几个N-(5-邻菲罗啉基)二酸单酰胺的合成

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英文篇名：Synthesis of Several N-(5-Phenanthroline) Diacid Monoamides 作者：雷光东 ; 邓兵 ; 黄辉 英文作者：LEI Guang-dong,DENG Bing,HUANG Hui(College of Chemistry and Chemical Engineering,Neijiang Normal University,Neijiang,Sichuan 641100,China) 关键词：邻菲罗啉 ; N-(5-邻菲罗啉基)丁二酸单酰胺 ; N-(5-邻菲罗啉基)戊二酸单酰胺 ; N-(5-邻菲罗啉基)己二酸单酰胺 英文关键词：phenanthroline;N-(5-phenanthroline) succinic acid amide;N-(5-phenanthroline) glutaric acid amide;N-(5-phenanthroline) adipic acid amide 中文刊名：NJSG 英文刊名：Journal of Neijiang Normal University 机构：内江师范学院化学化工学院; 出版日期：2013-02-25 出版单位：内江师范学院学报 年：2013 期：v.28;No.161 基金：四川省教育厅科研基金项目(07ZC031) 语种：中文; 页：NJSG201302009 页数：3 CN：02 ISSN：51-1621/Z 分类号：38-40

摘要

以邻菲罗啉为原料,首先经硝化、还原制得5-邻菲罗啉胺,再将5-邻菲罗啉胺与几种二元酸酐发生酰化反应合成了N-(5-邻菲罗啉基)丁二酸单酰胺、N-(5-邻菲罗啉基)戊二酸单酰胺和N-(5-邻菲罗啉基)己二酸单酰胺,并且使用红外光谱证实了它们的结构.
        5-amino-1,10-phenanthroline was synthesized from phenanthroline through nitrification and reduction reaction.Then several compounds,such as N-(5-phenanthroline) succinic acid amide,N-(5-phenanthroline) glutaric acid amide and N-(5-phenanthroline) adipic acid amide,were synthesized from 5-amino-1,10-phenanthroline and several dibasic acid anhydrides by means of acylation reactions.The structures of the three products were corroborated by infrared spectroscopy.

引文

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