新一代环保型增塑剂柠檬酸三丁酯绿色合成进展
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摘要
柠檬酸三丁酯是一种无毒、绿色环保型的增塑剂,是替代目前广泛使用的有毒增塑剂的新一代环保型增塑剂之一。概述了柠檬酸三丁酯的主要性质及主要合成方法,对可用于制备柠檬酸三丁酯的固体酸催化剂进行了分类,总结了其在酯化反应中的应用。分析认为,有机固体酸催化剂是制备柠檬酸三丁酯的合适催化剂。
The tributyl citrate is a non-toxic, green and environmentally friendly plasticizer, one of the new generation plasticizers to replace the widely used toxic plasticizers, and has become a research hotspot. The main properties of the tributyl citrate are listed in detail,and the main synthesis methods of the tributyl citrate are reviewed. The solid acid catalysts for the synthesis of the tributyl citrate are classified and their applications in the esterification are summarized. It is concluded that the organic solid acid catalyst is a suitable catalyst for the preparation of the tributyl citrate.
The tributyl citrate is a non-toxic, green and environmentally friendly plasticizer, one of the new generation plasticizers to replace the widely used toxic plasticizers, and has become a research hotspot. The main properties of the tributyl citrate are listed in detail,and the main synthesis methods of the tributyl citrate are reviewed. The solid acid catalysts for the synthesis of the tributyl citrate are classified and their applications in the esterification are summarized. It is concluded that the organic solid acid catalyst is a suitable catalyst for the preparation of the tributyl citrate.
引文
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[17]SvitokováM,Daucík P,Balog K.Sedimentation of ion exchange resin particles in bitumen matrices[J].Petroleum and Coal,2010,52(2):99-106.
[18]侯信,黄文强,何炳林.强酸性阳离子交换树脂的热稳定性[J].离子交换与吸附,1995,11(5):465-472
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[20]崔小明.绿色增塑剂柠檬酸三丁酯的生产技术进展[J].化工文摘,2009(1):19-21.
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[25]吴英华.硫酸氢钠催化合成柠檬酸三丁酯[J].山西化工,2007(3):10-12.
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[27]雍靓,解从霞,杨凯,等.酸功能化离子液体催化合成柠檬酸三丁酯[J].分子催化,2008(2):105-110.
[28]周华锋,李文泽,张丽清.多孔二氧化硅负载硅钨酸催化合成柠檬酸三丁酯[J].化学研究与应用,2014(1):125-129.
[29]张圆圆,刘哲林,吴克,等.Keggin型杂多酸Hn XW12O40(X=P5+,Si4+,B3+;n=3,4,5)催化合成柠檬酸三丁酯[J].分子科学学报,2019,35(2):115-120.
[30]周喜,李泽贤,张超.磷钨酸铵铝复合盐催化合成柠檬酸三丁酯[J].精细化工,2019,36(5):919-922.
[31]王少鹏.分子筛SBA-15负载杂多酸催化剂的制备及其催化合成柠檬酸三丁酯的研究[D].太原:太原理工大学,2007.
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[34]Liao Y,Peng M,Tong P J,et al.Synthesis of tributyl citrate using a novel solid acid catalyst prepared by the biomass waste[R].Chengdu:China Academic Journal Electronic Publishing House,2011:924-927
[35]陈平,邓威,张晓丽.耐温强酸性阳离子交换树脂合成柠檬酸三丁酯[J].抚顺石油学院学报,2003(4):24-26,37.
[36]刘庆辉,詹宏昌,汤敏擘.固体酸催化剂的分类以及研究近况[J].广州化工,2008(2):14-17.
[37]Jiang T S,Zhao Q,Li M,et al,Preparation of mesoporous titania solid superacid and its catalytic property[J].Journal of Hazardous Materials,2008,159(2):204-209.
[38]张昭,沈俊,张明俊,等.介孔二氧化钛及其SO42-/TiO2固体超强酸制备方法:CN1807259[P].2006-07-26.
[39]刘桂荣,王洪章.固体超强酸催化剂的研究进展[J].江西化工,2005(3):23-27,60.
[40]Yu F W,Ji D X,Nie Y,et al.Study on the pyrolysis of cellulose for bio-oil with mesoporous molecular sieve catalysts[J].Applied Biochemistry and Biotechnology,2012,168(1):174-182.
[41]Fan Y,Shi G,Liu H Y,et al.Morphology tuning of supported MoS2slabs for selectivity enhancement of fluid catalytic cracking gasoline hydrodesulfurization catalysts[J].Applied Catalysis B,Environmental,2009,91(1):73-82.
[42]张世方.催化重整工艺技术发展[J].中外能源,2012(6):60-65.
[43]赵云,刘春燕,贺宁,等.组合纳米ZSM-5沸石上全馏分FCC汽油的选择性裂解[C]//第十七届全国分子筛学术大会会议论文集.北京:中国化学会分子筛专业委员会,2013:2.
[44]李凯.ZSM-5催化剂成型技术及其甲苯歧化性能[D].南京:南京工业大学,2006.
[45]庞小文,孟凡会,卢建军,等.甲醇制汽油工艺及催化剂制备的研究进展[J].化工进展,2013(5):1014-1019.
[46]章月,蒋平平,董玉明,等.新型纳米SO2-4/TiO2催化剂制备及催化合成醋酸丁酯[J].工业催化,2012(12):63-66.
[47]Parangi T F,Patel R M,Chudasama U V.Synthesis and characterization of mesoporous Si-MCM-41 materials and their application as solid acid catalysts in some esterification reactions[J].Bulletin of Materials Science,2014,37(3):609-615.
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