阻燃材料热分析技术研究进展
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摘要
阻燃材料的热分析是一种检测阻燃性能的常用手段,可分析阻燃材料在高温下的物理变化和化学变化,以及吸热和放热等变化。阻燃材料的热分析对阻燃剂的选择具有十分重要的作用。从最常用的热重分析(TG)、差示扫描量热(DSC)、差热分析(DTA)以及热分析仪器与其他仪器联用检测等方法进行阐述,并简要说明了热分析的有关热动力学。提出了未来阻燃剂和阻燃材料热分析仪器的发展方向。
Thermal analysis of flame-retardant materials is a common method to detect the flame-retardant properties, which can analyze the physical and chemical changes of flame-retardant materials at high temperature, as well as the changes of heat absorption and heat release. Thermal analysis of flame-retardant material plays an important role in the selection of flame retardant. In this paper, the most commonly used thermogravimetric analysis(TG), differential scanning calorimetry(DSC),differential thermal analysis(DTA)and the combined detection of thermal analysis instruments and other instruments are described, and the relevant thermal dynamics of thermal analysis are briefly described. The future development direction of flame retardant and flame-retardant material thermal analysis instrument is put forward.
Thermal analysis of flame-retardant materials is a common method to detect the flame-retardant properties, which can analyze the physical and chemical changes of flame-retardant materials at high temperature, as well as the changes of heat absorption and heat release. Thermal analysis of flame-retardant material plays an important role in the selection of flame retardant. In this paper, the most commonly used thermogravimetric analysis(TG), differential scanning calorimetry(DSC),differential thermal analysis(DTA)and the combined detection of thermal analysis instruments and other instruments are described, and the relevant thermal dynamics of thermal analysis are briefly described. The future development direction of flame retardant and flame-retardant material thermal analysis instrument is put forward.
引文
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[2]孙春波.探析高分子材料的阻燃方法[J].科技风,2018(13):16.
[3]汪大光.电气线路火灾原因分析及防范对策[J].中国科技信息,2013(12):206.
[4]李梦媛,陈海翔,张林鹤.金属热颗粒引燃可燃堆积材料的实验研究[J].火灾科学,2017,26(3):140-146.
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[7]于伯龄.Ⅰ级反应DTG,DTA与DSC曲线峰顶温度关系的研究[J].北京服装学院学报(自然科学版),2001,21(1):26-30.
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[11]潘玉琴,刘媛,孔霞.PBT/AlPi/MPP/CB复合材料结晶及流变性能研究[J].塑料科技,2017,45(2):25-29.
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[13]Lyu,Wenyan,Cui,Yihua,Zhang,Xujie,et al.Thermal stability,flame retardance,and mechanical properties of polyamide 66modified by a nitrogen-phosphorous reacting flame retardant[J].Journal of Applied Polymer Science,2016,133(24):1-9.
[14]Taghizadeh M T,Yeganeh N,Rezaei M.The investigation of thermal decomposition pathway and products of poly(vinyl alcohol)by TG-FTIR[J].Journal of Applied Polymer Science,2015,132(25):1-9.
[15]周国丽,关晋平.阻燃真丝织物的热重差热分析研究[J].丝绸,2013,50(3):19-22.
[16]Hotová,Gabriela,Slovák,Václav.Determination of the surface oxidation degree of the carbonaceous materials by quantitative tg-ms analysis[J].Analytical Chemistry,2017,89(3):1710-1715.
[17]Liu Y,Li Z,Wang J,et al.Thermal degradation and pyrolysis behavior of aluminum alginate investigated by TG-FTIR-MS and Py-GC-MS[J].Polymer Degradation&Stability,2015,118(2):59-68.
[18]Alongi J,Blasio A D,Milnes J,et al.Thermal degradation of DNA,an all-in-one natural intumescent flame retardant[J].Polymer Degradation&Stability,2015,113:110-118.
[19]Muravyev N V,Koga N,Meerov D B,et al.Kinetic analysis of overlapping multistep thermal decomposition comprising exothermic and endothermic processes:thermolysis of ammonium dinitramide[J].Physical Chemistry Chemical Physics Pccp,2017,19(4):3254.
[20]Vágv o咬lgyi V,Hales M,Frost R L,et al.Conventional and controlled rate thermal analysis of nesquehonite Mg(HCO3)(OH)·2(H2O)[J].Journal of Thermal Analysis&Calorimetry,2008,94(2):523-528.
[21]沈玉芳,陈栋华,胡小安.热分析动力学处理方法现状及进展[J].中南民族大学学报(自然科学版),2002,21(3):11-15.
[22]张瑜,袁树杰.家电塑料外壳的热解特性与动力学分析[J].消防理论研究,2018,37(7):874-877.
[23]关瑞芳,李宁.无机阻燃剂的应用现状及其发展前景[J].合成材料老化与应用,2013,42(4):55-57.
[24]蒋震宇,张春林.我国塑料制品包装行业“十一·五”期间发展情况及“十二·五”发展建议[J].塑料包装,2011,21(2):1-7.
[25]麻炳辉,李萌,王鹤童.阻燃剂的环保化发展趋势和聚合型溴系阻燃剂的应用[J].盐业与化工,2009,38(6):44-46.
[26]王利秋.聚合物/无机物纳米复合材料的阻燃性研究[J].纤维复合材料,2012,29(4):14-19.
[27]柳超,陈国荣,李忠裕,等.有机/无机杂化多元素协同阻燃剂的合成及其阻燃改性环氧树脂的研究[J].厦门大学学报(自然科学版),2018,57(2):177-185.
[2]孙春波.探析高分子材料的阻燃方法[J].科技风,2018(13):16.
[3]汪大光.电气线路火灾原因分析及防范对策[J].中国科技信息,2013(12):206.
[4]李梦媛,陈海翔,张林鹤.金属热颗粒引燃可燃堆积材料的实验研究[J].火灾科学,2017,26(3):140-146.
[5]颜龙,贾晓林,夏云春,等.含阻燃涂料的装饰材料热稳定性的热重法研究[J].青岛科技大学学报(自然科学版),2011,32(4):390-394.
[6]Elbaz A M,Gani A,Hourani N,et al.TG/DTG,FT-ICR mass spectrometry,and nmr spectroscopy study of heavy fuel oil[J].Energy&Fuels,2015,29(12):1739.
[7]于伯龄.Ⅰ级反应DTG,DTA与DSC曲线峰顶温度关系的研究[J].北京服装学院学报(自然科学版),2001,21(1):26-30.
[8]Han B,Qu H,Niemi H,et al.Mechanistic study of magnesium carbonate semibatch reactive crystallization with magnesium hydroxide and CO2[J].Industrial&Engineering Chemistry Research,2014,53(30):12077-12082.
[9]李志强,向兰,魏飞.阻燃级氢氧化镁的阻燃消烟机理及制备方法[J].盐业与化工,2004,33(2):1-3.
[10]王香娣,张春晖,陈世龙,等.含相变材料的动力电池组用有机硅灌封胶的制备[J].有机硅材料,2017(s1):48-50.
[11]潘玉琴,刘媛,孔霞.PBT/AlPi/MPP/CB复合材料结晶及流变性能研究[J].塑料科技,2017,45(2):25-29.
[12]Gómez I,Otazo E M,Hernández H,et al.Thermal degradation study of PVA derivative with pendant phenylthionecarbamate groups by DSC/TGA and GC/MS[J].Polymer Degradation&Stability,2015,112:132-136.
[13]Lyu,Wenyan,Cui,Yihua,Zhang,Xujie,et al.Thermal stability,flame retardance,and mechanical properties of polyamide 66modified by a nitrogen-phosphorous reacting flame retardant[J].Journal of Applied Polymer Science,2016,133(24):1-9.
[14]Taghizadeh M T,Yeganeh N,Rezaei M.The investigation of thermal decomposition pathway and products of poly(vinyl alcohol)by TG-FTIR[J].Journal of Applied Polymer Science,2015,132(25):1-9.
[15]周国丽,关晋平.阻燃真丝织物的热重差热分析研究[J].丝绸,2013,50(3):19-22.
[16]Hotová,Gabriela,Slovák,Václav.Determination of the surface oxidation degree of the carbonaceous materials by quantitative tg-ms analysis[J].Analytical Chemistry,2017,89(3):1710-1715.
[17]Liu Y,Li Z,Wang J,et al.Thermal degradation and pyrolysis behavior of aluminum alginate investigated by TG-FTIR-MS and Py-GC-MS[J].Polymer Degradation&Stability,2015,118(2):59-68.
[18]Alongi J,Blasio A D,Milnes J,et al.Thermal degradation of DNA,an all-in-one natural intumescent flame retardant[J].Polymer Degradation&Stability,2015,113:110-118.
[19]Muravyev N V,Koga N,Meerov D B,et al.Kinetic analysis of overlapping multistep thermal decomposition comprising exothermic and endothermic processes:thermolysis of ammonium dinitramide[J].Physical Chemistry Chemical Physics Pccp,2017,19(4):3254.
[20]Vágv o咬lgyi V,Hales M,Frost R L,et al.Conventional and controlled rate thermal analysis of nesquehonite Mg(HCO3)(OH)·2(H2O)[J].Journal of Thermal Analysis&Calorimetry,2008,94(2):523-528.
[21]沈玉芳,陈栋华,胡小安.热分析动力学处理方法现状及进展[J].中南民族大学学报(自然科学版),2002,21(3):11-15.
[22]张瑜,袁树杰.家电塑料外壳的热解特性与动力学分析[J].消防理论研究,2018,37(7):874-877.
[23]关瑞芳,李宁.无机阻燃剂的应用现状及其发展前景[J].合成材料老化与应用,2013,42(4):55-57.
[24]蒋震宇,张春林.我国塑料制品包装行业“十一·五”期间发展情况及“十二·五”发展建议[J].塑料包装,2011,21(2):1-7.
[25]麻炳辉,李萌,王鹤童.阻燃剂的环保化发展趋势和聚合型溴系阻燃剂的应用[J].盐业与化工,2009,38(6):44-46.
[26]王利秋.聚合物/无机物纳米复合材料的阻燃性研究[J].纤维复合材料,2012,29(4):14-19.
[27]柳超,陈国荣,李忠裕,等.有机/无机杂化多元素协同阻燃剂的合成及其阻燃改性环氧树脂的研究[J].厦门大学学报(自然科学版),2018,57(2):177-185.
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