模拟酸雨作用下红壤中多环芳烃的稳定性及释放机制研究
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摘要
本文以红壤为研究对象,研究了酸雨作用下多环芳烃在红壤中的稳定性及释放机制。首先,运用土柱淋溶实验模拟实际的降雨过程,分析了淋出液中溶解性有机质及多环芳烃的释放特征,并对淋出液中多环芳烃和溶解性有机质进行关联分析,得出：在模拟酸雨作用下红壤中有机质和多环芳烃均能被释放出来,模拟酸雨的pH值和淋溶量是影响有机质和多环芳烃释放的重要因素,且多环芳烃是什随着有机质起被释放出来的。其次,分析了红壤不同粒级有机矿质复合体中多环芳烃的分布,发现：不同粒级有机矿质复合体中多环芳烃的含量不同,且多环芳烃的含量与各粒级有机质含量呈显著正相关。最后,从有机矿质复合体的角度,综合运用了傅立叶红外光谱FTIR)、扫描电子显微镜(SEM)、X射线衍射(XRD)和激光共聚焦显微镜(LSCM)、等微观表征手段和波谱学分析方法,探讨了酸雨作用下红壤中多环芳烃的释放机制,得出：酸雨使红壤中铁、铝的形态发生转化,盐基离子被释放出来,从而破坏了红壤有机矿质复合体的结构,使有机矿质复合体中的有机质和多环芳烃一起被释放出来,且酸雨对复合体中低环多环芳烃的释放影响较大,多高环多环芳烃的释放影响较小。
In this dissertation, the stability and release mechanism of polycyclic aromatic hydrocarbons (PAHs) from red soil under simulated acid rain was investigated. First, soil column leaching experiments was used to simulate the actual rainfall of Hunan province, and the release characterization of dissolved organic matter (DOM) and PAHs was studied, meanwhile, Correlation analysis between DOM and PAHs in eluates was carried out. It was concluded that organic matter and PAHs can be released from red soil under simulated acid rain, and pH and leaching volume play important roles in this process. and PAHs associated with organic matter were released. Second, the distribution of PAHs in different soil particle-size fractions was studied and it was shown the content of PAHs was different in different soil particle-size fractions and there was a strong positive linear relationship between total PAHs concentration and total organic carbon. Last, from the angle of the organic-mineral aggregates, Fourier transform infrared spectroscopy, scanning electron microscopy. X-ray diffraction and laser scanning confocal microscope were used jointly to elucidate the release mechanism of PAHs from red soil under simulated acid rain. Conclusion was drawn that the modality of iron and aluminum in red soil under simulated acid rain were transformed and base cations were released, therefore the structure of organic-mineral aggregates was destroyed, as a result, organic matter and PAHs were released together and simulated acid rain has a greater impact on low-aromatic ring PAHs than high-aromatic ring PAHs.
In this dissertation, the stability and release mechanism of polycyclic aromatic hydrocarbons (PAHs) from red soil under simulated acid rain was investigated. First, soil column leaching experiments was used to simulate the actual rainfall of Hunan province, and the release characterization of dissolved organic matter (DOM) and PAHs was studied, meanwhile, Correlation analysis between DOM and PAHs in eluates was carried out. It was concluded that organic matter and PAHs can be released from red soil under simulated acid rain, and pH and leaching volume play important roles in this process. and PAHs associated with organic matter were released. Second, the distribution of PAHs in different soil particle-size fractions was studied and it was shown the content of PAHs was different in different soil particle-size fractions and there was a strong positive linear relationship between total PAHs concentration and total organic carbon. Last, from the angle of the organic-mineral aggregates, Fourier transform infrared spectroscopy, scanning electron microscopy. X-ray diffraction and laser scanning confocal microscope were used jointly to elucidate the release mechanism of PAHs from red soil under simulated acid rain. Conclusion was drawn that the modality of iron and aluminum in red soil under simulated acid rain were transformed and base cations were released, therefore the structure of organic-mineral aggregates was destroyed, as a result, organic matter and PAHs were released together and simulated acid rain has a greater impact on low-aromatic ring PAHs than high-aromatic ring PAHs.
引文
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