钛系锂离子筛盐湖提锂的研究进展
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摘要
随着新能源行业的迅速发展,带动了锂需求量的显著增长,锂提取技术近年来受到广泛关注。中国是盐湖锂资源大国,盐湖锂储量约占全国锂总储量的78%。但是,中国的盐湖锂资源镁含量高,不易分离提取高纯度锂工业产品;因此,研究开发盐湖提锂技术,具有非常重要的应用价值。在众多的盐湖提锂技术当中,锂离子筛吸附提锂,因其选择性好,对镁的分离效果好,适用于镁锂比高的盐湖卤水体系,这对解决盐湖提锂问题有重要指导意义。选择近年来发展比较热的钛系锂离子筛,从提锂机理、制备方法和应用等方面的研究对钛系离子筛进行一个综述,最后对钛系离子筛的未来研究方向进行展望。
With the rapid development of new energy industry and a remarkable growth of lithium demand, lithium extraction technology receives extensive attentions in recent years. China is a country with abundant lithium resources, and salt-lake lithium reserves takes about 78% of the total lithium reservees. However, it is difficult to produce high-purity industrial lithium products from salt-lake in China, due to high magnesium content. Lithium extraction technology which can be applied in high magnesium content lithium resources shows its great prospect in China. Among various salt-lake lithium extraction technologies, lithium ion-sieve(LIS) technology with good selectivity of lithium and separation of magnesium, especiallysuits for extracting lithium from salt-lake brine with high Mg/Li ratio. In this review, we summarize recently research progress in mechanism, preparation methods and applications, and present future prospect from science and technology of titanium lithium-ion sieve.
With the rapid development of new energy industry and a remarkable growth of lithium demand, lithium extraction technology receives extensive attentions in recent years. China is a country with abundant lithium resources, and salt-lake lithium reserves takes about 78% of the total lithium reservees. However, it is difficult to produce high-purity industrial lithium products from salt-lake in China, due to high magnesium content. Lithium extraction technology which can be applied in high magnesium content lithium resources shows its great prospect in China. Among various salt-lake lithium extraction technologies, lithium ion-sieve(LIS) technology with good selectivity of lithium and separation of magnesium, especiallysuits for extracting lithium from salt-lake brine with high Mg/Li ratio. In this review, we summarize recently research progress in mechanism, preparation methods and applications, and present future prospect from science and technology of titanium lithium-ion sieve.
引文
[1]GROSJEAN C,MIRANDA P H,PERRIN M,et al.Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industry[J].Renewable and Sustainable Energy Reviews,2012,16(3):1735-1744.
[2]GARRETT D E.Handbook of Lithium and Natural Calcium Chloride[M].2004.
[3]EBENSPERGER A,MAXWELL P,MOSCOSO C.The lithium industry:Its recent evolution and future prospects[J].Resources Policy,2006,30(3):218-231.
[4]邓南平,马晓敏,阮艳莉,等.锂硫电池系统研究与展望[J].化学进展,2016,28(9):1435-1454.
[5]周大伟,李峒峒.独角兽还是灰犀牛[J].中国有色金属报,2019-01-01(004).
[6]VIKSTR M H,DAVIDSSON S,H K M.Lithium availability and future production outlooks[J].Applied Energy,2013,110(110):252-266.
[7]SPEIRS J,CONTESTABILE M,HOUARI Y,et al.The future of lithium availability for electric vehicle batteries[J].Renewable and Sustainable Energy Reviews,2014,35:183-193.
[8]刘元会,邓天龙.国内外从盐湖卤水中提锂工艺技术研究进展[J].世界科技研究与发展,2006,28(5):69-75.
[9]HAMZAOUI A H,M'NIF A,HAMMI H,et al.Contribution to the lithium recovery from brine[J].Desalination,2003,158(1):221-224.
[10]游清治.世界锂的资源、生产与应用前景[J].世界有色金属,2008,(5):42-45.
[11]刘东帆,孙淑英,于建国.盐湖卤水提锂技术研究与发展[J].化工学报,2018,69(1):141-155.
[12]AVERILL W A,OLSON D L.A review of extractive processes for lithium from ores and brines[J].Energy,1978,3(3):305-313.
[13]张金才,王敏,戴静.卤水提锂的萃取体系概述[J].盐湖研究,2005,13(1):42-48.
[14]温贤勇.杯[4]芳烃锂离子印迹聚合物的制备及其海水提锂性能的基础研究[D].浙江:浙江工业大学,2014.
[15]CHITRAKAR R,MAKITA Y,OOI K,et al.Lithium recovery from salt lake brine by H2TiO3[J].Dalton Transactions,2014,43(23):8933-8939.
[16]HOSOGI Y,KATO H,KUDO A.Visible light response of AgLi1/3M2/3O2(M=Ti and Sn)synthesized from layered Li2MO3using molten AgNO3[J].Journal Of Materials Chemistry,2008,18(6):647-653.
[17]DENISOVA T A,MAKSIMOVA L G,POLYAKOV E V,et al.Metatitanic acid:Synthesis and properties[J].Russian Journal Of Inorganic Chemistry,2006,51(5):691-699.
[18]HE G,ZHANG L,ZHOU D,et al.The optimal condition for H2TiO3-lithium adsorbent preparation and Li+adsorption confirmed by an orthogonal test design[J].Ionics,2015,21(8):2219-2226.
[19]ZHANG L,LIU Y,HUANG L,et al.A novel study on preparation of H2TiO3-lithium adsorbent with titanyl sulfate as titanium source by inorganic precipitation-peptization method[J].RSC Advances,2018,8(3):1385-1391.
[20]LEONT'EVA G,VOL'KHIN V,ONORIN S,et al.ChemInform Abstract:SYNTHESE UND EIGENSCHAFTEN DESIONEN‐SIEB‐KATIONENAUSTAUSCHERS ISM‐2[J].Chemischer Informationsdienst,1975,6(38)
[21]董殿权,张凤宝,张国亮,等.Li4Ti5O12的合成及对Li+的离子交换动力学[J].物理化学学报,2007,23(6):950-954.
[22]刘杰.锂离子电池钛酸锂系列负极材料的制备及其电化学性能研究[D].天津大学,2015.
[23]ONODERA Y,IWASAKI T,HAYASHI H,et al.ChemInform Abstract:A New Inorganic Material with High Selective Adsorbability for Lithium Ions[J].Cheminform,1989,20(17).
[24]蔡邦肖.日本的海水化学资源提取技术研究[J].海洋学研究,2000,18(4):52-52.
[25]闫树旺,黄志华.粒状二氧化钛交换剂的研制及从卤水中提取锂[J].离子交换与吸附,1994,(3):219-225.
[26]钟辉,郭灵虹.偏钛酸型锂离子交换剂固相合成反应动力学[J].应用化学,1998,(3):103-105.
[27]钟辉.偏钛酸型锂交换体制备、机理及其从液态锂矿提锂研究[D].成都理工大学,2004.
[28]钟辉.偏钛酸型锂离子交换剂的交换性质及从气田卤水中提锂[J].应用化学,2000,17(3):307-309.
[29]TANG D,ZHOU D,ZHOU J,et al.Preparation of H2TiO3-lithium adsorbent using low-grade titanium slag[J].Hydrometallurgy,2015,157:90-96.
[30]WANG S,LI P,CUI W,et al.Hydrothermal synthesis of lithium-enrichedβ-Li2TiO3with an ion-sieve application:excellent lithium adsorption[J].RSC Advances,2016,6(104):102608-102616.
[31]GU D,SUN W,HAN G,et al.Lithium ion sieve synthesized via an improved solid state method and adsorption performance for West Taijinar Salt Lake brine[J].Chemical Engineering Journal,2018,350:474-483.
[32]颜辉,钟辉,陈念.新型锂吸附剂的制备研究[J].无机盐工业,2014,46(2):38.
[33]ZHANG Q,LI S,SUN S,et al.Lithium selective adsorption on low-dimensional titania nanoribbons[J].Chemical Engineering Science,2010,65(1):165-168.
[34]LI N,GAN K,LU D,et al.Preparation of three-dimensional macroporous-mesoporous lithium ion sieve with high Li+adsorption capacity[J].Research on Chemical Intermediates,2017,44(2):1105-1117.
[35]MOAZENI M,HAJIPOUR H,ASKARI M,et al.Hydrothermal synthesis and characterization of titanium dioxide nanotubes as novel lithium adsorbents[J].Materials Research Bulletin,2015,61(61):70-75.
[36]HAO Y,ZHANG Q,ZHANG J,et al.Enhanced sintering characteristics and microwave dielectric properties of Li2TiO3due to nano-size and nonstoichiometry effect[J].Journal Of Materials Chemistry,2012,22(45):23885.
[37]ZHAOYIN W.Sol-gel synthesis and sintering of nano-size Li2TiO3powder[J].Materials Letters,2008,62(6-7):837-839.
[38]DEPTUA A,BRYKAA M,ADA W,et al.Preparation of spherical particles of Li2TiO3(with diameters below 100μm)by sol-gel process[J].Fusion Engineering&Design,2009,84(2):681-684.
[39]陈念.溶胶-凝胶法合成锂离子筛及其吸附性能研究[D].成都理工大学,2015.
[40]ZHANG L,ZHOU D,YAO Q,et al.Preparation of H2TiO3-lithium adsorbent by the sol-gel process and its adsorption performance[J].Applied Surface Science,2016,368:82-87.
[41]LI N,LU D,ZHANG J,et al.Yolk-shell structured composite for fast and selective lithium ion sieving[J].J Colloid Interface Sci,2018,520:33-40.
[42]郑建国.钛、锆复合氧化物的合成及对Li+的吸附交换性能研究[D].青岛科技大学,2016.
[43]XU X,ZHOU Y,FAN M,et al.Lithium adsorption performance of a three-dimensional porous H2TiO3-type lithium ion-sieve in strong alkaline Bayer liquor[J].RSC Advances,2017,7(31):18883-18891.
[44]董殿权,毕参参,李晶,等.三维有序大孔锂离子筛的制备及其交换性能研究[J].无机化学学报,2012,28(7):1423-1428.
[45]DONG D,WANG W,WANG M.Preparation of 3DONLi4Ti5O12and Behavior of Li+Ion Exchange[J].Applied Mechanics and Materials,2014,618:175-179.
[46]余亮良.尖晶石型锰系锂离子筛的制备及其性能研究[D].中南大学,2010.
[47]刘文涛,刘亦凡.锂离子交换体Li1.5Ti1.625O4的研究(Ⅲ)-Li1.5Ti1.625O4的造粒、改型及油田咸水中锂的回收[J].离子交换与吸附,2011,27(4):69-74.
[48]陈自正,沈卫华,陈立芳,等.纳米H2TiO3锂吸附剂的水热合成及其吸附性能[J].中国有色金属学报,2017,27(3):547-554.
[49]LIMJUCO L A,NISOLA G M,LAWAGON C P,et al.H2TiO3composite adsorbent foam for efficient and continuous recovery of Li+from liquid resources[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2016,504:267-279.
[50]张理元,刘义武,周大利,等.泡沫陶瓷基偏钛酸型锂离子吸附剂的动态吸附和洗脱性能研究(英文)[J].四川大学学报(自然科学版),2017,54(6)
[51]ZHANG L,ZHOU D,HE G,et al.Synthesis of H2TiO3-lithium adsorbent loaded on ceramic foams[J].Materials Letters,2015,145:351-354.
[52]李超.锂离子筛成型过程研究[D].华东理工大学,2014.
[53]UMENO A,MIYAI Y,TAKAGI N,et al.Preparation and Adsorptive Properties of Membrane-Type Adsorbents for Lithium Recovery from Seawater[J].Industrial&Engineering Chemistry Research,2002,41(17):4281-4287.
[54]CHUNG,KANGSUP,LEE,et al.Inorganic adsorbent containing polymeric membrane reservoir for the recovery of lithium from seawater[J].ournal of Membrane Science,2008,325(2):503-508.
[55]王盼.锂离子筛膜的制备及其吸附性能研究[D].中国海洋大学[D].2013.
[2]GARRETT D E.Handbook of Lithium and Natural Calcium Chloride[M].2004.
[3]EBENSPERGER A,MAXWELL P,MOSCOSO C.The lithium industry:Its recent evolution and future prospects[J].Resources Policy,2006,30(3):218-231.
[4]邓南平,马晓敏,阮艳莉,等.锂硫电池系统研究与展望[J].化学进展,2016,28(9):1435-1454.
[5]周大伟,李峒峒.独角兽还是灰犀牛[J].中国有色金属报,2019-01-01(004).
[6]VIKSTR M H,DAVIDSSON S,H K M.Lithium availability and future production outlooks[J].Applied Energy,2013,110(110):252-266.
[7]SPEIRS J,CONTESTABILE M,HOUARI Y,et al.The future of lithium availability for electric vehicle batteries[J].Renewable and Sustainable Energy Reviews,2014,35:183-193.
[8]刘元会,邓天龙.国内外从盐湖卤水中提锂工艺技术研究进展[J].世界科技研究与发展,2006,28(5):69-75.
[9]HAMZAOUI A H,M'NIF A,HAMMI H,et al.Contribution to the lithium recovery from brine[J].Desalination,2003,158(1):221-224.
[10]游清治.世界锂的资源、生产与应用前景[J].世界有色金属,2008,(5):42-45.
[11]刘东帆,孙淑英,于建国.盐湖卤水提锂技术研究与发展[J].化工学报,2018,69(1):141-155.
[12]AVERILL W A,OLSON D L.A review of extractive processes for lithium from ores and brines[J].Energy,1978,3(3):305-313.
[13]张金才,王敏,戴静.卤水提锂的萃取体系概述[J].盐湖研究,2005,13(1):42-48.
[14]温贤勇.杯[4]芳烃锂离子印迹聚合物的制备及其海水提锂性能的基础研究[D].浙江:浙江工业大学,2014.
[15]CHITRAKAR R,MAKITA Y,OOI K,et al.Lithium recovery from salt lake brine by H2TiO3[J].Dalton Transactions,2014,43(23):8933-8939.
[16]HOSOGI Y,KATO H,KUDO A.Visible light response of AgLi1/3M2/3O2(M=Ti and Sn)synthesized from layered Li2MO3using molten AgNO3[J].Journal Of Materials Chemistry,2008,18(6):647-653.
[17]DENISOVA T A,MAKSIMOVA L G,POLYAKOV E V,et al.Metatitanic acid:Synthesis and properties[J].Russian Journal Of Inorganic Chemistry,2006,51(5):691-699.
[18]HE G,ZHANG L,ZHOU D,et al.The optimal condition for H2TiO3-lithium adsorbent preparation and Li+adsorption confirmed by an orthogonal test design[J].Ionics,2015,21(8):2219-2226.
[19]ZHANG L,LIU Y,HUANG L,et al.A novel study on preparation of H2TiO3-lithium adsorbent with titanyl sulfate as titanium source by inorganic precipitation-peptization method[J].RSC Advances,2018,8(3):1385-1391.
[20]LEONT'EVA G,VOL'KHIN V,ONORIN S,et al.ChemInform Abstract:SYNTHESE UND EIGENSCHAFTEN DESIONEN‐SIEB‐KATIONENAUSTAUSCHERS ISM‐2[J].Chemischer Informationsdienst,1975,6(38)
[21]董殿权,张凤宝,张国亮,等.Li4Ti5O12的合成及对Li+的离子交换动力学[J].物理化学学报,2007,23(6):950-954.
[22]刘杰.锂离子电池钛酸锂系列负极材料的制备及其电化学性能研究[D].天津大学,2015.
[23]ONODERA Y,IWASAKI T,HAYASHI H,et al.ChemInform Abstract:A New Inorganic Material with High Selective Adsorbability for Lithium Ions[J].Cheminform,1989,20(17).
[24]蔡邦肖.日本的海水化学资源提取技术研究[J].海洋学研究,2000,18(4):52-52.
[25]闫树旺,黄志华.粒状二氧化钛交换剂的研制及从卤水中提取锂[J].离子交换与吸附,1994,(3):219-225.
[26]钟辉,郭灵虹.偏钛酸型锂离子交换剂固相合成反应动力学[J].应用化学,1998,(3):103-105.
[27]钟辉.偏钛酸型锂交换体制备、机理及其从液态锂矿提锂研究[D].成都理工大学,2004.
[28]钟辉.偏钛酸型锂离子交换剂的交换性质及从气田卤水中提锂[J].应用化学,2000,17(3):307-309.
[29]TANG D,ZHOU D,ZHOU J,et al.Preparation of H2TiO3-lithium adsorbent using low-grade titanium slag[J].Hydrometallurgy,2015,157:90-96.
[30]WANG S,LI P,CUI W,et al.Hydrothermal synthesis of lithium-enrichedβ-Li2TiO3with an ion-sieve application:excellent lithium adsorption[J].RSC Advances,2016,6(104):102608-102616.
[31]GU D,SUN W,HAN G,et al.Lithium ion sieve synthesized via an improved solid state method and adsorption performance for West Taijinar Salt Lake brine[J].Chemical Engineering Journal,2018,350:474-483.
[32]颜辉,钟辉,陈念.新型锂吸附剂的制备研究[J].无机盐工业,2014,46(2):38.
[33]ZHANG Q,LI S,SUN S,et al.Lithium selective adsorption on low-dimensional titania nanoribbons[J].Chemical Engineering Science,2010,65(1):165-168.
[34]LI N,GAN K,LU D,et al.Preparation of three-dimensional macroporous-mesoporous lithium ion sieve with high Li+adsorption capacity[J].Research on Chemical Intermediates,2017,44(2):1105-1117.
[35]MOAZENI M,HAJIPOUR H,ASKARI M,et al.Hydrothermal synthesis and characterization of titanium dioxide nanotubes as novel lithium adsorbents[J].Materials Research Bulletin,2015,61(61):70-75.
[36]HAO Y,ZHANG Q,ZHANG J,et al.Enhanced sintering characteristics and microwave dielectric properties of Li2TiO3due to nano-size and nonstoichiometry effect[J].Journal Of Materials Chemistry,2012,22(45):23885.
[37]ZHAOYIN W.Sol-gel synthesis and sintering of nano-size Li2TiO3powder[J].Materials Letters,2008,62(6-7):837-839.
[38]DEPTUA A,BRYKAA M,ADA W,et al.Preparation of spherical particles of Li2TiO3(with diameters below 100μm)by sol-gel process[J].Fusion Engineering&Design,2009,84(2):681-684.
[39]陈念.溶胶-凝胶法合成锂离子筛及其吸附性能研究[D].成都理工大学,2015.
[40]ZHANG L,ZHOU D,YAO Q,et al.Preparation of H2TiO3-lithium adsorbent by the sol-gel process and its adsorption performance[J].Applied Surface Science,2016,368:82-87.
[41]LI N,LU D,ZHANG J,et al.Yolk-shell structured composite for fast and selective lithium ion sieving[J].J Colloid Interface Sci,2018,520:33-40.
[42]郑建国.钛、锆复合氧化物的合成及对Li+的吸附交换性能研究[D].青岛科技大学,2016.
[43]XU X,ZHOU Y,FAN M,et al.Lithium adsorption performance of a three-dimensional porous H2TiO3-type lithium ion-sieve in strong alkaline Bayer liquor[J].RSC Advances,2017,7(31):18883-18891.
[44]董殿权,毕参参,李晶,等.三维有序大孔锂离子筛的制备及其交换性能研究[J].无机化学学报,2012,28(7):1423-1428.
[45]DONG D,WANG W,WANG M.Preparation of 3DONLi4Ti5O12and Behavior of Li+Ion Exchange[J].Applied Mechanics and Materials,2014,618:175-179.
[46]余亮良.尖晶石型锰系锂离子筛的制备及其性能研究[D].中南大学,2010.
[47]刘文涛,刘亦凡.锂离子交换体Li1.5Ti1.625O4的研究(Ⅲ)-Li1.5Ti1.625O4的造粒、改型及油田咸水中锂的回收[J].离子交换与吸附,2011,27(4):69-74.
[48]陈自正,沈卫华,陈立芳,等.纳米H2TiO3锂吸附剂的水热合成及其吸附性能[J].中国有色金属学报,2017,27(3):547-554.
[49]LIMJUCO L A,NISOLA G M,LAWAGON C P,et al.H2TiO3composite adsorbent foam for efficient and continuous recovery of Li+from liquid resources[J].Colloids&Surfaces A Physicochemical&Engineering Aspects,2016,504:267-279.
[50]张理元,刘义武,周大利,等.泡沫陶瓷基偏钛酸型锂离子吸附剂的动态吸附和洗脱性能研究(英文)[J].四川大学学报(自然科学版),2017,54(6)
[51]ZHANG L,ZHOU D,HE G,et al.Synthesis of H2TiO3-lithium adsorbent loaded on ceramic foams[J].Materials Letters,2015,145:351-354.
[52]李超.锂离子筛成型过程研究[D].华东理工大学,2014.
[53]UMENO A,MIYAI Y,TAKAGI N,et al.Preparation and Adsorptive Properties of Membrane-Type Adsorbents for Lithium Recovery from Seawater[J].Industrial&Engineering Chemistry Research,2002,41(17):4281-4287.
[54]CHUNG,KANGSUP,LEE,et al.Inorganic adsorbent containing polymeric membrane reservoir for the recovery of lithium from seawater[J].ournal of Membrane Science,2008,325(2):503-508.
[55]王盼.锂离子筛膜的制备及其吸附性能研究[D].中国海洋大学[D].2013.
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