过硫酸盐氧化修复有机污染土壤的研究现状
|
摘要
基于过硫酸盐新兴高级氧化技术,分析了活化过硫酸盐氧化作用的机理和活化方法,重点介绍了热活化和过渡金属活化过硫酸盐在有机污染土壤中的研究现状,包括菲、柴油、石油、石油烃、芘、十溴联苯醚、对硝基氯苯等污染土壤的处理效果、制约因素或动力学规律等。并结合目前存在的问题提出了5方面的针对性建议:加强基础理论研究,加强污染风险防控;深入研究过硫酸盐活化方式,提高过硫酸盐活化效率和利用率;研发组合修复工艺技术和智能化土壤修复装备;加强对复合污染物土壤的联合修复;开发水土共生体系一体化修复技术。以期相关成果能为活化过硫酸盐修复有机污染土壤相关技术研究与工程应用提供参考。
Research including advanced oxidation technology of persulfate,the oxidation mechanism and activation methods of activated persulfate were analyzed,the research situation of remediation of organics-contaminated soil by thermally activated persulfate and transition metal activated persulfate,on phenanthrene,diesel,crude oil,hydrocarbon,pyrene,deca-brominated diphenyl ether,and p-nitrochlorobenzene,were introduced.Recommendations were made in five aspects:strengthen basic theoreticresearch,increase activate efficiency and utilization ratio of persulfate oxidation,develop synergetic remediation technology and intelligent soil remediation equipment,enhance integrated remediation for soil with combined pollution,and develop water-soil symbiotic remediation technology.Such improvements and developments could be referredto in the engineering application of remediation technologies in the future.
Research including advanced oxidation technology of persulfate,the oxidation mechanism and activation methods of activated persulfate were analyzed,the research situation of remediation of organics-contaminated soil by thermally activated persulfate and transition metal activated persulfate,on phenanthrene,diesel,crude oil,hydrocarbon,pyrene,deca-brominated diphenyl ether,and p-nitrochlorobenzene,were introduced.Recommendations were made in five aspects:strengthen basic theoreticresearch,increase activate efficiency and utilization ratio of persulfate oxidation,develop synergetic remediation technology and intelligent soil remediation equipment,enhance integrated remediation for soil with combined pollution,and develop water-soil symbiotic remediation technology.Such improvements and developments could be referredto in the engineering application of remediation technologies in the future.
引文
[1] 陈卫平,谢天,李笑诺,等.欧美发达国家场地土壤污染防治技术体系概述[J].土壤学报,2018,55(3):557-568.
[2] 陈保冬,赵方杰,张莘,等.土壤生物与土壤污染研究前沿与展望[J].生态学报,2015,35(20):6604-6613.
[3] 李佳,曹兴涛,隋红,等.石油污染土壤修复技术研究现状与展望[J].石油学报(石油加工),2017,33(5):811-833.
[4] MARTINES J L.Antibiotics and antibiotic resistance genes in natural environments[J].Science,2008,321(5887):365-367.
[5] 环境保护部,国土资源部.全国土壤污染状况调查公报[EB/OL].(2014-04-17)[2018-09-17].http://www.mee.gov.cn/gkml/sthjbgw/qt/201404/t20140417_270670.htm.
[6] 郭书海,吴波,胡清,等.污染土壤修复技术预测[J].环境工程学报,2017,11(6):2797-3804.
[7] 吴昊,孙丽娜,王辉,等.活化过硫酸钠原位修复石油类污染土壤研究进展[J].环境化学,2015,34(11):2085-2095.
[8] 刘红梅,褚华强,陈家斌,等.过硫酸盐在地下水和土壤修复中的应用[J].现代化工,2015,35(4):42-46.
[9] 李社锋,王文坦,邵雁,等.活化过硫酸盐高级氧化技术的研究进展及工程应用[J].环境工程,2016,34(9):171-174.
[10] 晏井春.含铁化合物活化过硫酸盐及其在有机污染物修复中的应用[D].武汉:华中科技大学,2012:1-128.
[11] 杨世迎,陈友媛,胥慧真,等.过硫酸盐活化高级氧化新技术[J].化学进展,2009,20(9):1433-1438.
[12] LIANG C,WANG Z S,BRUELL C J.Influence of p H on persulfate oxidation of TCE at ambient temperatures[J].Chemosphere,2007,66(1):106-113.
[13] THOMSON N,SRA K,XU X Y.Improved understanding of in situ chemical oxidation soil reactivity[R].University of Waterloo,2009.
[14] OZIOMA A,CHUKWUNONYE O,LEO O.Assessment of ability of three chemical oxidants to remove hydrocarbons from soils polluted by bonny light crude oil[J].Eur chem bull,2013,2(4):226-230.
[15] WALDEMER R H,TRATNYEK P G,JOHNSON R L,et al.Oxidation of chlorinated ethenes by heat activated persulfate:Kinetics and products[J].Environmental science technology,2007,41(3):1010-1015.
[16] 吴昊,孙丽娜,王辉,等.活化过硫酸钠原位修复石油类污染土壤研究进展[J].环境化学,2015,34(11):2085-2095.
[17] LEMAIRE J,BUES M A,KABECHE T.Oxidant selection to treat an aged PAH contaminated soil by in situ chemical oxidation[J].Journal of environmental chemical engineering,2013,1(4):1261-1268.
[18] LUO L,LIN S,HUANG H L,et al.Relationships between aging of PAHs and soil properties[J].Environmental pollution,2012,170:177-182.
[19] 李永涛,赖连珏,岳东.无机阴离子对热活化过硫酸盐体系中降解MDEA模拟废水的影响[J].环境工程学报,2018,12(3):788-795.
[20] 陈晓庆.热激发过硫酸盐降解土壤中对硝基苯酚的研究[D].武汉:华中科技大学,2015:1-46.
[21] HUANG Y F,HUANG Y H.Identification of produced powerful radicals involved in the mineralization of bisphenol A using a novel UV-Na2S2O8/H2O2-Fe(II,III) two-stage oxidation process[J].Journal of hazardous materials,2009,162(2/3):1211-1216.
[22] CRIQUET J,LEITNER N K V.Degradation of acetic acid with sulfate radical generated by persulfate ions photolysis[J].Chemosphere,2009,77(2):194-200.
[23] 李炳智.超声/过硫酸盐联合降解1,1,1-三氯乙烷的机理研究[J].安全与环境学报,2013,13(4):29-36.
[24] DING Y,ZHU L H,YAN J C,et al.Spectrophotometric determination of persulfate by oxidative decolorization of azo dyes for wastewater treatment[J].Journal of environmental monitoring jem,2011,13(11):3057-3063.
[25] 陈垚,董良飞,张凤娥.超声波-热联合活化过硫酸盐氧化修复有机氯农药污染土壤[J].常州大学学报(自然科学版),2017,29(1):35-40.
[26] 杨世迎,杨鑫,王萍,等.过硫酸盐高级氧化技术的活化方法研究进展[J].现代化工,2009,29(4):13-19.
[27] 王兵,李娟,莫正平,等.基于硫酸自由基的高级氧化技术研究及应用进展[J].环境工程,2012,30(4):53-57.
[28] 周颖.过硫酸钠修复石油污染土壤的活化方式及其活化参数的实验研究[D].新疆:新疆农业大学,2016:1-65.
[29] 徐开泰,林匡飞,陆强,等.热活化过硫酸钠降解土壤体系中的菲[J].环境工程,2018,36(1):187-194.
[30] 罗进.活化过硫酸盐氩化修复柴油污染土壤研究[D].成都:西南石油大学,2017,54-55.
[31] 李永涛,罗进,岳东.热活化过硫酸盐氧化修复柴油污染土壤[J].环境污染与防治,2017,39(10):1143-1146.
[32] 周颖,谢海燕,赵晨曦,等.活化过硫酸盐处置石油污染土壤技术研究[J].新疆环境保护,2016,38(2):12-17.
[33] NADIM F,HUANG K C,DAHMANI A M.Remediation of soil ground water contaminated with PAH using heat and Fe(Ⅱ)-EDTA catalyzed persulfate oxidation[J].Water,air & soil pollution:focus,2006,6(1):227-232.
[34] YEN C H,CHEN K F,KAO C M,et al.Application of persulfate to remediate petroleum hydrocarbon-contamination soil:feasibility and comparison with common oxidants[J].Journal of hazardous materials,2011,186(2/3):2097-2012.
[35] 曾彪.铁化合物活化过硫酸钠氧化修复多氯联苯污染土壤研究[D].浙江:浙江大学,2014:1-54.
[36] 张宏玲,李森,张杨,等.过渡金属离子活化过硫酸盐去除土壤中的芘[J].环境工程学报,2016,10(10):6009-6014.
[37] 高金龙,马玉琳,孟庆来,等.二价铁活化过硫酸盐降解土壤中十溴联苯醚[J].环境工程学报,2016,10(12):7339-7343.
[38] CAO J,ZHANG W,BROWN D G,et al.Oxidation of lindane with Fe(Ⅱ)-activated sodium persulfate[J].Environmental engineering science,2008,25(2):221-228.
[39] 文勤亮,张瀚文,许海波,等.零价铁还原-过硫酸盐氧化联合降解土壤中对硝基氯苯的研究[J].南京农业大学学报,2014,37(6):111-118.
[40] 吴非,陈谷汎,林伟翰,等.包覆型纳米零价铁活化过硫酸处理柴油污染土壤[J].环境科学学报,2016,36(7):2589-2595.
[2] 陈保冬,赵方杰,张莘,等.土壤生物与土壤污染研究前沿与展望[J].生态学报,2015,35(20):6604-6613.
[3] 李佳,曹兴涛,隋红,等.石油污染土壤修复技术研究现状与展望[J].石油学报(石油加工),2017,33(5):811-833.
[4] MARTINES J L.Antibiotics and antibiotic resistance genes in natural environments[J].Science,2008,321(5887):365-367.
[5] 环境保护部,国土资源部.全国土壤污染状况调查公报[EB/OL].(2014-04-17)[2018-09-17].http://www.mee.gov.cn/gkml/sthjbgw/qt/201404/t20140417_270670.htm.
[6] 郭书海,吴波,胡清,等.污染土壤修复技术预测[J].环境工程学报,2017,11(6):2797-3804.
[7] 吴昊,孙丽娜,王辉,等.活化过硫酸钠原位修复石油类污染土壤研究进展[J].环境化学,2015,34(11):2085-2095.
[8] 刘红梅,褚华强,陈家斌,等.过硫酸盐在地下水和土壤修复中的应用[J].现代化工,2015,35(4):42-46.
[9] 李社锋,王文坦,邵雁,等.活化过硫酸盐高级氧化技术的研究进展及工程应用[J].环境工程,2016,34(9):171-174.
[10] 晏井春.含铁化合物活化过硫酸盐及其在有机污染物修复中的应用[D].武汉:华中科技大学,2012:1-128.
[11] 杨世迎,陈友媛,胥慧真,等.过硫酸盐活化高级氧化新技术[J].化学进展,2009,20(9):1433-1438.
[12] LIANG C,WANG Z S,BRUELL C J.Influence of p H on persulfate oxidation of TCE at ambient temperatures[J].Chemosphere,2007,66(1):106-113.
[13] THOMSON N,SRA K,XU X Y.Improved understanding of in situ chemical oxidation soil reactivity[R].University of Waterloo,2009.
[14] OZIOMA A,CHUKWUNONYE O,LEO O.Assessment of ability of three chemical oxidants to remove hydrocarbons from soils polluted by bonny light crude oil[J].Eur chem bull,2013,2(4):226-230.
[15] WALDEMER R H,TRATNYEK P G,JOHNSON R L,et al.Oxidation of chlorinated ethenes by heat activated persulfate:Kinetics and products[J].Environmental science technology,2007,41(3):1010-1015.
[16] 吴昊,孙丽娜,王辉,等.活化过硫酸钠原位修复石油类污染土壤研究进展[J].环境化学,2015,34(11):2085-2095.
[17] LEMAIRE J,BUES M A,KABECHE T.Oxidant selection to treat an aged PAH contaminated soil by in situ chemical oxidation[J].Journal of environmental chemical engineering,2013,1(4):1261-1268.
[18] LUO L,LIN S,HUANG H L,et al.Relationships between aging of PAHs and soil properties[J].Environmental pollution,2012,170:177-182.
[19] 李永涛,赖连珏,岳东.无机阴离子对热活化过硫酸盐体系中降解MDEA模拟废水的影响[J].环境工程学报,2018,12(3):788-795.
[20] 陈晓庆.热激发过硫酸盐降解土壤中对硝基苯酚的研究[D].武汉:华中科技大学,2015:1-46.
[21] HUANG Y F,HUANG Y H.Identification of produced powerful radicals involved in the mineralization of bisphenol A using a novel UV-Na2S2O8/H2O2-Fe(II,III) two-stage oxidation process[J].Journal of hazardous materials,2009,162(2/3):1211-1216.
[22] CRIQUET J,LEITNER N K V.Degradation of acetic acid with sulfate radical generated by persulfate ions photolysis[J].Chemosphere,2009,77(2):194-200.
[23] 李炳智.超声/过硫酸盐联合降解1,1,1-三氯乙烷的机理研究[J].安全与环境学报,2013,13(4):29-36.
[24] DING Y,ZHU L H,YAN J C,et al.Spectrophotometric determination of persulfate by oxidative decolorization of azo dyes for wastewater treatment[J].Journal of environmental monitoring jem,2011,13(11):3057-3063.
[25] 陈垚,董良飞,张凤娥.超声波-热联合活化过硫酸盐氧化修复有机氯农药污染土壤[J].常州大学学报(自然科学版),2017,29(1):35-40.
[26] 杨世迎,杨鑫,王萍,等.过硫酸盐高级氧化技术的活化方法研究进展[J].现代化工,2009,29(4):13-19.
[27] 王兵,李娟,莫正平,等.基于硫酸自由基的高级氧化技术研究及应用进展[J].环境工程,2012,30(4):53-57.
[28] 周颖.过硫酸钠修复石油污染土壤的活化方式及其活化参数的实验研究[D].新疆:新疆农业大学,2016:1-65.
[29] 徐开泰,林匡飞,陆强,等.热活化过硫酸钠降解土壤体系中的菲[J].环境工程,2018,36(1):187-194.
[30] 罗进.活化过硫酸盐氩化修复柴油污染土壤研究[D].成都:西南石油大学,2017,54-55.
[31] 李永涛,罗进,岳东.热活化过硫酸盐氧化修复柴油污染土壤[J].环境污染与防治,2017,39(10):1143-1146.
[32] 周颖,谢海燕,赵晨曦,等.活化过硫酸盐处置石油污染土壤技术研究[J].新疆环境保护,2016,38(2):12-17.
[33] NADIM F,HUANG K C,DAHMANI A M.Remediation of soil ground water contaminated with PAH using heat and Fe(Ⅱ)-EDTA catalyzed persulfate oxidation[J].Water,air & soil pollution:focus,2006,6(1):227-232.
[34] YEN C H,CHEN K F,KAO C M,et al.Application of persulfate to remediate petroleum hydrocarbon-contamination soil:feasibility and comparison with common oxidants[J].Journal of hazardous materials,2011,186(2/3):2097-2012.
[35] 曾彪.铁化合物活化过硫酸钠氧化修复多氯联苯污染土壤研究[D].浙江:浙江大学,2014:1-54.
[36] 张宏玲,李森,张杨,等.过渡金属离子活化过硫酸盐去除土壤中的芘[J].环境工程学报,2016,10(10):6009-6014.
[37] 高金龙,马玉琳,孟庆来,等.二价铁活化过硫酸盐降解土壤中十溴联苯醚[J].环境工程学报,2016,10(12):7339-7343.
[38] CAO J,ZHANG W,BROWN D G,et al.Oxidation of lindane with Fe(Ⅱ)-activated sodium persulfate[J].Environmental engineering science,2008,25(2):221-228.
[39] 文勤亮,张瀚文,许海波,等.零价铁还原-过硫酸盐氧化联合降解土壤中对硝基氯苯的研究[J].南京农业大学学报,2014,37(6):111-118.
[40] 吴非,陈谷汎,林伟翰,等.包覆型纳米零价铁活化过硫酸处理柴油污染土壤[J].环境科学学报,2016,36(7):2589-2595.
© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号 地址：北京市海淀区学院路29号 邮编：100083 电话：办公室：(+86 10)66554848；文献借阅、咨询服务、科技查新：66554700 |