煤层注水抑制瓦斯解吸效应实验研究与应用
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摘要
本论文围绕煤层注水防治煤与瓦斯突出机理这一主线,针对抑制解吸效应研究偏少、缺乏定量化研究的问题,采用实验室试验、数值模拟和现场试验相结合的方法,对煤层注水抑制瓦斯解吸效应进行了重点研究。在实验室试验方面,研制了煤层注水抑制瓦斯解吸效应实验室模拟测试装置,并提出了抑制解吸效应的研究方法与研究指标,通过测试先注水煤样的等温吸附-解吸特性,先吸附甲烷再注水煤样的等温解吸特性、瓦斯解吸速度及残存瓦斯含量,对抑制解吸效应进行了定量探讨,得出了抑制解吸效应与注水参数的响应关系;同时,通过数值模拟、现场试验及注水前后孔隙特性的对比分析,对抑制解吸效应进行了深入研究,对煤层注水的防突机理作了进一步的探讨。
测试结果表明,注入水分对吸附瓦斯的解吸有阻碍作用,注水煤样等温解吸过程中的吸附量和残存瓦斯含量均大于干燥煤样,且随着水分的增加,初始解吸速度降低,衰减速度减慢;覆压作用下,初始解吸速度增大,衰减速度加快,但注入水分后,初始解吸速度降低,衰减速度变慢。
研究表明:抑制解吸效应与注水量、注水压力、覆压大小及煤样粒度有关,它是煤层注水防突机理中的一项重要作用,其存在有利于煤与瓦斯突出防治。
With the main line of coal and gas outburst prevention mechanism in coal seam water injection, this paper points at problems of less study and lack of quantitative study on inhibitory effect on gas desorption at home and abroad. With methods of laboratory tests, numerical simulation and field test, inhibitory effect on gas desorption in coal seam water injection is studied. In the laboratory test, laboratory simulation test device of inhibitory effect on gas desorption after water injection is developed, and research methods and indicators are brought forward. By tests of adsorption-desorption characteristics of pre-injected water coal sample; desorption isotherm, desorption rate and residual gas content at atmospheric pressure of pre-adsorbed gas then water-injected coal sample, the inhibitory effect is researched in quantitative style, then it is obtained of the response relationship between inhibitory effect and water injection parameters. At the same time, the inhibitory effect is further demonstrated by numerical simulation, field test method and comparative analysis of coal pore structure characteristics before and after injection, and the mechanism of outburst prevention is further explored.
Test results show that: To a coal sample after water injection, residual moisture has an blocking effect on methane desorption, so its adsorption volume in desorption isotherms and its residual gas content is greater than that of dried coal, with the increase of water content, initial desorption rate decreases and its decay rate slows down; Under overburden pressure, initial desorption rate increases and decay rate accelerates, but, after water injected, initial desorption rate decreases and decay rate becomes slower.
The research indicates that inhibitory effect on gas desorption is related to water injection quantity, injection pressure, overburden pressure, particle size of coal sample and original gas content, and it is an important role in the mechanism of coal and gas outburst prevention, and it is conducive to prevent and control coal and gas outburst.
测试结果表明,注入水分对吸附瓦斯的解吸有阻碍作用,注水煤样等温解吸过程中的吸附量和残存瓦斯含量均大于干燥煤样,且随着水分的增加,初始解吸速度降低,衰减速度减慢;覆压作用下,初始解吸速度增大,衰减速度加快,但注入水分后,初始解吸速度降低,衰减速度变慢。
研究表明:抑制解吸效应与注水量、注水压力、覆压大小及煤样粒度有关,它是煤层注水防突机理中的一项重要作用,其存在有利于煤与瓦斯突出防治。
With the main line of coal and gas outburst prevention mechanism in coal seam water injection, this paper points at problems of less study and lack of quantitative study on inhibitory effect on gas desorption at home and abroad. With methods of laboratory tests, numerical simulation and field test, inhibitory effect on gas desorption in coal seam water injection is studied. In the laboratory test, laboratory simulation test device of inhibitory effect on gas desorption after water injection is developed, and research methods and indicators are brought forward. By tests of adsorption-desorption characteristics of pre-injected water coal sample; desorption isotherm, desorption rate and residual gas content at atmospheric pressure of pre-adsorbed gas then water-injected coal sample, the inhibitory effect is researched in quantitative style, then it is obtained of the response relationship between inhibitory effect and water injection parameters. At the same time, the inhibitory effect is further demonstrated by numerical simulation, field test method and comparative analysis of coal pore structure characteristics before and after injection, and the mechanism of outburst prevention is further explored.
Test results show that: To a coal sample after water injection, residual moisture has an blocking effect on methane desorption, so its adsorption volume in desorption isotherms and its residual gas content is greater than that of dried coal, with the increase of water content, initial desorption rate decreases and its decay rate slows down; Under overburden pressure, initial desorption rate increases and decay rate accelerates, but, after water injected, initial desorption rate decreases and decay rate becomes slower.
The research indicates that inhibitory effect on gas desorption is related to water injection quantity, injection pressure, overburden pressure, particle size of coal sample and original gas content, and it is an important role in the mechanism of coal and gas outburst prevention, and it is conducive to prevent and control coal and gas outburst.
引文
[1]人民日报,中国能源状况及展望,人民日报出版社,1999年12月
[2]俞启香.矿井瓦斯防治[M].徐州:中国矿业大学出版社,1990
[3]瞿涛宝.论煤层注水处理瓦斯的效果[J].煤矿安全,1994,25 (5):39-42,28
[4]B.B.Beamish, P.J.Crosdaler. Instantaneous outbursts in underground coal mines:An overview and association with coal type[J]. International Journal of Coal Geology, 1998,35 (1-4):27-55
[5]M.B. Diaz Aguado, C. Gonzalez Nicieza. Control and prevention of gas outbursts in coal mines, Riosa–Olloniego coalfield, Spain[J].International Journal of Coal Geology, 2007, 69:253–266
[6]胡千庭,周世宁,周心权.煤与瓦斯突出过程的力学作用机理[J].煤炭学报,2008,33(12):1368-1372
[7]于不凡,王佑安.煤矿瓦斯灾害防治及利用技术手册(修订版)[M].北京,煤炭工业出版社,2005
[8]程远平,俞启香.中国煤矿区域性瓦斯治理技术的发展[J].采矿与安全工程学报,2007,24(4):383-390
[9]吴继周.略论煤层注水[J].煤矿安全,1982,13(2):1-6
[10]张永吉,李占德,秦伟翰等.煤层注水技术[M].北京:煤炭工业出版社,2001
[11]钱鸣高,石平五.矿山压力与岩层控制[M].徐州:中国矿业大学出版社,2003
[12][苏]О.И.切尔诺夫,Е.С.罗赞采夫.瓦斯突出危险煤层井田的准备[M].宋世钊,于不凡译.北京:煤炭工业出版社,1980
[13]王兆丰,李志强.水力挤出措施消突机理研究[J].煤矿安全,2004,35(12):1-4
[14]蒋承林.煤层注水的防突机理分析[J].湘潭工学院学报,1999,14(3) :1-4
[15]刘明举,潘辉,李拥军等.煤巷水力挤出防突措施的研究与应用[J].煤炭学报,2007,32(2):168-171
[16]王凯,郭灵强,俞启香等.综采工作面水力超前卸压防突数值模拟与试验研究[J].煤炭学报,2007,32(8):832-837
[17]李宗翔,潘一山,题正义等.木城涧矿煤层高压注水的数值模拟分析[J].岩石力学与工程学报,2005,24(11):1895-1899
[18]马中飞,俞启香.水力卸压防止承压散体煤和瓦斯突出机理[J].中国矿业大学学报,2007,36(1):103-106
[19]马中飞,俞启香.工作面水力卸压防突作用的数值模拟[J].中国安全科学学报,2006,16(10):27-31
[20]刘建新,李志强.煤巷掘进工作面水力挤出措施防突机理[J].煤炭学报,2006,31(2):183-186
[21]李平.水力挤出技术在突出煤层中的应用[J].煤炭科学技术,2007,35(8):45-47,52
[22]魏国营,张书军,辛新平.突出煤层掘进防突技术研究[J].中国安全科学学报,2005,15(6):100-104
[23]王惠宾,汪远东,卢平.煤层注水中添加湿润剂的研究[J].煤炭学报,1994,19(2):151-160
[24]聂百胜,何学秋,冯志华等.磁化水在煤层注水中的应用[J].辽宁工程技术大学学报,2007,26(1):1-3
[25]王青松,金龙哲,孙金华.煤层注水过程分析和煤体润湿机理研究[J].安全与环境学报,2004,4(1):70-73
[26]金龙哲,蒋仲安,任宝宏等.煤层注水中水分蒸发现象的研究[J].中国安全科学学报,2000,10(3):58-62
[27]秦文贵,张延松.煤孔隙分布与煤层注水增量的关系[J].煤炭学报,2000,25(5):514-517
[28]Joubert J I, Grein C T. Sorption of methane in moist coal [J]. Fuel, 1973, 52:181-185
[29]Levine J R, Johnson P. High pressure microbalance sorption studies [A].International coalbed methane symposium[C],1993: 187-195
[30]张庆玲,煤储层条件下水分—平衡水分测定方法研究[J].煤田地质与勘探,1998,27(4):25-27
[31]张群,杨锡禄.平衡水分条件下煤对甲烷的等温吸附特性研究[J].煤炭学报,1999,24(6):566-567
[32]张占存,马丕梁.水分对不同煤种瓦斯吸附特性影响的实验研究[J].煤炭学报,2008,33(2):144-147
[33]桑树勋,朱炎铭,张井等.液态水影响煤吸附甲烷的实验研究:以沁水盆地南部煤储层为例.科学通报,2005,50(增刊Ⅰ)
[34]Saunder J T,Tsai B M C. Adsorption of gases on coals and heated-treated coals at elevated temperature and pressure[J]. Fuel, 1985, 64
[35]Yang R T, Saunders J T. Adsorption of gases on coals and heated-treated coals at elevated temperature and pressure[J]. Fuel, 1985, 64:616-620.
[36]Glass A S, Larsen J W. Surface thermodynamics for nonpolar adsorption on Illinois No.6 coal by inverse gas chromatography[J]. Energy&Fuel, 1993, 7:994-10000.
[37]陈昌国,魏锡文等.用从头计算研究煤表面与甲烷分子相互作用[J].重庆大学学报,2000,23(3):77-83
[38]近藤精一,石川达雄,安部郁夫等著[日].吸附科学[M].李国希译.北京:化学工业出版社,2006
[39]Sommen J V D, Zwietering P. Chemical structure and properties of coal sorption capacity for methane[J]. Fuel, 1955, 34
[40]S.J格雷格K.S.W辛[美].吸附、比表面积与孔隙率[M].高敬琮译.北京:化学工业出版社,1989
[41]段世铎,谭逸玲.界面化学[M].北京:高等教育出版社,1990.6
[42]朱步瑶,赵振国.界面化学基础[M].北京:化工工业出版社,1996.9
[43]刘常洪,杨思敬.关于煤甲烷吸附体系吸附规律的试验研究[J].煤矿安全,1992,23(4):1-5
[44]于洪观,范维唐,孙茂远,叶建平.煤中甲烷等温吸附模型的研究[J].煤炭学,2004,29 (4)
[45]Rupple T C, Grein C T. Adsorption of methane on dry coal at elevated pressure[J]. Fuel, 1974,53
[46]缑发现.用直接法测定煤层瓦斯含量来推算损失量的方法[J].煤矿安全,1997,7
[47]张庆玲,曹利戈.煤的等温吸附测试中数据处理问题研究[J].煤炭学报,2003,28(02)
[48]桑树勋,朱炎铭,张时音等.煤吸附气体的固气作用机理(Ⅰ)—煤孔隙结构与固气作用[J].天然气工业,2005,25(1):13-15
[49]桑树勋,朱炎铭,张井等.煤吸附气体的固气作用机理(Ⅱ)—煤吸附气体的物理过程与理论模型[J].天然气工业,2005,25(1):16-18
[50]艾鲁尼A T.煤矿瓦斯动力学现象的预测和预防[M].唐修义,宋德淑,王荣龙译.北京:煤炭工业出版社,1992
[51]Clarkson C R. Bustin R M. The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study[J]. Fuel, 1999, 78
[52] Laxminarayana Ch, Crosdale P J. Modeling methane adsorption isotherms using pore filling models:a case study on India coals[J]. International coalbed methane symposium, 1999
[53] Weishauptova Z, Medek J. Bound forms of methane in the porous system of coal[J]. Fuel, 1998,77
[54]陈昌国,鲜晓红.微孔充填理论研究无烟煤和炭对甲烷的吸附特性[J].重庆大学学报,1998,21(2)
[55]刘志钧.关于煤的吸附甲烷容量的研究[J].煤矿安全,1988, 10
[56] Levy J H, Day S J, Killingley J S. Methane capacities of Bowen Basin coals related to coal properties [J]. Fuel 1997
[57]张新民,张遂安等.中国煤层甲烷[M].西安:陕西科学技术出版社,1994
[58] Ettinger I L, Eremin I, Zimakov B et al. Natural factors influencing coal sorption properties:Petrography and the sorption properties of coals[J]. Fuel, 1966, 45
[59]Lamberson M N, Bustin R M.Coalbed Methane Characteristics of Gates Formation Coals, Northeastern British Columbia:Effect of Maceral Composition[J].AAPG, 1993, 77
[60]Crosdale P J, Beamish B B, Valix M. Coalbed methane sorption related to coal composition[J]. Int. J.Coal Geol., 1998, 35
[61]Laxminarayana Ch, Crosdale P J. Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia coals [J]. Int. J Coal Geol., 1999,40
[62]Moffat D H, Weale K E. Sorption by coal of methane at high pressure [J]. Fuel, 1955, 43
[63]Ruppel T C, Grein C T, Bienstock D. Adsorption of methane on drycoal at elevated pressure [J]. Fuel, 1974, 55
[64]钟玲文.煤的吸附性能及影响因素[J].中国地质大学学报,2004,29(3):327-332,368
[65]傅雪海,秦勇.李贵中等.特高煤级煤平衡水条件下的吸附试验[J].石油实验地质.2002,24(2)
[66]张时音,桑树勋.液态水影响不同煤级煤吸附甲烷的差异及其机理[J].地质学报, 2008 ,82 (10) :1350-1354
[67]张时音,桑树勋,杨志刚.液态水对煤吸附甲烷影响的机理分析[J].中国矿业大学学报, 2009 ,38 (5):707-712
[68]聂百胜,何学秋,王恩元等.煤吸附水的微观机理[J].中国矿业大学学报, 2004 ,33 (4):379-383
[69]张慧.煤孔隙的成因研究及其成因[J].煤炭学报,2001,26(1):40-44
[70]张红日,杨思敬.煤的低温氮吸附实验研究[J].山东矿业学院学报,1993,12(3):245-249
[71]傅雪海,秦勇,薛秀廉.分形理论在煤储层物性研究中的应用[J].煤,2000,9(4):1-3
[72]维索茨基H B.天然气地质学[M].戴金星等译.北京:石油工业出版社,1986
[73]郝琦.煤的显微孔隙形态特征及其成因探讨[J].煤炭学报,1987,12(4):51-57
[74] P.G.Sevenster. Diffusion of Gases through Coal[J]. Fuel,1959,38
[75]K.Winter, H.Janas. Gas Emission characteristics of coal and Methods of Determining the Desorbable Gas Content by Means of Desorbometers[J]. XIV International Conference of Coal Mine Safety Research
[76]宋世钊译.煤矿沼气涌出[M].煤炭工业出版社,1983年
[77]苏文叔.综采工作面沼气涌出规律及预测[J].煤炭科学研究总院重庆分院,1985
[78]于良臣等.矿井瓦斯涌出量预测方法的研究[J].煤炭科学研究总院抚顺分院,1990
[79]E.M.Airey,Gas Emission from Broken Coal[J].Int. J. Rock Mech. and Min. Sci.,Vol.5,1968
[80]B.A.Bolt & Innes,Diffusion of Carbon Dioxide from Coal[J]. Fuel, 1959, 38
[81]王佑安,杨思敬.煤和瓦斯突出危险煤层的某些特征[J].煤炭学报,1980,1
[82]孙重旭.煤样解吸瓦斯泄出的研究及其突出煤层煤样瓦斯解吸的特点[J].煤与瓦斯突出第三次学术论文集,1983
[83]杨其銮.关于煤屑瓦斯放散规律的试验研究及其在煤的突出危险性和瓦斯含量预测方面的应用(D).煤炭科学研究总院抚顺分院,1986
[84]张遂安,叶建平,唐书恒等.煤对甲烷气体吸附—解吸机理的可逆性实验研究[J].天然气工业,2005,25(1)
[85]于洪观,范维唐,孙茂远等.煤对超临界甲烷的吸附与解吸特性研究[J].煤炭转化,2004,27(2)
[86]马东民,史纪敦,张守刚.沁南地区煤层气的解吸特征实验研究[J].西安科枝大学学报.2007,27(4)
[87]唐巨鹏,潘一山,李成全等.有效应力对煤层气解吸渗流影响试验研究[J].岩石力学与工程学报, 2006,25(8)
[88]王兆丰.空气、水和泥浆介质中煤层气解吸规律与应用研究[D].徐州:中国矿业大学,2001.
[89]邵军.关于钻屑瓦斯解吸指标的探讨[J].煤矿安全,1991,3
[90]程五一,王佑安,王魁军.实验室确定钻屑解吸指标△h2临界值方法的研究[J].煤炭工程,1997,3:19-22
[91]胡千庭.对钻屑瓦斯解吸指标预测突出敏感性的探讨[J].煤矿安全,1997,10:41-44
[92]卢鉴章,刘见中.煤矿灾害防治技术现状与发展.煤炭科学技术,2006,34(5)
[93]章梦涛,梁冰,潘一山.煤岩流体力学[M].北京:科学出版社,1995.8.
[100]赵阳升,胡耀青,杨栋,郑少河.气液二相流体裂缝渗流规律的模拟实验研究[J].岩石力学与工程学报,1999,18(3):354-356
[101]孙可明,梁冰,王锦山.煤层气开采中两相流阶段的流固耦合渗流[J].辽宁工程技术大学学报,2001,20(1):36-39
[102]林良俊,马凤山.煤层气产出过程中气-水两相流与煤岩变形耦合数学模型研究[J].水文地质工程地质,2001,01
[103]骆祖江,付延玲,王增辉.非饱和带水气二相渗流动力学模型[J].煤田地质与勘探,1999,05
[104]孟宪明.煤孔隙结构和煤对气体吸附特性研究[硕士学位论文].山东:山东科技大学,2007
[105]BAI Fasong, DING Guangxiang. Inversion method of the gas permeability in 2D coal seam[J].Journal of China Coal Society, 1999,24(4): 388-391
[106]M.Th. van Genuchten. A closed-form equation for predicting the hydraulic of conductivity of unsaturated soils [J].Soil Sci. Soc.Am.1980, 44:892–898
[107] SUN Ke-ming, LIANG Bing, Wang Jin-shan.The Fluid-Solid Seepage of Two Phase (Gas andWater) in Coal Seams. Gas Reservoir [J].2001,20 (1):36–39
[108]何学秋.含瓦斯煤岩流变动力学[M].徐州:中国矿业大学出版社,1995
[109]包剑影,苏隧,李贵贤.阳泉煤矿瓦斯治理技术[M].北京:煤炭工业出版社,1996
[110]翟云芳.渗流力学[M].北京:石油工业出版社,2003
[112]胡殿明,林柏泉.煤层瓦斯赋存规律及防治技术[M].徐州:中国矿业大学出版社,2006
[113]刘宝琛,詹哲明,崔志莲.煤受压变形及破坏的试验研究.北京:煤炭学报,1983.2:54-56
[114]蒋承林,俞启香.煤与瓦斯突出的球壳失稳机理及防治技术.徐州:中国矿业大学出版社,1998
[115]胡千庭,蒋时才,苏文叔.我国煤矿瓦斯灾害防治对策[J].矿业安全与环保,2000,27(1):1-4
[116]Wang Zhaofeng, Liu Jun. Study on mechanism of outburst prevention by hydraulic extrusion measure based on numerical simulation [J], Progress in Safety Science and Technology(Vol. 2),2004
[117]李志强,王兆丰.煤巷掘进工作面中高压注水措施消突机理研究[J].焦作工学院学报(自然科学版),2004,23(3):165-169
[2]俞启香.矿井瓦斯防治[M].徐州:中国矿业大学出版社,1990
[3]瞿涛宝.论煤层注水处理瓦斯的效果[J].煤矿安全,1994,25 (5):39-42,28
[4]B.B.Beamish, P.J.Crosdaler. Instantaneous outbursts in underground coal mines:An overview and association with coal type[J]. International Journal of Coal Geology, 1998,35 (1-4):27-55
[5]M.B. Diaz Aguado, C. Gonzalez Nicieza. Control and prevention of gas outbursts in coal mines, Riosa–Olloniego coalfield, Spain[J].International Journal of Coal Geology, 2007, 69:253–266
[6]胡千庭,周世宁,周心权.煤与瓦斯突出过程的力学作用机理[J].煤炭学报,2008,33(12):1368-1372
[7]于不凡,王佑安.煤矿瓦斯灾害防治及利用技术手册(修订版)[M].北京,煤炭工业出版社,2005
[8]程远平,俞启香.中国煤矿区域性瓦斯治理技术的发展[J].采矿与安全工程学报,2007,24(4):383-390
[9]吴继周.略论煤层注水[J].煤矿安全,1982,13(2):1-6
[10]张永吉,李占德,秦伟翰等.煤层注水技术[M].北京:煤炭工业出版社,2001
[11]钱鸣高,石平五.矿山压力与岩层控制[M].徐州:中国矿业大学出版社,2003
[12][苏]О.И.切尔诺夫,Е.С.罗赞采夫.瓦斯突出危险煤层井田的准备[M].宋世钊,于不凡译.北京:煤炭工业出版社,1980
[13]王兆丰,李志强.水力挤出措施消突机理研究[J].煤矿安全,2004,35(12):1-4
[14]蒋承林.煤层注水的防突机理分析[J].湘潭工学院学报,1999,14(3) :1-4
[15]刘明举,潘辉,李拥军等.煤巷水力挤出防突措施的研究与应用[J].煤炭学报,2007,32(2):168-171
[16]王凯,郭灵强,俞启香等.综采工作面水力超前卸压防突数值模拟与试验研究[J].煤炭学报,2007,32(8):832-837
[17]李宗翔,潘一山,题正义等.木城涧矿煤层高压注水的数值模拟分析[J].岩石力学与工程学报,2005,24(11):1895-1899
[18]马中飞,俞启香.水力卸压防止承压散体煤和瓦斯突出机理[J].中国矿业大学学报,2007,36(1):103-106
[19]马中飞,俞启香.工作面水力卸压防突作用的数值模拟[J].中国安全科学学报,2006,16(10):27-31
[20]刘建新,李志强.煤巷掘进工作面水力挤出措施防突机理[J].煤炭学报,2006,31(2):183-186
[21]李平.水力挤出技术在突出煤层中的应用[J].煤炭科学技术,2007,35(8):45-47,52
[22]魏国营,张书军,辛新平.突出煤层掘进防突技术研究[J].中国安全科学学报,2005,15(6):100-104
[23]王惠宾,汪远东,卢平.煤层注水中添加湿润剂的研究[J].煤炭学报,1994,19(2):151-160
[24]聂百胜,何学秋,冯志华等.磁化水在煤层注水中的应用[J].辽宁工程技术大学学报,2007,26(1):1-3
[25]王青松,金龙哲,孙金华.煤层注水过程分析和煤体润湿机理研究[J].安全与环境学报,2004,4(1):70-73
[26]金龙哲,蒋仲安,任宝宏等.煤层注水中水分蒸发现象的研究[J].中国安全科学学报,2000,10(3):58-62
[27]秦文贵,张延松.煤孔隙分布与煤层注水增量的关系[J].煤炭学报,2000,25(5):514-517
[28]Joubert J I, Grein C T. Sorption of methane in moist coal [J]. Fuel, 1973, 52:181-185
[29]Levine J R, Johnson P. High pressure microbalance sorption studies [A].International coalbed methane symposium[C],1993: 187-195
[30]张庆玲,煤储层条件下水分—平衡水分测定方法研究[J].煤田地质与勘探,1998,27(4):25-27
[31]张群,杨锡禄.平衡水分条件下煤对甲烷的等温吸附特性研究[J].煤炭学报,1999,24(6):566-567
[32]张占存,马丕梁.水分对不同煤种瓦斯吸附特性影响的实验研究[J].煤炭学报,2008,33(2):144-147
[33]桑树勋,朱炎铭,张井等.液态水影响煤吸附甲烷的实验研究:以沁水盆地南部煤储层为例.科学通报,2005,50(增刊Ⅰ)
[34]Saunder J T,Tsai B M C. Adsorption of gases on coals and heated-treated coals at elevated temperature and pressure[J]. Fuel, 1985, 64
[35]Yang R T, Saunders J T. Adsorption of gases on coals and heated-treated coals at elevated temperature and pressure[J]. Fuel, 1985, 64:616-620.
[36]Glass A S, Larsen J W. Surface thermodynamics for nonpolar adsorption on Illinois No.6 coal by inverse gas chromatography[J]. Energy&Fuel, 1993, 7:994-10000.
[37]陈昌国,魏锡文等.用从头计算研究煤表面与甲烷分子相互作用[J].重庆大学学报,2000,23(3):77-83
[38]近藤精一,石川达雄,安部郁夫等著[日].吸附科学[M].李国希译.北京:化学工业出版社,2006
[39]Sommen J V D, Zwietering P. Chemical structure and properties of coal sorption capacity for methane[J]. Fuel, 1955, 34
[40]S.J格雷格K.S.W辛[美].吸附、比表面积与孔隙率[M].高敬琮译.北京:化学工业出版社,1989
[41]段世铎,谭逸玲.界面化学[M].北京:高等教育出版社,1990.6
[42]朱步瑶,赵振国.界面化学基础[M].北京:化工工业出版社,1996.9
[43]刘常洪,杨思敬.关于煤甲烷吸附体系吸附规律的试验研究[J].煤矿安全,1992,23(4):1-5
[44]于洪观,范维唐,孙茂远,叶建平.煤中甲烷等温吸附模型的研究[J].煤炭学,2004,29 (4)
[45]Rupple T C, Grein C T. Adsorption of methane on dry coal at elevated pressure[J]. Fuel, 1974,53
[46]缑发现.用直接法测定煤层瓦斯含量来推算损失量的方法[J].煤矿安全,1997,7
[47]张庆玲,曹利戈.煤的等温吸附测试中数据处理问题研究[J].煤炭学报,2003,28(02)
[48]桑树勋,朱炎铭,张时音等.煤吸附气体的固气作用机理(Ⅰ)—煤孔隙结构与固气作用[J].天然气工业,2005,25(1):13-15
[49]桑树勋,朱炎铭,张井等.煤吸附气体的固气作用机理(Ⅱ)—煤吸附气体的物理过程与理论模型[J].天然气工业,2005,25(1):16-18
[50]艾鲁尼A T.煤矿瓦斯动力学现象的预测和预防[M].唐修义,宋德淑,王荣龙译.北京:煤炭工业出版社,1992
[51]Clarkson C R. Bustin R M. The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study[J]. Fuel, 1999, 78
[52] Laxminarayana Ch, Crosdale P J. Modeling methane adsorption isotherms using pore filling models:a case study on India coals[J]. International coalbed methane symposium, 1999
[53] Weishauptova Z, Medek J. Bound forms of methane in the porous system of coal[J]. Fuel, 1998,77
[54]陈昌国,鲜晓红.微孔充填理论研究无烟煤和炭对甲烷的吸附特性[J].重庆大学学报,1998,21(2)
[55]刘志钧.关于煤的吸附甲烷容量的研究[J].煤矿安全,1988, 10
[56] Levy J H, Day S J, Killingley J S. Methane capacities of Bowen Basin coals related to coal properties [J]. Fuel 1997
[57]张新民,张遂安等.中国煤层甲烷[M].西安:陕西科学技术出版社,1994
[58] Ettinger I L, Eremin I, Zimakov B et al. Natural factors influencing coal sorption properties:Petrography and the sorption properties of coals[J]. Fuel, 1966, 45
[59]Lamberson M N, Bustin R M.Coalbed Methane Characteristics of Gates Formation Coals, Northeastern British Columbia:Effect of Maceral Composition[J].AAPG, 1993, 77
[60]Crosdale P J, Beamish B B, Valix M. Coalbed methane sorption related to coal composition[J]. Int. J.Coal Geol., 1998, 35
[61]Laxminarayana Ch, Crosdale P J. Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia coals [J]. Int. J Coal Geol., 1999,40
[62]Moffat D H, Weale K E. Sorption by coal of methane at high pressure [J]. Fuel, 1955, 43
[63]Ruppel T C, Grein C T, Bienstock D. Adsorption of methane on drycoal at elevated pressure [J]. Fuel, 1974, 55
[64]钟玲文.煤的吸附性能及影响因素[J].中国地质大学学报,2004,29(3):327-332,368
[65]傅雪海,秦勇.李贵中等.特高煤级煤平衡水条件下的吸附试验[J].石油实验地质.2002,24(2)
[66]张时音,桑树勋.液态水影响不同煤级煤吸附甲烷的差异及其机理[J].地质学报, 2008 ,82 (10) :1350-1354
[67]张时音,桑树勋,杨志刚.液态水对煤吸附甲烷影响的机理分析[J].中国矿业大学学报, 2009 ,38 (5):707-712
[68]聂百胜,何学秋,王恩元等.煤吸附水的微观机理[J].中国矿业大学学报, 2004 ,33 (4):379-383
[69]张慧.煤孔隙的成因研究及其成因[J].煤炭学报,2001,26(1):40-44
[70]张红日,杨思敬.煤的低温氮吸附实验研究[J].山东矿业学院学报,1993,12(3):245-249
[71]傅雪海,秦勇,薛秀廉.分形理论在煤储层物性研究中的应用[J].煤,2000,9(4):1-3
[72]维索茨基H B.天然气地质学[M].戴金星等译.北京:石油工业出版社,1986
[73]郝琦.煤的显微孔隙形态特征及其成因探讨[J].煤炭学报,1987,12(4):51-57
[74] P.G.Sevenster. Diffusion of Gases through Coal[J]. Fuel,1959,38
[75]K.Winter, H.Janas. Gas Emission characteristics of coal and Methods of Determining the Desorbable Gas Content by Means of Desorbometers[J]. XIV International Conference of Coal Mine Safety Research
[76]宋世钊译.煤矿沼气涌出[M].煤炭工业出版社,1983年
[77]苏文叔.综采工作面沼气涌出规律及预测[J].煤炭科学研究总院重庆分院,1985
[78]于良臣等.矿井瓦斯涌出量预测方法的研究[J].煤炭科学研究总院抚顺分院,1990
[79]E.M.Airey,Gas Emission from Broken Coal[J].Int. J. Rock Mech. and Min. Sci.,Vol.5,1968
[80]B.A.Bolt & Innes,Diffusion of Carbon Dioxide from Coal[J]. Fuel, 1959, 38
[81]王佑安,杨思敬.煤和瓦斯突出危险煤层的某些特征[J].煤炭学报,1980,1
[82]孙重旭.煤样解吸瓦斯泄出的研究及其突出煤层煤样瓦斯解吸的特点[J].煤与瓦斯突出第三次学术论文集,1983
[83]杨其銮.关于煤屑瓦斯放散规律的试验研究及其在煤的突出危险性和瓦斯含量预测方面的应用(D).煤炭科学研究总院抚顺分院,1986
[84]张遂安,叶建平,唐书恒等.煤对甲烷气体吸附—解吸机理的可逆性实验研究[J].天然气工业,2005,25(1)
[85]于洪观,范维唐,孙茂远等.煤对超临界甲烷的吸附与解吸特性研究[J].煤炭转化,2004,27(2)
[86]马东民,史纪敦,张守刚.沁南地区煤层气的解吸特征实验研究[J].西安科枝大学学报.2007,27(4)
[87]唐巨鹏,潘一山,李成全等.有效应力对煤层气解吸渗流影响试验研究[J].岩石力学与工程学报, 2006,25(8)
[88]王兆丰.空气、水和泥浆介质中煤层气解吸规律与应用研究[D].徐州:中国矿业大学,2001.
[89]邵军.关于钻屑瓦斯解吸指标的探讨[J].煤矿安全,1991,3
[90]程五一,王佑安,王魁军.实验室确定钻屑解吸指标△h2临界值方法的研究[J].煤炭工程,1997,3:19-22
[91]胡千庭.对钻屑瓦斯解吸指标预测突出敏感性的探讨[J].煤矿安全,1997,10:41-44
[92]卢鉴章,刘见中.煤矿灾害防治技术现状与发展.煤炭科学技术,2006,34(5)
[93]章梦涛,梁冰,潘一山.煤岩流体力学[M].北京:科学出版社,1995.8.
[100]赵阳升,胡耀青,杨栋,郑少河.气液二相流体裂缝渗流规律的模拟实验研究[J].岩石力学与工程学报,1999,18(3):354-356
[101]孙可明,梁冰,王锦山.煤层气开采中两相流阶段的流固耦合渗流[J].辽宁工程技术大学学报,2001,20(1):36-39
[102]林良俊,马凤山.煤层气产出过程中气-水两相流与煤岩变形耦合数学模型研究[J].水文地质工程地质,2001,01
[103]骆祖江,付延玲,王增辉.非饱和带水气二相渗流动力学模型[J].煤田地质与勘探,1999,05
[104]孟宪明.煤孔隙结构和煤对气体吸附特性研究[硕士学位论文].山东:山东科技大学,2007
[105]BAI Fasong, DING Guangxiang. Inversion method of the gas permeability in 2D coal seam[J].Journal of China Coal Society, 1999,24(4): 388-391
[106]M.Th. van Genuchten. A closed-form equation for predicting the hydraulic of conductivity of unsaturated soils [J].Soil Sci. Soc.Am.1980, 44:892–898
[107] SUN Ke-ming, LIANG Bing, Wang Jin-shan.The Fluid-Solid Seepage of Two Phase (Gas andWater) in Coal Seams. Gas Reservoir [J].2001,20 (1):36–39
[108]何学秋.含瓦斯煤岩流变动力学[M].徐州:中国矿业大学出版社,1995
[109]包剑影,苏隧,李贵贤.阳泉煤矿瓦斯治理技术[M].北京:煤炭工业出版社,1996
[110]翟云芳.渗流力学[M].北京:石油工业出版社,2003
[112]胡殿明,林柏泉.煤层瓦斯赋存规律及防治技术[M].徐州:中国矿业大学出版社,2006
[113]刘宝琛,詹哲明,崔志莲.煤受压变形及破坏的试验研究.北京:煤炭学报,1983.2:54-56
[114]蒋承林,俞启香.煤与瓦斯突出的球壳失稳机理及防治技术.徐州:中国矿业大学出版社,1998
[115]胡千庭,蒋时才,苏文叔.我国煤矿瓦斯灾害防治对策[J].矿业安全与环保,2000,27(1):1-4
[116]Wang Zhaofeng, Liu Jun. Study on mechanism of outburst prevention by hydraulic extrusion measure based on numerical simulation [J], Progress in Safety Science and Technology(Vol. 2),2004
[117]李志强,王兆丰.煤巷掘进工作面中高压注水措施消突机理研究[J].焦作工学院学报(自然科学版),2004,23(3):165-169
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