用户名: 密码: 验证码:
人造暖云雾凝结核的微物理性能研究
详细信息    查看官网全文
摘要
本文采用高速摄影、低压电子冲击仪(ELPI)、电镜(SEM)、X射线衍射(XRD)等多种分析测试手段对凝结核的粒度分布、化学组成和表观形貌等进行研究,利用实验和数值分析相结合的研究方法,全面分析人造暖云雾凝结核的微物理性能及其变化规律,获得了凝结核的数密度、体积浓度和粒度分布谱、成核率等关键微物理性能参数。凝结核主要成分为氯化物,粒径分布范围是0.261~1.59μm,峰值粒径为0.609~0.942μm,数密度约为3.98×10~5~5.12×10~5个/cm~3,体积浓度为2.02×10~5~2.30×10~5μm~3/cm~3,其最大成核率约为3.07×10~(12)个/g。实验结果表明,由于大粒子对于体积浓度的贡献度较大,因此凝结核粒子的数密度分布特征与体积浓度分布特征并不完全一致。
In this paper, electrical low-pressure impactor(ELPI),scanning electron microscope(SEM), and XRD diffraction instrument(XRD) techniques were used to characterize the particle size distribution, chemical composition and microstructure of coagulate nucleus of warm fog. By means of real-time observation and sampling of coagulate nucleus, the microphysical performance,number density,particle size distribution and nucleation rate of coagulate nucleus of artificial fog were acquired. The coagulate nucleus ware mainly made up of chloridate. The particle size distribution range was 0.261~1.59μm, and the crest value of size distribution was 0.609~0.942μm. The number density of coagulate nucleus was 3.98×10~5~5.12×10~5/cm~3,the volume concentration of coagulate nucleus was 2.02×10~5~2.30×10~5μm~3/cm~3. The maximum nucleation ratio was 3.07×10~(12)/g. These experiment results showed that the big particles of coagulate nucleus play a more important role on the volume concentration, and the number density distribution feature of coagulate nucleus is different from that of the volume concentration feature.
引文
[1]Johnson G R;Ristovski Z;Morawska L.Method for measuring the hygroscopic behavior of lower volatility fractions in an internally mixed aerosol[J].J.Aerosol Sci,2004(35):443-455.
    [2]Abderrrahim D;Abdelfetah M.Water activities,osmotic and activity cofficients in aqueous mixture of sodium and magnesium chlorides at 298.15K by the hygrometric method[J].Fluid Phase Equilibria,2003(206):13-25.
    [3]Kreidenweis S M,Koehler K,De Mott P J,et al.Water activity and activation diameters from hygroscopicity data-Part I:theory and application to inorganic salts[J].Atmos Chem Phys,2005(5):1357-1370.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700