含N,P,S,Si,F等杂原子的光引发剂的研究现状及进展
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- 英文论文题名：Research Status and Advances of Photoinitiators Containing N,P,S,Si,F atoms
- 论文作者：庞玉莲 ; 邹应全
- 英文论文作者：PANG Yu-lian ; ZOU Ying-quan ; College of Chemistry ; Beijing Normal University ; Hubei Gurun Technology Co. ; Ltd
- 年：2016
- 作者机构：北京师范大学化学学院;湖北固润科技有限公司;
- 论文关键词：杂原子 ; 光引发剂 ; 光解机理
- 英文论文关键词：heteroatom ; photoinitiators ; photodecomposition mechanism
- 会议召开时间：2016-09-07
- 会议录名称：2016第十七届中国辐射固化年会暨首届安庆市化工新材料产业高峰论坛论文报告集
- 语种：中文
- 分类号：TQ314.241
- 学会代码：GGXH
- 会议名称：2016第十七届中国辐射固化年会暨首届安庆市化工新材料产业高峰论坛
- 会议地点：中国安徽安庆
- 主办单位：中国感光学会辐射固化专业委员会、安庆市政府
- 学会名称：中国感光学会辐射固化专业委员会
- 页数：21
- 文件大小：1164k
- 原文格式：O
- 会议级别：全国
摘要
光引发剂是一类能在紫外光区(250~400mm)或可见光区(400~600nm)吸收一定波长的能量,产生自由基、阳离子等,从而引发单体聚合交联固化的化合物,是光固化体系的重要组成部分。很多光引发剂都含有含N,P,S,Si,F等杂原子,这些光引发剂由于所含杂原子的不同而具有各自的特性。本文按所含杂原子的种类,总结了这些光引发剂的结构、光解机理及应用领域,展望了未来光引发剂的发展方向。
Photoinitiator is a kind of compound that can absorb UV or visible light energy to produce free radicals or cationic,which initiate the monomer polymerizing.lt is an important part of UV curing system.Photoinitiators usually contain heteroatom such as N,P,S,Si,F,which have respective properties.In this paper,according to the different heteroatom,the classification,character,synthetic method and application fields of these photoinitiators are summarized,and the developing direction of photoinitiator is pointed out.
Photoinitiator is a kind of compound that can absorb UV or visible light energy to produce free radicals or cationic,which initiate the monomer polymerizing.lt is an important part of UV curing system.Photoinitiators usually contain heteroatom such as N,P,S,Si,F,which have respective properties.In this paper,according to the different heteroatom,the classification,character,synthetic method and application fields of these photoinitiators are summarized,and the developing direction of photoinitiator is pointed out.
引文
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[27]Kutzner Fabian,Gaudl Kaiuwe,Yoshinobu sakura.Michael addition reaction product and active energy ray-curable composition.[P]US Patent.0190846.2012-07-26.
[28]Citing fan,Chris Chiu,Yi-HSun Yang.lOw odour oligomeric photoinitiator and method of making the same[P].US Patent,8222243,2011-09-20.
[29]Schwalm R.,Reih W.,Tuning the mechanical properties of UV coatings towards hard and flexible systems.[J]Prog.Org.Coat.,1997;32:191.
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[31]Kolczak U.,Rist G.,Dietliker K.,Wirz J.,Reaction Mechanism of Monoacyl-and Bisacylphosphine Oxide Photoinitiators Studied by 31P-,13C-,and H-CIDNP and ESR,J.Am.Chem.Soc,(118)1996,6477-6489.
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[35]Paczkowski J,Kucybala Z,Scigalski F,Wrzyszczynski A,Sulfur-containning initiators and coinitiators of free radical polymerization.[J]J.Photochem.Photobiol.A:Chern.,2003;159:115.
[36]Paczkowski J,Kucybala Z,Scigalski F,Wrzyszczynski A,Sulfur-containning initiators and coinitiators of free radical polymerization.[J]J.Photochem.Photobiol.A:Chem.,2003;159:115.
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[38]Cokbaglan L,Arsu N,Yagci Y,Jockusch S,Turro N J,2-mercatothioxanthone as a novel photoinitiator for free radical polymerization.Macromolecules,2003;36:2649.
[39]Aydin M,Arsu N,Yagci Y,One-Component Bimolecular Photoinitiating Systems.[J]Macromol.Rapid.Commun.,2003;24:718.
[40]Liska R.,Photoinitiators with functional groups.VI.Chemically bound sensitizers.[J].Polym.Sci.Part A:Polym Chem,2004;42:2285.
[41]Kura H.Oka H.,Ohiwa M.,Matsumura T.,Kimura A.,Iwasaki Y.,Ohno T.,Matsumura M.,Murai H.,tochemistry and photocuring properties of thiol-substituted a-aminoalkylphenone as radical photoinitiator.J.Polym.Sci.Part B:Polym.Phys.,2005;43:1684.
[42]Allen N S.,Corrales T.,Edge M.,Catalina F.,Bianco-Pina M,A.Green,Photochemistry and photopolymerization activities of novel alkylthiobenzophenone photoinitiators.[J]Euro.Polym.J.1997;34:303.
[43]Kura H,Oka H,Ohiwa M.,Matsumura T,Kimura A,Iwasaki Y,Ohno T,Matsumura M.,Murai H,Photochemistry and photocuring properties of thiol-substituted a-aminoalkylphenone as radical photoinitiator.[J]J.Polym.Sci.Part B:Polym.Phys.,2005;43:1684.
[44]顾江楠,李红茹,余尚先,含硫光引发剂的进展[J]感光材料,1998,1,8-12.
[45]Lozano A E.,Alonso A.,Catalina F.,Peinado C,A theoretical study of the addition of silyl radicals to olefinic monomers.Macromol.Theo.Simul.1999;8:93.
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