,32/33:98-103.
[57]Ayyappan S.,Subbanna G.N.,Gopalan R.,et al.Nanoparticles of nickel and Silver Produced by the polyol reduction of the metal salts intercalated in montmorillonite[J].Solid State Ionics,1996,84(3-4):271-281.
[58]Hegde M.S.,Laicher D..Synthesis and chemical reactivity of polyol prepared monodisperse nickel poders[J].Solid State Ionics,1997,93:33-50.
[59]齐艳妮,殷德宏,王秀平等.乙二醇溶剂中纳米镍的制备研究[J].材料科学与工程学报,2005,23(3):416-421.
[60]Anne Duteil,Gunter Schmid,Wolfgang Meyer-Zaika.Ligand stabilized nickel colloids[J].Journal of the Chemical Society,Chemical Communications,1995,(1):31.
[61]徐菊,喻克宁,梁焕珍等.用Ni(OH)_2浆化氢还原法制备纳米金属镍粉的反应机制[J].材料研究学报,2002,16(2):158.
[62]Wada Y.,Sakata T.,Mori H.,Sumida T.,Kitamura T.,Yanagida S.,Kuramoto H..Preparation of nano-sized nickel metal particles by microwave irradiation[J].Chemistry Letters,1999,28(7):607-608.
[63]Capek I..Preparation of metal nanoparticles in water-in-oil(W/O)microemulsion [J].Advances in Colloid and Interface Science,2004,110:49-74.
[64]Martin J.E.,Wilcoxon J.P.,Odinek J.,et al..Control of the Interparticle spacing in Gold Nanoparticle superlattics[J].J.Phys.Chem.B,2000,104(40):9475-9486.
[65]Martin J.E.,Wilcoxon J.P.,Odinek J.,et al..Superlattics of Platinum and Palladium Nanopartices[J].J.Phys.Chem.B,2002,106(5):971-978.
[66]Wilcoxon J.P.,Provencio P.P..Use of surfactant micelles to Control the structural phase of nanosize iron clusters[J].J.Phy.Chem.B,1999,103(45):9809-9812.
[67]Taleb A.,Petit C.,Pileni M.P.Optical Properties of Self-Assembled 2D and 3D Superlattices of Silver Nanoparticles[J].J.Phys.Chem.B.,1998,102(12):2214-2220.
[68]Petit C.,Taleb A.,Pileni M.P.Cobalt Nanosized Particles Organized in a 2D Superlattice:Synthesis,Characterization,and Magnetic Properties[J].J.Phys.Chem.B,1999,103:1805-1810.
[69]Legrand J.,Petit C.,Pileni M.P.Domain Shapes and Superlattices Made of 8 nm Cobalt Nanocrystals:Fabrication and Magnetic Properties[J].J.Phys.Chem.B,2001,105:5643-5646.
[70]Martino A.,Stokel M.,Hicks M.,et al.The synthesis and characterization of iron colloid catalysts in inverse micelle solutions[J].Appl.Catal.A:General,1997,161:235.
[71]Chen D.H.,Wu S.H..Synthesis of nickel nanoporticles in water-in-oil microemulsions[J].Chem.Mater.,2000,12(5):1354-1360.
[72]Ni X.M.,Su X.B.,Yang Z.P.,et al..The Preparation of Nickel nanorods in water-in-oil microemulsion[J].Joumal of Crystal Grouth,2003,252:612-617.
[73]M.Arturo Lopez-Quintela,Jose Rivas.Chemical Reactions in Microemulsions:A Powerful Method to Obtain Ultrafine Particles[J].Journal of Colloid and Interface Science,1993,158:446-451.
[74]张朝平,邓伟,胡林等.微乳液法制备超细Ni-Fe复合物微粒[J].无机材料学报,2001,16(3):481-485.
[75]胡林,张朝平.镍/铁复合纳米微粒中与粒径相关的控制参数及磁性能分析[J].化学物理学报,2001,14(5):518-522.
[76]Legrand J.,Taleb A.,Gota S.,et al.Synthesis and XPS Characterization of Nickel Boride Nanoparticles[J].Langmuir,2002,18(10):4131-4137.
[77]Chatterjee A.,Chakravorty D.[J].J.Mater.Sci.,1992,50:566.
[78]Kapoor S.,Salunke H.G.,Tripathil A.K.,et al..Radiolytic preparation and catalytic properties of nanophase nickel metal Particles[J].Materials Research Bulletin,2000,35:143-148.
[79]陈祖耀,陈畋,朱英杰等.γ-射线辐射从溶液环境中制得金属镍超细粉的晶粒度和磁学性质[J].化学物理学报,1997,10(1):26-30.
[80]Wang F.,Zhang Z.C.,Chang Z.Q..Effects of magnetic field on the morphology of nickel nanocrystals prepared by gamma-irradiation in aqueous solution[J].Materials Letters,2002,55(1-2):27-29.
[81]何峰,汪武祥,韩雅芳等.制备超细金属粉末的新型电解法[J].粉末冶金技术,2001, 19(2):80-82.
[82]Mishra R.S.,Valiev R.Z.,Mcfadden S.X.,et al..Severe plastic deformation processing and high strain rate superplasticity in an aluminum matix composite[J].Scripta Materialia,1990,40(1):1151-1155.
[83]王文平,高燕,薛群基等.电沉积镍纳米晶材料制备及性能[J].电镀与涂饰,2004,23(3):1-2.
[84]Delplancke J.L.,Dille J.,Reisse J.,et al..Magnetic nanopowders:ultrasound-assisted electrochemical preparation and properties[J].Chem.Mater.,2000,12(4):946-955.
[85]Xia B.,Lenggoro I.W.,Okuyama K..Preparation of Ni particles by ultrasonic spray pyrolysis of NiCl_2·6H_2O precursor containing ammonia[J].J.Mater.Sci.,2001,30:1701-1705.
[86]张晟卯,张春丽,吴志申等.室温离子液体介质中尺寸、结构可控Ni纳米微粒的制备及结构表征[J].化学学报,2004,62(15):1443-1446.
[87]Eckert J.,Holzer J.C.,et al..Synthesis and characterization of ball milled nanocrystallie fcc metals[J].Mater.Res.Soc.Symp.Proc.,1992,238:745.
[88]李宇农,何建军,龙小军.纳米金属粉末研究进展[J].粉末冶金工业,2004,14(1):34-39.
[89]Deng J.F.,Li H.X.,Wang W.J..Progress in design of new amorphous alloy catalysts[J].CatalysisToday,1999,51:113-125.
[90]Wong S.T.,Lee J.F.,Chen J.M.Preparation and characterization of MCM-41 and silica supported nickel boride catalysts[J].J.Mol.Catal.A:Chem.,2001,165(1-2):159-167.
[91]Deng J.F.,Zhang X.P.,Min E.Z.Amorphous Nickel-Phosphorus Alloy Deposited on a Support and Its Hydrogenation Activity[J].Appl.Catal.,1988,37:339-343.
[92]沈俭一,李智渝,陈懿.Ni-B超细非晶合金的化学制备,反应机理及性质研究[J].无机化学学报,1995,11(1):1-7.
[93]Shen J.Y.,Li Z.Y.,Yan Q.J.,Chen Y..Reaction of bivalent metal ions with borohydride in aqueous solution for the preparation of ultrafine amorphous alloy particles[J].J.Phys.Chem.,1993,97(32):8504-8511.
[94]李同信,张秀峰,李合秋等.非晶态超微粒子镍合金催化剂的研究I.Ni-B合金的制备及表征[J].催化学报,1995,16(4):299-303.
[95]Li H.X.,Li H.,Dai W.L.,Qiao M.H..Preparation of the Ni-B amorphous alloys with Variable boron content and its correlation to the hydrogenation activity[J].Applied Catalysis A..General,2003,238:119-130.
[96]He Y.G.,Qiao M.H.,HuH.R.,et al..Preparation of amorphousNi-B alloy:the effete of feeding order,Precursor salt,PH and adding rate[J].Materials Letters,2002,56:952-957.
[97]马爱增.负载型Ni—B非晶态合金催化剂的表征及催化性能[J].催化学报,1999,20(6):603-607.
[98].杨建明,吕剑,安忠维.非晶合金镍系催化剂研究进展[J].工业催化,2000,8(5):18-24.
[99].徐长青,朱大建,李光兴.Ni-B非晶态催化材料研究进展[J].功能材料,2004增刊,35:1974-1982.
[100]张迪倡,宗保宁,金泽明等.稀土(Y、Ce、Sm)对Ni-P非晶态合金热稳定性的影响 [J].物理化学学报,1993,9(3):325-330.
[101]Hou Y.J.,Wang Y.Q.,Mi W.L.,et al..Effects of Lanthanum addition on Ni-B amorphous alloy catalysts used in anthraquinone hydrogenation[J].React.Kinet.Catal.Lett.,2003,80(2):233-239.
[102]Hou Y.J.,Wang Y.Q.,He F.,et al..Effeets of Lanthanum addition on Ni-B/γ-Al_2O_3amorphous alloy catalysts used in anthraquinone hydrogenation[J].Applied Catalysis A:General,2004,259:35-40.
[103]李风仪,张荣斌,石秋杰,罗来涛.稀土在负载型非晶态Ni-B/Al_2O_3合金上作用研究[J].稀土,2000,21(4):38-42.
[104]王晓光,闫文胜,钟文杰.EXAFS研究Ni-B和Ni-Le-B超细非晶态合金的退火晶化[J].高等学校化学学报,2001,22(3):349-354.
[105]王晓光,张新夷,李忠瑞.Ni-B和Ni-Le-B超细非晶态合金的退火晶化及其催化性能[J].催化学报,2001,22(4):397-401.
[106]石秋杰,张雪红,李凤仪.钐对非晶态NiB合金催化剂性能及表面性质的影响[J].催化学报,1998,19(4):295-299.
[107]Qiujie Shi,Fengyi Li,Laitao Luo。Modification of the Properties of an Amorphous NiB Alloy Catalyst by Samarium[J].Reaction Kinetics and Catalysis Letters,2001,74(1):171-176.
[108]王鹏,仇立干,邢蓉.钐对Ni-B/SiO_2非晶态合金催化剂的催化性能及表面性质的影响[J].稀土,1999,20(1):45-49.
[109]王明辉,李和兴.Ni-B/SiO_2非晶态催化剂应用硝基苯液相加氢制苯胺[J].催化学报,2001,22(3):287-290.
[110]程庆彦,李伟,吴仪隽等.TiO_2负载非晶态NiB催化剂的制备、表征及HDS动力学研究[J].燃料化学学报,2000,28(3):249-252.
[111]王来军,李伟,张明慧等.非晶态合金催化剂NiB(P)/TiO_2的粉末化学镀法制备及其加氢催化性能的研究[J].南开大学学报(自然科学版),2004,37(1):1-6.
[112]Cheng Q Y,Li W,Zhou Y,Zhang M H,Guan N J,Tao K J.Ni-B/TiO_2 Amorphous Catalyst Used in Heavy Arenes of Petrochemicals Hydrogenation[J].Chinese Chemical Letters,2001,12(12):1123-1126.
[113]He Y.G.,Qiao M.H.,Hu H.R.,et al.Characterization and catalytic behavior of amorphous Ni-B/AC catalysts prepared in different impregnation sequences[J].Appl.Catal.A:General,2002,228:29-37.
[114]张荣斌,李凤仪.钕对非晶态Ni-B/膨润土催化剂性能的影响[J].稀土,2004,25(3):42-45.
[115]石秋杰,陈昭萍,罗来涛等.海泡石对非晶态NiB合金催化剂的改性研究[J].物理化学学报,2000,16(6):501-505.
[116]刘波,陈雪莹,庄继华等.负载型Ni-B非晶态合金的制备及其催化加氢活性研究[J].复旦学报(自然科学版),2002,41(4):424-428.
[117]韦世强,李忠瑞,张新夷等.超细Ni-B非晶态合金的退火晶化及其催化性能[J].科学通报,2000,45(18):1941-1944.
[118]Dai W.L.,Li H.X.,Cao Y.,et al..Evidence for the antioxidation effect of Boron on the ultrafine amorphous Ni-B alloy catalyst[J].Langmuir,2002,18(24):9605-9608.
[119]Okamoto Y.,Nitta Y.,Imanaka T.,Teranishi S..Surface Characterization of nickel boride and nickel phosphide catalysts by X-ray photoelectron spectroscopy [J].J.Chem.Soc.FaradayTrans.I,1979,15..2027-2039.
[120]杨军,邓景发.超细Ni-B非晶态合金表面的AES研究[J].化学物理学报,1994,7(2):136-140.
[121]戴维林,曹勇,范康平,邓景发.纳米Ni-Co-B非晶态合金抗氧化行为的原位XPS 研究[J].高等校化学学报,2003,24(3):473-476.
[122]张菊,郑小明,吴念慈,丁云杰.NiCoB超细非晶合金的化学制备和热稳定性研究[J].物理化学学报,1995,11(2):113-17.
[123]马延风,张明慧,李伟等.NiB、NiP与NiPB非晶态合金的物性与催化性能研究[J].南开大学学报(自然科学版),2004,37(3):61-72.
[124]沈俭一,张庆红,李智渝等.超细非晶镍合金的化学制备及类金属元素对性质的影响[J].化学学报,1995,53:1168-1172.
[125]Wang W.J.,Li H.X.,Xie S.H.,et al..Regeneration at room temperature for amorphous NiB/SiO_2 Catalyst deactivaled in cyclopentadiene hydrogenation[J].Appl.Catal.A,1999,184:33-39.
[126]唐忠,张帆,陶庭树等.Ni-Cu-B非晶态合金催化剂对双烯选择性加氢性能的研究[J].石油化工,2000,29(10):754-756.
[127]唐博合金,吕仁庆,项寿鹤.负载型Ni-B非晶态合金在裂解汽油加氢反应中的应用研究[J].石油学报(石油化工),2004,20(2):63-68.
[128]陈海鹰,邓景发,盛世善.非晶态金属合金作催化材料的研究:V.Ni—W—P非晶态合金微粉催化加氢活性研究[J].化学学报,1994,52:877-882.
[129]马爱增,陆婉珍,闵恩泽.非晶态合金催化剂对乙烯中微量乙炔的选择加氢[J].石油学报,1996,12(2):29-37.
[130]Moular A.,Smith G.V.,Mihaly B.,et al..Selective hydrogenation of enthylene ever amorphousNi-SiO_2[J].J.Catal.,1986,101:67.
[131]李同信,张秀峰,李合秋.非晶态超微粒子镍合金催化剂的研究[J].催化学报,1995,16(5):399-402.
[132]Zhang R.B.,Li F.G.,Zhang N.,et al..Benzene hydrogenation over amorphous NiB/bentonite catalyst and promoting effect ofNd[J].Appl.Catal.A,2003,239:17-23.
[133]Li J.,Qiao M.H.,Deng J.F..Amorphous Ni-B/γ-Al_2O_3 Catalyst Prepared in modified drying approach and its excellent activity in benzene hydrogenation[J].Journal of Molecular Catalysis A:Chemical,2001,169:295-301.
[134]Lee S.P.,Chen Y..Nitrobenzene hydrogenation on Ni-P,Ni-B,and Ni-P-B materials [J].J.Mol.Catal.A,2000,152:213-223.
[135]Lee S.P.,Chen Y..Catalytic properties of Ni-B and Ni-P ultrafine materials[J].Joumal of Chemical Technology and Biotechnology,2000,75:1073-1079.
[136]Li H.X.,Xu Y.P.,Li H.,et al..Gas-Phase hydrogenation of adiponitrile with selectivity to primary amineover supported Ni-B amorphous catalysts[J].Appl.Catal.A,2001,216:51-58.
[137]王鹏,李辉,曹勇等.负载型非晶合金催化剂(Ni-B/SiO_2)与已晴气固相常压加氢的研究[J].复旦学报(自然科学版),1999,38(1):2-6.
[138]Wang M.H.,Li H.X.,Wu Y.D.,Zhang J..Comparative studies on the catalytic behaviors between the Ni-B amorphous alloy and other Ni-Based catalysts during liquid phase hydrogenation of acetonitrile to ethylamine[J].Materials Letters,2003,57:2954-2964.
[139]徐长青,朱大建,李光兴.Ni-B/SiO_2非晶态催化剂对苯乙酮的催化加氢研究[J].分子催化,2004,18(4):281-285.
[140]乔明华,谢颂海,戴维林.超细非晶态NiWB合金的制备及葡萄糖加氢性能的研究[J].化学学报,2000,58(7):904-908.
[141]梁薇,负载型非晶态合金的结构及催化加氢性能[J].工业催化,2005,13(9):56-60.
[142]张菊,郑小明.超细Ni-(Co)-B非晶态合金的XPS研究[J].科技通报,13(1):26-28.
[143]贺岩峰,齐晓周,廖巧丽等.离子交换树脂负载Ni-B催化剂上异丙醇的液相脱氢[J].石油化工,1998,27(5):329-332.
[144]曲微丽,邬冰,孙芸等.乙二醇在Pt-WO3/C上的电催化氧化[J].物理化学学报,2005,21(7):804-807.
[145]Chu D.,Jiang R..Novel electrocatalysts for direct methanol fuel cells[J].Solid state Ionics,2002,148(3):591-599.
[146]Choon Choi W.,IhL Woo S..Bimetallic Pt-Ru nanowire network for anode material in a direct-methanol fuel cell[J].J.Power Sources,2003,124(2):420-425.
[147]Kim J.W.,Park S.M..Electrochemical Oxidation of Ethanol at Thermally Prepared RuO_2-Modifified Electrodes in Alkaline Media[J].Journal of the Electrochemical Society,1999,146(3):1075-1080.
[148]Nakagawa K.,Konaka R.,Nakata T.Oxidation with Nickel Peroxide.I.Oxidation of Alcohols[J].J.Org.Chem.,1962,27(5):1597-1601.
[149]George M.V.,Balachandran K.S._Nickel-peroxide oxidation of organic compounds [J].Chem.Rev.,1975,75(4):491-519.
[150]Chen Y.L.,Chou T.C.Kinetics and Mechanism of Anodic Oxidation of n-Butanol by Nickel Peroxide[J].Ind.Eng.Chem.Res.,1996,35:2172-2176.
[151]Christoskova St.G.,Danova N.,Georgieva M.,et al.Investigation of a nickel oxide system for heterogeneous oxidation of organic compounds[J].Appl.Catal.,A,1995,12:219-229.
[152]Amjad M.,Pletcher D.,Smith C.The oxidation of at a nickel anode in alkaline t-butanol/water mixtures[J].Journal of the Electrochemical Society,1977,124(2):203-206.
[153]Yoshihito Kunugi,Tsutomu Nonaka,Yong-Bo Chong and Nobuatsu Watanabe.Electroorganic reactions on organic electrodes—part 15:Electrolysis using composite-plated electrodes—part Ⅳ.Polarization study on a hydrophobic Ni/PTFE composite-plated nickel electrode[J].Electroehim.Acta,1992,37(2):353-355.
[154]Manandhar K.,Plecther D.The preparation of high surface area nickel oxide electrodes for synthesis[J].J.Appl.Electrochem.,1979,9:707-713.
[155]黄令,许书楷,汤皎宁,杨防祖,周绍民.Ni-Mo-PTFE复合电极的制备及其对甲醇电氧化的催化性能[J].应用化学,1997,14(8):21-24.
[156]Zeng Y.,Yu S.C.,Li Z.L.,Chen K.,Zhou S.M..Kinetic Model of ethanol oxidation on Ni-Mo alloyelectrode[J].ActaPhysico-Chimica Sinica,2000,16(11):1013-1021.
[157]黄令,杨防祖,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上乙醇的电氧化[J].应用化学,2005,22(6):590-594.
[158]黄令,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上丙醇的电氧化[J]. 高等学校化学学报,1997,18(6):932-937.
[159]孔景临,薛宽宏,何春建等.镍纳米线电极的电化学氧化还原行为及其对乙醇的电化学氧化催化作用[J].应用化学,2001,18(6):462-465.
[160]孔景临,薛宽宏,邵颖等.镍纳米线电极对乙醇的电催化氧化动力学参数的测定[J].物理化学学报,2002,18(3):268-271.
[161]Lo Yi Ling;Hwang Bing Joe.Kinetics of ethanol oxidation on electroless Ni-P/SnO_2/Ti electrodes in KOH solutions[J].J.Electrochem.Soc.,1995,142(2):445-450.
[162]Berchmans S,Gomathi H,Rao G P.Electrooxidation of alcohols and sugars catalysed on a nickel oxide modified glassy carbon electrode[J].J.Electroanal.Chem..,1995,394(1-2):267-270.
[163]Schrebler Guzman R S,Vilche J R,Arvia A J.The potentiodynamic behaviour of nickel in potassium hydroxide solutions[J].J.Appl.Electrochem.,1978,8:67-70.
[164]Robertson P M.On the oxidation of alcohols and amines at nickel oxide electrodes:Mechanistic aspects[J].J.Electroanal.Chem.,1980,111(1):97-104.
[165]俞守耕.低温燃料电池电催化剂的研究近况[J].电源技术,2004,28(12):798-802.
[166]刘昌见,李德平,鲍晓军.蒽的电化学加氢[J].化工学报,2004,55(11):1809-1814.
[167]Ramesh Raju R.,Damodar J.,Jayarama Reddy S..The electrocatalytic hydrogenation of α-aryl acrylic acids[J].Electrochemistry Communication,2002,4:115-117.
[168]Chambrion P.,Roger L.,Lessard J.,etal..The influence of surfactants on the electrocatalytic hydrogenation of organic compounds in micellar,emulsified,and hydroorganic solutions at Raney nickel electrodes[J].Can.J.Chem.,1995,73:804-818.
[169]Itoh N.,Xu W.C.,Hara S.,et al..Electrochemical coupling of benzene hydrogenation and water electrolysis[J].Catalysis Today,2000,56:307-314.
[170]Santana D.D.,Melo G.O.,Lima M.V..Electrocatalytic hydrogenation of organic compounds using nickel sacrificial anode[J].Journal of Electroanalytical Chemistry,2004,569:71-78.
[171]Hu X E,Yang H W,Wang X J,Bai R S.Electrohydrogenation of 4-amino-5-nitrosodimethyluracil with a foamed nickel cathode[J].Journal of Applied Electrochemistry,2002,32:321-328.
[172]Robin D,Comtois M,Martel A.The electrocatalytic hydrogenation of fused polycyclic aromatic compounds at Raney nickel electrodes:in influence of catalyst activation and electrolysis conditions[J].Can.J,Chem.,1990,68:1218-1227.
[173]Mahdavi B,Chambrion P,Binette J..Electrocatalytic hydrogenation of conjugated enones on nickel boride,nickel,and Raney nickel electrodes[J].Can.J.Chem.,1995,73:846-852.
[174]Doherty A P,Christensen P A,Hammntt A.[J].Journal of Electroanalytical Chemistry,1995,386:39-44.
[175]肖秀峰,刘榕芳,朱则善.以Zn-PTFE复合电极电合成频那醇[J].化学通报,2001,10:651-654.
[176]鲁战光,文丽蓉,张积树等.阴极电还原葡萄糖合成山梨醇的研究[J].精细化工中间体,2001,31(5):30-32.
[177]Polcaro A.M.,Demini M.S.,Palmas S.,Electrodeposition of catalysts for hydrogenation of organic molecules:hydrogenation of benzaldehyde[J].Electrochimica Acta,1992, 37(2):365-367.
[178]Quiroz M.A.,Cordova F.,Lamy-Pitara E.,Barbier J..Electrocatalytic hydrogenation of m-xylene on platinized-Platinum electrodes[J].ElectrochimicaActa,2000,45:4291-4298.
[179]Cleghorn S.J.C.,Pletcher D..The mechanism of electrocatalytic hydrogenation of organic molecules at palladium black cathodes[J].Electrochimica Acta,1993,38(213):425-430.
[180]Byran A.,Grimshaw J..Electrochemical conversion of 4-phenylbuten-2-one into 4-phenylbutan-2-ones.Electrocatalytic hydrogenation at a nickel surface[J].Electrochimica Acta,1997,42(13-14):2101-2107.
[181]Zouaoui A.,Stephan O.,Ourari A.,et al..Electrocatalytic hydrogena-tion of ketones and enones at nickel microparticles dispersed into poly(pyrrole-alkylammonium)films [J].Electrochimica Acta,2000,46:49-58.
[182]Martel A.,Mahdavi B.,Lessard J.,etal..Electrocatalytic hydrogenation of phenol on various electrode materials[J].Can.J.Chem.,1997,75:1862-1867.
[183]Ilikti H.,Rekik N.,Thomalla M..Electrocatalytic hydrogenation of phenol in aqueous solutions at a Raney nickel electrode in the presence of cationic surfactants[J].Journal of Applied Electrochemistry,2002,32:603-609.
[184]Ilikti H.,Rekik N.,Thomalla M..Electrocatalytic hydrogenation of alkyl-substitued phenols in aqueous solutions at a Raney nickel electrode in the presence of a non-micelle-forming cationic surfactant[J].Journal of Applied Electrochemistry,2004,34:127-136.
[185]Mahdavi B.,Lafrance A.,Martel A.,et al..Electrocatalytic hydrogeno- lysis oflignin model dimers at Raney nickel electrodes[J].Joumal of Applied Electrochemistry,1997,27:605-611.
[186]Menini R.,Martel A.,Menard H.,et al..The electrocatalytic hydrogenation of phenanthrene at Raney nickel electrodes:the influence of an inert gas pressure[J].Electrochimica Acta,1998,43(12-13):1697-1730.
[187]Coche L.,Ehui B.,Limosin D.,Moutet J.C..Electrocatalytic hydrogenation using precious metal microparticle in redox-active polymer films[J].J.Org.Chem,1990,55(23):5905-5910.
[188]Zouaoui A.,Stephan O.,Carrier M.,Moutet J.C..Electrodeposition of copper into functionalized polypyrrole films[J].Journal of Electroanalytical Chemistry,1999,474:113-122.
[189]Horanyi G..In Horiuti's footsteps:links between catalysis and electrocatalysis [J].Journal of Molecular Catalysis A:Chemical,2003,199:7-17.
[190]Lamy-Pitara E.,Belegridi I.,Barbier J..Liquid phase catalytic hydrogenation under potential control of the catalyst[J].Catalysis Today,1995,24:151-156.
[191]张丽芳.陈赤阳,项志军.环已烷氧化法制备环已酮工艺研究进展[J].北京石油化工学院,2004,12(2).
[192]Amouzegar K.,Savadogo O..Electrocatalytic hydrogenation of phenol on dispersed Pt:reaction mechanism and support effect[J].Electrochimica Acta,1998,43(5-6):503-508.
[193] Amouzegar K., Savadogo O..Electrocatalytic hydrogenation of phenol on dispersed Pt: effect of metal electrochemically active surface area and electrode material [J]. Journal of Applied Electrochemistry, 1991, 27: 539-542.
[194] Dube P., Kerdouss F., Laplante F., et al..Electrocatalytic hydrogenation of cyclohexanone: Simple dynamic cell design[J]. Journal of Applied Electrochemistry, 2003, 33: 541-547.
[1]范雄.X射线金属学[M].北京:机械工业出版社,1981
[2]常铁军,祁欣等.材料近代分析测试方法[M].哈尔滨:哈尔滨工业大学出版社,1999
[3]陈镜泓,李传儒.热分析及其应用[M].北京:科学出版社,1985
[4]熊兆贤等.无机材料研究方法[M].厦门:厦门大学出版社,2001
[5]陆家和,陈长彦.现代分析技术[M].北京:清华大学出版社,1995
[6]张立德,牟季美.纳米材料和纳米结构[M].北京:科学出版社,2001
[7]辛勤.固体催化剂研究方法(上册)[M].北京:科学出版社,2004
[8]黄惠忠.纳米材料分析[M].北京:化学工业出版社,2003
[9]刘世宏,王当憨,潘承璜.X射线光电子能谱分析[M].北京:科学出版社,1988
[10]范康年.谱学导论[M].北京:高等教育出版社,2001
[11]辛勤.固体催化剂研究方法(下册)[M].北京:科学出版社,2004
[12]王典芬.X射线光电子能谱在非金属材料研究中的应用[M].武汉:武汉工业大学出版社,1994
[13]Briggs D.,Seah M.P.,Practical Surface analysis by Auger and X-ray photoelectron spectroscopy[M].New York:John Wiley & Sons,1984
[1]Deng Jingfa,Li Hexing,Wang Weijiang.Progress in design of new amorphous alloy catalysts[J].Catal Today,1999,51:113-125.
[2]Wong S T,Lee J F,Chen J M.Preparation and characterization of MCM-41 and silica supported nickel boride catalysts[J].J Mol Catal A:Chem,2001,165:159-167.
[3]Tony S,Vesselina R.Hydriding properties of Ni-B alloy studied by DSC and thermorgravimetry[J].Thermochimica,1999,326:69-73.
[4]Legrand J.,Taleb A.,Gota S.,et al.Synthesis and XPS Characterization of Nickel Boride Nanoparticles[J].Langmuir,2002,18(10):4131-4137.
[5]Corrias A,Ennas G,Musinu A,Marongiu G,Paschina G.amorphous transition metal-boron ultrafine particles prepared by chemical methods[J].Chem.Mater.,1993,5(12):1722-1726
[6]Wang M H,Li H X,Wu Y D,Zhang J.Comparative studies on the catalytic behaviors between the Ni-B amorphous alloy and other Ni-Based catalysts during liquid phase hydrogenation of acetonitrile to ethylamine[J].Materials Letters,2003,57:2954-2964.
[7]Brooks A R,Clayton C R,Doss k,Lu Y C.On the role of Cr in the passivity of stainless steel[J].J.Electrochem.Soc.,1986,133:2459-2464
[8]Clayton C R,Lu Y C.A bipolar model of the passivity of stainless steels—Ⅲ.The mechanism of MoO_4~(2-)formation and incorporation[J].Corrosion Science,1989,29(7):881-898
[9]Lu Y C,Clayton C R.An XPS study of the passive and transpassive behavior of molybdenum in deaerated 0.1 M HCl[J].Corrosion Science,1989,29(8):927-937
[10]Yousif,K.M.;Smish,B.E.;Jeynes,C.J..[J].Mater.Sci.,1996,31:185
[11]Glavee,G.N.;Klabunde,K.J.;Sorensen,C.M.;Hadjipanayis,G.C.Borohydride reduction of nickel and copper ions in aqueous and nonaqueous media.Controllable chemistry leading to nanoscale metal and metal boride particles[J].Langmuir,1994,10(12):4726-4730
[12]Dai W L,Li H X,Cao Y,et al..Evidence for the antioxidation effect of Boron on the ultrafine amorphous Ni-B alloy catalyst[J].Langmuir,2002,18(24):9605-9608.
[13]Wagner,C.D.;Riggs,W.M.;Davis,L.E.;Moulder,J.F.Handbook of X-ray photoelectron Spectroscopy,Perkin-Elmer Corporation,Physical Electronics Division,Eden Prairie,MN,1978
[14]Petit C,Taleb A,Pileni M P.Self-organization of magnetic nanosized cobalt particles[J]. Advanced Materials, 1998, 10: 259-261.
[15] Beccaria, A.M.;Wang, Y.Z.;Poggi, G. Surf.Interface Anal., 1994, 21: 442
[16] Davidson A, Tempere J F, Che M, Roulet H, Dufour GSpectroscopic Studies of Nickel(II) and Nickel(III) Species Generated upon Thermal Treatments of Nickel/Ceria-Supported Materials [J].J.Phys.Chem., 1996, 100(12): 4919-4929.
[1]Manandlhar K,Plecther D.The preperation of high surface area nickel oxide electrode for synthesis[J].J.Appl.Electrochem.,1979,9:707-713.
[2]Kim J W,Park S M.Electrochemical oxidation of ethanol at thermally prepared RuO_2-Modifified electrodes in alkaline media[J].J.Electrochem.Soc.,1999,146(3):1075-1080.
[3]Cao D,Bergens S H A direct 2-propanol polymer electrolyle fuel cell[J].J.Power Sources,2003,124(1):12-17.
[4]ZENG Yue,YU Shang-Ci,LI Ze-Lin,et al.Kinetic model of ethanol oxidation on Ni-Mo alloy electrode[J].Acta Phys.-chim.Sin.,2000,16(11):1013-1021.
[5]孔景临,薛宽宏,邵颖.镍纳米线电极对乙醇的电催化氧化动力学参数的测定[J].物理化学学报,2002,18(3):268-271.
[6]黄令.功能性电沉积层的形成、结构与性能研究)[D].厦门,厦门大学,1997.
[7]查全性等.电极过程动力学导论[M].北京:科学出版社,2002,368-376.
[8]Cha C S,Li C M.,Yang H X,et al..Powder microelectrodes[J].J.Electroanal.Chem.,1994,47:368-374.
[9]胡蓉晖,杨汉西,刘金成等.微电极定量方法评价贮氢合金的电化学性质[J].电化学,1996,(4):391-396.
[10]Hu X H,Ai X,P,Yang H X,et al..A study of LiMn_2O_4 synthesized from Li_2CO_3 and MnCO_3[J].J.Power Sources,1998,74:240-243.
[11]胡晓宏,艾新平,杨汉西等.锂离子蓄电池正极材料的快速评价[J].电源技术,2003,27(3):281-283.
[12]Burke L D,Twomey T A M.Voltammetric behaviour of nickel in base with particular reference to thick oxide growth[J].J.Electroanal.Chem.,1984,162(1-2):101-119.
[13]Schrebler Guzman R S.Non-equilibrium effects in the nickel hydroxide electrode [J].J.Appl.Electrochem.,1979,9:183-189.
[14]Schrebler Guzman R S,Vilche J R,Arvia A J.The potentiodynamic behaviour of nickel in potassium hydroxide solutions[J].J.Appl.Electrochem.,1978,8:67-70.
[15]黄令,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上丙醇的电氧化[J].高等学校化学学报,1997,18(6):932-937.
[16]马淳安.有机电化学合成导论[M].北京:科学出版社,2002.
[17]孔景临,薛宽宏,何春建.镍纳米线电极的电化学氧化还原行为及其对乙醇的电化学氧化催化作用[J].应用化学,2001,18(6):462-465.
[18]刘建华,杨敬武,唐致远.掺杂球形氢氧化镍的循环伏安特性[J].天津大学学报,2000,33(1):118-121.
[19]周震,阎杰,林进,张允什.纳米Ni(OH)_2的质子扩散行为研究[J].电源技术,1999,23(6):319-321.
[20]王志兴,李新海,陈启元.微电极在Ni(OH)_2使用寿命测定中的应用[J].中南工业大学学报,1997,28(6):551-554.
[21]Wang X Y,Yan J.,Zhang Y S,et al.Cycle voltammetic studies of pasted nickel hydroxide electrode microencapsulated by cobalt[J].J.Appl.Electrochem,1998,28: 1377-1382.
[22]Berchmans S,Gomathi H,Rao G P.Electrooxidation of alcohols and sugars catalysed on a nickel oxide modified glassy carbon electrode[J].J.Electroanal.Chem.,1995,394(1-2):267-270.
[23]Lo Yi Ling;Hwang Bing Joe.Kinetics of ethanol oxidation on electroless Ni-P/SnO_2/Ti electrodes in KOH solutions[J].J.Electrochem.Soc.,1995,142(2):445-450.
[24]查全性等.电极过程动力学导论[M].北京:科学出版社,2002,183-189.
[25]马淳安.有机电化学合成导论[M].北京:科学出版社,2002,47-55.
[26]黄令,杨防祖,许书楷,周绍民.碱性介质中高择优取向(220)镍电极上乙醇的电氧化[J].应用化学,2005,22(6):590-594.
[1]Deng Jingfa,Li Hexing,Wang Weijiang.Progress in design of new amorphous alloy catalysts[J].Catal Today,1999,51:113-125.
[2]Lee S P,Chen Y W.Effects of preparation on the catalytic properties of Ni-P-B ultrafine materials[J].Ind.Eng.Chem.Res.,2001,40(6):1495-1499.
[3]Ivanov M V,Lubin E N,Drovosekov A B.X-Ray Photoelectron Spectroscopy of Chemically Deposited Amorphous and Crystalline Ni-B Coatings[J].Protection of Metals,2003,39(2):133-141
[4]Dai Weilin,Li Hexing,Cao Yong,et al.Evidence for the antioxidation effect of boron on the ultrafine amorphous Ni-B alloy catalyst[J].Langmuir,2002,18:9605-9608.
[5]马延风,张明慧,李伟,张宝贵,陶克毅.高比表面NiP非晶态合金的制备及其催化性能[J].催化学报,2004,25(12):973-978
[6]王晓光,闫文胜,钟文杰.EXAFS研究Ni-B和Ni-Le-B超细非晶态合金的退火晶化[J].高等学校化学学报,2001,22(3):349-354.
[7]郑一雄,姚士冰,周绍民.Ni-Mo-B非晶态合金纳米颗粒的抗氧化性能研究[J].物理化学学报,2004,20(11)::1352-1356.
[8]Zysler R D,Ramos C A.Chemical synthesis and characterization of amorphous Fe-Ni-B magnetic nanoparticles[J].J.Materials Science,2001,36:2291-2294.
[9]戴维林,曹勇,范康平,邓景发.纳米Ni-Co-B非晶态合金抗氧化行为的原位XPS 研究[J].高等校化学学报,2003,24(3):473-476.
[10]Capek I.Preparation of metal nanoparticles in water-in-oil(w/o)microemulsion[J].Advances in Colleid and Interface Science[J],2004,110:49-74.
[11]Mandal M,Kundu S,Ghosh S K.etal.Wet chemical method for synthesis of superparamagnetic alloyed Ni-Pd and Ni-Pt nanomagnets in micelles[J].J.Colloid and Interface Science,2003,265:23-28.
[12]Lin X M,Sorensen C M.Temperature Dependence of Morphology and Magnetic Properties of Cobalt Nanoparticles Prepared by an Inverse Micelle Technique[J].Langmuir[J],1998,14:7140-7146.
[13]Khiew P S,Huang N M,Radiman S.etal.Synthesis of NiS nanoparticles using a sugar-ester nonionic water-in-oil microemulsion[J].Materials Letters,2004,58:762-767
[14]Janos B Nagy,Isabelle Bodart-Ravet,Eric G Derouane.Faraday Discussions of the Chemical Society[J],1989,87:189-198.
[15]Legrand J,Taleb A,Gota S,et al.Synthesis and XPS Characterization of Nickel Boride Nanoparticles[J].Langmuir,2002,18(10):4131-4137.
[16]Lufimpadio N,Nagy J B,Derouane E G.Surfactants Solution[J],1984,3:1483-1485.
[17]张朝平,邓伟,胡林等.微乳液法制备超细Ni-Fe复合物微粒[J].无机材料学报,2001,16(3):481-485.
[18]方鲲,李守平,崔陇兰.超微镍粒子/聚苯胺纳米复合材料制备及其表征[J].化学物理学报),2003,16(3):163-165
[19]郭建华,张蕴珊.电镀镍硼合金镀层结构与性能[J].东北大学学报(自然科学版), 1995,94(1):41-45
[20]韦世强,李忠瑞,张新夷等.超细Ni-B非晶态合金的退火晶化及其催化性能[J].科学通报,2000,45(18):1941-1944
[21]Moulder J F,Stickle W F,Sobol P E.etal..Handbook of x-ray Photoelectron Spectroscopy[M],Minnesota:Physical Electronics,Inc.,1995
[22]Okamoto Y,Nitta Y,Imanaka T,Teranishi S.Surface Characterization of nickel boride and nickel phosphide catalysts by X-ray photoelectron spectroscopy[J].J.Chem.Soc.Faraday Trans.I,1979,15:2027-2039.
[23]沈俭一,李智渝,陈懿.Ni-B超细非晶合金的化学制备,反应机理及性质研究[J].无机化学学报,1995,11(1):1-7.
[24]Krasteva N,Forty V,Armyanov S J.Thermal stability of Ni-P and Ni-Cu-P amorphous alloys[J].Electrochem.Soc.,1994,141:2864-2867.
[1]刘永辉.电化学测试技术[M].北京:北京航空学院出版社,1987
[2]陈体衔.实验电化学[M].厦门:厦门大学出版社,1993
[3]Nichols R J,Bewick A.Spectroscopic identification of the adsorbed intermediate in hydrogen evolution on platinum[J].J.Electroanal.Chem.,1988,243(2):445-453.
[4]Noritoshi Nanbu,Fusao Kitamura,Takeo Ohsaka.Adsorption of atomic hydrogen on a polycrystalline Pt electrode surface studied by FT-IRAS:the influence of adsorbed carbon monoxide on the spectral feature[J].J.Electroanal.Chem.,2000,485(2):128-134.
[5]Martins M E,Zinola C F,Andreasen G,SalvarezzaA C,ArviaA J.Possible existence of subsurface H-atom adsorbates and H_2 electrochemical evolution reaction intermediates on platinum in acid solutions[J].J.Electroanal.Chem.,1998,445:135-154.
[6]Clavilier J,Faure R,Guinet G,Durand R.Preparation of monocrystalline Pt microelectrodes and electrochemical study of the plane surfaces cut in the direction of the 111 and 110 planes[J].J.Electroanal.Chem.,1980,107(1):205-209.
[7]Clavilier J,Armand D,Wu B L.Electrochemical study of the initial surface condition of platinum surfaces with(100)and(111)orientations[J].J.Electroanal.Chem.,1982,135(1):159-166.
[8]Yoshio Takasu,Yuichi Fujii,Kozo Yasuda,Yukinori Iwanaga,Yoshiharu Matsuda.Electrocatalytic properties of ultrafine platinum particles for hydrogen electrode reaction in an aqueous solution of sulfuric acid[J].Electrochim.Acta,1989,34(3-4):453-458.
[9]Masae P Sumino,Shigeo Shibata.Specific adsorption of hydrogen on polycrystalline platinum electrode[J].Electrochim.Acta,1992,37(14):2629-2635.
[10]Hu C C,Wen T C.Effects of the nickel oxide on the hydrogen evolution and para-nitroaniline reduction at Ni-deposited graphite electrodes in NaOH[J].Electrochimica Acta,1998,43(12-13):1747-1756.
[11]De Giz M J,Machcado S A S,Avaca L A,Gonzalez E R.High area Ni-Zn and Ni-Co-Zn codeposits as hydrogen electrodes in alkaline solutions[J].J.Appl.Electrochem.,1992,22:973-977.
[12]Beden B,Bewick A.The anodic layer on nickel in alkaline solution:an investigation using in situ IR spectroscopy [J].Electrochimica.Acta, 1988, 33(11): 1695-1698.
[13] Hahn F, Floner D, Beden B, Lamy C. In situ investigation of the behaviour of a nickel electrode in alkaline solution by uv-vis and ir reflectance spectroscopies[J]. Electrochimica Acta, 1987, 32(11): 1631-1636.
[14] Burchardt T, Hansen V, Valand T.Microstructure and catalytic activity towards the hydrogen evolutiou reaction of electro-deposited NiP_x alloys[J]. Electrochimica Acta, 2001, 46: 2761-2706.
[15] Vandenborre H, Vermeiren P H, Leysen R.Hydrogen evolution at nickel sulphide cathodes in alkaline medium[J].Electrochim.Acta, 1984, 29(3): 297-301.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |