振动强磨及酸溶处理对铁酸锌粉体性状的影响
详细信息 查看官网全文
- 英文论文题名：Influence of Strong Vibration Grinding and Acid Soluble Processing to Character of Zinc Ferrite Powder
- 论文作者：徐明 ; 杨金林 ; 马少健 ; 刘平
- 英文论文作者：XU Ming ; YANG Jinlin ; MA Shaojian ; LIU Ping ; School of Resources and Metallurgy ; Guangxi University ; Guilin University of Technology at Nanning
- 年：2016
- 作者机构：广西大学资源与冶金学院;桂林理工大学南宁分校;
- 论文关键词：振动强磨 ; 酸溶 ; 铁酸锌 ; 粉体
- 英文论文关键词：strong vibration grinding ; acid soluble ; zinc ferrite ; powder
- 会议召开时间：2016-11-18
- 会议录名称：第一届先进材料前沿学术会议论文集（《材料导报》2016年第30卷第Z1期）
- 语种：中文
- 分类号：TQ132.41;TB383.3
- 学会代码：CLDB
- 会议名称：第一届先进材料前沿学术会议
- 会议地点：中国陕西西安
- 主办单位：《材料导报》杂志社
- 学会名称：材料导报编辑部
- 页数：4
- 文件大小：930k
- 原文格式：O
- 会议级别：全国
摘要
通过机械振动强磨及酸溶处理对焙烧法所制纯铁酸锌进行细化,采用XRD分析不同处理条件下铁酸锌的晶粒尺寸、晶胞参数及晶格应变大小,采用SEM分析颗粒微观形貌,采用孔径与比表面分析仪分析比表面积和孔径尺寸。结果表明:当实验条件分别为振动磨12 min、40℃/50 g·L~(-1)酸溶后磨12 min及90℃/250 g·L~(-1)酸溶后磨12 min时,晶粒尺寸及微观应变均呈先增大再减小再增大的变化趋势。90℃/250 g·L~(-1)条件下酸溶处理后再机械强磨比直接机械处理的比表面增大而单点平均孔半径会减小,孔容则基本不变。40℃/50 g·L~(-1)酸浸后磨12 min制得的铁酸锌粉体粒度较小,基本处于200~300 m,均一性较好。
Pure zinc ferrite particles were refined through strong mechanical vibration grinding and acid soluble treatment.The grain size,the crystal cell parameters and the lattice strain of zinc ferrite were analyzed by the method of XRD,SEM analysis was used on the study of particle microstructure,specific surface area and aperture size were analyzed with pore size and specific surface analyzer under different conditions.The results show that grain size and micro strain were increased firstly,then decrease,and increase lastly when the condition is vibration grinding for 12 min,acid leaching under the condition of 40 ℃/50 g·L~(-1)and 90 ℃/250 g ·L~(-1) then vibration grinding for 12 min,respectively.Compared with direct mechanical processing,the specific surface increased,single point average pore radius decreased and pore volume is basically unchanged under mechanical grinding after acid soluble at 90℃/250 g·L~(-1).Particle size of zinc ferrite powder vibration grinding for 12 min after acid leaching at 40 ℃/50 g ·L~(-1) is about200-300 nm and has good uniformity.
Pure zinc ferrite particles were refined through strong mechanical vibration grinding and acid soluble treatment.The grain size,the crystal cell parameters and the lattice strain of zinc ferrite were analyzed by the method of XRD,SEM analysis was used on the study of particle microstructure,specific surface area and aperture size were analyzed with pore size and specific surface analyzer under different conditions.The results show that grain size and micro strain were increased firstly,then decrease,and increase lastly when the condition is vibration grinding for 12 min,acid leaching under the condition of 40 ℃/50 g·L~(-1)and 90 ℃/250 g ·L~(-1) then vibration grinding for 12 min,respectively.Compared with direct mechanical processing,the specific surface increased,single point average pore radius decreased and pore volume is basically unchanged under mechanical grinding after acid soluble at 90℃/250 g·L~(-1).Particle size of zinc ferrite powder vibration grinding for 12 min after acid leaching at 40 ℃/50 g ·L~(-1) is about200-300 nm and has good uniformity.
引文
1 Tie Shengnian,Li Xing,Li Yunjun.Preparation technology and application of ultrafine powder materials[J].China Powder Sci Technol,2009,15(3):68(in Chinese).铁生年,李星,李昀珺.超细粉体材料的制备技术及应用[J].中国粉体技术,2009,15(3):68.
2 Liu Bo,Wang Zhumei,Liao Runhua,et al.Preparation and photocatalytic properties of B-doped TiO_2 nano-powder by sol-gel method[J].Bull Chinese Ceram Soc,2016,35(2):399(in Chinese).刘波,王竹梅,廖润华,等.溶胶凝胶法制备B掺杂TiO_2纳米粉体及其光催化性能研究[J].硅酸盐通报,2016,35(2):399.
3 Chang Qing,Ru Hongqiang,Yu Liang,et al.Influence of citric acid on synthesis of powdered hydroxy apatite with Ca(NO_3)_2-P_2O_5 System[J].J Northeastern University:Nat Sci,2011,32(1):85(in Chinese).常青,茹红强,喻亮,等.柠檬酸对Ca(NO_3)_2-P_2O_5体系合成羟基磷灰石粉体的影响[J].东北大学学报:自然科学版,2011,32(1):85.
4 Yang Fan,Kang Xiaoli,Luo Jiangshan,et al.Preparation of nanocrystalline Zr powders by mechanical ball milling and their burning behavior[J].Chin J Energetic Mater,2016,24(1):91(in Chinese).杨帆,康晓丽,罗江山,等.机械球磨法制备纳米晶Zr粉及其燃烧性能[J].含能材料,2016,24(1):91.
5 Huang Junhua,Gao Lian,Chen Jinyuan,et al.Controlling crystalUnity of nano-titania powder prepared by the hydrolysis of titanium alkoxide[J].J Inorg Mater,1996,11(1):51(in Chinese).黄军华,高濂,陈锦元,等.纳米TiO_2粉体制备过程中结晶度的控制[J].无机材料学报,1996,11(1):51.
6 Xiao Jin,Deng Songyun,WU Shenghui,et al.Preparation technology of aluminium nitride[J].Chin J Inorg Chem,2010,26(3):464(in Chinese).肖劲,邓松云,吴胜辉,等.氮化铝粉体制备工艺研究[J].无机化学学报,2010,26(3):464.
7 Yang Hui,Zhang Yuanyuan.Effects of CS molecules on the morphology of HA/CS composite powders prepared by Co-precipitation method[J].J Synthetic Cryst,2012,41(1):209(in Chinese).杨辉,张园园.壳聚糖分子对共沉淀法合成羟基磷灰石/壳聚糖粉体材料晶体形貌的影响[J].人工晶体学报,2012,41(1):209.
8 Liu Jianke,Han Chen,Xia Ao,et al.Research on morphology control of Li_3V_2(PO_4)_3 prepared by sol-gel method[J].J Synthetic Cryst,2016,45(2):393(in Chinese).刘建科,韩晨,夏傲,等.溶胶凝胶法制备Li_3V_2(PO_4)_3粉体的形貌控制研究[J].人工晶体学报,2016,45(2):393.
9 Wang Mitang,Li Mei,Liu Zhaogang,et al.Mechanism and characterization and countermeasures of agglomeration of ultrafine particles[J].China Powder Sci Technol,2008,14(3):46(in Chinese).王觅堂,李梅,柳召刚,等.超细粉体的团聚机理和表征及消除[J].中国粉体技术,2008,14(3):46.
10 Sun Yong,Xiao Dingquan,Zhu Jianguo,et al.The influence of different powder-preparing techniques on properties of potassium-sodium niobium lead-free piezoelectric ceramics[J].J Funct Mater,2009,6(40):953(in Chinese).孙勇,肖定全,朱建国,等.不同粉体制备工艺对铌酸钠钾无铅压电陶瓷性能的影响[J].功能材料,2009,6(40):953.
11 Chen Xulong,Zhao Guowei,Liao Zhengen,et al.Comparative study on properties of angelica in ultrafine powder and common powder[J].Chinese J Experimental Traditional Medical Formulae,2010,16(18):Kin Chinese).陈绪龙,赵国巍,廖正根,等.当归超微粉体和普通粉体的粉体学性质比较[J].中国实验方剂学杂志,2010,16(18):1.
12 Chen Yongming,Tang Motang,Li Chengguo,et al.Preparation of zinc ferrite using ferrite resource in Zn-In concentrate[J].J Mater Metall,2007,6(3):196(in Chinese).陈永明,唐谟堂,李诚国,等.铟锌精矿铁资源制取铁酸锌新工艺[J].材料与冶金学报,2007,6(3):196.
13 Wang Huan,Di Yunping,Xu Lihua.Preparation of nano-photocatalytic ZnFe_2O_4 powders using the Dachang tin ore in Guangxi[J].Rare Metal Mater Eng,2008,37(2):394(in Chinese).王缓,邸云萍,徐利华.利用广西大厂锡矿制备铁酸锌光催化粉体[J].稀有金属材料与工程,2008,37(2):394.
14 Liu Jianjun,He Hongliang,Jin Xiaogang.Method for synthesizing nanosized nickel ferrite by shock wave[J].Chin J Mater Res,1999,13(6):650(in Chinese).刘建军,贺红亮,金孝刚.用冲击波合成法制备纳米铁酸镍粉体[J].材料研究学报,1999,13(6):650.
15 Tian Qinghua,Huang Kai,Guo Xueyi.Research progress on preparation of nano-sized zinc ferrite powders[J].Mater Sci Eng Powder Metall,2005,10(4):200(in Chinese).田庆华,黄凯,郭学益.纳米铁酸锌粉末制备的研究进展[J].粉末冶金材料科学与工程,2005,10(4):200.
16 Xu Kang,Liu Jianjun,Xu Tao,et al.Synthesis of nanometer-sized zinc frrite by shock wave treatment method[J].J Inorg Mater,1997,12(5):759(in Chinese).徐康,刘建军,徐洮,等.用冲击波合成法制备纳米铁酸锌粉体——一种制备纳米粉体的新技术[J].无机材料学报,1997,12(5):759.
2 Liu Bo,Wang Zhumei,Liao Runhua,et al.Preparation and photocatalytic properties of B-doped TiO_2 nano-powder by sol-gel method[J].Bull Chinese Ceram Soc,2016,35(2):399(in Chinese).刘波,王竹梅,廖润华,等.溶胶凝胶法制备B掺杂TiO_2纳米粉体及其光催化性能研究[J].硅酸盐通报,2016,35(2):399.
3 Chang Qing,Ru Hongqiang,Yu Liang,et al.Influence of citric acid on synthesis of powdered hydroxy apatite with Ca(NO_3)_2-P_2O_5 System[J].J Northeastern University:Nat Sci,2011,32(1):85(in Chinese).常青,茹红强,喻亮,等.柠檬酸对Ca(NO_3)_2-P_2O_5体系合成羟基磷灰石粉体的影响[J].东北大学学报:自然科学版,2011,32(1):85.
4 Yang Fan,Kang Xiaoli,Luo Jiangshan,et al.Preparation of nanocrystalline Zr powders by mechanical ball milling and their burning behavior[J].Chin J Energetic Mater,2016,24(1):91(in Chinese).杨帆,康晓丽,罗江山,等.机械球磨法制备纳米晶Zr粉及其燃烧性能[J].含能材料,2016,24(1):91.
5 Huang Junhua,Gao Lian,Chen Jinyuan,et al.Controlling crystalUnity of nano-titania powder prepared by the hydrolysis of titanium alkoxide[J].J Inorg Mater,1996,11(1):51(in Chinese).黄军华,高濂,陈锦元,等.纳米TiO_2粉体制备过程中结晶度的控制[J].无机材料学报,1996,11(1):51.
6 Xiao Jin,Deng Songyun,WU Shenghui,et al.Preparation technology of aluminium nitride[J].Chin J Inorg Chem,2010,26(3):464(in Chinese).肖劲,邓松云,吴胜辉,等.氮化铝粉体制备工艺研究[J].无机化学学报,2010,26(3):464.
7 Yang Hui,Zhang Yuanyuan.Effects of CS molecules on the morphology of HA/CS composite powders prepared by Co-precipitation method[J].J Synthetic Cryst,2012,41(1):209(in Chinese).杨辉,张园园.壳聚糖分子对共沉淀法合成羟基磷灰石/壳聚糖粉体材料晶体形貌的影响[J].人工晶体学报,2012,41(1):209.
8 Liu Jianke,Han Chen,Xia Ao,et al.Research on morphology control of Li_3V_2(PO_4)_3 prepared by sol-gel method[J].J Synthetic Cryst,2016,45(2):393(in Chinese).刘建科,韩晨,夏傲,等.溶胶凝胶法制备Li_3V_2(PO_4)_3粉体的形貌控制研究[J].人工晶体学报,2016,45(2):393.
9 Wang Mitang,Li Mei,Liu Zhaogang,et al.Mechanism and characterization and countermeasures of agglomeration of ultrafine particles[J].China Powder Sci Technol,2008,14(3):46(in Chinese).王觅堂,李梅,柳召刚,等.超细粉体的团聚机理和表征及消除[J].中国粉体技术,2008,14(3):46.
10 Sun Yong,Xiao Dingquan,Zhu Jianguo,et al.The influence of different powder-preparing techniques on properties of potassium-sodium niobium lead-free piezoelectric ceramics[J].J Funct Mater,2009,6(40):953(in Chinese).孙勇,肖定全,朱建国,等.不同粉体制备工艺对铌酸钠钾无铅压电陶瓷性能的影响[J].功能材料,2009,6(40):953.
11 Chen Xulong,Zhao Guowei,Liao Zhengen,et al.Comparative study on properties of angelica in ultrafine powder and common powder[J].Chinese J Experimental Traditional Medical Formulae,2010,16(18):Kin Chinese).陈绪龙,赵国巍,廖正根,等.当归超微粉体和普通粉体的粉体学性质比较[J].中国实验方剂学杂志,2010,16(18):1.
12 Chen Yongming,Tang Motang,Li Chengguo,et al.Preparation of zinc ferrite using ferrite resource in Zn-In concentrate[J].J Mater Metall,2007,6(3):196(in Chinese).陈永明,唐谟堂,李诚国,等.铟锌精矿铁资源制取铁酸锌新工艺[J].材料与冶金学报,2007,6(3):196.
13 Wang Huan,Di Yunping,Xu Lihua.Preparation of nano-photocatalytic ZnFe_2O_4 powders using the Dachang tin ore in Guangxi[J].Rare Metal Mater Eng,2008,37(2):394(in Chinese).王缓,邸云萍,徐利华.利用广西大厂锡矿制备铁酸锌光催化粉体[J].稀有金属材料与工程,2008,37(2):394.
14 Liu Jianjun,He Hongliang,Jin Xiaogang.Method for synthesizing nanosized nickel ferrite by shock wave[J].Chin J Mater Res,1999,13(6):650(in Chinese).刘建军,贺红亮,金孝刚.用冲击波合成法制备纳米铁酸镍粉体[J].材料研究学报,1999,13(6):650.
15 Tian Qinghua,Huang Kai,Guo Xueyi.Research progress on preparation of nano-sized zinc ferrite powders[J].Mater Sci Eng Powder Metall,2005,10(4):200(in Chinese).田庆华,黄凯,郭学益.纳米铁酸锌粉末制备的研究进展[J].粉末冶金材料科学与工程,2005,10(4):200.
16 Xu Kang,Liu Jianjun,Xu Tao,et al.Synthesis of nanometer-sized zinc frrite by shock wave treatment method[J].J Inorg Mater,1997,12(5):759(in Chinese).徐康,刘建军,徐洮,等.用冲击波合成法制备纳米铁酸锌粉体——一种制备纳米粉体的新技术[J].无机材料学报,1997,12(5):759.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |