On Quantitative Analysis Method of Detecting the Content of Molten Alloy Steel Element Based on LIBS Technology

详细信息    查看官网全文

• 英文论文题名：On Quantitative Analysis Method of Detecting the Content of Molten Alloy Steel Element Based on LIBS Technology
• 论文作者：Zhang Qin ; Yang Peng ; Feng Meiling ; Sun Junqing
• 英文论文作者：Zhang Qin ; Yang Peng ; Feng Meiling ; Sun Junqing ; Tianjin Key Laboratory of Intelligence Computing and Novel Software Technology ; Tianjin University of Technology
• 年：2017
• 作者机构：Tianjin Key Laboratory of Intelligence Computing and Novel Software Technology,Tianjin University of Technology;
• 英文论文关键词：laser induced breakdown spectroscopy ; quantitative analysis ; partial least squares method ; relative standard error
• 会议召开时间：2017-07-26
• 会议录名称：第36届中国控制会议论文集（B）
• 英文会议录名称：Proceedings of the 36th Chinese Control Conference（B）
• 语种：英文
• 分类号：TF701.3
• 学会代码：KZLL
• 会议名称：第36届中国控制会议
• 会议地点：中国辽宁大连
• 主办单位：中国自动化学会控制理论专业委员会
• 学会名称：中国自动化学会控制理论专业委员会
• 页数：5
• 文件大小：305k
• 原文格式：D
• 会议级别：全国

摘要

Based on laser induced breakdown spectroscopy(LIBS) technique, the content of the main elements in the liquid steel of steel alloy can be detected in real time during melting process. In order to improve the detecting accuracy, the quantitative analysis method of laser induced breakdown spectroscopy(LIBS) for the melting alloy steels has been investigated. In this paper,the clustering method combined with the partial least squares method is applied in the metallurgical industry to determine the the element concentration of the steels. The experimental results show that the relative standard error is less than 1.316% and the average absolute error is 0.869%. The accuracy of the method is better than that of traditional partial least squares method, and the relative standard error of measurement is obviously reduced.
Based on laser induced breakdown spectroscopy(LIBS) technique, the content of the main elements in the liquid steel of steel alloy can be detected in real time during melting process. In order to improve the detecting accuracy, the quantitative analysis method of laser induced breakdown spectroscopy(LIBS) for the melting alloy steels has been investigated. In this paper,the clustering method combined with the partial least squares method is applied in the metallurgical industry to determine the the element concentration of the steels. The experimental results show that the relative standard error is less than 1.316% and the average absolute error is 0.869%. The accuracy of the method is better than that of traditional partial least squares method, and the relative standard error of measurement is obviously reduced.

引文

[1]Quantitative analysis and application of laser induced breakdown spectroscopy[J].Journal of Hangzhou University of Electronic Science and Technology.2012.
    [2]Sun Lanxiang,Yu Haibin,Cong Zhibo,Xin Yong.On-line semi-quantitative analysis of liquid steel components by LIBS[J].Journal of Instrumentation and Instruments.2011(11).
    [3]Bai Yingkui.Near-infrared spectroscopy in the application of drug detection[D].Jilin University.2005.
    [4]Liu Jiashui.Near-infrared spectroscopy applied to the quality evaluation of South slab research[D].2013.
    [5]Ji Zhenguo,Li Tieqiang,Xi Junhua,Mao Q Nan.Laser induced breakdown spectroscopy and its application in elemental analysis[J].Chinese Journal of Materials Science and Engineering.2011.
    [6]Zhang Tianlong.Laser-induced breakdown spectroscopy in the stoichiometric method and its application in metallurgical analysis[D].Northwestern University.2015.
    [7]LU Wan zhen YUAN Hong-fu,XU Guang tong et al.M odern Analysis T echnique of Near-Infrared Spectra.Beijing:Chinese Petro-Chemical Press,2000.
    [8]MIN Shun-geng,LI Ning,ZHANG Ming-xiang.Spectroscopy and Spectral Analysis,2004,24(10):1205.
    [9]LU Xian-yang,XU Guo-wei,FEI Teng,WANG Qiuping,WANG Sheng-bo.Experimental study on compositional analysis of laser induced plasma in metal materials[J].2011[1]
    [10]Gu Yanhong.LIBS technology used in the scallop shell metal Content of the experimental study[D].Ocean University of China.2014.
    [11]Shao Yan.Laser-induced breakdown spectroscopy for the composition of alloy steel[D].Changchun University of Science and Technology.2012.
    [12]HUBMER G,KITZBERGER R,MORW ALD K.Application of LIBS to the in-line process control of liquid high-alloy steel under presssure[J].Analytical and Bioanalytical Chemistry,2006,385(2):219-224.
    [13]Li Jing et al.Determination of Magnesium,Sodium and Potassium in Aqueous Solution based on Laser Induced Plasma Spectrometry[J].Chinese Journal of Experimental Mechanics,2007,22(4):27-31.