流体中烃类组分与金属成矿关系研究及其在找矿勘查中的应用
|
摘要
自然界中烃类组分赋存空间之广、范围之大超乎人们的想象:地表和近地表各类岩石和土壤中普遍存在烃类组分;研究证据表明现代海底烟囱、海槽现代活动热水区和火山喷发气体中也含有烃类组分;现代大陆、大洋深钻手段已证实在地壳8～12km的深度仍存在大量含烃类的高盐度流体;幔源基性——超基性岩以及玄武岩的包裹体中也发现有烃类组分的存在;甚至在陨石(碳质球粒陨石)中同样发现了包括烷烃组分在内的各类有机化合物。对烃类组分的研究不应局限于石油、天然气和煤炭等能源矿产,而应该推广到金属矿床及其成矿流体的研究中来。烃类气体具有组分多元化和性质稳定的特点,更重要的是烃类各组分间的相关特征和配分规律是其地质流体演化过程的重要参数,所以通过对烃类组分的研究,可以更好的了解成矿物质来源、流体演化和成矿模式,从而指导今后找矿新方法的研究和应用。
为了将流体演化过程中烃类组分的细微变化用直观的方法和手段表现出来,本文提出了建立烃类组分标准化背景并将各类烃类组分进行标准化处理的思路,其意义类似地球化学中球粒陨石作为标准化稀土元素背景的建立。探索性将具有幔源流体特征的峨眉山玄武岩作为烃类组分的标准化背景,应用效果证明该方法手段可将不同类型地质体烃类组分的差异性和演化的规律性非常直观的表现出来,使研究方法从以往单纯的烃类组分宏观异常特征归纳,发展为对烃类组分的叠加改造、配分模式以及相关特征的微观规律研究;将以往烃类组分仅作为有机质参与金属成矿的表征现象,发展为一种应用于成矿物质来源、成矿流体演化及成矿作用和规律的研究工具和手段。烃类组分与金属成矿关系密切,从矿质的初始富集到活化转移、富集成矿、直至矿体形成后的变质改造整个过程,烃类作为重要的伴生组分始终参与其中并在不同的演化阶段表现出不同的特征。所以全面而系统地研究烃类组分在各类金属矿床以及不同地质体上的宏观和微观特征,一方面有利于成矿流体来源性质、成矿特征和成矿模式的理论研究,另一方面在实际金属矿产勘查方面也有非常大的应用前景。
The space and scope of hydrocarbon existed in the nature are so extensive. It widely existed in many kinds of rock of earth's surface(or near earth's surface) , also occurrences in chimney of modern sea bottom, hot water area of modern sea slot movable and volcano gas. It has been make sure that great quantities of high salt degree fluid containing hydrocarbon existed in the earth’s crust of 8~12 km depth. The researchers also discovered hydrocarbon in inclusions of basic-ultrabasic rock and basalt from mantle of the earth ,even various organic compounds(include hydrocarbon) had been found in the meteorite(carbonaceous chondrite). The research works on hydrocarbon shouldn’t be limited only in the energy minerals such as petroleum, natural gas and coal etc,in fact it should be expanded to the research of metal mineral and mineral fluid. Hydrocarbon has a set of diversification and the property stable characteristics. And the relativity and distribution coefficient for each unit of hydrocarbon are more important parameters of the geologic fluid evolution. So the research works on hydrocarbon could be helpful to comprehend mineral source, fluid evolution, metllogenic mode and give guide to the new method seeking for mineral exploration .
For the purpose of directly embodiment for the fine distinction of fluid evolving of hydrocarbon, the author offers a proposal to establish standardized background for hydrocarbon. Its significance is same as establishment of standardized background for REE with chondritic meteorite. The standardized background of hydrocarbon is experimented to be established with the hydrocarbon of Emeishan basalts which have the characteristic of mantle source fluid. The effect has been attested that the otherness of difference kind of hydrocarbon and the regularity of fluid evolution could be embodied clearly by this way .It not only actuates the research on hydrocarbon from pute macrofeature to microscopic feature, but also expanded the research methods from surface phenomena that hydrocarbon being simple participant in metallic ore forming to the important tool and instrument for researching source of ore , evolving of ore solution, regularity of mineralization.
It has intimate connection between metallic ore forming and hydrocarbon in the whole process: from mineralizing fluid preliminary enrichment , activity transfer ,metallic ore forming,until the metamorphism and alteration. As associate component, hydrocarbon is the important active participant and had different characteristics during the metallic ore forming. So the systematized research of hydrocarbon including macro feature and microscopic features from different geologic bodies would be helpful not only to the theory study of mineral source, fluid evolution and metllogenic mode, but also to the actual metallic ore deposit exploration.
为了将流体演化过程中烃类组分的细微变化用直观的方法和手段表现出来,本文提出了建立烃类组分标准化背景并将各类烃类组分进行标准化处理的思路,其意义类似地球化学中球粒陨石作为标准化稀土元素背景的建立。探索性将具有幔源流体特征的峨眉山玄武岩作为烃类组分的标准化背景,应用效果证明该方法手段可将不同类型地质体烃类组分的差异性和演化的规律性非常直观的表现出来,使研究方法从以往单纯的烃类组分宏观异常特征归纳,发展为对烃类组分的叠加改造、配分模式以及相关特征的微观规律研究;将以往烃类组分仅作为有机质参与金属成矿的表征现象,发展为一种应用于成矿物质来源、成矿流体演化及成矿作用和规律的研究工具和手段。烃类组分与金属成矿关系密切,从矿质的初始富集到活化转移、富集成矿、直至矿体形成后的变质改造整个过程,烃类作为重要的伴生组分始终参与其中并在不同的演化阶段表现出不同的特征。所以全面而系统地研究烃类组分在各类金属矿床以及不同地质体上的宏观和微观特征,一方面有利于成矿流体来源性质、成矿特征和成矿模式的理论研究,另一方面在实际金属矿产勘查方面也有非常大的应用前景。
The space and scope of hydrocarbon existed in the nature are so extensive. It widely existed in many kinds of rock of earth's surface(or near earth's surface) , also occurrences in chimney of modern sea bottom, hot water area of modern sea slot movable and volcano gas. It has been make sure that great quantities of high salt degree fluid containing hydrocarbon existed in the earth’s crust of 8~12 km depth. The researchers also discovered hydrocarbon in inclusions of basic-ultrabasic rock and basalt from mantle of the earth ,even various organic compounds(include hydrocarbon) had been found in the meteorite(carbonaceous chondrite). The research works on hydrocarbon shouldn’t be limited only in the energy minerals such as petroleum, natural gas and coal etc,in fact it should be expanded to the research of metal mineral and mineral fluid. Hydrocarbon has a set of diversification and the property stable characteristics. And the relativity and distribution coefficient for each unit of hydrocarbon are more important parameters of the geologic fluid evolution. So the research works on hydrocarbon could be helpful to comprehend mineral source, fluid evolution, metllogenic mode and give guide to the new method seeking for mineral exploration .
For the purpose of directly embodiment for the fine distinction of fluid evolving of hydrocarbon, the author offers a proposal to establish standardized background for hydrocarbon. Its significance is same as establishment of standardized background for REE with chondritic meteorite. The standardized background of hydrocarbon is experimented to be established with the hydrocarbon of Emeishan basalts which have the characteristic of mantle source fluid. The effect has been attested that the otherness of difference kind of hydrocarbon and the regularity of fluid evolution could be embodied clearly by this way .It not only actuates the research on hydrocarbon from pute macrofeature to microscopic feature, but also expanded the research methods from surface phenomena that hydrocarbon being simple participant in metallic ore forming to the important tool and instrument for researching source of ore , evolving of ore solution, regularity of mineralization.
It has intimate connection between metallic ore forming and hydrocarbon in the whole process: from mineralizing fluid preliminary enrichment , activity transfer ,metallic ore forming,until the metamorphism and alteration. As associate component, hydrocarbon is the important active participant and had different characteristics during the metallic ore forming. So the systematized research of hydrocarbon including macro feature and microscopic features from different geologic bodies would be helpful not only to the theory study of mineral source, fluid evolution and metllogenic mode, but also to the actual metallic ore deposit exploration.
引文
[1] Bailey D K . Fluid transport and metasomatic storage in the mantle. In: Chemical transport in metasomatic processes.NATO ASI Series C: Mathermatical and Physical Sciences. 1987,218:39-51
[2] Boyle,R. W. The Geochemistry of Gold and its deposits, Geological survey of Canada,Bulletion, 1979, Vol 280:431-438
[3] Burrus R.C. Hydrocarbon fluid inclusion in studies of sedimentary diagenesis,Mineral Assoc.,Canada Short Course Handbook 6,1981.
[4] Chen Yuanrong and Jia Guoxiang.Research and application of new methods to oil-gas geochemical exploration. Acta Geologica Sinica, 2000.Vol.74,No.3
[5] Dozy,J.J. A geological model for the genesis of lead-zinc ores of the Mississippi Valley,USA,Trans. Inst.Min. Metal, Sec.B,1970.
[6] F.I.KASSIMOVA,F.P.MELNIKOV. The problem of hydrocarbon inclusions in the diamond associated minerals. EARTH SCIENCE FRONTIERS,2001,8(3): 53-54
[7] Ferguson, J&Bubela. B. 1975, Simulation of sedimentary ore-forming processes:concentration of Pb and Zn from brines into orgnic and febearing carbonate sediments. Geologishe Rundschan, 64:767~782.
[8] Ferguson, J&Bubela. B.The concentration of Cu(Ⅱ),Pb(Ⅱ),&Zn(Ⅱ) from aqueous solutions by particulate algal matter.Chem.Geol. 1975,13:163～186.
[9] Fraser,D.C.Organnic of copper . Econ. 1961.Geol.56:1063~1078.
[10] Giordano T H. A preliminary evolution of organic ligands and metallogenic complexing in Mississippi Valley Type Ore solutions. Eton. Geol.1985,80:96- 106
[11] Grilhaumou.N. Characterization of hydrocarbon fluid inclusions by infra-red and fluorescence microspectro-metry,Mineralogical Magazine, 1990,54:311～324.
[12] James.E.Gingrish. Journal of Geochemical Exploration.1984,Vo.21
[13] Khorasani,G.K. Novel development in Fluorescence microscopy of complex organic mixtures: Application in petroleum geochemistry,OrgGeochem,1987,11(3):157～165
[14] Lowestern J B. Carbon dioxide in magmas and implications for hydrotbermal systems. Mineralium Deposita, 2001,36:490- 502
[15] MacGroman D, Surdam R C. Difunctional Carboxylic and acid anions in oil-fieldwaters,Organic Geochem. 1988, 12:245～259
[16] Pasava J, Kribek B, Dobes P, et al. Tin-polymetallic sulfide deposits in the eastern part of the Dachana tin field (South China) and the role of black shales in their origin[J]. Mineralium Deposita. 2003. 38:39-66
[17] Qiu Y M,Groves D I,MacNaughton R J,Phillips G N. Nature age and tectonic setting of granitoid-hosted, orogenic gold deposits of the Jiaodong Penisula,eastern North China craton China.Mineralium Deposita. 2002 ,37:283-305
[18] Rashid M.A.& King,L.H. Molecular weight distribution measurements on humic and fulvic acid fraction from marine clays on the Scotion Shelf .Geochim et Cosmochim Acta .1969,33: 147-151
[19] Rashid M.A. Role of humic acids of marine origin and their different molecular weight fractions in complexing Di- and Trivalent metals,Soil Science, 1971,Vol.111.
[20] Rashid M.A.et al. Modification in the solubility and precipition behavior of various metals as a result of their interaction with sedimentary humic acid. Chem.Geol. 1973,11:89~97.
[21] Rashid M.A. et. Al. Geological enviroment of methane-rich recent sedimentary basin in the Gulf of St. Lowrence.Chem. Geol. 1975, 15:83-86
[22] Richard D.T. Hydrocarbons associated with lead-zinc ores at Laiswell, Sweden, Nature.1975, 225.
[23] Rose,A.W. et.Al. Geochemistry in Mineral Exploration Second Edition Academic Press. Acta Geologica Sinica, 1979,Vol.74,No.3,2000.
[24] Saxby J.D. The significance of organic matter in ore genesis.in book:Handbook of Strata-Bound and Stratiform ore Deposits,ed by Wolk K.H.,Oxford, 1976,Vol.2.
[25] Simoneit B.R.T. Hydrothermal petroleum:genesis,migration and deposition in Guaymas Basin, Gulf of California,Canadian J.Earth Sci. 1985,Vol.22.
[26] Surdam R C,The Chemistry of Secondary porosity: In clastic diagenesis,Am Assoc Pet Geol Mem, 1984,37:127～150
[27] Wopenka B, Pasteris J.D , Freeman J J. Analysis of individual fluid inclusions by fourier transform infrared and Raman microspectroscopy,Geochim Cosmochim Acta, 1990,54:519～533.
[28] 陈毓川,黄民智,徐珏等.大厂锡石-硫化物多金属矿带地质特征及成矿系列.地质学报,1985,(3):228-240
[29] 陈毓川,黄民智,徐珏,胡云中等.大厂锡矿地质.北京:地质出版社.1993.
[30] 陈远荣,戴塔根等.金属矿床有机烃气常见异常模式和成因机理研究.中国地质,2001,(4)
[31] 陈远荣,贾国相,徐庆鸿.气体集成快速定位预测隐伏矿的新技术研究.北京:地质出版社. 2003.
[32] 陈远荣,邵世才,徐庆鸿,张月红.马鞍桥金矿的有机烃气结合原生晕测量找矿预测.物探与化探.2003.27(6):465-467.
[33] 陈远荣,徐庆鸿. 山东夏甸金矿地球化学异常分带模型及 V 号矿带深部找矿预测研究.桂林矿产地质研究院科研报告.2002.
[34] 陈远荣,尹意求,贾国相等.地球化学综合方法找矿应用试验研究—以广西贵港庆丰—平南旺石铅锌矿带为例.有色金属矿产与勘查,1999,(6)
[35] 程敦模.有机质在层控汞矿床成因中的作用.沉积学报,1984,(2)
[36] 邓军,杨立强,刘伟等.胶东招掖矿集区巨量金质来源和流体成矿效应.地质科学,2001,36( 4):257-268
[37] 杜乐天. 幔汁 H-A-C-O-N-S 流体. 大地构造与成矿学.1988 ,12(1):87-94
[38] 范德廉,等.南方几省下寒武统黑色岩系及层状多元素富集层.沉积岩石学研究.科学出版社,1981.
[39] 傅家谟,刘德汉,卢家烂.有机质演化对金属元素离散和富集的控制作用.基金项目科研总结.中国科学院有机地球化学开放实验室.1986,1990
[40] 傅家谟,刘德汉.有机质演化与沉积矿床成因(Ⅱ)煤成烃类与层控矿床.沉积学报, 1983.4:15-28.
[41] 傅家漠,刘德汉,卢家烂.层控矿床有机地球化学研究中的几个问题.见:中国科学院地球化学研究所有机地球化学国家重点开放实验室年报(1988).北京:科学出版社,1990,174-185
[42] 高岗,郝石生,朱雷,常亮. 湖相生物碎屑灰岩热模拟气特征. 现代地质.1998,12(1):103-107
[43] 高建国,谈树成,晏建国,等.云南个旧南部地区元素的地球化学特征. 矿物学报,2001,21(4):585-590
[44] 个旧锡矿深部与外围成矿预测及矿山增储研究.云南省省院省校科技合作项目,2004
[45] 何立贤.汞矿带中金矿成矿条件及赋存规律.贵州地质.1990,7(3):187-194
[46] 赫英,王定一,冯有良.胜利油田火山岩中的流体包裹体成分及其意义.地球化学,1996,25(5):468- 474
[47] 侯增谦,张绮玲.冲绳海槽现代活动热水区 CO2-烃类流体:流体包裹体证据. 中国科学,1998,28(2)142-148
[48] 胡凯,刘英俊,王鹤年.华南若千重要含金建造及其金矿床有机地球化学.南京大学学报,1993, 5 (1): 49-57
[49] 贾国相,陈远荣,姚锦琪.我国特殊景观区油气综合化探技术.北京:石油出版社,2003, 61-64.
[50] 李厚民,毛景文,张长青,许虹,陈毓川,王登红. 滇黔交界地区玄武岩铜矿同位素地球化学特征.矿床地质,2004,23(2):232-239.
[51] 李九玲,元锋,徐庆生.微细浸染型(卡林型)金矿成矿过程中碳和有机质的作用.矿床地质,1996, 15(3)193-206
[52] 李瑞生.陕西周至马鞍桥金矿床地质特征及成因分析.陕西地质,1997,15(2):32-38
[53] 李生郁,徐丰孚.轻烃及硫化物气体测量寻找多金属隐伏矿方法试验.物探与化探, 1997, 21(2):128-138.
[54] 李生郁,郑康乐,徐丰孚.微量轻烃气体快速分析方法及其在金属矿化探中的应用.物探与化探,1990,4:303-311.
[55] 李石锦. 云南个旧矿区富锡、铜矿体成矿学浅析.大地构造与成矿学,1998,22(2):148-155
[56] 李树基、张志信等.个旧锡矿地质.北京:冶金工业出版社,1984
[57] 李晓峰,华仁民. 韧性剪切带内流体作用的研究.岩石矿物学杂志.2000,19(4):333-340
[58] 李晓峰.扬子地台西缘金矿成矿流体地球化学.博士后研究工作报告,2003.
[59] 李兆麟,翟伟,李文,石贵勇,文拥军.河台韧性剪切带金矿床成矿物理化学条件研究及熔融包裹体的发现.岩石学报,2000,16(4):514-520.
[60] 廖宗廷,李光明. 巴力一龙头山生物礁古油气藏的特征及成因.同济大学学报,1999,27(1):92-95
[61] 廖宗廷,杨斌. 古海洋中的热水喷口一广西大厂例析.同济大学学报,1995,23(5):564-567
[62] 廖宗廷.广西大厂超大型锡多金属矿床成矿条件及成矿模式.地质找矿论丛.1994,9(2):1-7
[63] 刘春学,秦德先,党玉涛,谈树成.个旧锡矿高松矿田综合信息矿产预测.地球科学进展,2003,18(专刊)
[64] 刘喜山等.变形变质作用及成矿.北京:中国科学技术出版社,1992.
[65] 刘英俊,邱德同编著.勘查地球化学.北京:科学出版社. 1987.
[66] 卢焕章,李秉伦,沈昆.包裹体地球化学.北京:地质出版社,1990,171-177.
[67] 卢焕章.从包裹体研究探索太古代一些金矿的成矿机理.矿物学报,1991,11(4):289～297
[68] 卢焕章.现代海底烟囱中流体包裹体的研究. 岩石学报,2003,19(2):236-241
[69] 毛景文, 李荫清.河北省东坪碲化物金矿床流体包裹体研究:地幔流体与成矿作用. 矿床地质, 2001,20(1):23-26
[70] 毛景文, 魏家秀.大水沟碲矿床流体包裹体的 He、Ar 同位素组成及其示踪成矿流体的来源. 地球学报, 2000.21(1):58-61
[71] 毛景文,赫英,丁悌平. 胶东金矿形成期间地幔流体参与成矿过程的碳、氧同位素证据.矿床地质,2002,21(2):121-128
[72] 毛景文,李晓峰,张荣华,王义天,赫英,张作衡等. 深部流体成矿系统.北京:中国大地出版社,2005
[73] 毛景文,王志良,李厚民,王成玉,陈毓川.云南鲁甸地区二叠纪玄武岩中铜矿床的碳氧同位素对成矿过程的指示.地质论评,2003,49(6):610-613.
[74] 穆太升,董鑫,曲延波,许洪泉,孙忠实.招远市夏甸金矿含金流体成因及就位机制的研究. 山东地质,2001,17(3-4):25-29
[75] 祁士华,阮天健.C11金矿床上的轻烃异常研究.黄金地质,1995,(6).
[76] 秦德先,田毓龙,朱大明.个旧锡矿 33 号矿群地质特征与其外围找矿方向. 矿物学报,2001,21(4):591-595
[77] 阮天健,朱有光.地球化学找矿.北京:地质出版社. 1985.
[78] 邵世才.爆破角砾岩型金矿床的成因及其定位机制.矿物学报,1995. 15(2):231-232.
[79] 沈昆,胡受奚,孙景贵,凌洪飞,赵懿英,孙世明.山东招远大尹格庄金矿成矿流体特征.岩石学报,2000,16(4):542-550
[80] 沈照理译.成矿规律研究中的古水文地质分析.北京:科学出版社,1981
[81] 苏犁,宋述光,王志海.北祁连山玉石沟地幔橄榄岩中富 CH4流体包裹体及其意义.科学通报,1999,(8):73-76
[82] 孙丰月, 石准立, 冯本智. 胶东金矿地质及幔源 C-H-O 流体分异成岩成矿. 长春: 吉林人民出版社, 1998, 1-170
[83] 孙景贵,胡受奚,沈昆,姚凤良.胶东金矿区矿田体系中基性-中酸性岩脉的碳、氧同位素地球化学研究.岩石矿物学杂志,2001,20(1):47-56
[84] 孙晓明,David I. Norman,孙凯,陈炳辉,陈敬德.粤中长坑金银矿硫化物中包裹体的轻烃组成及矿床成因的探讨.自然科学进展,1999,10(9):818-823
[85] 孙晓明,David I. Norman,孙凯,陈敬德,陈炳辉. 流体包裹体轻烃有机气体组成及对矿床成因的制约. 矿床地质,2001,20(1):15-21
[86] 孙忠实,邓军,翟裕生,冯本智.源含金流体主动就位与容矿断裂形成机制.地质地球化学. 1999,27( 4) : 17- 22
[87] 谭运金,韦龙明.扬子地块西北缘及西南缘卡林型金矿的有机质地质地球化学.矿床地质,1997,16(3):130- 138
[88] 涂光炽,杨蔚华,卢家烂等.中国层控矿床地球化学(第二卷).北京:科学出版社,1988. 27-35
[89] 涂光炽. 中国超大型矿床(Ⅰ). 北京:科学出版社. 2000:59-64,129-157,387-396
[90] 汪本善.我国某些煤中锗的成矿条件.地质科学,1963,(4).
[91] 王登红,陈毓川,陈文,桑海清,李华芹,路远发等. 广西南丹大厂超大型锡多金属矿床的成矿时代,地质学报,2004,78(1):132-136
[92] 王恩德,关广岳.金矿床的有机地球化学研究——腐质酸对金银迁移沉淀的作用.地球化学,1993,1:55-60.
[93] 隗合明,丁华.陕西马鞍桥金矿床成因探讨. 黄金地质.1999,5(2):1-8
[94] 魏刚锋,姜修道,刘永华,杜佩轩.铧厂沟金矿床地质特征及控矿因素分析.矿床地质.2000,19(2):138-146
[95] 吴传璧,等著.油气化探发展脉络与思考.北京:地质出版社,1996.
[96] 伍勤生,许俊珍,杨惠.个旧含锡花岗岩锶同位素特征及成矿作用研究.地球化学.1984,(4):293-298
[97] 徐九华, 谢玉玲, 申世良.小秦岭与胶东金矿成矿流体特征对比.矿床地质 1997,16(2):151-162
[98] 徐九华,谢玉玲,王丽君,朱和平,王立权.地幔矿物中 CO2 流体包裹体的微量元素特征.岩石学报,2003,19( 2):307-313
[99] 徐庆鸿,陈远荣,毛景文,李晓峰,李厚民.有机烃在预测隐伏金矿床中的应用及其成因探索. 地质论评,2005,51(5):583-588
[100] 徐庆鸿,谢文清,陈远荣.福建邱村金矿综合地球化学异常分带模型与找矿预测标志. 地质与勘探,2005,41(1):56-61
[101] 徐庆鸿.地应变固体潮对微渗漏作用的动力贡献研究.地学前缘,2001,8(3):177-180
[102] 杨斌,廖宗廷.广西大厂礁灰岩区碳沥青的产状特征及其与多金属成矿关系探讨. 沉积学报,1999,(17)668-673
[103] 杨富全,毛景文,王义天.新疆阿合奇县布隆金矿成矿流体及成矿作用.地学前缘,2004,11(4):504-508.
[104] 杨敏之.金矿床围岩蚀变带地球化学——以胶东金矿为例.北京:地质出版社,1998.1-120
[105] 杨敏之.金矿床新类型、金矿床地球化学、金矿床成矿预测原理(上册).冶金天津地质研究院编.天津:天津出版社局,1989.
[106] 杨天宇,王涵云.原油和干酪根热演变下限模拟实验在研究高变质地区中的应用.天然气工业,1984,4(3):21-24
[107] 杨蔚华,刘友梅.滇中中生代层控铜矿床的地球化学.中国科学,B 辑,1983.
[108] 杨志明,谢玉玲,李光明,徐九华,王葆华.西藏冈底斯斑岩铜矿带厅宫铜矿床流体包裹体研究. 矿床地质,2005,24(6):584-593
[109] 姚晓梅,丁悌平. 广西大厂锡多金属矿床硅质岩和层状矿体氧硅同位素研究. 地球学报.1994,1-2:124-130
[110] 冶金工业部西南冶金地质勘探公司.个旧锡矿地质.北京:冶金工业出版社,1984
[111] 叶连俊.外生矿床陆源汲取成矿论.地质科学,1963,(2).
[112] 叶造军,施继锡,胡瑞忠.贵州大厂锑矿有机质与有机成矿作用.矿物学报,1997,17(3):310-315
[113] 於崇文等.云南个旧成矿区锡石-硫化物矿床原生金属分带形成的地球化学动力学机制.地质学报.1990,64(3):226-237.
[114] 曾允孚,王正英,田洪钧.广西大厂龙头山矿区矿床成因新探.成都地质学院学报,1982,(3):15 一 26.
[115] 翟裕生,邓军,李晓波.区成域矿学.北京:地质出版社,1999, 78-79.
[116] 张欢,高振敏,马德云,陶琰.云南个旧锡矿床成因研究综述. 地质地球化学,2003,31(3):72-73
[117] 张景荣,朱法华.蓝藻富集金的模拟实验及其地质意义.地球化学,1993,1:61～66.
[118] 张丽红.个旧矿区玄武岩地球化学特征及其成矿关系.有色金属设计,2004,31(3):21-22
[119] 张起钻. 广西大厂锡多金属矿田 100 号矿体地质特征及成矿机理探讨. 矿产与地质,1999,13(6):324-329
[120] 张清,邓金灿,邓金灿,陈远荣,徐庆鸿,韦山桃.广西大厂锡矿烃气测量试验研究.矿产与地质,2002,4(16):248-250.
[121] 张群喜,孙忠实.山东夏甸金矿慢源流体初探.地球学报.2003,24(2):127-131
[122] 张拴宏,王书兵.陕西周至马鞍桥金矿控矿构造及成矿模式.地质找矿论丛.1999,14(3):71-77
[123] 张文淮,谭铁龙.江西省金山金矿有机流体与金矿关系. 矿床地质.1998,17(1):15-22
[124] 张文淮.成矿流体及成矿机制.地学前缘.1996,3(3～4):247-249.
[125] 张志坚,夏卫华,张文淮等.锡铁山铅锌矿床有机包裹体及其研究意义.地球科学,1995, 20( 2) : 225-230
[126] 张志坚,张文淮. 有机成矿流体研究进展. 地质科技情报,1998,17(2):45-49
[127] 张志坚,张文淮.有机包裹体研究现状.地质科技情报,1995,14(3):39-43
[128] 郑明华等.层控金矿床概论.成都:成都科技大学出版社,1989. 205-212
[129] 郑庆鳌,杨涤生. 云南个旧锡多金属矿成矿演化与成矿模式.有色金属矿产与勘查,1997,6(2):82-87
[130] 郑庆年,广东凡口铅锌矿.冶金工业出版社,1996
[131] 中国科学院地球化学研究所.高等地球化学 .北京:科学出版社,2000. 352-359.
[132] 中科院地球化学研究所有机地球化学与沉积地球化学研究室.有机地球化学. 北京:科学出版社. 1982.
[133] 中科院地球化学研究所有机地球化学与沉积地球化学研究室.有机地球化学论文集. 北京:科学出版社. 1986.
[134] 周建平,徐克勤,华仁民, 等. 滇东南锡多金属矿床成因商榷. 云南地质, 1997,16(4):309-349
[135] 周建平,徐克勤,华仁民, 等. 个旧等锡矿中沉积组构的发现与矿床成因新探. 自然科学进展,1999,9(5):419-422
[136] 朱永峰,艾永富,赵永超.关于岩浆热液矿床形成的几个问题——以斑岩铜矿为例.矿床地质,1995,14(4):382-383.
[137] 朱永峰,曾贻善,古丽冰.太行山金矿成矿流体的成分——显微红外光谱研究.矿床地质,2000,19(3):266-268.
[138] 朱永峰.液态不混溶作用:成矿机制之一——以太行山地区的金矿为例.矿物岩石地球化学通报,1999,18(1):6-8.
[139] 庄永秋,王任重,杨树培,尹金明.云南个旧锡铜多金属矿床.北京:地震出版社,1996
[2] Boyle,R. W. The Geochemistry of Gold and its deposits, Geological survey of Canada,Bulletion, 1979, Vol 280:431-438
[3] Burrus R.C. Hydrocarbon fluid inclusion in studies of sedimentary diagenesis,Mineral Assoc.,Canada Short Course Handbook 6,1981.
[4] Chen Yuanrong and Jia Guoxiang.Research and application of new methods to oil-gas geochemical exploration. Acta Geologica Sinica, 2000.Vol.74,No.3
[5] Dozy,J.J. A geological model for the genesis of lead-zinc ores of the Mississippi Valley,USA,Trans. Inst.Min. Metal, Sec.B,1970.
[6] F.I.KASSIMOVA,F.P.MELNIKOV. The problem of hydrocarbon inclusions in the diamond associated minerals. EARTH SCIENCE FRONTIERS,2001,8(3): 53-54
[7] Ferguson, J&Bubela. B. 1975, Simulation of sedimentary ore-forming processes:concentration of Pb and Zn from brines into orgnic and febearing carbonate sediments. Geologishe Rundschan, 64:767~782.
[8] Ferguson, J&Bubela. B.The concentration of Cu(Ⅱ),Pb(Ⅱ),&Zn(Ⅱ) from aqueous solutions by particulate algal matter.Chem.Geol. 1975,13:163～186.
[9] Fraser,D.C.Organnic of copper . Econ. 1961.Geol.56:1063~1078.
[10] Giordano T H. A preliminary evolution of organic ligands and metallogenic complexing in Mississippi Valley Type Ore solutions. Eton. Geol.1985,80:96- 106
[11] Grilhaumou.N. Characterization of hydrocarbon fluid inclusions by infra-red and fluorescence microspectro-metry,Mineralogical Magazine, 1990,54:311～324.
[12] James.E.Gingrish. Journal of Geochemical Exploration.1984,Vo.21
[13] Khorasani,G.K. Novel development in Fluorescence microscopy of complex organic mixtures: Application in petroleum geochemistry,OrgGeochem,1987,11(3):157～165
[14] Lowestern J B. Carbon dioxide in magmas and implications for hydrotbermal systems. Mineralium Deposita, 2001,36:490- 502
[15] MacGroman D, Surdam R C. Difunctional Carboxylic and acid anions in oil-fieldwaters,Organic Geochem. 1988, 12:245～259
[16] Pasava J, Kribek B, Dobes P, et al. Tin-polymetallic sulfide deposits in the eastern part of the Dachana tin field (South China) and the role of black shales in their origin[J]. Mineralium Deposita. 2003. 38:39-66
[17] Qiu Y M,Groves D I,MacNaughton R J,Phillips G N. Nature age and tectonic setting of granitoid-hosted, orogenic gold deposits of the Jiaodong Penisula,eastern North China craton China.Mineralium Deposita. 2002 ,37:283-305
[18] Rashid M.A.& King,L.H. Molecular weight distribution measurements on humic and fulvic acid fraction from marine clays on the Scotion Shelf .Geochim et Cosmochim Acta .1969,33: 147-151
[19] Rashid M.A. Role of humic acids of marine origin and their different molecular weight fractions in complexing Di- and Trivalent metals,Soil Science, 1971,Vol.111.
[20] Rashid M.A.et al. Modification in the solubility and precipition behavior of various metals as a result of their interaction with sedimentary humic acid. Chem.Geol. 1973,11:89~97.
[21] Rashid M.A. et. Al. Geological enviroment of methane-rich recent sedimentary basin in the Gulf of St. Lowrence.Chem. Geol. 1975, 15:83-86
[22] Richard D.T. Hydrocarbons associated with lead-zinc ores at Laiswell, Sweden, Nature.1975, 225.
[23] Rose,A.W. et.Al. Geochemistry in Mineral Exploration Second Edition Academic Press. Acta Geologica Sinica, 1979,Vol.74,No.3,2000.
[24] Saxby J.D. The significance of organic matter in ore genesis.in book:Handbook of Strata-Bound and Stratiform ore Deposits,ed by Wolk K.H.,Oxford, 1976,Vol.2.
[25] Simoneit B.R.T. Hydrothermal petroleum:genesis,migration and deposition in Guaymas Basin, Gulf of California,Canadian J.Earth Sci. 1985,Vol.22.
[26] Surdam R C,The Chemistry of Secondary porosity: In clastic diagenesis,Am Assoc Pet Geol Mem, 1984,37:127～150
[27] Wopenka B, Pasteris J.D , Freeman J J. Analysis of individual fluid inclusions by fourier transform infrared and Raman microspectroscopy,Geochim Cosmochim Acta, 1990,54:519～533.
[28] 陈毓川,黄民智,徐珏等.大厂锡石-硫化物多金属矿带地质特征及成矿系列.地质学报,1985,(3):228-240
[29] 陈毓川,黄民智,徐珏,胡云中等.大厂锡矿地质.北京:地质出版社.1993.
[30] 陈远荣,戴塔根等.金属矿床有机烃气常见异常模式和成因机理研究.中国地质,2001,(4)
[31] 陈远荣,贾国相,徐庆鸿.气体集成快速定位预测隐伏矿的新技术研究.北京:地质出版社. 2003.
[32] 陈远荣,邵世才,徐庆鸿,张月红.马鞍桥金矿的有机烃气结合原生晕测量找矿预测.物探与化探.2003.27(6):465-467.
[33] 陈远荣,徐庆鸿. 山东夏甸金矿地球化学异常分带模型及 V 号矿带深部找矿预测研究.桂林矿产地质研究院科研报告.2002.
[34] 陈远荣,尹意求,贾国相等.地球化学综合方法找矿应用试验研究—以广西贵港庆丰—平南旺石铅锌矿带为例.有色金属矿产与勘查,1999,(6)
[35] 程敦模.有机质在层控汞矿床成因中的作用.沉积学报,1984,(2)
[36] 邓军,杨立强,刘伟等.胶东招掖矿集区巨量金质来源和流体成矿效应.地质科学,2001,36( 4):257-268
[37] 杜乐天. 幔汁 H-A-C-O-N-S 流体. 大地构造与成矿学.1988 ,12(1):87-94
[38] 范德廉,等.南方几省下寒武统黑色岩系及层状多元素富集层.沉积岩石学研究.科学出版社,1981.
[39] 傅家谟,刘德汉,卢家烂.有机质演化对金属元素离散和富集的控制作用.基金项目科研总结.中国科学院有机地球化学开放实验室.1986,1990
[40] 傅家谟,刘德汉.有机质演化与沉积矿床成因(Ⅱ)煤成烃类与层控矿床.沉积学报, 1983.4:15-28.
[41] 傅家漠,刘德汉,卢家烂.层控矿床有机地球化学研究中的几个问题.见:中国科学院地球化学研究所有机地球化学国家重点开放实验室年报(1988).北京:科学出版社,1990,174-185
[42] 高岗,郝石生,朱雷,常亮. 湖相生物碎屑灰岩热模拟气特征. 现代地质.1998,12(1):103-107
[43] 高建国,谈树成,晏建国,等.云南个旧南部地区元素的地球化学特征. 矿物学报,2001,21(4):585-590
[44] 个旧锡矿深部与外围成矿预测及矿山增储研究.云南省省院省校科技合作项目,2004
[45] 何立贤.汞矿带中金矿成矿条件及赋存规律.贵州地质.1990,7(3):187-194
[46] 赫英,王定一,冯有良.胜利油田火山岩中的流体包裹体成分及其意义.地球化学,1996,25(5):468- 474
[47] 侯增谦,张绮玲.冲绳海槽现代活动热水区 CO2-烃类流体:流体包裹体证据. 中国科学,1998,28(2)142-148
[48] 胡凯,刘英俊,王鹤年.华南若千重要含金建造及其金矿床有机地球化学.南京大学学报,1993, 5 (1): 49-57
[49] 贾国相,陈远荣,姚锦琪.我国特殊景观区油气综合化探技术.北京:石油出版社,2003, 61-64.
[50] 李厚民,毛景文,张长青,许虹,陈毓川,王登红. 滇黔交界地区玄武岩铜矿同位素地球化学特征.矿床地质,2004,23(2):232-239.
[51] 李九玲,元锋,徐庆生.微细浸染型(卡林型)金矿成矿过程中碳和有机质的作用.矿床地质,1996, 15(3)193-206
[52] 李瑞生.陕西周至马鞍桥金矿床地质特征及成因分析.陕西地质,1997,15(2):32-38
[53] 李生郁,徐丰孚.轻烃及硫化物气体测量寻找多金属隐伏矿方法试验.物探与化探, 1997, 21(2):128-138.
[54] 李生郁,郑康乐,徐丰孚.微量轻烃气体快速分析方法及其在金属矿化探中的应用.物探与化探,1990,4:303-311.
[55] 李石锦. 云南个旧矿区富锡、铜矿体成矿学浅析.大地构造与成矿学,1998,22(2):148-155
[56] 李树基、张志信等.个旧锡矿地质.北京:冶金工业出版社,1984
[57] 李晓峰,华仁民. 韧性剪切带内流体作用的研究.岩石矿物学杂志.2000,19(4):333-340
[58] 李晓峰.扬子地台西缘金矿成矿流体地球化学.博士后研究工作报告,2003.
[59] 李兆麟,翟伟,李文,石贵勇,文拥军.河台韧性剪切带金矿床成矿物理化学条件研究及熔融包裹体的发现.岩石学报,2000,16(4):514-520.
[60] 廖宗廷,李光明. 巴力一龙头山生物礁古油气藏的特征及成因.同济大学学报,1999,27(1):92-95
[61] 廖宗廷,杨斌. 古海洋中的热水喷口一广西大厂例析.同济大学学报,1995,23(5):564-567
[62] 廖宗廷.广西大厂超大型锡多金属矿床成矿条件及成矿模式.地质找矿论丛.1994,9(2):1-7
[63] 刘春学,秦德先,党玉涛,谈树成.个旧锡矿高松矿田综合信息矿产预测.地球科学进展,2003,18(专刊)
[64] 刘喜山等.变形变质作用及成矿.北京:中国科学技术出版社,1992.
[65] 刘英俊,邱德同编著.勘查地球化学.北京:科学出版社. 1987.
[66] 卢焕章,李秉伦,沈昆.包裹体地球化学.北京:地质出版社,1990,171-177.
[67] 卢焕章.从包裹体研究探索太古代一些金矿的成矿机理.矿物学报,1991,11(4):289～297
[68] 卢焕章.现代海底烟囱中流体包裹体的研究. 岩石学报,2003,19(2):236-241
[69] 毛景文, 李荫清.河北省东坪碲化物金矿床流体包裹体研究:地幔流体与成矿作用. 矿床地质, 2001,20(1):23-26
[70] 毛景文, 魏家秀.大水沟碲矿床流体包裹体的 He、Ar 同位素组成及其示踪成矿流体的来源. 地球学报, 2000.21(1):58-61
[71] 毛景文,赫英,丁悌平. 胶东金矿形成期间地幔流体参与成矿过程的碳、氧同位素证据.矿床地质,2002,21(2):121-128
[72] 毛景文,李晓峰,张荣华,王义天,赫英,张作衡等. 深部流体成矿系统.北京:中国大地出版社,2005
[73] 毛景文,王志良,李厚民,王成玉,陈毓川.云南鲁甸地区二叠纪玄武岩中铜矿床的碳氧同位素对成矿过程的指示.地质论评,2003,49(6):610-613.
[74] 穆太升,董鑫,曲延波,许洪泉,孙忠实.招远市夏甸金矿含金流体成因及就位机制的研究. 山东地质,2001,17(3-4):25-29
[75] 祁士华,阮天健.C11金矿床上的轻烃异常研究.黄金地质,1995,(6).
[76] 秦德先,田毓龙,朱大明.个旧锡矿 33 号矿群地质特征与其外围找矿方向. 矿物学报,2001,21(4):591-595
[77] 阮天健,朱有光.地球化学找矿.北京:地质出版社. 1985.
[78] 邵世才.爆破角砾岩型金矿床的成因及其定位机制.矿物学报,1995. 15(2):231-232.
[79] 沈昆,胡受奚,孙景贵,凌洪飞,赵懿英,孙世明.山东招远大尹格庄金矿成矿流体特征.岩石学报,2000,16(4):542-550
[80] 沈照理译.成矿规律研究中的古水文地质分析.北京:科学出版社,1981
[81] 苏犁,宋述光,王志海.北祁连山玉石沟地幔橄榄岩中富 CH4流体包裹体及其意义.科学通报,1999,(8):73-76
[82] 孙丰月, 石准立, 冯本智. 胶东金矿地质及幔源 C-H-O 流体分异成岩成矿. 长春: 吉林人民出版社, 1998, 1-170
[83] 孙景贵,胡受奚,沈昆,姚凤良.胶东金矿区矿田体系中基性-中酸性岩脉的碳、氧同位素地球化学研究.岩石矿物学杂志,2001,20(1):47-56
[84] 孙晓明,David I. Norman,孙凯,陈炳辉,陈敬德.粤中长坑金银矿硫化物中包裹体的轻烃组成及矿床成因的探讨.自然科学进展,1999,10(9):818-823
[85] 孙晓明,David I. Norman,孙凯,陈敬德,陈炳辉. 流体包裹体轻烃有机气体组成及对矿床成因的制约. 矿床地质,2001,20(1):15-21
[86] 孙忠实,邓军,翟裕生,冯本智.源含金流体主动就位与容矿断裂形成机制.地质地球化学. 1999,27( 4) : 17- 22
[87] 谭运金,韦龙明.扬子地块西北缘及西南缘卡林型金矿的有机质地质地球化学.矿床地质,1997,16(3):130- 138
[88] 涂光炽,杨蔚华,卢家烂等.中国层控矿床地球化学(第二卷).北京:科学出版社,1988. 27-35
[89] 涂光炽. 中国超大型矿床(Ⅰ). 北京:科学出版社. 2000:59-64,129-157,387-396
[90] 汪本善.我国某些煤中锗的成矿条件.地质科学,1963,(4).
[91] 王登红,陈毓川,陈文,桑海清,李华芹,路远发等. 广西南丹大厂超大型锡多金属矿床的成矿时代,地质学报,2004,78(1):132-136
[92] 王恩德,关广岳.金矿床的有机地球化学研究——腐质酸对金银迁移沉淀的作用.地球化学,1993,1:55-60.
[93] 隗合明,丁华.陕西马鞍桥金矿床成因探讨. 黄金地质.1999,5(2):1-8
[94] 魏刚锋,姜修道,刘永华,杜佩轩.铧厂沟金矿床地质特征及控矿因素分析.矿床地质.2000,19(2):138-146
[95] 吴传璧,等著.油气化探发展脉络与思考.北京:地质出版社,1996.
[96] 伍勤生,许俊珍,杨惠.个旧含锡花岗岩锶同位素特征及成矿作用研究.地球化学.1984,(4):293-298
[97] 徐九华, 谢玉玲, 申世良.小秦岭与胶东金矿成矿流体特征对比.矿床地质 1997,16(2):151-162
[98] 徐九华,谢玉玲,王丽君,朱和平,王立权.地幔矿物中 CO2 流体包裹体的微量元素特征.岩石学报,2003,19( 2):307-313
[99] 徐庆鸿,陈远荣,毛景文,李晓峰,李厚民.有机烃在预测隐伏金矿床中的应用及其成因探索. 地质论评,2005,51(5):583-588
[100] 徐庆鸿,谢文清,陈远荣.福建邱村金矿综合地球化学异常分带模型与找矿预测标志. 地质与勘探,2005,41(1):56-61
[101] 徐庆鸿.地应变固体潮对微渗漏作用的动力贡献研究.地学前缘,2001,8(3):177-180
[102] 杨斌,廖宗廷.广西大厂礁灰岩区碳沥青的产状特征及其与多金属成矿关系探讨. 沉积学报,1999,(17)668-673
[103] 杨富全,毛景文,王义天.新疆阿合奇县布隆金矿成矿流体及成矿作用.地学前缘,2004,11(4):504-508.
[104] 杨敏之.金矿床围岩蚀变带地球化学——以胶东金矿为例.北京:地质出版社,1998.1-120
[105] 杨敏之.金矿床新类型、金矿床地球化学、金矿床成矿预测原理(上册).冶金天津地质研究院编.天津:天津出版社局,1989.
[106] 杨天宇,王涵云.原油和干酪根热演变下限模拟实验在研究高变质地区中的应用.天然气工业,1984,4(3):21-24
[107] 杨蔚华,刘友梅.滇中中生代层控铜矿床的地球化学.中国科学,B 辑,1983.
[108] 杨志明,谢玉玲,李光明,徐九华,王葆华.西藏冈底斯斑岩铜矿带厅宫铜矿床流体包裹体研究. 矿床地质,2005,24(6):584-593
[109] 姚晓梅,丁悌平. 广西大厂锡多金属矿床硅质岩和层状矿体氧硅同位素研究. 地球学报.1994,1-2:124-130
[110] 冶金工业部西南冶金地质勘探公司.个旧锡矿地质.北京:冶金工业出版社,1984
[111] 叶连俊.外生矿床陆源汲取成矿论.地质科学,1963,(2).
[112] 叶造军,施继锡,胡瑞忠.贵州大厂锑矿有机质与有机成矿作用.矿物学报,1997,17(3):310-315
[113] 於崇文等.云南个旧成矿区锡石-硫化物矿床原生金属分带形成的地球化学动力学机制.地质学报.1990,64(3):226-237.
[114] 曾允孚,王正英,田洪钧.广西大厂龙头山矿区矿床成因新探.成都地质学院学报,1982,(3):15 一 26.
[115] 翟裕生,邓军,李晓波.区成域矿学.北京:地质出版社,1999, 78-79.
[116] 张欢,高振敏,马德云,陶琰.云南个旧锡矿床成因研究综述. 地质地球化学,2003,31(3):72-73
[117] 张景荣,朱法华.蓝藻富集金的模拟实验及其地质意义.地球化学,1993,1:61～66.
[118] 张丽红.个旧矿区玄武岩地球化学特征及其成矿关系.有色金属设计,2004,31(3):21-22
[119] 张起钻. 广西大厂锡多金属矿田 100 号矿体地质特征及成矿机理探讨. 矿产与地质,1999,13(6):324-329
[120] 张清,邓金灿,邓金灿,陈远荣,徐庆鸿,韦山桃.广西大厂锡矿烃气测量试验研究.矿产与地质,2002,4(16):248-250.
[121] 张群喜,孙忠实.山东夏甸金矿慢源流体初探.地球学报.2003,24(2):127-131
[122] 张拴宏,王书兵.陕西周至马鞍桥金矿控矿构造及成矿模式.地质找矿论丛.1999,14(3):71-77
[123] 张文淮,谭铁龙.江西省金山金矿有机流体与金矿关系. 矿床地质.1998,17(1):15-22
[124] 张文淮.成矿流体及成矿机制.地学前缘.1996,3(3～4):247-249.
[125] 张志坚,夏卫华,张文淮等.锡铁山铅锌矿床有机包裹体及其研究意义.地球科学,1995, 20( 2) : 225-230
[126] 张志坚,张文淮. 有机成矿流体研究进展. 地质科技情报,1998,17(2):45-49
[127] 张志坚,张文淮.有机包裹体研究现状.地质科技情报,1995,14(3):39-43
[128] 郑明华等.层控金矿床概论.成都:成都科技大学出版社,1989. 205-212
[129] 郑庆鳌,杨涤生. 云南个旧锡多金属矿成矿演化与成矿模式.有色金属矿产与勘查,1997,6(2):82-87
[130] 郑庆年,广东凡口铅锌矿.冶金工业出版社,1996
[131] 中国科学院地球化学研究所.高等地球化学 .北京:科学出版社,2000. 352-359.
[132] 中科院地球化学研究所有机地球化学与沉积地球化学研究室.有机地球化学. 北京:科学出版社. 1982.
[133] 中科院地球化学研究所有机地球化学与沉积地球化学研究室.有机地球化学论文集. 北京:科学出版社. 1986.
[134] 周建平,徐克勤,华仁民, 等. 滇东南锡多金属矿床成因商榷. 云南地质, 1997,16(4):309-349
[135] 周建平,徐克勤,华仁民, 等. 个旧等锡矿中沉积组构的发现与矿床成因新探. 自然科学进展,1999,9(5):419-422
[136] 朱永峰,艾永富,赵永超.关于岩浆热液矿床形成的几个问题——以斑岩铜矿为例.矿床地质,1995,14(4):382-383.
[137] 朱永峰,曾贻善,古丽冰.太行山金矿成矿流体的成分——显微红外光谱研究.矿床地质,2000,19(3):266-268.
[138] 朱永峰.液态不混溶作用:成矿机制之一——以太行山地区的金矿为例.矿物岩石地球化学通报,1999,18(1):6-8.
[139] 庄永秋,王任重,杨树培,尹金明.云南个旧锡铜多金属矿床.北京:地震出版社,1996
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |