印染废水的电化学氧化脱色研究进展
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摘要
随着电化学的发展和高效能反应装置的出现,电化学脱色被应用于废水的处理和净化中。文中从不同电极反应方式下的电化学脱色方法出发,总结了近年来纺织印染行业常用种类染料的电化学处理技术研究现状,叙述了不同染料电化学降解原理,探讨电池配置、电极材料、电解质等反应装置的组成,重点分析各因素对印染废水降解和脱色原理及脱色效率。结果表明,直接染料、活性染料和酸性染料的染色废水多采用间接氧化法处理,还原染料可采用直接氧化法和间接氧化法。为加速强氧化性物质生成可通过使用新型电极材料如DSA电极、BDD电极或加入催化剂等手段实现。电化学对印染废水氧化脱色需要根据染料种类选择合适的电池材料,并对试验参数进行合理调控,以实现高效化、大规模使用的脱色技术与方法。
With the development of electrochemistry and the emergence of high-efficient reaction devices, electrochemical decolorization has been applied to the treatment and purification of wastewater. Based on the electrochemical decolorization method under different electrode reaction modes, this paper summarized the research progresses of electrochemical treatment technology for dyes commonly used in textile printing and dyeing industry in the past years. The principles of electrochemical degradation for different dyes were described. The composition of battery configuration, electrode materials and electrolytes were also discussed. The degradation and decolorization principles and efficiency of printing and dyeing wastewater were analyzed. The results show that the wastewater from direct dyes, reactive dyes and acid dyes are mostly treated by indirect oxidation methods, and those from vat dyes can be either directly oxidized or indirectly oxidized. In order to accelerate the formation of strong oxidizing substances, novel electrodes material such as a DSA electrode, a BDD electrode or a catalyst can be applied.Electrochemical oxidation and decolorization of printing and dyeing wastewater requires selection of suitable battery materials according to the type of dyes, and through reasonable adjustment of experimental parameters, high-efficient, large-scale decolorization techniques and methods can be achieved.
With the development of electrochemistry and the emergence of high-efficient reaction devices, electrochemical decolorization has been applied to the treatment and purification of wastewater. Based on the electrochemical decolorization method under different electrode reaction modes, this paper summarized the research progresses of electrochemical treatment technology for dyes commonly used in textile printing and dyeing industry in the past years. The principles of electrochemical degradation for different dyes were described. The composition of battery configuration, electrode materials and electrolytes were also discussed. The degradation and decolorization principles and efficiency of printing and dyeing wastewater were analyzed. The results show that the wastewater from direct dyes, reactive dyes and acid dyes are mostly treated by indirect oxidation methods, and those from vat dyes can be either directly oxidized or indirectly oxidized. In order to accelerate the formation of strong oxidizing substances, novel electrodes material such as a DSA electrode, a BDD electrode or a catalyst can be applied.Electrochemical oxidation and decolorization of printing and dyeing wastewater requires selection of suitable battery materials according to the type of dyes, and through reasonable adjustment of experimental parameters, high-efficient, large-scale decolorization techniques and methods can be achieved.
引文
[1]AKERDI A G,BAHRAMI S H,ARAMI M,et al.Photocatalytic discoloration of acid red 14 aqueous solution using titania nanoparticles immobilized on graphene oxide fabricated plate[J].Chemosphere,2016(159):293-299.
[2]史会剑,朱大伟,胡欣欣,等.印染废水处理技术研究进展探析[J].环境科学与管理,2015,40(2):74-76+80.
[3]STREECK J,HANK C,NEUNER M,et al.Bio-electrochemical conversion of industrial wastewater-COD combined with downstream methanol synthesis-an economic and life cycle assessment[J].Green Chemistry,2018,20(12):2742-2762.
[4]IRFAN M,BUTT T,IMTIAZ N,et al.The removal of COD,TSS and colour of black liquor by coagulation-flocculation process at optimized pH,settling and dosing rate[J].Arabian Journal of Chemistry,2017(10):2307-2318.
[5]LEVIDOW L,ZACCARIA D,MAIAR,et al.Improving water-efficient irrigation:prospects and difficulties of innovative practices[J].Agricultural Water Management,2014(146):84-94.
[6]SARKKA H,BHATNAGAR A,SIL-LANPAA M,et al.Recent developments of electro-oxidation in water treatmenta review[J].Journal of Electroanalytical Chemistry,2015(754):46-56.
[7]CHAPLIN B P.Critical review of electrochemical advanced oxidation processes for water treatment applications[J].Environmental Science:Processes&Impacts,2014,16(6):1182-1203.
[8]ISARAINCHAVEZ E,BARO M D,ROSSINYOL E,et al.Comparative electrochemical oxidation of methyl orange azo dye using Ti/Ir-Pb,Ti/Ir-Sn,Ti/RuPb,Ti/Pt-Pd and Ti/RuO2anodes[J].Electrochimica Acta,2017(244):199-208.
[9]ONCEL M S,MUHCU A,DEMIR-BAS E,et al.A comparative study of chemical precipitation and electrocoagulation for treatment of coal acid drainage wastewater[J].Journal of Environmental Chemical Engineering,2013,1(4):989-995.
[10]王勇辰.探讨铁屑内电解法处理电镀含铬废水的研究[J].科学技术创新,2017(27):47-48.
[11]刘圣厚,张笑吟,刘楠.电催化氧化法对酸性藏蓝染料废水脱色的研究[J].科技创业家,2014(9):67.
[12]方良充.探究影响电化学方法降解酸性艳绿染料废水效果的因素[J].中国资源综合利用,2018,36(4):23-26.
[13]OTURAN M A,AARON J.Advanced oxidation processes in water/wastewater treatment:principles and applications.a review[J].Critical Revi-ews in Environmental Science and Tech-nology,2014,44(23):2577-2641.
[14]GARCIASEGURA S,OCON J D,CHONG M N,et al.Electrochemical oxidation remediation of real wastewater effluents-a review[J].Process Safety and Environmental Protection,2018(113):48-67.
[15]YANG J,HONG L,LIU Y,et al.Treatment of oilfield fracturing wastewater by a sequential combination of flocculation,fenton oxidation and SBR process[J].Environmental Technology,2014,35(22):2878-2884.
[16]PHI N Q,孙兆楠,胡筱敏.铁阳极电化学对直接大红4BE模拟废水脱色[J].环境工程学报,2012,6(11):3994-3998.
[17]李然,唐淑娟,刘桂英.印染废水电化学脱色研究[J].印染,2004(14):27-29.
[18]WANG Y,WANG A,LIU W,et al.Accelerated azo dye removal by biocathode formation in single-chamber biocatalyzed electrolysis systems[J].Bioresource Technology,2013(146):740-743.
[19]黄皖唐.电子介体修饰阳极MFC和生物阴极MFMEC对刚果红脱色的研究[D].广州:华南理工大学,2017.
[20]KARIYAJJANAVAR P,JOGTTAP-PA N,NAYAKA Y A,et al.Studies on degradation of reactive textile dyes solution by electrochemical method[J].Journal of Hazardous Materials,2011,190(3):952-961.
[21]HU C,HU B,WANG Y,et al.TiO2nanotube arrays based DSA electrode and application in treating dye wastewater[J].Russian Journal of Electr-ochemistry,2016,52(5):420-426.
[22]WANG Y,CHEN M,HUANG Q,et al.Experimental study of a solar-driven photo-electrochemical hybrid system for the decolorization of acid red 26[J].E-nergy Conversion and Management,2017(150):775-786.
[23]PARSA J B,MERATI Z,ABBASIM,et al.Modeling and optimizing of electrochemical oxidation of C.I.reactive orange 7 on the Ti/Sb-SnO2as anode via response surface methodology[J].Journal of Industrial and Engineering Chemistry,2013,19(4):1350-1355.
[24]邢剑飞,王珺,李侃,等.不同基底BDD电极对模拟染料废水的降解脱色试验[J].净水技术,2013,32(1):55-59,98.
[25]FERN魣NDEZ D,ROBLES I,RO-DR魰GUEZ-VALADEZ F J,et al.Novel arrangement for an electro-fenton reactor that does not require addition of iron,acid and a final neutralization stage,towards the development of a cost-effective technology for the tre-atment of wastewater[J].Chemosphere,2018,199(5):251-255.
[26]IRIKURA K,BOCCHI N,ROMEUC,et al.Electrodegradation of the Acid Green 28 dye using Ti/β-PbO2and TiPt/β-PbO2anodes[J].Journal of Environmental Management,2016,183(1):306-313.
[27]ISARAINCHAVEZ E,BARO M D,ROSSINYOL E,et al.Comparative electrochemical oxidation of methyl orange azo dye using Ti/Ir-Pb,Ti/Ir-Sn,Ti/RuPb,Ti/Pt-Pd and Ti/RuO2anodes[J].Electrochimica Acta,2017(244):199-208.
[28]刘艳,左燕君.电化学法处理染料废水的脱色实验研究[J].环境与发展,2018,30(1):84-85.
[29]班福忱,姜亚玲,韩雪,等.阴阳极同时作用电化学法降解水中甲基橙[J].沈阳建筑大学学报:自然科学版,2016,32(2):347-352.
[30]BECHTOLD T,TURCANU A,SCH-ROTT W,et al.Electrochemical decolourisation of dispersed indigo on borondoped diamond anodes[J].Diamond and Related Materials,2006,15(10):1513-1519.
[31]李笑岚.酸性靛蓝在ACF电极上的电化学脱色[D].大连:大连理工大学,2006.
[32]SANROMAN M A,PAZOS M,RI-CART M T,et al.Decolourisation of textile indigo dye by DC electric current[J].Engineering Geology,2005,77(3):253-261.
[33]占伟.脉冲电催化氧化处理染料废水研究[D].武汉:华中科技大学,2013.
[34]HENDAOUI K,AYARI F,RAYA-NA I B,et al.Real indigo dyeing effluent decontamination using continuous electrocoagulation cell:Study and optimization using Response Surface Methodology[J].Process Safety and Environmental Protection,2018,116(1):578-589.
[35]FAJARDO A S,MARTINS R C,SILVA D R,et al.Electrochemical abatement of amaranth dye solutions using individual or an assembling of flow cells with Ti/Pt and Ti/Pt-SnSb anodes[J].Separation and Purification Technology,2017,179(1):194-203.
[36]THIAM A,SIRES I,GARRIDO JA,et al.Decolorization and mineralization of Allura Red AC aqueous solutions by electrochemical advanced oxidation processes[J].Journal of Hazardous Materials,2015,290(1):34-42.
[2]史会剑,朱大伟,胡欣欣,等.印染废水处理技术研究进展探析[J].环境科学与管理,2015,40(2):74-76+80.
[3]STREECK J,HANK C,NEUNER M,et al.Bio-electrochemical conversion of industrial wastewater-COD combined with downstream methanol synthesis-an economic and life cycle assessment[J].Green Chemistry,2018,20(12):2742-2762.
[4]IRFAN M,BUTT T,IMTIAZ N,et al.The removal of COD,TSS and colour of black liquor by coagulation-flocculation process at optimized pH,settling and dosing rate[J].Arabian Journal of Chemistry,2017(10):2307-2318.
[5]LEVIDOW L,ZACCARIA D,MAIAR,et al.Improving water-efficient irrigation:prospects and difficulties of innovative practices[J].Agricultural Water Management,2014(146):84-94.
[6]SARKKA H,BHATNAGAR A,SIL-LANPAA M,et al.Recent developments of electro-oxidation in water treatmenta review[J].Journal of Electroanalytical Chemistry,2015(754):46-56.
[7]CHAPLIN B P.Critical review of electrochemical advanced oxidation processes for water treatment applications[J].Environmental Science:Processes&Impacts,2014,16(6):1182-1203.
[8]ISARAINCHAVEZ E,BARO M D,ROSSINYOL E,et al.Comparative electrochemical oxidation of methyl orange azo dye using Ti/Ir-Pb,Ti/Ir-Sn,Ti/RuPb,Ti/Pt-Pd and Ti/RuO2anodes[J].Electrochimica Acta,2017(244):199-208.
[9]ONCEL M S,MUHCU A,DEMIR-BAS E,et al.A comparative study of chemical precipitation and electrocoagulation for treatment of coal acid drainage wastewater[J].Journal of Environmental Chemical Engineering,2013,1(4):989-995.
[10]王勇辰.探讨铁屑内电解法处理电镀含铬废水的研究[J].科学技术创新,2017(27):47-48.
[11]刘圣厚,张笑吟,刘楠.电催化氧化法对酸性藏蓝染料废水脱色的研究[J].科技创业家,2014(9):67.
[12]方良充.探究影响电化学方法降解酸性艳绿染料废水效果的因素[J].中国资源综合利用,2018,36(4):23-26.
[13]OTURAN M A,AARON J.Advanced oxidation processes in water/wastewater treatment:principles and applications.a review[J].Critical Revi-ews in Environmental Science and Tech-nology,2014,44(23):2577-2641.
[14]GARCIASEGURA S,OCON J D,CHONG M N,et al.Electrochemical oxidation remediation of real wastewater effluents-a review[J].Process Safety and Environmental Protection,2018(113):48-67.
[15]YANG J,HONG L,LIU Y,et al.Treatment of oilfield fracturing wastewater by a sequential combination of flocculation,fenton oxidation and SBR process[J].Environmental Technology,2014,35(22):2878-2884.
[16]PHI N Q,孙兆楠,胡筱敏.铁阳极电化学对直接大红4BE模拟废水脱色[J].环境工程学报,2012,6(11):3994-3998.
[17]李然,唐淑娟,刘桂英.印染废水电化学脱色研究[J].印染,2004(14):27-29.
[18]WANG Y,WANG A,LIU W,et al.Accelerated azo dye removal by biocathode formation in single-chamber biocatalyzed electrolysis systems[J].Bioresource Technology,2013(146):740-743.
[19]黄皖唐.电子介体修饰阳极MFC和生物阴极MFMEC对刚果红脱色的研究[D].广州:华南理工大学,2017.
[20]KARIYAJJANAVAR P,JOGTTAP-PA N,NAYAKA Y A,et al.Studies on degradation of reactive textile dyes solution by electrochemical method[J].Journal of Hazardous Materials,2011,190(3):952-961.
[21]HU C,HU B,WANG Y,et al.TiO2nanotube arrays based DSA electrode and application in treating dye wastewater[J].Russian Journal of Electr-ochemistry,2016,52(5):420-426.
[22]WANG Y,CHEN M,HUANG Q,et al.Experimental study of a solar-driven photo-electrochemical hybrid system for the decolorization of acid red 26[J].E-nergy Conversion and Management,2017(150):775-786.
[23]PARSA J B,MERATI Z,ABBASIM,et al.Modeling and optimizing of electrochemical oxidation of C.I.reactive orange 7 on the Ti/Sb-SnO2as anode via response surface methodology[J].Journal of Industrial and Engineering Chemistry,2013,19(4):1350-1355.
[24]邢剑飞,王珺,李侃,等.不同基底BDD电极对模拟染料废水的降解脱色试验[J].净水技术,2013,32(1):55-59,98.
[25]FERN魣NDEZ D,ROBLES I,RO-DR魰GUEZ-VALADEZ F J,et al.Novel arrangement for an electro-fenton reactor that does not require addition of iron,acid and a final neutralization stage,towards the development of a cost-effective technology for the tre-atment of wastewater[J].Chemosphere,2018,199(5):251-255.
[26]IRIKURA K,BOCCHI N,ROMEUC,et al.Electrodegradation of the Acid Green 28 dye using Ti/β-PbO2and TiPt/β-PbO2anodes[J].Journal of Environmental Management,2016,183(1):306-313.
[27]ISARAINCHAVEZ E,BARO M D,ROSSINYOL E,et al.Comparative electrochemical oxidation of methyl orange azo dye using Ti/Ir-Pb,Ti/Ir-Sn,Ti/RuPb,Ti/Pt-Pd and Ti/RuO2anodes[J].Electrochimica Acta,2017(244):199-208.
[28]刘艳,左燕君.电化学法处理染料废水的脱色实验研究[J].环境与发展,2018,30(1):84-85.
[29]班福忱,姜亚玲,韩雪,等.阴阳极同时作用电化学法降解水中甲基橙[J].沈阳建筑大学学报:自然科学版,2016,32(2):347-352.
[30]BECHTOLD T,TURCANU A,SCH-ROTT W,et al.Electrochemical decolourisation of dispersed indigo on borondoped diamond anodes[J].Diamond and Related Materials,2006,15(10):1513-1519.
[31]李笑岚.酸性靛蓝在ACF电极上的电化学脱色[D].大连:大连理工大学,2006.
[32]SANROMAN M A,PAZOS M,RI-CART M T,et al.Decolourisation of textile indigo dye by DC electric current[J].Engineering Geology,2005,77(3):253-261.
[33]占伟.脉冲电催化氧化处理染料废水研究[D].武汉:华中科技大学,2013.
[34]HENDAOUI K,AYARI F,RAYA-NA I B,et al.Real indigo dyeing effluent decontamination using continuous electrocoagulation cell:Study and optimization using Response Surface Methodology[J].Process Safety and Environmental Protection,2018,116(1):578-589.
[35]FAJARDO A S,MARTINS R C,SILVA D R,et al.Electrochemical abatement of amaranth dye solutions using individual or an assembling of flow cells with Ti/Pt and Ti/Pt-SnSb anodes[J].Separation and Purification Technology,2017,179(1):194-203.
[36]THIAM A,SIRES I,GARRIDO JA,et al.Decolorization and mineralization of Allura Red AC aqueous solutions by electrochemical advanced oxidation processes[J].Journal of Hazardous Materials,2015,290(1):34-42.
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