化学清洗废水处理技术的研究进展
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摘要
化学清洗废水是指工业领域去除生产设备金属表面因安装或运行过程形成的污垢而产生的废水。水质因清洗对象、清洗方式和清洗剂的不同而复杂多变,并且处理困难。通过对实际酸、碱清洗废水的水质特性分析,研究了不同清洗废水中特征污染物的处理技术,并提出了废水处理的相关管理建议。
Chemical cleaning wastewater is generated from removing fouling on the surface of production equipment due to installation or operation process in the industrial field. The treatment of water quality is difficult due to the complexity of cleaning objects,cleaning methods and cleaning agents. The water quality characteristics of the actual acid and alkaline cleaning wastewater are analyzed,the treatment technology of characteristic pollutants in different cleaning wastewaters is studied,and the management suggestions for wastewater treatment are proposed for the treatment technology of chemical cleaning wastewater.
Chemical cleaning wastewater is generated from removing fouling on the surface of production equipment due to installation or operation process in the industrial field. The treatment of water quality is difficult due to the complexity of cleaning objects,cleaning methods and cleaning agents. The water quality characteristics of the actual acid and alkaline cleaning wastewater are analyzed,the treatment technology of characteristic pollutants in different cleaning wastewaters is studied,and the management suggestions for wastewater treatment are proposed for the treatment technology of chemical cleaning wastewater.
引文
[1]杨冬野,雷建平.复合酸酸洗工艺在600 MW超临界机组中的应用[J].清洗世界,2008,24(5):24-27.
[2]陈勇,凌琰.工业清洗行业发展机遇及企业发展[J].清洗世界,2014,30(9):1-8.
[3]袁渭军,赵瑞云,赵菁,等.US-Fenton法处理电厂锅炉酸洗废液的实验研究[J].西安工业大学学报,2016,36(5):345-351.
[4]宋嘉美.某铜加工厂废乳液及脱脂废水处理工艺设计[J].有色金属加工,2017,46(3):64-66.
[5]周福盛.电解脱脂废水的深度处理实例[J].科技创新与应用,2016(31):45-45.
[6]岳增刚.锅炉酸洗废水一体化处理工艺应用研究[J].化学工程,2018,46(1):12-14.
[7]何婷,何业俊,吴翔.脱脂和磷化废水处理工艺及工程实践[J].中国给水排水,2016(20):91-93.
[8]OLMEZ H T,ARSLAN A I,BASAR G.Multivariate analysis of anionic,cationic and nonionic textile surfactant degradation w ith the H2O2/UV-C process by using the capabilities of response surface methodology[J].J Hazard M ater,2011(1):193-203.
[9]CHEN P J,ROSENFELDT E J,KULLMAN S W,et al.Biological assessments of a mixture of endocrine disruptors at environmentally relevant concentrations in w ater follow ing UV/H2O2oxidation[J].Sci Total Environ,2007(1-3):18-26.
[10]REIS A R,TABEI K,SAKAKIBARA Y.Oxidation mechanism and overall removal rates of endocrine disrupting chemicals by aquatic plants[J].J Hazard M ater,2014(2):79-88.
[11]LA GUARDIA M J,HALE R C,HARVEY E,et al.Alkylphenol ethoxylate degradation products in land-applied sewage sludge(biosolids)[J].Environ Sci Technol,2001,35(24):4798-4804.
[12]黄隆煜,刘勇,李大国,等.EDTA酸洗技术在1 000 MW机组锅炉化学清洗中的应用[J].腐蚀与防护,2011,32(1):60-62.
[13]陈颖敏,左俊利,王亚慧.保定电厂协调EDTA锅炉化学清洗探析[J].锅炉技术,2008,39(3):57-60.
[14]滕维忠,郭俊文,柯于进,等.华能沁北电厂2×600 MW超临界机组热力系统的化学清洗[J].热力发电,2007,36(2):73-75.
[15]董怡君,王淑莹,张宇坤,等.高亚硝态氮钝化清洗废水的生物处理及过程控制[J].化工学报,2014,65(8):3164-3169.
[16]RAJAKOVIC'V,SKALA D.Separation of w ater-in-oil emulsions by freeze/thaw method and microw ave radiation[J].Sep Pur Technol,2017,49(2):192-196.
[17]PICARD F,CHAOUKI J.Sodium hypochlorite oxidation of petroleum aliphatic contaminants in calcareous soils[J].Chemosphere,2016,145:200-206.
[18]YEN C H,CHEN K F,KAO C M,et al.Application of persulfate to remediate petroleum hydrocarbon-contaminated soil:Feasibility and comparison w ith common oxidants[J].JHazard M ater,2011(2-3):2097-2102.
[19]LI X,CAO X,WU G,et al.Ozonation of diesel-fuel contaminated sand and the implications for remediation end-points[J].Chemosphere,2014,109(5):71-76.
[20]SENN A M,RUSSO Y M,LITTER M I.Treatment of w astew ater from an alkaline cleaning solution by combined coagulation and photo-Fenton processes[J].Sep Pur Technol,2014,132:552-560.
[21]TORRES L G,BELLOC C,VACA M,et al.Coagulationflocculation process applied to w astew aters generated in hydrocarbon-contaminated soil w ashing:interactions among coagulant and flocculant concentrations and pH value[J].Journal of Environmental Science&Health Part A Toxic/hazardous Substances&Environmental Engineering,2009,44(13):1449-1456.
[22]DA SILVA S W,KLAUCK C R,SIQUEIRA M A,et al.Degradation of the commercial surfactant nonylphenol ethoxylate by advanced oxidation processes[J].J Hazard M ater,2015(8):241.
[23]KARCI A,ARSLANALATON I,BEKBOLET M.Advanced oxidation of a commercially important nonionic surfactant:investigation of degradation products and toxicity[J].J Hazard M ater 2013(3):275-282.
[24]LI K,XIONG J,CHEN T,et al.Preparation of graphene/TiO2composites by nonionic surfactant strategy and their simulated sunlight and visible light photocatalytic activity tow ards representative aqueous POPs degradation[J].J Hazard M ater,2013(1):19-28.
[25]RENAULT F,SANCEY B,BADOT P M,et al.Chitosan for coagulation/flocculation processes-an eco-friendly approach[J].Eur Polym J,2009,45(5):1337-1348.
[26]鲁萨.模拟矿山酸性废水中重金属化学沉淀去除及污泥表征[D].上海:东华大学,2011.
[27]刘景允.综合电镀废水处理技术与工艺研究[D].天津:天津大学,2008.
[28]JIN H,JI Z,YUAN J,et al.Research on removal of fluoride in aqueous solution by alumina-modified expanded graphite composite[J].J Alloys Compd,2014(9):361-367.
[29]邵占卫,杨江华,胡小锐.Ca(OH)2-CaCl2沉淀法处理核工业高氟废水[J].工业水处理,2017,37(7):70-73.
[30]禹路,宗盼盼.CaCl2-PAM处理太阳能电池产业含氟废水[J].低碳世界,2017(4):22-23.
[31]刘宏江,李鹏,贺军四,等.含氟废水处理的机理和工艺流程的研究[J].铜业工程,2012(6):81-84.
[32]GLVEZ J L,DUFOUR J,NEGRO C,et al.Determination of iron and chromium fluorides solubility for the treatment of w astes from stainless steel mills[J].Chem Eng J,2008,136(2):116-125.
[33]刘航,彭稳,陆继长,等.吸附法处理含氟水体的研究进展[J].水处理技术,2017(9):13-18.
[34]JAGTAP S,YENKIE M K N,LABHSETWAR N,et al.Defluoridation of drinking w ater using chitosan based mesoporous alumina[J].M icropor M esopor M ater,2011,142(2-3):454-463.
[35]DROUICHE N,AOUDJ S,LOUNICI H,et al.Fluoride removal from pretreated photovoltaic w astew ater by electrocoagulation:an investigation of the effect of operational parameters[J].Procedia Engineering,2012,33(3):385-391.
[36]ARAHMAN N,MULYATI S,LUBIS M R,et al.The removal of fluoride from w ater based on applied current and membrane types in electrodialyis[J].J Fluorine Chem,2016(10):97-102.
[37]岳楠,周康根,董舒宇,等.次氯酸钠氧化去除废水中氨氮的研究[J].应用化工,2015(4):602-604.
[38]ZHANG X,LI W,REN P,et al.Chlorine/UV induced photochemical degradation of total ammonia nitrogen(TAN)and process optimization[J].Rsc Advances,2015,5:63793-63799.
[39]HUANG H,YANG L,XUE Q,et al.Removal of ammonium from sw ine w astew ater by zeolite combined w ith chlorination for regeneration[J].J Environ M anage,2015,160:333-341.
[40]AN Y,ZHOU Z,QIAO W,et al.Simultaneous removal of phosphorus and dissolved organic matter from a sludge in situ reduction process effluent by coagulants[J].Rsc Advances,2017,7:42305-42311.
[41]LI N,SHENG G P,LU Y Z,et al.Removal of antibiotic resistance genes from w astew ater treatment plant effluent by coagulation[J].Water Res,2017,111:204-212.
[42]WANG D,GUO F,WU Y,et al.Technical,economic and environmental assessment of coagulation/filtration tertiary treatment processes in full-scale w astew ater treatment plants[J].J Clean Prod,2017(9):1185-1194.
[43]BURAGOHAIN S,DEKA D C,DEVI A.Fenton oxidation and combined Fenton-microbial treatment for remediation of crude oil contaminated soil in Assam-India[J].Environmental Science Processes and Impacts,2013,15(10):1913-1920.
[44]SANTANA-MARTNEZ G,ROA-MORALES G,CAMPO EM D,et al.Electro-Fenton and Electro-Fenton-like w ith in situ electrogeneration of H2O2and catalyst applied to 4-chlorophenol mineralization[J].Electrochim Acta,2016,195:246-256.
[45]ALEXANDER J C,RAMREZ-CORTINA C R.A comparative study:degradation of 2,5-dichlorophenol in w astew ater and distilled w ater by ozone and ozone-UV[J].Ozone-Sci Eng,2016,38(3):181-193.
[2]陈勇,凌琰.工业清洗行业发展机遇及企业发展[J].清洗世界,2014,30(9):1-8.
[3]袁渭军,赵瑞云,赵菁,等.US-Fenton法处理电厂锅炉酸洗废液的实验研究[J].西安工业大学学报,2016,36(5):345-351.
[4]宋嘉美.某铜加工厂废乳液及脱脂废水处理工艺设计[J].有色金属加工,2017,46(3):64-66.
[5]周福盛.电解脱脂废水的深度处理实例[J].科技创新与应用,2016(31):45-45.
[6]岳增刚.锅炉酸洗废水一体化处理工艺应用研究[J].化学工程,2018,46(1):12-14.
[7]何婷,何业俊,吴翔.脱脂和磷化废水处理工艺及工程实践[J].中国给水排水,2016(20):91-93.
[8]OLMEZ H T,ARSLAN A I,BASAR G.Multivariate analysis of anionic,cationic and nonionic textile surfactant degradation w ith the H2O2/UV-C process by using the capabilities of response surface methodology[J].J Hazard M ater,2011(1):193-203.
[9]CHEN P J,ROSENFELDT E J,KULLMAN S W,et al.Biological assessments of a mixture of endocrine disruptors at environmentally relevant concentrations in w ater follow ing UV/H2O2oxidation[J].Sci Total Environ,2007(1-3):18-26.
[10]REIS A R,TABEI K,SAKAKIBARA Y.Oxidation mechanism and overall removal rates of endocrine disrupting chemicals by aquatic plants[J].J Hazard M ater,2014(2):79-88.
[11]LA GUARDIA M J,HALE R C,HARVEY E,et al.Alkylphenol ethoxylate degradation products in land-applied sewage sludge(biosolids)[J].Environ Sci Technol,2001,35(24):4798-4804.
[12]黄隆煜,刘勇,李大国,等.EDTA酸洗技术在1 000 MW机组锅炉化学清洗中的应用[J].腐蚀与防护,2011,32(1):60-62.
[13]陈颖敏,左俊利,王亚慧.保定电厂协调EDTA锅炉化学清洗探析[J].锅炉技术,2008,39(3):57-60.
[14]滕维忠,郭俊文,柯于进,等.华能沁北电厂2×600 MW超临界机组热力系统的化学清洗[J].热力发电,2007,36(2):73-75.
[15]董怡君,王淑莹,张宇坤,等.高亚硝态氮钝化清洗废水的生物处理及过程控制[J].化工学报,2014,65(8):3164-3169.
[16]RAJAKOVIC'V,SKALA D.Separation of w ater-in-oil emulsions by freeze/thaw method and microw ave radiation[J].Sep Pur Technol,2017,49(2):192-196.
[17]PICARD F,CHAOUKI J.Sodium hypochlorite oxidation of petroleum aliphatic contaminants in calcareous soils[J].Chemosphere,2016,145:200-206.
[18]YEN C H,CHEN K F,KAO C M,et al.Application of persulfate to remediate petroleum hydrocarbon-contaminated soil:Feasibility and comparison w ith common oxidants[J].JHazard M ater,2011(2-3):2097-2102.
[19]LI X,CAO X,WU G,et al.Ozonation of diesel-fuel contaminated sand and the implications for remediation end-points[J].Chemosphere,2014,109(5):71-76.
[20]SENN A M,RUSSO Y M,LITTER M I.Treatment of w astew ater from an alkaline cleaning solution by combined coagulation and photo-Fenton processes[J].Sep Pur Technol,2014,132:552-560.
[21]TORRES L G,BELLOC C,VACA M,et al.Coagulationflocculation process applied to w astew aters generated in hydrocarbon-contaminated soil w ashing:interactions among coagulant and flocculant concentrations and pH value[J].Journal of Environmental Science&Health Part A Toxic/hazardous Substances&Environmental Engineering,2009,44(13):1449-1456.
[22]DA SILVA S W,KLAUCK C R,SIQUEIRA M A,et al.Degradation of the commercial surfactant nonylphenol ethoxylate by advanced oxidation processes[J].J Hazard M ater,2015(8):241.
[23]KARCI A,ARSLANALATON I,BEKBOLET M.Advanced oxidation of a commercially important nonionic surfactant:investigation of degradation products and toxicity[J].J Hazard M ater 2013(3):275-282.
[24]LI K,XIONG J,CHEN T,et al.Preparation of graphene/TiO2composites by nonionic surfactant strategy and their simulated sunlight and visible light photocatalytic activity tow ards representative aqueous POPs degradation[J].J Hazard M ater,2013(1):19-28.
[25]RENAULT F,SANCEY B,BADOT P M,et al.Chitosan for coagulation/flocculation processes-an eco-friendly approach[J].Eur Polym J,2009,45(5):1337-1348.
[26]鲁萨.模拟矿山酸性废水中重金属化学沉淀去除及污泥表征[D].上海:东华大学,2011.
[27]刘景允.综合电镀废水处理技术与工艺研究[D].天津:天津大学,2008.
[28]JIN H,JI Z,YUAN J,et al.Research on removal of fluoride in aqueous solution by alumina-modified expanded graphite composite[J].J Alloys Compd,2014(9):361-367.
[29]邵占卫,杨江华,胡小锐.Ca(OH)2-CaCl2沉淀法处理核工业高氟废水[J].工业水处理,2017,37(7):70-73.
[30]禹路,宗盼盼.CaCl2-PAM处理太阳能电池产业含氟废水[J].低碳世界,2017(4):22-23.
[31]刘宏江,李鹏,贺军四,等.含氟废水处理的机理和工艺流程的研究[J].铜业工程,2012(6):81-84.
[32]GLVEZ J L,DUFOUR J,NEGRO C,et al.Determination of iron and chromium fluorides solubility for the treatment of w astes from stainless steel mills[J].Chem Eng J,2008,136(2):116-125.
[33]刘航,彭稳,陆继长,等.吸附法处理含氟水体的研究进展[J].水处理技术,2017(9):13-18.
[34]JAGTAP S,YENKIE M K N,LABHSETWAR N,et al.Defluoridation of drinking w ater using chitosan based mesoporous alumina[J].M icropor M esopor M ater,2011,142(2-3):454-463.
[35]DROUICHE N,AOUDJ S,LOUNICI H,et al.Fluoride removal from pretreated photovoltaic w astew ater by electrocoagulation:an investigation of the effect of operational parameters[J].Procedia Engineering,2012,33(3):385-391.
[36]ARAHMAN N,MULYATI S,LUBIS M R,et al.The removal of fluoride from w ater based on applied current and membrane types in electrodialyis[J].J Fluorine Chem,2016(10):97-102.
[37]岳楠,周康根,董舒宇,等.次氯酸钠氧化去除废水中氨氮的研究[J].应用化工,2015(4):602-604.
[38]ZHANG X,LI W,REN P,et al.Chlorine/UV induced photochemical degradation of total ammonia nitrogen(TAN)and process optimization[J].Rsc Advances,2015,5:63793-63799.
[39]HUANG H,YANG L,XUE Q,et al.Removal of ammonium from sw ine w astew ater by zeolite combined w ith chlorination for regeneration[J].J Environ M anage,2015,160:333-341.
[40]AN Y,ZHOU Z,QIAO W,et al.Simultaneous removal of phosphorus and dissolved organic matter from a sludge in situ reduction process effluent by coagulants[J].Rsc Advances,2017,7:42305-42311.
[41]LI N,SHENG G P,LU Y Z,et al.Removal of antibiotic resistance genes from w astew ater treatment plant effluent by coagulation[J].Water Res,2017,111:204-212.
[42]WANG D,GUO F,WU Y,et al.Technical,economic and environmental assessment of coagulation/filtration tertiary treatment processes in full-scale w astew ater treatment plants[J].J Clean Prod,2017(9):1185-1194.
[43]BURAGOHAIN S,DEKA D C,DEVI A.Fenton oxidation and combined Fenton-microbial treatment for remediation of crude oil contaminated soil in Assam-India[J].Environmental Science Processes and Impacts,2013,15(10):1913-1920.
[44]SANTANA-MARTNEZ G,ROA-MORALES G,CAMPO EM D,et al.Electro-Fenton and Electro-Fenton-like w ith in situ electrogeneration of H2O2and catalyst applied to 4-chlorophenol mineralization[J].Electrochim Acta,2016,195:246-256.
[45]ALEXANDER J C,RAMREZ-CORTINA C R.A comparative study:degradation of 2,5-dichlorophenol in w astew ater and distilled w ater by ozone and ozone-UV[J].Ozone-Sci Eng,2016,38(3):181-193.
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