钴冶炼系统中P204反萃液有价金属的控电位硫化分离技术
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摘要
介绍钴冶炼工艺及P204反萃液产出,总结P204反萃液处理方法的研究进展,提出有价金属的控电位选择性分离的技术。通过热力学计算并绘制Me-S-H_2O系φ-pH图,从理论上证明有价金属的控电位选择性硫化分离技术可行;分别研究了控电位硫化除铜、控电位硫化除钴与黄药除钴、控电位硫化沉锌和中和沉锰4个过程的实施效果。结果表明:该方法可以实现有价金属的分步分离且金属回收率均可达到99%以上,沉淀物硫化铜、黄原酸钴、硫化锌和碳酸锰都可以作为冶炼原料再利用,处理后液为无害溶液可直接排放。实现了P204反萃液中有价金属分步沉淀和无害化处理的双重目的。
The production of P204 stripping solution was introduced and the common treatments of P204 stripping solution were summarized.The value metals selective separation under potential controlling from P204 stripping solution was proposed.And then,theφ-pH diagram of Me-S-H_2O system was plotted based on thermodynamic calculation.Finally,both the selective separation under controlling potential of Cu,Co and Zn and Mn carbonate precipitation were studied,respectively.The precipitation rates of Cu~(2+),Co~(2+),Zn~(2+),and Mn~(2+)were as high as 99%.The precipitates,CuS,Co(C_2H_5OCSS)_2,ZnS and MnSO_4,can be reused as raw materials in metallurgy.The effluent is eco-friendly to discharge.Therefore,the goal of valuable metal selective precipitation and the less-hazardous handling of P204 stripping solution were achieved.
The production of P204 stripping solution was introduced and the common treatments of P204 stripping solution were summarized.The value metals selective separation under potential controlling from P204 stripping solution was proposed.And then,theφ-pH diagram of Me-S-H_2O system was plotted based on thermodynamic calculation.Finally,both the selective separation under controlling potential of Cu,Co and Zn and Mn carbonate precipitation were studied,respectively.The precipitation rates of Cu~(2+),Co~(2+),Zn~(2+),and Mn~(2+)were as high as 99%.The precipitates,CuS,Co(C_2H_5OCSS)_2,ZnS and MnSO_4,can be reused as raw materials in metallurgy.The effluent is eco-friendly to discharge.Therefore,the goal of valuable metal selective precipitation and the less-hazardous handling of P204 stripping solution were achieved.
引文
[1]王伟东,仇卫华,丁倩倩.锂离子电池三元材料:工艺技术及生产应用[M].北京:化学工业出版社,2015.WANG Wei-dong,QIU Wei-hua,DING Qian-qian.Nickel cobalt manganese based cathode materials for Li-ion batteries technology production and application[M].Beijing:Chemical Industry press,2015.
[2]张福良,崔笛,胡永达,彭杰,雷晓力,马骋,杜轶伦.钴矿资源形势分析及管理对策建议[J].中国矿业,2014,23(7):6-10.ZHANG Fu-liang,CUI Di,HU Yong-da,PENG Jie,LEIXiao-li,MA Cheng,DU Yi-lun.Analysis on the development situation of cobalt ore resources and recommended management strategies[J].China Mining Magazine,2014,23(7):6-10.
[3]翟秀静.重金属冶金学[M].北京:冶金工业出版社,2011.ZHAI Xiu-jing.Heavy metal metallurgy[M].Beijing:Metallurgical Industry Press,2011.
[4]李辉.关于钴湿法冶金工业废水处理研究[J].世界有色金属,2016(15):170-173.LI Hui.Study on the treatment of wastewater from process of cobalt metallurgy[J].World Nonferrous Metal,2016(15):170-173.
[5]史本善.石灰-铁盐法在沈阳冶炼厂污水二次净化中的应用[J].有色金属,1998,50(4):137-140.SHI Ben-shan.Application of lime-ferric salt process to purification of waste water at Shenyang smelter[J].Nonferrous Metals,1998,50(4):137-140
[6]文荣贵,杜虎.含钴废水处理方法及其研究进展[J].工业用水与废水,2014,45(5):5-9.WEN Rong-gui,DU Hu.Research progress on cobalt-containing wastewater treatment[J].Industry Water&Wastewater,2014,45(5):5-9.
[7]王燕.物化法处理镍钴电池废水的试验研究[D].长沙:湖南大学,2010.WANG Yan.Experimental study on the treatment of nickel-cobalt battery wastewater by physical and chemical methods[D].Changsha:Hunan University,2010.
[8]田庆华,辛云涛,姚标,郭学益.锌湿法冶金过程中中臭氧氧化沉淀除去微量钴[J].中国有色金属学报,2013,23(4):1140-1144.TIAN Qing-hua,XIN Yun-tao,YAO Biao,GUO Xue-yi.Efficient purification of trace cobalt in zinc hydrometallurgical process by ozone oxidation[J].The Chinese Journal of Nonferrous Metals,2013,23(4):1140-1144.
[9]何焕华,蔡乔方.中国镍钴冶金[M].北京:冶金工业出版社,2009.HE Huan-hua,CAI Qiao-fang.Chinese metallurgy of nickel and cobalt[M].Beijing:Metallurgy Industry Press,2009.
[10]王松,谢洪勇.硫化法处理酸性含重金属废水技术现状及发展[J].当代化工,2018,47(6):1272-1278.WANG Song,XIE Hong-yong.Present situation and development of acid metal-containing wastewater treatment by sulfuration method[J].Contemporary Chemical Industry,2018,47(6):1272-1278.
[11]许永,刘峰彪,杨晓松.硫化法处理酸性含重金属离子废水的实验研究[J].矿冶,2014,23(1):68-71.XU Yong,LIU Feng-biao,YANG Xiao-song.Experimental study on treatment of acidic waste water containing heavy metal ions by sulphidization method[J].Mining&Metallurgy,2014,23(1):68-71.
[12]刘强.酸性重金属废水的联合处理实验研究[J].黄金,2018,39(2):64-66.LIU Qiang.Experimental research on combined treatment of acidic heavy metal polluted wastewater[J].Gold,2018,39(2):64-66.
[13]许玉东,孙燕茹.热镀锌厂酸洗废水和锌灰中回收硫化锌[J].环境工程学报,2014,8(3):948-954.XU Yu-dong,SUN Yan-ru.Recovery of zinc sulfide from acidic wastewater and zinc ash of hot galvanizing plants[J].Chinese Journal of Environmental Engineering.2014,8(3):948-954.
[14]杜长福,伍一根.我国钴湿法冶金行业废水处理概述[J].世界有色金属,2015,12:76-77.DU Chang-fu,WU Yi-gen.Summary of China’s cobalt hydrometallurgy industry wastewater treatment[J].World Nonferrous Metals,2015,12:76-77.
[15]VEEKEN A H M,AKOTO L,POL L W H,WEIJMA J.Control of the sulfide(S2-)concentration for optimal zinc removal by sulfide precipitation in a continuously stirred tank reactor[J].Water Research,2003,37:3709-3717.
[16]VEEKEN A H M,RULKENS W H.Innovative developments in the selective removal and reuse of heavy metals from wastewaters[J].Water Science and Technology,2003,47(10):9-16.
[17]SAMPAIO R M M,TIMMERS R A,XU Y,KEESMAN K J,LENS P N.Selective precipitation of Cu from Zn in a p Scontrolled continuously stirred tank reactor[J].Journal of Hazardous Materials,2009,165:256-265.
[18]LEWIS A E.Review of metal sulphide precipitation[J].Hydrometallurgy,2010,104:222-234.
[19]郭朝晖,姜智超,刘亚男,王硕.混凝沉淀法处理钨多金属矿选矿废水[J].中国有色金属学报,2014,24(9):2393-2399.GUO Zhao-hui,JIANG Zhi-chao,LIU Ya-nan,WANG Shuo.Coagulation and sedimentation treating wastewater from Wcontaining multi-metal ore dressing process[J].The Chinese Journal of Nonferrous Metals,2014,24(9):2393-2399.
[20]韩新罡,席晓丽,马立文,聂祚仁,周志理.配合-沉淀体系中铁与钴、镍的分离性能[J].中国有色金属学报,2013,23(11):3218-3224.HAN Xin-gang,XI Xiao-li,MA Li-wen,NIE Zuo-ren,ZHOU Zhi-li.Separation properties of ion to cobalt and nickel in complexation-precipitation system[J].The Chinese Journal of Nonferrous Metals,2013,23(11):3218-3224.
[21]彭容秋.锌冶金[M].长沙:中南大学出版社,2005.PENG Rong-qiu.Zinc metallurgy[M].Changsha:Center South University Press,2005.
[22]李正根.提高钴冶炼回收率的生产实践[J].有色冶炼,1993(3):11-13.LI Zheng-gen.Practice of improve recover ratio of cobalt metallurgy[J].Nonferrous Metallurgy,1993(3):11-13.
[23]林江顺,蒋开喜.钴锰渣除杂提纯钴工艺研究[J].有色金属,2002,54(3):36-38.LIN Jiang-shun,JIANG Kai-xi.Cobalt recovery from cobalt manganese material[J].Nonferrous Metals,2002,54(3):36-38.
[24]刘智颖,汪晓军,赵爽.还原性铁粉置换法处理化学镀低浓度含镍漂洗水[J].电镀与涂饰,2018,35(8):427-430.LIU Zhi-ying,WANG Xiao-jun,ZHAO Shuang.Treatment of low-nickel-content rinse water from electroless plating process by displacement reaction with reductive iron powder[J].Electroplating&Finishing,2018,35(8):427-430.
[25]马方通,高利坤,董方,陈龙.硫脲浸金及置换法从硫脲溶液中回收金研究现状[J].湿法冶金,2017,36(4):257-270.MA Fang-tong,GAO Li-kun,DONG Fang,CHEN Long.Situations of leaching and replacement of gold in acidic thioutra solution[J].Hydrometallurgy of China,2017,36(4):257-270.
[26]黄捷,王强胜,李建芬.铁置换法处理含铜废水的实验研究[J].化学工程师,2015,240(9):36-38.HUANG Jie,WANG Qiang-sheng,LI Jian-fen.Experiment research on treatment of copper-containing wastewater by iron replacement method[J].Chemical Engineer,2015,240(9):36-38.
[27]马兰,段莉萍,郝丽萍,覃广河,王力.置换法处理含铜废液的研究[J].兵器材料科学与工程,2014,37(6):43-45.MA Lan,DUAN Li-ping,HAO Li-ping,QIN Guang-he,WANG Li.Treatment of waste containing copper with replacement method[J].Ordnance Material Science and Engineering,2014,37(6):43-45.
[28]王杰,张覃,李先海,沈智慧,叶军建.锌粉置换硫代硫酸盐浸金液中金实验研究[J].矿业工程,2016,36(3):91-93.WANG Jie,ZHANG Qin,LI Xian-hai,SHEN Zhi-hui,YEJun-jian.Experimental study on recovering gold from thiosulfate leaching liquid with zinc powder[J].Mining and Metallurgical Engineering,2016,36(3):91-93.
[29]余洪,胡显智,字富庭,聂彦合,迟衡,王强.置换法回收硫代硫酸盐浸金液中金的研究进展[J].稀有金属,2015,39(5):473-480.YU Hong,HU Xian-zhi,ZI Fu-ting,NIE Yan-he,CHI Heng,WANG Qiang.Progress in gold cementation from ammonium thiosulfate solution[J].Chinese Journal of Rare Metals,2015,39(5):473-480.
[30]杨志强,王玉华,李娟.一种从钴铜锌锰生产废液中选择性回收钴铜的方法.中国:201410810213.0[P].2014-12-24.YANG Zhi-qiang,WANG Yu-hua,LI Juan.A method for selectively recover copper and cobalt from Co-Cu-Zn-Mn production wastewaters.China:201410810213.0[P].2014-12-24.
[31]邹涛,刘明远.离子交换法处理工业废水中重金属的现状与发展[J].山东化工,2017,46(10):190-192.ZOU Tao,LIU Ming-yuan.Present status and development of ion exchange method for treatment of heavy metals in industrial waste water[J].Shandong Chemical Industry,2017,46(10):190-192.
[32]王彧.重金属废水治理方法的研究进展[J].山西建筑,2016,42(24):189-190.WANG Yu.Recent progress of the treatment of heavy metal wastewater[J].Shanxi Architecture,2016,42(24):189-190.
[33]刘航.树脂吸附处理冶炼含钴废水的实践[J].有色冶金节能,2010,8(4):50-53.LIU Hang.Practice of adsorption treatment of cobalt-containing wastewater by resin[J].Energy Saving of Nonferrous Metallurgy,2010,8(4):50-53.
[34]赵倩.硫酸盐稀溶液中铜钴综合回收应用与理论探讨[D].长春:吉林大学,2013.ZHAO Qian.Application and theory of comprehensive recovery of copper and cobalt in dilute sulfate solution[J].Changchun:Jilin University,2013.
[35]陈国栋.一种回收氯化锰残液中钴、铜、锌、锰的方法.中国:ZL201110159956.2[P].2015-08-12.CHEN Guo-dong.A method of recover cobalt,copper,zinc,and manganese from Mn Cl2 residue solution.China:ZL201110159956.2[P].2015-08-12.
[36]邱胤轩.Versatic/Mextral1984H萃取分离废水中的铜镍钴锌镉的研究[D].北京:北京有色金属研究总院,2014.QIU Yin-xuan.The synergistic extraction and separation of copper,nickel,cobalt,zinc,and cadmium from wastewater by Versatic10/Mextral984H system[D].Beijing:General Research Institute for Nonferrous Metals,2014.
[37]DAMBIES L,JAWORSKA A,ZAKRZEWSKA-TRZNADEL G,SARTOWSKA B.Comparison of acidic polymers for the removal of cobalt from water solutions by polymer assisted ultrafiltration[J].Journal of Hazardous Materials,2010,178:988-993.
[38]王欣鹏,蒯琳萍,车俊霞.反渗透技术处理模拟核电站放射性废水中的钴[J].核化学与放射化学,2013,33(2):114-118.WANG Xin-peng,KUAI Lin-ping,CHE Jun-xia.Treatment of simulated radioactive waste water by reverse osmosis[J].Journal of Nuclear and Radiochemistry,2013,33(2):114-118.
[39]陈月芳,曹丽霞,林海,董颖博,程皝,霍汉鑫.中药渣和麦麸对模拟矿山酸性废水中Cu2+的吸附[J].中国有色金属学报,2013,23(6):1775-1782.CHEN Yue-fang,CAO Li-xia,LIN Hai,DONG Ying-bo,CHENG Huang,HUO Han-xin.Adsorption of Cu2+from simulated acid mine drainage by herb-medicine residue and wheat bran[J].The Chinese Journal of Nonferrous Metals,2013,23(6):1775-1782.
[40]SMICIKLAS I,DIMOVIA I,MITRIA M.Removal of Co2+from aqueous solutions by hydroxyapatite[J].Water Research,2006,40(12):2267-2274.
[41]李云东,袁志华,李慧琴,田辉.含钴废水的粉煤灰处理效果初报[J].中国农学通报,2007,23(8):459-461.LI Yun-dong,YUAN Zhi-hua,LI Hui-qin,TIAN Hui.Removing Co2+from aqueous solution by using fly ash as the adsorbent[J].Chinese Agricultural Science Bulletin,2007,23(8):459-461.
[42]YANG Tian-zu,FU Xin-xin,LIU Wei-feng,CHEN Lin,ZHANG Du-chao.Hydrometallurgical treatment of copper smelting dust by oxidation leaching and fractional precipitation technology[J].JOM,2017,69:1982-1986.
[43]LIU Wei-feng,RAO Shuai,WANG Wen-yao,YANG Tian-zu,YANG Lin,CHEN Lin,ZHANG Du-chao.Selective leaching of cobalt and iron from cobalt white alloy in sulfuric acid solution with catalyst[J].Int J Miner Process,2015,141:8-14.
[44]LIN Qing-quan,GU Guo-hua,WANG Hui,WANGChong-qing,LIU You-cai,ZHU Ren-feng,FU Jian-gang.Separation of manganese from calcium and magnesium in sulfate solution via carbonate precipitation[J].Transaction of Nonferrous Metals Society of China,2016,26(4):1118-1125.
[2]张福良,崔笛,胡永达,彭杰,雷晓力,马骋,杜轶伦.钴矿资源形势分析及管理对策建议[J].中国矿业,2014,23(7):6-10.ZHANG Fu-liang,CUI Di,HU Yong-da,PENG Jie,LEIXiao-li,MA Cheng,DU Yi-lun.Analysis on the development situation of cobalt ore resources and recommended management strategies[J].China Mining Magazine,2014,23(7):6-10.
[3]翟秀静.重金属冶金学[M].北京:冶金工业出版社,2011.ZHAI Xiu-jing.Heavy metal metallurgy[M].Beijing:Metallurgical Industry Press,2011.
[4]李辉.关于钴湿法冶金工业废水处理研究[J].世界有色金属,2016(15):170-173.LI Hui.Study on the treatment of wastewater from process of cobalt metallurgy[J].World Nonferrous Metal,2016(15):170-173.
[5]史本善.石灰-铁盐法在沈阳冶炼厂污水二次净化中的应用[J].有色金属,1998,50(4):137-140.SHI Ben-shan.Application of lime-ferric salt process to purification of waste water at Shenyang smelter[J].Nonferrous Metals,1998,50(4):137-140
[6]文荣贵,杜虎.含钴废水处理方法及其研究进展[J].工业用水与废水,2014,45(5):5-9.WEN Rong-gui,DU Hu.Research progress on cobalt-containing wastewater treatment[J].Industry Water&Wastewater,2014,45(5):5-9.
[7]王燕.物化法处理镍钴电池废水的试验研究[D].长沙:湖南大学,2010.WANG Yan.Experimental study on the treatment of nickel-cobalt battery wastewater by physical and chemical methods[D].Changsha:Hunan University,2010.
[8]田庆华,辛云涛,姚标,郭学益.锌湿法冶金过程中中臭氧氧化沉淀除去微量钴[J].中国有色金属学报,2013,23(4):1140-1144.TIAN Qing-hua,XIN Yun-tao,YAO Biao,GUO Xue-yi.Efficient purification of trace cobalt in zinc hydrometallurgical process by ozone oxidation[J].The Chinese Journal of Nonferrous Metals,2013,23(4):1140-1144.
[9]何焕华,蔡乔方.中国镍钴冶金[M].北京:冶金工业出版社,2009.HE Huan-hua,CAI Qiao-fang.Chinese metallurgy of nickel and cobalt[M].Beijing:Metallurgy Industry Press,2009.
[10]王松,谢洪勇.硫化法处理酸性含重金属废水技术现状及发展[J].当代化工,2018,47(6):1272-1278.WANG Song,XIE Hong-yong.Present situation and development of acid metal-containing wastewater treatment by sulfuration method[J].Contemporary Chemical Industry,2018,47(6):1272-1278.
[11]许永,刘峰彪,杨晓松.硫化法处理酸性含重金属离子废水的实验研究[J].矿冶,2014,23(1):68-71.XU Yong,LIU Feng-biao,YANG Xiao-song.Experimental study on treatment of acidic waste water containing heavy metal ions by sulphidization method[J].Mining&Metallurgy,2014,23(1):68-71.
[12]刘强.酸性重金属废水的联合处理实验研究[J].黄金,2018,39(2):64-66.LIU Qiang.Experimental research on combined treatment of acidic heavy metal polluted wastewater[J].Gold,2018,39(2):64-66.
[13]许玉东,孙燕茹.热镀锌厂酸洗废水和锌灰中回收硫化锌[J].环境工程学报,2014,8(3):948-954.XU Yu-dong,SUN Yan-ru.Recovery of zinc sulfide from acidic wastewater and zinc ash of hot galvanizing plants[J].Chinese Journal of Environmental Engineering.2014,8(3):948-954.
[14]杜长福,伍一根.我国钴湿法冶金行业废水处理概述[J].世界有色金属,2015,12:76-77.DU Chang-fu,WU Yi-gen.Summary of China’s cobalt hydrometallurgy industry wastewater treatment[J].World Nonferrous Metals,2015,12:76-77.
[15]VEEKEN A H M,AKOTO L,POL L W H,WEIJMA J.Control of the sulfide(S2-)concentration for optimal zinc removal by sulfide precipitation in a continuously stirred tank reactor[J].Water Research,2003,37:3709-3717.
[16]VEEKEN A H M,RULKENS W H.Innovative developments in the selective removal and reuse of heavy metals from wastewaters[J].Water Science and Technology,2003,47(10):9-16.
[17]SAMPAIO R M M,TIMMERS R A,XU Y,KEESMAN K J,LENS P N.Selective precipitation of Cu from Zn in a p Scontrolled continuously stirred tank reactor[J].Journal of Hazardous Materials,2009,165:256-265.
[18]LEWIS A E.Review of metal sulphide precipitation[J].Hydrometallurgy,2010,104:222-234.
[19]郭朝晖,姜智超,刘亚男,王硕.混凝沉淀法处理钨多金属矿选矿废水[J].中国有色金属学报,2014,24(9):2393-2399.GUO Zhao-hui,JIANG Zhi-chao,LIU Ya-nan,WANG Shuo.Coagulation and sedimentation treating wastewater from Wcontaining multi-metal ore dressing process[J].The Chinese Journal of Nonferrous Metals,2014,24(9):2393-2399.
[20]韩新罡,席晓丽,马立文,聂祚仁,周志理.配合-沉淀体系中铁与钴、镍的分离性能[J].中国有色金属学报,2013,23(11):3218-3224.HAN Xin-gang,XI Xiao-li,MA Li-wen,NIE Zuo-ren,ZHOU Zhi-li.Separation properties of ion to cobalt and nickel in complexation-precipitation system[J].The Chinese Journal of Nonferrous Metals,2013,23(11):3218-3224.
[21]彭容秋.锌冶金[M].长沙:中南大学出版社,2005.PENG Rong-qiu.Zinc metallurgy[M].Changsha:Center South University Press,2005.
[22]李正根.提高钴冶炼回收率的生产实践[J].有色冶炼,1993(3):11-13.LI Zheng-gen.Practice of improve recover ratio of cobalt metallurgy[J].Nonferrous Metallurgy,1993(3):11-13.
[23]林江顺,蒋开喜.钴锰渣除杂提纯钴工艺研究[J].有色金属,2002,54(3):36-38.LIN Jiang-shun,JIANG Kai-xi.Cobalt recovery from cobalt manganese material[J].Nonferrous Metals,2002,54(3):36-38.
[24]刘智颖,汪晓军,赵爽.还原性铁粉置换法处理化学镀低浓度含镍漂洗水[J].电镀与涂饰,2018,35(8):427-430.LIU Zhi-ying,WANG Xiao-jun,ZHAO Shuang.Treatment of low-nickel-content rinse water from electroless plating process by displacement reaction with reductive iron powder[J].Electroplating&Finishing,2018,35(8):427-430.
[25]马方通,高利坤,董方,陈龙.硫脲浸金及置换法从硫脲溶液中回收金研究现状[J].湿法冶金,2017,36(4):257-270.MA Fang-tong,GAO Li-kun,DONG Fang,CHEN Long.Situations of leaching and replacement of gold in acidic thioutra solution[J].Hydrometallurgy of China,2017,36(4):257-270.
[26]黄捷,王强胜,李建芬.铁置换法处理含铜废水的实验研究[J].化学工程师,2015,240(9):36-38.HUANG Jie,WANG Qiang-sheng,LI Jian-fen.Experiment research on treatment of copper-containing wastewater by iron replacement method[J].Chemical Engineer,2015,240(9):36-38.
[27]马兰,段莉萍,郝丽萍,覃广河,王力.置换法处理含铜废液的研究[J].兵器材料科学与工程,2014,37(6):43-45.MA Lan,DUAN Li-ping,HAO Li-ping,QIN Guang-he,WANG Li.Treatment of waste containing copper with replacement method[J].Ordnance Material Science and Engineering,2014,37(6):43-45.
[28]王杰,张覃,李先海,沈智慧,叶军建.锌粉置换硫代硫酸盐浸金液中金实验研究[J].矿业工程,2016,36(3):91-93.WANG Jie,ZHANG Qin,LI Xian-hai,SHEN Zhi-hui,YEJun-jian.Experimental study on recovering gold from thiosulfate leaching liquid with zinc powder[J].Mining and Metallurgical Engineering,2016,36(3):91-93.
[29]余洪,胡显智,字富庭,聂彦合,迟衡,王强.置换法回收硫代硫酸盐浸金液中金的研究进展[J].稀有金属,2015,39(5):473-480.YU Hong,HU Xian-zhi,ZI Fu-ting,NIE Yan-he,CHI Heng,WANG Qiang.Progress in gold cementation from ammonium thiosulfate solution[J].Chinese Journal of Rare Metals,2015,39(5):473-480.
[30]杨志强,王玉华,李娟.一种从钴铜锌锰生产废液中选择性回收钴铜的方法.中国:201410810213.0[P].2014-12-24.YANG Zhi-qiang,WANG Yu-hua,LI Juan.A method for selectively recover copper and cobalt from Co-Cu-Zn-Mn production wastewaters.China:201410810213.0[P].2014-12-24.
[31]邹涛,刘明远.离子交换法处理工业废水中重金属的现状与发展[J].山东化工,2017,46(10):190-192.ZOU Tao,LIU Ming-yuan.Present status and development of ion exchange method for treatment of heavy metals in industrial waste water[J].Shandong Chemical Industry,2017,46(10):190-192.
[32]王彧.重金属废水治理方法的研究进展[J].山西建筑,2016,42(24):189-190.WANG Yu.Recent progress of the treatment of heavy metal wastewater[J].Shanxi Architecture,2016,42(24):189-190.
[33]刘航.树脂吸附处理冶炼含钴废水的实践[J].有色冶金节能,2010,8(4):50-53.LIU Hang.Practice of adsorption treatment of cobalt-containing wastewater by resin[J].Energy Saving of Nonferrous Metallurgy,2010,8(4):50-53.
[34]赵倩.硫酸盐稀溶液中铜钴综合回收应用与理论探讨[D].长春:吉林大学,2013.ZHAO Qian.Application and theory of comprehensive recovery of copper and cobalt in dilute sulfate solution[J].Changchun:Jilin University,2013.
[35]陈国栋.一种回收氯化锰残液中钴、铜、锌、锰的方法.中国:ZL201110159956.2[P].2015-08-12.CHEN Guo-dong.A method of recover cobalt,copper,zinc,and manganese from Mn Cl2 residue solution.China:ZL201110159956.2[P].2015-08-12.
[36]邱胤轩.Versatic/Mextral1984H萃取分离废水中的铜镍钴锌镉的研究[D].北京:北京有色金属研究总院,2014.QIU Yin-xuan.The synergistic extraction and separation of copper,nickel,cobalt,zinc,and cadmium from wastewater by Versatic10/Mextral984H system[D].Beijing:General Research Institute for Nonferrous Metals,2014.
[37]DAMBIES L,JAWORSKA A,ZAKRZEWSKA-TRZNADEL G,SARTOWSKA B.Comparison of acidic polymers for the removal of cobalt from water solutions by polymer assisted ultrafiltration[J].Journal of Hazardous Materials,2010,178:988-993.
[38]王欣鹏,蒯琳萍,车俊霞.反渗透技术处理模拟核电站放射性废水中的钴[J].核化学与放射化学,2013,33(2):114-118.WANG Xin-peng,KUAI Lin-ping,CHE Jun-xia.Treatment of simulated radioactive waste water by reverse osmosis[J].Journal of Nuclear and Radiochemistry,2013,33(2):114-118.
[39]陈月芳,曹丽霞,林海,董颖博,程皝,霍汉鑫.中药渣和麦麸对模拟矿山酸性废水中Cu2+的吸附[J].中国有色金属学报,2013,23(6):1775-1782.CHEN Yue-fang,CAO Li-xia,LIN Hai,DONG Ying-bo,CHENG Huang,HUO Han-xin.Adsorption of Cu2+from simulated acid mine drainage by herb-medicine residue and wheat bran[J].The Chinese Journal of Nonferrous Metals,2013,23(6):1775-1782.
[40]SMICIKLAS I,DIMOVIA I,MITRIA M.Removal of Co2+from aqueous solutions by hydroxyapatite[J].Water Research,2006,40(12):2267-2274.
[41]李云东,袁志华,李慧琴,田辉.含钴废水的粉煤灰处理效果初报[J].中国农学通报,2007,23(8):459-461.LI Yun-dong,YUAN Zhi-hua,LI Hui-qin,TIAN Hui.Removing Co2+from aqueous solution by using fly ash as the adsorbent[J].Chinese Agricultural Science Bulletin,2007,23(8):459-461.
[42]YANG Tian-zu,FU Xin-xin,LIU Wei-feng,CHEN Lin,ZHANG Du-chao.Hydrometallurgical treatment of copper smelting dust by oxidation leaching and fractional precipitation technology[J].JOM,2017,69:1982-1986.
[43]LIU Wei-feng,RAO Shuai,WANG Wen-yao,YANG Tian-zu,YANG Lin,CHEN Lin,ZHANG Du-chao.Selective leaching of cobalt and iron from cobalt white alloy in sulfuric acid solution with catalyst[J].Int J Miner Process,2015,141:8-14.
[44]LIN Qing-quan,GU Guo-hua,WANG Hui,WANGChong-qing,LIU You-cai,ZHU Ren-feng,FU Jian-gang.Separation of manganese from calcium and magnesium in sulfate solution via carbonate precipitation[J].Transaction of Nonferrous Metals Society of China,2016,26(4):1118-1125.
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