聚乙烯醇无卤阻燃研究进展
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摘要
鉴于环保的压力,无卤阻燃剂逐渐替代含卤阻燃剂,用在聚乙烯醇(Polyvinyl alcohol,PVA)阻燃处理中。本文综述了近年来无卤阻燃PVA的最新研究进展,总结分析了无机型阻燃剂、磷系阻燃剂、氮系阻燃剂、膨胀型阻燃剂及反应型阻燃剂对PVA的阻燃研究现状,介绍了不同类型阻燃剂的阻燃机理、优缺点以及典型阻燃剂对PVA阻燃性质和力学性质的影响;在此基础上讨论了PVA阻燃的独特性,充分利用PVA的结构特征,研制出适合PVA加工方式的阻燃剂复配配方是PVA阻燃研究的主要发展方向。
Halogen-free flame retardants are introduced into PVA to replace the conventional halogen-contained flame retardant owning to the increasing environmental pressure.The current research progress and development trend of halogen-free flame retardant for Polyvinyl alcohol(PVA)were reviewed.The studies of various kinds of PVA flame retardants containing inorganic flame retardant,phosphorus/nitrogen contained flame retardant,intumescent flame retardant and reactive flame retardant were summarized and analyzed.The flame retarding mechanism,the advantages and disadvantages of different PVA flame retardant,and the influence of typical flame retardant on properties of PVA were introduced.On this basis,the uniqueness of PVA flame retardant was discussed.The trend of PVA flame retardant research is to develop a compound formula suitable for PVA processing considering the structural features of PVA.
Halogen-free flame retardants are introduced into PVA to replace the conventional halogen-contained flame retardant owning to the increasing environmental pressure.The current research progress and development trend of halogen-free flame retardant for Polyvinyl alcohol(PVA)were reviewed.The studies of various kinds of PVA flame retardants containing inorganic flame retardant,phosphorus/nitrogen contained flame retardant,intumescent flame retardant and reactive flame retardant were summarized and analyzed.The flame retarding mechanism,the advantages and disadvantages of different PVA flame retardant,and the influence of typical flame retardant on properties of PVA were introduced.On this basis,the uniqueness of PVA flame retardant was discussed.The trend of PVA flame retardant research is to develop a compound formula suitable for PVA processing considering the structural features of PVA.
引文
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[2]严瑞宣.水溶性高分子.北京:化学工业出版社,1998,42.
[3]Liu P J,Ch W H,Liu Y,Bai S B,Wang Q.Polym Degrad Stab,2014,109:261~269.
[4]Liu P J,Bai S B,Wang Q.J App Poly Sci,2015,132(23):doi:10.1002/app.42020
[5]秦争,周瑞敏,朱逸莉.中国,201410568626.2014-10-22.
[6]Wang L,Snchez-Soto M,Maspoch M L.Mater Des,2013,52:609~614.
[7]Chen H B,Wang Y Z,Schiraldi D A.ACS Appl Mater Inter,2014,6:6790~6796.
[8]Wang Y T,Liao S F,Shang K,Chen M J,Huang J Q,Wang Y Z,Schiraldi D A.ACS Appl Mater Inter,2015,7:1780~1786.
[9]Kang A H,Shang K,Ye D D,Wang Y T,Wang H,Zhu Z M,Liao W,Xu S M,Wang Y Z,Schiraldi D A.Chem Eng J,2017,327:992~999.
[10]Shang K,Liao W,Wang Y Z.Chin Chem Lett,http://dx.doi.org/10.1016/j.cclet.2017.08.017.
[11]刘鹏举,陈文华,白时兵,王琪.工程塑料应用,2017,45(5):50~55.
[12]稻田真也,佐藤政弘,吉持驶视,大森昭夫,德永勋,洼津彰,西山正一,佐野友之.中国,98801482.3,1998-10-01.
[13]赵兴,张兴祥.天津纺织科技,2007,1:9~13.
[14]徐胜杰,丁琦伟.浙江化工,2001,32(1):59~60.
[15]朱小燕,严春杰.化工矿物与加工,2007,1:6~10.
[16]吴焕超,赵忠夫,李杨,王玉荣,张春庆,李战胜,胡雁鸣.高分子通报,2010,7:79~82.
[17]王德龙,刘娅,王玉忠.2004全国阻燃学术年会论文集,72~74.
[18]Wang Z Y,Hou H E,Wei K.Prog Org Coat,2005,53(1):29~37.
[19]邓坤,陈光明,杨丰科.化学通报,2012,75(1):975~980.
[20]李发炎.聚乙烯醇/镁铝双金属氢氧化物纳米复合材料的制备与性能研究.合肥:安徽工程大学硕士学位论文,2013.
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[22]Zhao C X,Liu Y,Wang D Y,Wang D L,Wang Y Z.Polym Degrad Stab,2008,93:1323~1331.
[23]包晨露,郭玉强,袁必和,宋磊,胡源.2012年中国阻燃学术年会论文集,12~16.
[24]邵建果,鲁红典.塑料,2012,41(4):30~32.
[25]Lu H,Wilkie C A,Ding M,Song L.Polym Degrad Stab,2011,96(7):1219~1224.
[26]Wang M,Han X W,Liu L,Zeng X F,Zou H K,Wang J X,Chen J F.Ind Eng Chem Res,2015,54:12805~2812.
[27]全凤玉,孙慧,夏延致,纪全.2010年中国阻燃学术会议论文集,24~28.
[28]Meisam S,Mehdi K,Farideh H,Hossein A K,Khalil F,Udo W.Particuology,2015,19:14~21.
[29]汪则灵.聚乙烯醇的阻燃改性研究.成都:西南交通大学硕士学位论文,2010.
[30]刘健,膨胀石墨的剥离和酯化及其在聚乙烯醇薄膜中的应用.苏州:苏州大学硕士学位论文,2015.
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[32]徐凤飘.聚乙烯醇阻燃变色纤维的制备与表征研究.上海:海工程技术大学硕士学位论文,2014.
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[34]陈婉璐,葛卫兵,姜猛进,叶光斗,徐建军.合成纤维工业,2014,37(5):34~38.
[35]葛卫兵,陈婉璐,姜猛进,徐建军.合成纤维工业,2014,37(1):33~37.
[36]付兴伟,王斌,葛卫兵,姜猛进,徐建军,叶光斗.合成纤维工业,2012,35(1):31~34.
[37]窦午红.阻燃功能化蒙脱土纳米粒子制备及其在聚乙烯醇中的应用研究.太原:中北大学硕士学位论文,2016.
[38]朱红伟.无卤聚乙烯醇阻燃纤维的制备与性能研究.成都:四川大学硕士学位论文,2007.
[39]Yu C H,Xu W X,Zhao X S,Xu J J,Jiang M J.Fiber Polym,2014,15(9):1828~1834.
[40]周迎松,于俊荣,沈燕,王彦,诸静,胡祖明.高分子材料科学与工程,2017,33(2):50~55.
[41]Guo D,Wang Q,Bai S B.Polym Adv Tech,2013,24(3):339~347.
[42]纪少思,周万立,刘鹏清,姜猛进,徐建军.高校化学工程学报,2016,30(3):693~699.
[43]Huang G B,Liang H D,Wang Y,Wang X,Gao J R,Fei Z D.Mater Chem Phys,2012,132(2/3):520~528.
[44]Wang D L,Liu Y,Wang D Y,Zhao C X,Mou Y R.Polym Degrad Stab,2007,92(8):1555~1564.
[45]Hu S,Song L,Pan H F,Hu Y.J Therm Anal Calorim,2013,112:859~864.
[46]林建盛,赵春霞,刘娅,王德义,王玉忠.2008年全国阻燃学术年会论文集,38~40.
[47]Zhou W,Ji S,Liu P,Jiang M J,Xu J J.Rsc Adv,2016,6(37):31059~31068.
[48]Liu L,Liu Y S,Liu Y.RSC Adv,2016,6(41):35051~35057.
[49]Peng S,Zhou M,Liu F,Zhang C,Liu X Q,Liu J Y,Zou L Y,Chen J.R Soc Open Sci,2017,4(8):170512.
[50]Jiang Y,Zhou W L,Jiang M J,Liu P Q,Xu J J.Polym Degrad Stab,2017,144:331~343.
[51]任元林,苏倩,信鹏月.高等学校化学学报,2013,34(5):1264~1269.
[52]马志鹏,王春霞,贾高鹏,王爱民,王杰,罗众,张再兴.纺织导报,2017,9:44~47.
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