用户名: 密码: 验证码:
集成模块式污水处理装置同步硝反硝化(SND)处理低碳氮(C/N)比污水的实验研究
详细信息    查看官网全文
摘要
中小城镇生活污水较分散、水量小、碳氮(C/N)比低,难以实现集中大规模处理和生物深度脱氮,外排则易引起接纳水体富营养化,因此实现小水量低C/N比污水一体化深度脱氮具有重要意义。以模拟低C/N比污水为研究对象,采用集成模块式污水处理装置与技术,研究了在不同DO、HRT、C/N比、p H下污水氨氮、总氮的去除,实现了同步硝化反硝化(SND),研究结果表明,DO=1.2-1.4 mg/L,总HRT=20h(第一反应区HRT=2h),原水C/N=5:1,p H=7.5时,NH3--N可以从15mg/L降至2.5mg/L,总氮可以从20mg/L降至4mg/L,去除率可以达到83%和80%;反应器以第一反应区为主反应区实现同步硝化反硝化(SND),SND动力学模型求解得出集成模块式污水处理SND动力学方程及反硝化过程中硝酸盐氮饱和常数KD=2.58,远高于普通活性污泥反硝化过程中的饱和常数0.2-0.5mg/L。集成模块式污水处理技术能高效去除低C/N比污水中的总氮,且具有运行稳定和抗冲击等优点。为中小城镇生活污水深度脱氮提供了技术支持和理论基础。
It is difficult to achieve centralized treatment and biological deep denitrogen of wastewater from small town due to low C/N ratio and small discharge. If the tail water discharged into water body, the eutrophication could be produced due to higher concentration of total nitrogen. Therefore, the study on deep denitrogen technology for low C/N ratio small discharge is of important significance. In this paper, the ammonia and total nitrogen(TN) removal efficiency of SND in an integrated device and its influence factors,such as DO concentration, HRT, C/N ratio, influent p H, etc., were studied and analyzed. The dynamic model of SND in the system was solved. The results showed that total nitrogen can be decreased to 4 mg·L-1 from20mg·L-1(80%), ammonia to 2.5 mg·L-1 from15mg·L-1(83%) by the SND in the integrated device at conditions of DO 1.2-1.4 mg·L-1, HRT 20h(2h in the first reaction zone), C/N ratio 5:1, influent p H 7.5. The TN removal was mainly happened in the in the first reaction zone. of 2.58 was obtained by solving dynamic model of SND in the system, which was well above that of traditional active sludge process(0.2-0.5mg·L-1). The results indicate that TN of low C/N ratio wastewater can be removed efficiently by this technology. The integrated wastewater treatment technology is of the advantages of operation stability and shock resistance etc., and could be a basis for advanced nitrogen removal of low C/N ratio small discharge from small town and countryside.
引文
[1]刘汉湖.生态工程技术在中小城镇污水处理中的应用[A].王国清.中国环境科学学会学术年会优秀论文集[C].中国环境科学出版社,北京:2006:2066-2069.
    [2]杨鲁豫,王琳,王宝贞.适宜中小城镇的水污染控制技术[J].中国给水排水,2001,17(1):23-25.
    [3]王孝华.中小城市水污染及控制[J].科技咨询导报,2007,219-220.
    [4]戴艺,王辉,李荧,等.缺氧/好氧/一体式MBR工艺处理养猪污水并回用[J].中国给水排水,2012,28(22):92-94.
    [5]吕炳南,陈志强.污水处理新技术[M].哈尔滨:哈尔滨工业大学出版社,2005.
    [6]Chui.P.C.,Terashima Y.,Tay,J.H.and Ozaki,H.Performance of a partly aerated biofilter in the removal of nitrogen[J].Wat.Sci.Tech.,1996,34(1-2):187-194.
    [7]刘富军.曝气生物滤池去除二级出水中的氨氮[J].环境科学与技术,2005,28(7):95-97.
    [8]李德生.好氧→缺氧→厌氧集成模块式污水快速脱氮反应装置及其处理方法:中国,201010209203.3[P].2010-6-17.
    [9]Seifi M,Fazaelipoor M H.Modeling simultaneous nitrification and denitrification(SND)in a fluidized bed biofilm reactor[J].Applied Mathematical Modelling,2012,36(11):5603-5613.
    [10]Elisabeth V Munch,Paul Lant,Jurg Kelle.Simultaneous nitrification and denitrification inbech-scale sequencing batch reaaors[J].Wat.Res.,1996,30(2):277-284
    [11]Christine H,Saine IC.Simultaneous nitrification/denitrification in all aerobic biofilm system[J].Wat.Sci Tech,1998,37.
    [12]Elisabeth V Munch,Paul Lant,Jurg Kelle.Simultaneous nitrification and denitrification in batch-scale sequencing batch reactors[J].Wat.Res.,1996,30(2):277-284.
    [13]Robertson L A,Gijs K J.Aerobic denitrification:a controversy revived[J].Arch Microbiol.,1984,139:351-354.
    [14]国家环境保护总局.水和废水监测分析方法,4thed[M].北京:中国环境科学出版社,2002.
    [15]Rivas F J.Jiont aerobic biodegradation of wastewater from table olive manufacturing industries and urban wastewater[J].Bioprocess Engineering,2000,23:283-286.
    [16]林燕,何义亮,孔海南,等.MBR中同步硝化反硝化及异养硝化现象试验研究[J].膜科学与技术,2006,26(2):22-26.
    [17]Christine H,Saine IC.Simultaneous nitrification/denitrification in all aerobic biofilm system[J].Wat.Sci.Tech,1998,37.
    [18]Jun B H,Miyanaga K,Tanji Y.Removal of nitrogenous and carbonaceous substances by a porous carrier membranehybrid process for wastewater treatment[J].Biochem.Eng,2003,14(1):37-44.
    [19]Bock E,Schmidt I,Stuven R,et al.Nitrogen loss caused by denitrifying notrosomoas cells using ammonium or hydrogen as electron donors and nitrite as electron acceptor[J],Arch.Microbiol,1995,163(1):16-20.
    [20]李峰,吕锡武.序批式反应器(SBR)处理氨氮废水的初步研究[J].江苏环境科技,1999,2:14-17.
    [21]Chui.P.C.,Terashima Y.,Tay,J.H.and Ozaki,H.Performance of a partly aerated biofilter in the removal of nitrogen[J].Wat.Sci.Tech.,1996,34(1-2):187-194.
    [22]顾夏声.废水生物处理数学模式(2版)[M],北京:清华大学出版社,1993:105-204.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700