煤中有害元素直接液化迁移行为及其环境效应
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摘要
以山西安太堡太原组11号煤层为研究对象,系统研究了柱状剖面上煤分层中微量元素的地球化学特征和成煤环境演化历程。结合典型煤相的分析,采用直接液化模拟实验等方法,分析比较了液化产物的化学结构特征和有害微量元素分布,探讨了其地质-地球化学机理。结果表明:安太堡11号煤层高硫、高灰特性使得液化产物中微量元素富集具有出彼此“混杂”的特征;液化产物不同溶剂萃取物的产率与显微组分组、黄铁矿(尤其是隐晶质)等因素之间的相关性,揭示微量元素迁移受煤中高度凝胶化组分的控制,微量元素与不同溶剂萃取物具有不同的有机亲和性。研究发现:苯萃取物中微量元素组合含量从亲硫元素-亲铁元素-亲石元素逐渐减少,四氢呋喃可溶物中主要是亲硫、亲铁元素组合;煤中在海侵作用下形成的高有机硫、黄铁矿硫、高有机活性组分的成煤地质特征与煤直接液化总产率正相关,并决定微量元素在液化液态产物中的富集组合主要是亲硫、亲铁元素。同时,探讨分析了煤中有害微量元素和挥发性有害化合物在液化气、液产物及固态残渣的分布特征及其可能产生的环境效应。
Taking the No.11 coal seam of the upper carboniferous Taiyuan formation of Antaibao open pit mine as a case, the research of geochemical characteristics of trace elements in sub-samples on column profile and evolution of coal-forming environment has been systematic studied. With the direct coal liquefaction test on typical sub-samples of various coal facies, deleterious trace elements group compositions and chemical structure of different solvent extracts from liquefying coal have been test and analyzed, the geological-geochemical mechanism has been explored. It concluded that the characteristics of high sulfur and high ash made the enrichment of deleterious trace elements of different liquefying coal products shows“intermix”feature. The correlation between different product yields of solvent extracts from liquefying coal and micro-macerals, pyrite(specially cryptocrystalline texture) indicated the migration of trace elements is controlled by the highly gelating components elements syngenetic combined with gelation organic components in coal, and the inorganic/organic affinity of trace elements with different solvent extracts is various. In benzene-soluble organics the trace elements compatible assemblage content decrease with the sequence of chalcophile element-siderophile element-lithophile element, while in tetrahydrofuran soluble organics the trace elements compatible assemblage content is main conclude chalcophile element-siderophile elementthe, the lithophile element assemblage content is not obvious relative to tetrahydrofuran soluble as the other two element assemblages. The coal-forming geological characteristics of high pyrite, organic sulfur, active component contents is opposite relative to the direct coal liquefaction yield, which determined the chalcophile elements, siderophile elements are the accumulate assemblage in liquefaction products. The possible environment effect of deleterious trace elements and harmful Volatile components in liquefaction products(such as gas, liquid ) and solid residue has been preliminary discussed.
Taking the No.11 coal seam of the upper carboniferous Taiyuan formation of Antaibao open pit mine as a case, the research of geochemical characteristics of trace elements in sub-samples on column profile and evolution of coal-forming environment has been systematic studied. With the direct coal liquefaction test on typical sub-samples of various coal facies, deleterious trace elements group compositions and chemical structure of different solvent extracts from liquefying coal have been test and analyzed, the geological-geochemical mechanism has been explored. It concluded that the characteristics of high sulfur and high ash made the enrichment of deleterious trace elements of different liquefying coal products shows“intermix”feature. The correlation between different product yields of solvent extracts from liquefying coal and micro-macerals, pyrite(specially cryptocrystalline texture) indicated the migration of trace elements is controlled by the highly gelating components elements syngenetic combined with gelation organic components in coal, and the inorganic/organic affinity of trace elements with different solvent extracts is various. In benzene-soluble organics the trace elements compatible assemblage content decrease with the sequence of chalcophile element-siderophile element-lithophile element, while in tetrahydrofuran soluble organics the trace elements compatible assemblage content is main conclude chalcophile element-siderophile elementthe, the lithophile element assemblage content is not obvious relative to tetrahydrofuran soluble as the other two element assemblages. The coal-forming geological characteristics of high pyrite, organic sulfur, active component contents is opposite relative to the direct coal liquefaction yield, which determined the chalcophile elements, siderophile elements are the accumulate assemblage in liquefaction products. The possible environment effect of deleterious trace elements and harmful Volatile components in liquefaction products(such as gas, liquid ) and solid residue has been preliminary discussed.
引文
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