聚乳酸增韧改性研究进展
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摘要
主要介绍了聚乳酸的化学增韧改性(共聚改性)和物理增韧改性(增塑、共混与无机刚性粒子复合),综述了近年来国内外聚乳酸增韧改性的研究现状及进展,并对今后聚乳酸增韧改性提出了建议。
The chemical toughening modification(copolymerization modification) and physical toughening modification(plasticization,blending,and inorganic rigid particle composition) were introduced,the research status and progress of toughening modification of poly(lactic acid) in recent years were reviewed,and some suggestions on toughening modification of poly(lactic acid) in the future were proposed.
The chemical toughening modification(copolymerization modification) and physical toughening modification(plasticization,blending,and inorganic rigid particle composition) were introduced,the research status and progress of toughening modification of poly(lactic acid) in recent years were reviewed,and some suggestions on toughening modification of poly(lactic acid) in the future were proposed.
引文
[1]陈杰,胡荣荣,刘环宇,等.聚乳酸耐热改性研究进展[J].塑料科技,2018,46(5):115-119.
[2]肖伟娜,黄雪,冯光志,等.聚乳酸增韧改性研究进展[J].化工进展,2011,30(3):578-582.
[3]高佳,李琳琳,王战勇.微生物降解聚乳酸生产乳酸的研究[J].科技通报,2013,29(5):173-176.
[4]Majid J,Elmira A T,Muhammad I.Poly-lactic acid:production,applications,nanocomposites and release studies[J].Comprehensive Reviewsin Food Scienceand Food Safety,2010,9:552-571.
[5]陈学思.绿色塑料聚乳酸的关键技术研发与产业化应用[J].科技促进发展,2015,11(3):354-359.
[6]王雪芳,王鸿博,傅佳佳,等.TiO2/聚乳酸复合纳米纤维膜的制备及其抗菌性能[J].材料科学与工程学报,2014,32(1):70-73.
[7]杨舒宇,徐鼐,庞素娟,等.PLA/椰壳纤维阻燃复合材料的制备与性能研究[J].塑料科技,2015,43(1):69-73.
[8]王春红,任子龙,李姗,等.苎麻织物表面改性对其增强热固性聚乳酸复合材料力学及阻燃性能的影响[J].复合材料学报,2015,32(2):444-450.
[9]胡晶,贾磊.可降解聚乳酸的合成及应用[J].广东化工,2016,43(8):81-82.
[10]袁理,李芬芬,康睿玲,等.聚乳酸增韧改性研究进展[J].中国塑料,2017,31(1):7-12.
[11]邓艳丽,杨斌,苗继斌,等.聚乳酸增韧研究进展[J].化工进展,2015,34(11):3 975-3 978.
[12]李文飞,刘军海.聚乳酸改性的研究进展[J].化工新型材料,2011,39(1):25-27.
[13]唐志民,马新宾.聚乳酸的化学改性及研究进展[J].现代化工,2016,36(5):17-20.
[14]张佩弦,赵西坡,彭少贤.聚乳酸共聚改性的研究现状及发展[J].化工时刊,2016,30(8):33-37.
[15]Fang H G,Jiang F,Wu Q H,et al.Super tough polylactide materials prepared through in situ reactive blending with peg-based diacrylate monomer[J].Acs Applied Materials&Interfaces,2014,16(6):13 552-13 563.
[16]Zhao T H,Yuan W Q,Yi-Dong Li,et al.Relating chemical structure to toughness via morphology control in fully sustainable sebacic acid cured epoxidized soybean oil toughened polylactide blends[J].Macromolecules,2018,51:2 027-2 037.
[17]Meng X T,Ngoc A N,Halil T,et al.Supertough PLA-silane nanohybrids by in situ condensation and grafting[J].ACSSustainable Chem Eng,2018(6):1 289-1 298.
[18]Li T Q,Zhang J Y,Deborah K S,et al.Toughening glassy poly(lactide)with block copolymer micelles[J].ACS Macro Lett,2016,5(3):359-364.
[19]Intaek L,Tessie R P,Frank S B.Sustainable poly(lactide-bbutadiene)multiblock copolymers with enhanced mechanical properties[J].Macromolecules,2013,46(18):7 387-7 398.
[20]苏思玲,金乐群,顾永安,等.E-MA-GMA三嵌段共聚物对聚乳酸的增韧改性[J].高分子材料科学与工程,2008,24(4):53-57.
[21]刘志阳,翁云宣,张敏.聚乳酸增韧改性研究进展[J].塑料助剂,2016(3):16-19.
[22]强涛,于德梅.聚乳酸增韧研究进展[J].高分子材料科学与工程,2010,26(9):167-170.
[23]吴盾,李会丽,陆颖,等.不同相对分子质量聚乙二醇增塑聚乳酸共混物的制备与性能[J].高分子材料科学与工程,2017,33(5):164-177.
[24]徐蒙蒙,尹朝辉,阳范文,等.复合增塑剂改性PLA共混物的结构与性能[J].工程塑料应用,2017,45(8):106-111.
[25]万同,杨光瑞,张婕,等.柠檬酸醚酯增塑剂的合成及增塑聚乳酸[J].材料工程,2015,43(5):67-74.
[26]郝艳平.聚乳酸增塑和聚对苯二甲酸丁二醇酯增韧改性研究[D].长春:吉林大学,2016.
[27]庞青青.溶液共混法增韧改性聚乳酸的研究[D].长春:吉林大学,2016.
[28]丁正,林强,彭少贤,等.完全降解聚乳酸共混增韧的研究进展[J].塑料,2016,45(2):95-97.
[29]Yang Y,Zhang L S,Xiong Z,et al.Research progress in the heat resistance,toughening and filling modification of PLA[J].Science China Chemistry,2016,59(11):1 355-1 368.
[30]王建琴,刘晨光.聚乳酸增韧改性最新研究进展[J].塑料科技,2015,43(6):65-70.
[31]张红红.超韧PLA共混体系的相形态、界面相容性及性能研究[D].青岛:青岛科技大学,2016.
[32]Zhao Q N,Ding Y,Yang B,et al.Highly efficient toughening effect of ultrafine full-vulcanized powdered rubber on poly(lactic acid)(PLA)[J].Polymer Testing,2013,32(2):299-305.
[33]王德禧.热塑性弹性体的现状和发展[J].塑料,2004,33(2):46-52.
[34]Thomas L,Etienne G,Carine A,et al.Fatty acid-based thermoplastic poly(ester-amide)as toughening and crystallization improver of poly(L-lactide)[J].European Polymer Journal,2015,65:276-285.
[35]Lu X,Wei X S,Huang J T,et al.Supertoughened poly(lactic acid)/polyurethane blend material by in situ reactive interfacial compatibilization via dynamic vulcanization[J].Industrial&Engineering Chemistry Research,2014,53(44):17 386-17 393.
[36]Wang Y H,Chen K L,Xu C H,et al.Supertoughened biobased poly(lactic acid)-epoxidized natural rubber thermoplastic vulcanizates:Fabrication,co-continuous phase structure,interfacial in situ compatibilization,and toughening mechanism[J].J Phys Chem B,2015,119(36):12 138-12 146.
[37]Chen Y K,Wang W T,Yuan D S,et al.Bio-based pla/nrpmma/nr ternary thermoplastic vulcanizates with balanced stiffness and toughness:“Soft-Hard”core-shell continuous rubber phase,in situ compatibilization,and properties[J].ACS Sustainable Chem Eng,2018,6:6 488-6 496.
[38]Liu G C,He Y S,Zeng J B,et al.Fully biobased and supertough polylactide-based thermoplastic vulcanizates fabricated by peroxide-induced dynamic vulcanization and interfacial compatibilization[J].Biomacromolecules,2014,15(11):4 260-4 271.
[39]Wu N J,Zhang H,Fu G L.Super-tough poly(lactide)thermoplastic vulcanizates based on modified natural rubber[J].ACS Sustainable Chem Eng,2017,5(1):78-84.
[40]杨斌.绿色塑料聚乳酸[M].北京:化学工业出版社,2007.
[41]侯家树.聚乳酸/聚丁二酸丁二醇酯共混体系的改性研究[D].郑州:郑州大学,2010.
[42]李玉林,何培新.高分子合金增韧机理的研究进展[J].高分子材料科学与工程,2002,18(5):26-30.
[43]张振兴.增强增韧聚乳酸研究[D].成都:四川大学,2007.
[44]Jiang L,Michael P W,Jinwen Z.Study of biodegradable polylactide/poly(butylene adipate-co-terephthalate)blends[J].Biomacromolecules,2006,7(1):199-207.
[45]Zhang K Y,Amar K M,Manju M.Fully biodegradable and biorenewable ternary blends from polylactide,poly(3-hydroxybutyrate-co-hydroxyva-lerate)and poly(butylene succinate)with balanced properties[J].ACS Appl Mater Interfaces,2012,4(6):3 091-3 101.
[46]Tiphaine M,Nade?ge F,Alain G,et al.Structure and barrier properties of multinanolayered biodegradable pla/pbsa films:confinement effect via forced assembly coextrusion[J].ACSAppl Mater Interfaces,2017,9(34):29 101-29 112.
[47]Zhang C M,Zhai T L,Turng L S,et al.Morphological,mechanical,and crystallization behavior of polylactide/polycaprolactone blends compatibilized by l-lactide/caprolactone copolymer[J].Ind Eng Chem Res,2015,54(38):9 505-9 511.
[48]Vincent O,Suprakas S R,Rotimi S.Toughening of biodegradable polylactide/poly(butylene succinate-coadipate)blends via in situ reactive compatibilization[J].ACSAppl Mater Interfaces,2013,5(10):4 266-4 276.
[49]Hu X R,Li Y,Li M Q,et al.Renewable and supertoughened polylactide-based composites:morphology,interfacial compatibilization,and toughening mechanism[J].Ind Eng Chem Res,2016,55(34):9 195-9 204.
[50]袁瑞登.无机填料改性聚乳酸的研究[D].大连:大连理工大学,2011.
[51]周志斌.无机纳米SiO2填充PLA/PBAT复合体系的制备及流变性能研究[D].株洲:湖南工业大学,2016.
[52]庄韦,张建华,刘靖,等.纳米TiO2/聚乳酸复合材料的制备和表征[J].复合材料学报,2008,25(3):8-11.
[53]Prodyut D,Amit K,Vimal K.Magnetic cellulose nanocrystal based anisotropic polylactic acid nanocomposite films:Influence on electrical,magnetic,thermal,and mechanical properties[J].ACS Appl Mater Interfaces,2016,28(8):18 393-18 409.
[54]Jin F L,Zhang H,Yao S S,et al.Effect of surface modification on impact strength and flexural strength of poly(lactic acid)/silicon carbide nanocomposites[J].Macromol Res,2018,26(3):211-214.
[55]Yao S S,Pang Q Q,Song R,et al.Fracture toughness improvement of poly(lactic acid)with siliconcarbide whiskers[J].Macromol Res,2016,24(11):961-964.
[56]Jin F L,Pang Q Q,Zhang T Y,et al.Synergistic reinforcing of poly(lactic acid)-based systems by polybutylene succinate and nano-calcium carbonate[J].Journal of Industrial and Engineering Chemistry,2015,32:77-84.
[57]Vincent O,Suprakas S R,Rotimi S.Effect of nanoclay loading on the thermal and mechanical properties of biodegradable polylactide/poly[(butylene succinate)-co-adipate]blend composites[J].ACS Appl Mater Interfaces,2012,4(5):2 395-2 405.
[2]肖伟娜,黄雪,冯光志,等.聚乳酸增韧改性研究进展[J].化工进展,2011,30(3):578-582.
[3]高佳,李琳琳,王战勇.微生物降解聚乳酸生产乳酸的研究[J].科技通报,2013,29(5):173-176.
[4]Majid J,Elmira A T,Muhammad I.Poly-lactic acid:production,applications,nanocomposites and release studies[J].Comprehensive Reviewsin Food Scienceand Food Safety,2010,9:552-571.
[5]陈学思.绿色塑料聚乳酸的关键技术研发与产业化应用[J].科技促进发展,2015,11(3):354-359.
[6]王雪芳,王鸿博,傅佳佳,等.TiO2/聚乳酸复合纳米纤维膜的制备及其抗菌性能[J].材料科学与工程学报,2014,32(1):70-73.
[7]杨舒宇,徐鼐,庞素娟,等.PLA/椰壳纤维阻燃复合材料的制备与性能研究[J].塑料科技,2015,43(1):69-73.
[8]王春红,任子龙,李姗,等.苎麻织物表面改性对其增强热固性聚乳酸复合材料力学及阻燃性能的影响[J].复合材料学报,2015,32(2):444-450.
[9]胡晶,贾磊.可降解聚乳酸的合成及应用[J].广东化工,2016,43(8):81-82.
[10]袁理,李芬芬,康睿玲,等.聚乳酸增韧改性研究进展[J].中国塑料,2017,31(1):7-12.
[11]邓艳丽,杨斌,苗继斌,等.聚乳酸增韧研究进展[J].化工进展,2015,34(11):3 975-3 978.
[12]李文飞,刘军海.聚乳酸改性的研究进展[J].化工新型材料,2011,39(1):25-27.
[13]唐志民,马新宾.聚乳酸的化学改性及研究进展[J].现代化工,2016,36(5):17-20.
[14]张佩弦,赵西坡,彭少贤.聚乳酸共聚改性的研究现状及发展[J].化工时刊,2016,30(8):33-37.
[15]Fang H G,Jiang F,Wu Q H,et al.Super tough polylactide materials prepared through in situ reactive blending with peg-based diacrylate monomer[J].Acs Applied Materials&Interfaces,2014,16(6):13 552-13 563.
[16]Zhao T H,Yuan W Q,Yi-Dong Li,et al.Relating chemical structure to toughness via morphology control in fully sustainable sebacic acid cured epoxidized soybean oil toughened polylactide blends[J].Macromolecules,2018,51:2 027-2 037.
[17]Meng X T,Ngoc A N,Halil T,et al.Supertough PLA-silane nanohybrids by in situ condensation and grafting[J].ACSSustainable Chem Eng,2018(6):1 289-1 298.
[18]Li T Q,Zhang J Y,Deborah K S,et al.Toughening glassy poly(lactide)with block copolymer micelles[J].ACS Macro Lett,2016,5(3):359-364.
[19]Intaek L,Tessie R P,Frank S B.Sustainable poly(lactide-bbutadiene)multiblock copolymers with enhanced mechanical properties[J].Macromolecules,2013,46(18):7 387-7 398.
[20]苏思玲,金乐群,顾永安,等.E-MA-GMA三嵌段共聚物对聚乳酸的增韧改性[J].高分子材料科学与工程,2008,24(4):53-57.
[21]刘志阳,翁云宣,张敏.聚乳酸增韧改性研究进展[J].塑料助剂,2016(3):16-19.
[22]强涛,于德梅.聚乳酸增韧研究进展[J].高分子材料科学与工程,2010,26(9):167-170.
[23]吴盾,李会丽,陆颖,等.不同相对分子质量聚乙二醇增塑聚乳酸共混物的制备与性能[J].高分子材料科学与工程,2017,33(5):164-177.
[24]徐蒙蒙,尹朝辉,阳范文,等.复合增塑剂改性PLA共混物的结构与性能[J].工程塑料应用,2017,45(8):106-111.
[25]万同,杨光瑞,张婕,等.柠檬酸醚酯增塑剂的合成及增塑聚乳酸[J].材料工程,2015,43(5):67-74.
[26]郝艳平.聚乳酸增塑和聚对苯二甲酸丁二醇酯增韧改性研究[D].长春:吉林大学,2016.
[27]庞青青.溶液共混法增韧改性聚乳酸的研究[D].长春:吉林大学,2016.
[28]丁正,林强,彭少贤,等.完全降解聚乳酸共混增韧的研究进展[J].塑料,2016,45(2):95-97.
[29]Yang Y,Zhang L S,Xiong Z,et al.Research progress in the heat resistance,toughening and filling modification of PLA[J].Science China Chemistry,2016,59(11):1 355-1 368.
[30]王建琴,刘晨光.聚乳酸增韧改性最新研究进展[J].塑料科技,2015,43(6):65-70.
[31]张红红.超韧PLA共混体系的相形态、界面相容性及性能研究[D].青岛:青岛科技大学,2016.
[32]Zhao Q N,Ding Y,Yang B,et al.Highly efficient toughening effect of ultrafine full-vulcanized powdered rubber on poly(lactic acid)(PLA)[J].Polymer Testing,2013,32(2):299-305.
[33]王德禧.热塑性弹性体的现状和发展[J].塑料,2004,33(2):46-52.
[34]Thomas L,Etienne G,Carine A,et al.Fatty acid-based thermoplastic poly(ester-amide)as toughening and crystallization improver of poly(L-lactide)[J].European Polymer Journal,2015,65:276-285.
[35]Lu X,Wei X S,Huang J T,et al.Supertoughened poly(lactic acid)/polyurethane blend material by in situ reactive interfacial compatibilization via dynamic vulcanization[J].Industrial&Engineering Chemistry Research,2014,53(44):17 386-17 393.
[36]Wang Y H,Chen K L,Xu C H,et al.Supertoughened biobased poly(lactic acid)-epoxidized natural rubber thermoplastic vulcanizates:Fabrication,co-continuous phase structure,interfacial in situ compatibilization,and toughening mechanism[J].J Phys Chem B,2015,119(36):12 138-12 146.
[37]Chen Y K,Wang W T,Yuan D S,et al.Bio-based pla/nrpmma/nr ternary thermoplastic vulcanizates with balanced stiffness and toughness:“Soft-Hard”core-shell continuous rubber phase,in situ compatibilization,and properties[J].ACS Sustainable Chem Eng,2018,6:6 488-6 496.
[38]Liu G C,He Y S,Zeng J B,et al.Fully biobased and supertough polylactide-based thermoplastic vulcanizates fabricated by peroxide-induced dynamic vulcanization and interfacial compatibilization[J].Biomacromolecules,2014,15(11):4 260-4 271.
[39]Wu N J,Zhang H,Fu G L.Super-tough poly(lactide)thermoplastic vulcanizates based on modified natural rubber[J].ACS Sustainable Chem Eng,2017,5(1):78-84.
[40]杨斌.绿色塑料聚乳酸[M].北京:化学工业出版社,2007.
[41]侯家树.聚乳酸/聚丁二酸丁二醇酯共混体系的改性研究[D].郑州:郑州大学,2010.
[42]李玉林,何培新.高分子合金增韧机理的研究进展[J].高分子材料科学与工程,2002,18(5):26-30.
[43]张振兴.增强增韧聚乳酸研究[D].成都:四川大学,2007.
[44]Jiang L,Michael P W,Jinwen Z.Study of biodegradable polylactide/poly(butylene adipate-co-terephthalate)blends[J].Biomacromolecules,2006,7(1):199-207.
[45]Zhang K Y,Amar K M,Manju M.Fully biodegradable and biorenewable ternary blends from polylactide,poly(3-hydroxybutyrate-co-hydroxyva-lerate)and poly(butylene succinate)with balanced properties[J].ACS Appl Mater Interfaces,2012,4(6):3 091-3 101.
[46]Tiphaine M,Nade?ge F,Alain G,et al.Structure and barrier properties of multinanolayered biodegradable pla/pbsa films:confinement effect via forced assembly coextrusion[J].ACSAppl Mater Interfaces,2017,9(34):29 101-29 112.
[47]Zhang C M,Zhai T L,Turng L S,et al.Morphological,mechanical,and crystallization behavior of polylactide/polycaprolactone blends compatibilized by l-lactide/caprolactone copolymer[J].Ind Eng Chem Res,2015,54(38):9 505-9 511.
[48]Vincent O,Suprakas S R,Rotimi S.Toughening of biodegradable polylactide/poly(butylene succinate-coadipate)blends via in situ reactive compatibilization[J].ACSAppl Mater Interfaces,2013,5(10):4 266-4 276.
[49]Hu X R,Li Y,Li M Q,et al.Renewable and supertoughened polylactide-based composites:morphology,interfacial compatibilization,and toughening mechanism[J].Ind Eng Chem Res,2016,55(34):9 195-9 204.
[50]袁瑞登.无机填料改性聚乳酸的研究[D].大连:大连理工大学,2011.
[51]周志斌.无机纳米SiO2填充PLA/PBAT复合体系的制备及流变性能研究[D].株洲:湖南工业大学,2016.
[52]庄韦,张建华,刘靖,等.纳米TiO2/聚乳酸复合材料的制备和表征[J].复合材料学报,2008,25(3):8-11.
[53]Prodyut D,Amit K,Vimal K.Magnetic cellulose nanocrystal based anisotropic polylactic acid nanocomposite films:Influence on electrical,magnetic,thermal,and mechanical properties[J].ACS Appl Mater Interfaces,2016,28(8):18 393-18 409.
[54]Jin F L,Zhang H,Yao S S,et al.Effect of surface modification on impact strength and flexural strength of poly(lactic acid)/silicon carbide nanocomposites[J].Macromol Res,2018,26(3):211-214.
[55]Yao S S,Pang Q Q,Song R,et al.Fracture toughness improvement of poly(lactic acid)with siliconcarbide whiskers[J].Macromol Res,2016,24(11):961-964.
[56]Jin F L,Pang Q Q,Zhang T Y,et al.Synergistic reinforcing of poly(lactic acid)-based systems by polybutylene succinate and nano-calcium carbonate[J].Journal of Industrial and Engineering Chemistry,2015,32:77-84.
[57]Vincent O,Suprakas S R,Rotimi S.Effect of nanoclay loading on the thermal and mechanical properties of biodegradable polylactide/poly[(butylene succinate)-co-adipate]blend composites[J].ACS Appl Mater Interfaces,2012,4(5):2 395-2 405.
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