湘南黄沙坪多金属矿床石榴子石地球化学特征及其对Cu与W-Sn复合成矿机理的指示
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摘要
黄沙坪矿床位于钦杭成矿带与南岭成矿带的交汇部位,是湘南地区矽卡岩-热液脉型Cu多金属与矽卡岩型W-Sn多金属复合成矿作用的典型代表。为厘清区内Cu与W-Sn成矿物理化学条件以及成矿流体的性质,本文对黄沙坪矿床两类矽卡岩中的石榴子石开展电子探针和LA-ICP-MS原位微区主微量元素研究。结果表明,成W-Sn矿矽卡岩中石榴子石为钙铝榴石-钙铁榴石(平均And71. 3-Gro23. 8)固溶体系列,具有一致的稀土元素配分模式,轻重稀土分异不明显,负Eu异常显著,明显亏损La,∑REE含量与Fe~(3+)/(Fe~(3+)+Al)具有负相关关系,具有较高的U含量,表明石榴子石可能是在相对还原的环境下缓慢结晶形成的。石榴子石中W和Sn的含量随石榴子石中钙铝榴石的比例增加而减少,有利于W-Sn在晚期热液中富集成矿。与Cu矿有关矽卡岩中的石榴子石几乎为纯的钙铁榴石(平均And90. 1-Gro9. 2),具有低的U、∑REE含量,轻重稀土元素分异明显,相对富集轻稀土,具有明显正Eu异常,表明石榴子石具有较快的生长速度,成矿流体具有相对较高的氧逸度和Cl的含量,这种环境有利于Cu在岩浆热液中迁移和富集成矿。因此,早期成矿流体成分以及氧化还原条件的差异可能是导致黄沙坪矿床W-Sn与Cu成矿差异的重要原因。
Huangshaping deposit,located in the intersection between the Nanling W-Sn metallogenic province and the Qin-Hang Cu polymetallic belt,is a representative deposit in southern Hunan Province with skarn-vein Cu polymetallic and skarn W-Sn polymetallic superimposed mineralization. To clarify metallogenic condition and nature of the ore-forming fluid of the W-Sn and Cu mineralization,we present in-situ EPMA and LA-ICP-MS analysis of garnet from two kinds of skarn in the Huangshaping deposit. The garnet associated with W-Sn mineralization is andradite-grossular series( average And71. 3-Gro23. 8) and have a consistent chondrite-normalized REE patterns with negative Eu anomalies and depletion in La. These garnets also display a positive correlation between ∑REE and Fe~(3+)/( Fe~(3+)+ Al),and enrichment of U. These characteristics indicate that the garnets grow slowly in a relative reduced condition. The content of W and Sn show a positive correlation with the content of Al in garnet,which is favorable for the enrichment and mineralization of W and Sn. In contrast,garnet related Cu mineralization is almost pure andradite( average And90. 1-Gro9. 2) with low content of U and ∑ REE. Chondrite-normalized REE patterns is characterized by enrichment of LREEs and positive Eu anomalies.These characteristics indicate that the garnets were formed rapidly from relative oxidized hydrothermal fluid with relative high Cl content,which is favorable for Cu mineralization. W-Sn and Cu superimposed mineralization in the Huangshaping deposit result from different hydrothermal fluid with different composition and redox state.
Huangshaping deposit,located in the intersection between the Nanling W-Sn metallogenic province and the Qin-Hang Cu polymetallic belt,is a representative deposit in southern Hunan Province with skarn-vein Cu polymetallic and skarn W-Sn polymetallic superimposed mineralization. To clarify metallogenic condition and nature of the ore-forming fluid of the W-Sn and Cu mineralization,we present in-situ EPMA and LA-ICP-MS analysis of garnet from two kinds of skarn in the Huangshaping deposit. The garnet associated with W-Sn mineralization is andradite-grossular series( average And71. 3-Gro23. 8) and have a consistent chondrite-normalized REE patterns with negative Eu anomalies and depletion in La. These garnets also display a positive correlation between ∑REE and Fe~(3+)/( Fe~(3+)+ Al),and enrichment of U. These characteristics indicate that the garnets grow slowly in a relative reduced condition. The content of W and Sn show a positive correlation with the content of Al in garnet,which is favorable for the enrichment and mineralization of W and Sn. In contrast,garnet related Cu mineralization is almost pure andradite( average And90. 1-Gro9. 2) with low content of U and ∑ REE. Chondrite-normalized REE patterns is characterized by enrichment of LREEs and positive Eu anomalies.These characteristics indicate that the garnets were formed rapidly from relative oxidized hydrothermal fluid with relative high Cl content,which is favorable for Cu mineralization. W-Sn and Cu superimposed mineralization in the Huangshaping deposit result from different hydrothermal fluid with different composition and redox state.
引文
Allen DE and Seyfried WE Jr.2005.REE controls in ultramafic hosted MOR hydrothermal systems:An experimental study at elevated temperature and pressure.Geochimica et Cosmochimica Acta,69(3):675-683
Bai TB and Koster van Groos AF.1999.The distribution of Na,K,Rb,Sr,Al,Ge,Cu,W,Mo,La,and Ce between granitic melts and coexisting aqueous fluids.Geochimica et Cosmochimica Acta,63(7-8):1117-1131
Blevin PL and Chappell BW.1992.The role of magma sources,oxidation states and fractionation in determining the granite metallogeny of eastern Australia.Earth and Environmental Science Transactions of the Royal Society of Edinburgh,83(1-2):305-316
Blevin PL and Chappell BW.1995.Chemistry,origin,and evolution of mineralized granites in the Lachlan fold belt,Australia:The metallogeny of I-and S-type granites.Economic Geology,90(6):1604-1619
Chen J,Halls C and Stanley CJ.1992.Tin-bearing skarns of South China:Geological setting and mineralogy.Ore Geology Reviews,7(3):225-248
Chen XW,Wu JB and Xi CZ.2008.Geological characteristics and genesis of Huangshaping lead-zinc polymetallic deposit in Hunan.Land&Resources Herald,5(4):45-48(in Chinese)
Ding T,Ma DS,Lu JJ,Zhang RQ,Zhang ST and Gao SY.2016.Petrogenesis of Late Jurassic granitoids and relationship to polymetallic deposits in southern China:The Huangshaping example.International Geology Review,58(13):1646-1672
Eadington PJ and Kinealy K.1983.Some aspects of the hydrothermal reactions of tin during skarn formation.Journal of the Geological Society of Australia,30(3-4):461-471
Flynn RT and Burnham CW.1978.An experimental determination of rare earth partition coefficients between a chloride containing vapor phase and silicate melts.Geochimica et Cosmochimica Acta,42(6):685-701
Gaspar M,Knaack C,Meinert LD and Moretti R.2008.REE in skarn systems:A LA-ICP-MS study of garnets from the Crown Jewel gold deposit.Geochimica et Cosmochimica Acta,72(1):185-205
He HQ,Wang JC and Jiang YC.2010.Preliminary analysis on the geological characteristics and genesis of Fe-W-Mo-Bi(Sn)polymetallic deposit in the southern Huangshaping lead-zinc mine district,Hunan.Mineral Exploration,1(4):323-333(in Chinese with English abstract)
Hu MY,He HL,Zhan XC,Fan XT,Wang G and Jia ZR.2008.Matrix normalization for In-situ multi-element quantitative analysis of zircon in Laser Ablation-Inductively Coupled Plasma Mass Spectrometry.Chinese Journal of Analytical Chemistry,36(7):947-953(in Chinese with English abstract)
Huang GF.1999.Geological characteristics and seeking mineral orientation of Huangshaping style Pb-Zn deposit in southern Hunan.Hunan Geology,18(2-3):84-90,115(in Chinese with English abstract)
Ishihara S.1977.The magnetite-series and ilmenite-series granitic rocks.Mining Geology,27(145):293-305
Jamtveit B,Wogelius RA and Fraser DG.1993.Zonation patterns of skarn garnets:Records of hydrothermal system evolution.Geology,21(2):113-116
Lei ZH,Chen FW,Chen ZH,Xu YM,Gong SQ,Li HQ,Mei YP,Qu WJ and Wang DH.2010.Petrogenetic and metallogenic age determination of the Huangshaping lead-zinc polymetallic deposit and its geological significance.Acta Geoscientica Sinica,31(4):532-540(in Chinese with English abstract)
Li FS,Kang RH,Hu XY,Ma WL,Huang XH,Zeng YH,Tang JB,Zhu X,Qin ZW,Zhang J and He LB.2012.Geological characteristics and ore-search prospect of the Weijia tungsten deposit in Nanling region.Geology in China,39(2):445-457(in Chinese with English abstract)
Li H,Watanabe K and Yonezu K.2014.Zircon morphology,geochronology and trace element geochemistry of the granites from the Huangshaping polymetallic deposit,South China:Implications for the magmatic evolution and mineralization processes.Ore Geology Reviews,60:14-35
Li XF,Huang C,Wang CZ and Wang LF.2016.Genesis of the Huangshaping W-Mo-Cu-Pb-Zn polymetallic deposit in southeastern Hunan Province,China:Constraints from fluid inclusions,trace elements,and isotopes.Ore Geology Reviews,79:1-25
Linnen RL,Pichavant M,Holtz F and Burgess S.1995.The effect of fO 2on the solubility,diffusion,and speciation of tin in haplogranitic melt at 850℃and 2kbar.Geochimica et Cosmochimica Acta,59(8):1579-1588
Linnen RL,Pichavant M and Holtz F.1996.The combined effects of fO 2and melt composition on SnO2solubility and tin diffusivity in haplogranitic melts.Geochimica et Cosmochimica Acta,60(24):4965-4976
Liu WH.2007.Mineralization mechanism of the Huangshaping lead-zinc polymetallic deposit and its application in ore prospecting.Ph.D.Dissertation.Changsha:Central South University,1-146(in Chinese)
Liu XF,Yuan SD and Wu SH.2012.Re-Os dating of the molybdenite from the Jinchuantang tin-bismuth deposit in Hunan Province and its geological significance.Acta Petrologica Sinica,28(1):39-51(in Chinese with English abstract)
Liu XF,Yuan SD,Shuang Y,Yuan YB,Mi JR and Xuan YS.2014.In situ LA-ICP-MS REE analyses of the skarn garnets from the Jinchuantang tin-bismuth deposit in Hunan Province,and their significance.Acta Petrologica Sinica,30(1):163-177(in Chinese with English abstract)
Ma LY,Lu YF,Qu WJ and Fu JM.2007.Re-Os isotopic chronology of molybdenites in Huangshaping lead-zinc deposit,Southeast Hunan,and its geological implications.Mineral Deposits,26(4):425-431(in Chinese with English abstract)
Mao JW,Guy G,Raimbault L and Shimazaki H.1996a.Manganese skarn in the Shizhuyuan polymetallic tungsten deposit,Hunan,China.Resource Geology,46(255):1-11
Mao JW,Li HY,Shimazaki H,Raimbault L and Guy B.1996b.Geology and metallogeny of the Shizhuyuan skarn-greisen deposit,Hunan Province,China.International Geology Review,38(11):1020-1039
Mao JW,Xie GQ,Guo CL and Chen YC.2007.Large-scale tungsten-tin mineralization in the Nanling region,South China:Metallogenic ages and corresponding geodynamic processes.Acta Petrologica Sinica,23(10):2329-2338(in Chinese with English abstract)
Mao JW,Xie GQ,Guo CL,Yuan SD,Cheng YB and Chen YC.2008.Spatial-temporal distribution of Mesozoic ore deposits in South China and their metallogenic settings.Geological Journal of China Universities,14(4):510-526(in Chinese with English abstract)
Mao JW,Chen MH,Yuan SD and Guo CL.2011.Geological characteristics of the Qinhang(or Shihang)metallogenic belt in South China and spatial-temporal distribution regularity of mineral deposits.Acta Geologica Sinica,85(5):636-658(in Chinese with English abstract)
Mao JW,Cheng YB,Chen MH and Pirajno F.2013.Major types and time-space distribution of Mesozoic ore deposits in South China and their geodynamic settings.Mineralium Deposita,48(3):267-294
McI ntire WL.1963.Trace element partition coefficients:A review of theory and applications to geology.Geochimica et Cosmochimica Acta,27(12):1209-1264
Meinert LD.1992.Skarns and skarn deposits.Geoscience Canada,19(4):145-162
Meinert LD,Hefton KK,Mayes D and Tasiran I.1997.Geology,zonation,and fluid evolution of the Big Gossan Cu-Au skarn deposit,Ertsberg district,Irian Jaya.Economic Geology,92(5):509-534
Meinert LD,Hedenquist JW,Satoh H and Matsuhisa Y.2003.Formation of anhydrous and hydrous skarn in Cu-Au ore deposits by magmatic fluids.Economic Geology,98(1):147-156
Meinert LD,Dipple GM and Nicolescu S.2005.World skarn deposits.Society of Economic Geologists,100:299-336
Menzer G.1926.Die kristallstruktur der granate.Zeitschift fur Kristallographie,63:157-158
Mungall JE.2002.Roasting the mantle:Slab melting and the genesis of major Au and Au-rich Cu deposits.Geology,30(10):915-918
Nicolescu S,Cornell DH,S9dervall U and Odelius H.1998.Secondary ion mass spectrometry analysis of rare earth elements in grandite garnet and other skarn related silicates.European Journal of Mineralogy,10(2):251-260
Peng HJ,Li HY,Pei RF,Zhang CQ,Zhou YM,Tian G,Li JX and Long F.2014.Mineralogical characteristics and metallogeny of the Hongniu-Hongshan copper deposit in Zhongdian area,Yunnan Province,China.Acta Petrologica Sinica,30(1):237-256(in Chinese with English abstract)
Peng HJ,Zhang CQ,Mao JW,Santosh M,Zhou YM and Hou L.2015.Garnets in porphyry-skarn systems:A LA-ICP-MS,fluid inclusion,and stable isotope study of garnets from the Hongniu-Hongshan copper deposit,Zhongdian area,NW Yunnan Province,China.Journal of Asian Earth Sciences,103:229-251
Peng JT,Zhou MF,Hu RZ,Shen NP,Yuan SD,Bi XW,Du AD and Qu WJ.2006.Precise molybdenite Re-Os and mica Ar-Ar dating of the Mesozoic Yaogangxian tungsten deposit,central Nanling district,South China.Mineralium Deposita,41(7):661-669
Reed MJ,Candela PA and Piccoli PM.2000.The distribution of rare earth elements between monzogranitic melt and the aqueous volatile phase in experimental investigations at 800℃and 200MPa.Contributions to Mineralogy and Petrology,140(2):251-262
Shannon RD.1976.Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides.Acta Crystallographica Section A,32(5):751-767
Sillitoe RH.1997.Characteristics and controls of the largest porphyry copper-gold and epithermal gold deposits in the circum-Pacificregion.Australian Journal of Earth Sciences,44(3):373-388
Smith MP,Henderson P,Jeffries TER,Long J and Williams CT.2004.The rare earth elements and uranium in garnets from the Beinn an Dubhaich Aureole,Skye,Scotland,UK:Constraints on processes in a dynamic hydrothermal system.Journal of Petrology,45(3):457-484
Sun WD,Liang HY,Ling MX,Zhan MZ,Ding X,Zhang H,Yang XY,Li YL,Ireland TR,Wei QR and WM.2013.The link between reduced porphyry copper deposits and oxidized magmas.Geochimica et Cosmochimica Acta,103:263-275
Van Westrenen W,Allan NL,Blundy JD,Purton JA and Wood BJ.2000.Atomistic simulation of trace element incorporation into garnets-comparison with experimental garnet-melt partitioning data.Geochimica et Cosmochimica Acta,64(9):1629-1639
Whittaker EJW and Muntus R.1970.Ionic radii for use in geochemistry.Geochimica et Cosmochimica Acta,34(9):945-956
Xie GQ,Mao JW and Zhao HJ.2011.Zircon U-Pb geochronological and Hf isotopic constraints on petrogenesis of Late Mesozoic intrusions in the southeast Hubei Province,Middle-Lower Yangtze River belt(MLYRB),East China.Lithos,125(1-2):693-710
Xie GQ,Mao JW,Zhu QQ,Yao L,Li YH,Li W and Zhao HJ.2015.Geochemical constraints on Cu-Fe and Fe skarn deposits in the Edong district,Middle-Lower Yangtze River metallogenic belt,China.Ore Geology Reviews,64:425-444
Yang JH,Kang LF,Peng JT,Zhong H,Gao JF and Liu L.2018.Insitu elemental and isotopic compositions of apatite and zircon from the Shuikoushan and Xihuashan granitic plutons:Implication for Jurassic granitoid-related Cu-Pb-Zn and W mineralization in the Nanling Range,South China.Ore Geology Reviews,93:382-403
Yao JM,Hua RM and Lin JF.2005.Zircon LA-ICPMS U-Pb dating and geochemical characteristics of Huangshaping granite in Southeast Hunan Province,China.Acta Petrologica Sinica,21(3):688-696(in Chinese with English abstract)
Yao JM,Hua RM,Qu WJ,Qi HW,Lin JF and Du AD.2007.Re-Os isotope dating of molybdenites in the Huangshaping Pb-Zn-W-Mo polymetallic deposit,Hunan Province,South China and its geological significance.Science in China(Series D),50(4):519-526
Yuan SD,Peng JT,Shen NP,Hu RZ and Dai TM.2007.40Ar-39Ar isotopic dating of the Xianghualing Sn-polymetallic orefield in southern Hunan,China and its geological implications.Acta Geologica Sinica,81(2):278-286
Yuan SD,Peng JT,Hu RZ,Li HM,Shen NP and Zhang DL.2008.Aprecise U-Pb age on cassiterite from the Xianghualing tinpolymetallic deposit(Hunan,South China).Mineralium Deposita,43(4):375-382
Yuan SD,Peng JT,Hao S,Li HM,Geng JZ and Zhang DL.2011.In situ LA-MC-ICP-MS and ID-TIMS U-Pb geochronology of cassiterite in the giant Furong tin deposit,Hunan Province,South China:New constraints on the timing of tin-polymetallic mineralization.Ore Geology Reviews,43(1):235-242
Yuan SD,Liu XF,Wang XD,Wu SH,Yuan YB,Li XK and Wang TZ.2012a.Geological characteristics and40Ar-39Ar geochronology of the Hongqiling tin deposit in southern Hunan Province.Acta Petrologica Sinica,28(12):3787-3797(in Chinese with English abstract)
Yuan SD,Zhang DL,Shuang Y,Du AD and Qu WJ.2012b.Re-Os dating of molybdenite from the Xintianling giant tungstenmolybdenum deposit in southern Hunan Province,China and its geological implications.Acta Petrologica Sinica,28(1):27-38(in Chinese with English abstract)
Yuan SD,Mao JW,Cook NJ,Wang XD,Liu XF and Yuan YB.2015.A Late Cretaceous tin metallogenic event in Nanling W-Sn metallogenic province:Constraints from U-Pb,Ar-Ar geochronology at the Jiepailing Sn-Be-F deposit,Hunan,China.Ore Geology Reviews,65:283-293
Yuan SD,Williams-Jones AE,Mao JW,Zhao PL,Yan C and Zhang DL.2018.The origin of the Zhangjialong tungsten deposit,South China:Implication for W-Sn mineralization in large granitebatholiths.Economic Geology,113(5):1191-1208
Yuan YB,Yuan SD,Liu XF,Mi JR,Xuan YS and Zhao PL.2014a.Sulfur isotopic characteristics of the Huangshaping granite and their geological significance in southern Hunan Province.Acta Geologica Sinica,88(12):2437-2442(in Chinese with English abstract)
Yuan YB,Yuan SD,Chen CJ and Huo R.2014b.Zircon U-Pb ages and Hf isotopes of the granitoids in the Huangshaping mining area and their geological significance.Acta Petrologica Sinica,30(1):64-78(in Chinese with English abstract)
Yuan YB.2015.The genetic difference between two metallogenic granites and the ore-forming material source of the Huangshaping deposit in southern Hunan.Master Degree Thesis.Beijing:China University of Geosciences,1-59(in Chinese)
Zhai DG,Liu JJ,Zhang HY,Wang JP,Su L,Yang XA and Wu SH.2014.Origin of oscillatory zoned garnets from the Xieertala Fe-Zn skarn deposit,northern China:In situ LA-ICP-MS evidence.Lithos,190-191:279-291
Zhang ZY,Xie GQ,Zhu QQ,Li W,Han YX and Wang FL.2016.Mineralogical characteristics of skarns of Caojiaba large tungsten deposit in central Hunan Province and their geological significance.Mineral Deposits,35(2):335-348(in Chinese with English abstract)
Zhao B,Li TJ and Li ZP.1983.Experimental study of physico-chemical conditions of the formation of skarns.Geochimica,(3):256-267(in Chinese with English abstract)
Zhao PL,Yuan SD,Mao JW,Santosh M,Li C and Hou KJ.2016.Geochronological and petrogeochemical constraints on the skarn deposits in Tongshanling ore district,southern Hunan Province:Implications for Jurassic Cu and W metallogenic events in South China.Ore Geology Reviews,78:120-137
Zhao PL,Yuan SD and Yuan YB.2016.Zircon LA-MC-ICP-MS U-Pb dating of the Xianglinpu granites from the Weijia tungsten deposit in southern Hunan Province and its implications for the Late Jurassic tungsten metallogenesis in the westernmost Nanling W-Sn metallogenic belt.Geology in China,43(1):120-131(in Chinese with English abstract)
Zhao PL,Yuan SD,Mao JW,Santosh M and Zhang DL.2017.Zircon U-Pb and Hf-O isotopes trace the architecture of polymetallic deposits:A case study of the Jurassic ore-forming porphyries in the Qin-Hang metallogenic belt,China.Lithos,292-293:132-145
Zhao PL,Yuan SD,Mao JW,Yuan YB,Zhao HJ,Zhang DL and Shuang Y.2018.Constraints on the timing and genetic link of the large-scale accumulation of proximal W-Sn-Mo-Bi and distal Pb-ZnAg mineralization of the world-class Dongpo orefield,Nanling Range,South China.Ore Geology Reviews,95:1140-1160
Zhao YM,Lin WW,Bi CG,Li DX and Jiang CJ.1990.China Skarn Deposit.Beijing:Geological Publishing House(in Chinese)
Zhu QQ,Xie GQ,Li W,Zhang F,Wang J,Zhang P and Yu BF.2014.In situ analysis of garnets from the Jingshandian iron skarn deposit,Hubei Province,and its geological implications.Geology in China,41(6):1944-1963(in Chinese with English abstract)
陈小文,伍建柏,息朝庄.2008.湖南黄沙坪铅锌多金属矿床地质特征及成因探讨.国土资源导刊,5(4):45-48
何厚强,王静纯,江元成.2010.湖南黄沙坪铅锌矿区南部铁钨钼铋(锡)多金属矿床成矿地质特征初析.矿产勘查,1(4):323-333
胡明月,何红蓼,詹秀春,樊兴涛,王广,贾泽荣.2008.基体归一定量技术在激光烧蚀-等离子体质谱法锆石原位多元素分析中的应用.分析化学,36(7):947-953
黄革非.1999.湘南地区“黄沙坪式”铅锌矿床地质特征及找矿方向.湖南地质,18(2-3):84-90,115
雷泽恒,陈富文,陈郑辉,许以明,龚述清,李华芹,梅玉萍,屈文俊,王登红.2010.黄沙坪铅锌多金属矿成岩成矿年龄测定及地质意义.地球学报,31(4):532-540
李福顺,康如华,胡绪云,马武良,黄新华,曾永红,唐俊彬,朱贤,秦志伟,赵杰,何立斌.2012.南岭魏家钨矿床地质特征及找矿前景分析.中国地质,39(2):445-457
刘悟辉.2007.黄沙坪铅锌多金属矿床成矿机理及其预测研究.博士学位论文.长沙:中南大学,1-146
刘晓菲,袁顺达,吴胜华.2012.湖南金船塘锡铋矿床辉钼矿Re-Os同位素测年及其地质意义.岩石学报,28(1):39-51
刘晓菲,袁顺达,双燕,原垭斌,弥佳茹,轩一撒.2014.湖南金船塘锡铋矿床石榴子石原位LA-ICP-MS稀土元素分析及其意义.岩石学报,30(1):163-177
马丽艳,路远发,屈文俊,付建明.2007.湖南黄沙坪铅锌多金属矿床的Re-Os同位素等时线年龄及地质意义.矿床地质,26(4):425-431
毛景文,谢桂青,郭春丽,陈毓川.2007.南岭地区大规模钨锡多金属成矿作用:成矿时限及地球动力学背景.岩石学报,23(10):2329-2338
毛景文,谢桂青,郭春丽,袁顺达,程彦博,陈毓川.2008.华南地区中生代主要金属矿床时空分布规律和成矿环境.高校地质学报,14(4):510-526
毛景文,陈懋弘,袁顺达,郭春丽.2011.华南地区钦杭成矿带地质特征和矿床时空分布规律.地质学报,85(5):636-658
彭惠娟,李洪英,裴荣富,张长青,周云满,田广,李建新,龙飞.2014.云南中甸红牛-红山矽卡岩型铜矿床矿物学特征与成矿作用.岩石学报,30(1):237-256
姚军明,华仁民,林锦富.2005.湘东南黄沙坪花岗岩LA-ICPMS锆石U-Pb定年及岩石地球化学特征.岩石学报,21(3):688-696
袁顺达,刘晓菲,王旭东,吴胜华,原垭斌,李雪凯,王铁柱.2012a.湘南红旗岭锡多金属矿床地质特征及Ar-Ar同位素年代学研究.岩石学报,28(12):3787-3797
袁顺达,张东亮,双燕,杜安道,屈文俊.2012b.湘南新田岭大型钨钼矿床辉钼矿Re-Os同位素测年及其地质意义.岩石学报,28(1):27-38
原垭斌,袁顺达,刘晓菲,弥佳茹,轩一撒,赵盼捞.2014a.湘南黄沙坪矿区花岗岩的硫同位素特征及其地质意义.地质学报,88(12):2437-2442
原垭斌,袁顺达,陈长江,霍然.2014b.黄沙坪矿区花岗岩类的锆石U-Pb年龄、Hf同位素组成及其地质意义.岩石学报,30(1):64-78
原垭斌.2015.湘南黄沙坪矿床两类岩体成矿差异性及成矿物质来源研究.硕士学位论文.北京:中国地质大学,1-59
张志远,谢桂青,朱乔乔,李伟,韩颖霄,王凤兰.2016.湘中曹家坝大型钨矿床的主要矽卡岩矿物学特征及其地质意义.矿床地质,35(2):335-348
赵斌,李统锦,李昭平.1983.夕卡岩形成的物理化学条件实验研究.地球化学,(3):256-267
赵盼捞,袁顺达,原垭斌.2016.湘南魏家钨矿区祥林铺岩体锆石LA-MC-ICP-MS U-Pb测年---对南岭西端晚侏罗世钨矿成岩成矿作用的指示.中国地质,43(1):120-131
赵一鸣,林文蔚,毕承思,李大新,蒋崇俊.1990.中国矽卡岩矿床.北京:地质出版社,1-354
朱乔乔,谢桂青,李伟,张帆,王建,张平,于炳飞.2014.湖北金山店大型矽卡岩型铁矿石榴子石原位微区分析及其地质意义.中国地质,41(6):1944-1963
Bai TB and Koster van Groos AF.1999.The distribution of Na,K,Rb,Sr,Al,Ge,Cu,W,Mo,La,and Ce between granitic melts and coexisting aqueous fluids.Geochimica et Cosmochimica Acta,63(7-8):1117-1131
Blevin PL and Chappell BW.1992.The role of magma sources,oxidation states and fractionation in determining the granite metallogeny of eastern Australia.Earth and Environmental Science Transactions of the Royal Society of Edinburgh,83(1-2):305-316
Blevin PL and Chappell BW.1995.Chemistry,origin,and evolution of mineralized granites in the Lachlan fold belt,Australia:The metallogeny of I-and S-type granites.Economic Geology,90(6):1604-1619
Chen J,Halls C and Stanley CJ.1992.Tin-bearing skarns of South China:Geological setting and mineralogy.Ore Geology Reviews,7(3):225-248
Chen XW,Wu JB and Xi CZ.2008.Geological characteristics and genesis of Huangshaping lead-zinc polymetallic deposit in Hunan.Land&Resources Herald,5(4):45-48(in Chinese)
Ding T,Ma DS,Lu JJ,Zhang RQ,Zhang ST and Gao SY.2016.Petrogenesis of Late Jurassic granitoids and relationship to polymetallic deposits in southern China:The Huangshaping example.International Geology Review,58(13):1646-1672
Eadington PJ and Kinealy K.1983.Some aspects of the hydrothermal reactions of tin during skarn formation.Journal of the Geological Society of Australia,30(3-4):461-471
Flynn RT and Burnham CW.1978.An experimental determination of rare earth partition coefficients between a chloride containing vapor phase and silicate melts.Geochimica et Cosmochimica Acta,42(6):685-701
Gaspar M,Knaack C,Meinert LD and Moretti R.2008.REE in skarn systems:A LA-ICP-MS study of garnets from the Crown Jewel gold deposit.Geochimica et Cosmochimica Acta,72(1):185-205
He HQ,Wang JC and Jiang YC.2010.Preliminary analysis on the geological characteristics and genesis of Fe-W-Mo-Bi(Sn)polymetallic deposit in the southern Huangshaping lead-zinc mine district,Hunan.Mineral Exploration,1(4):323-333(in Chinese with English abstract)
Hu MY,He HL,Zhan XC,Fan XT,Wang G and Jia ZR.2008.Matrix normalization for In-situ multi-element quantitative analysis of zircon in Laser Ablation-Inductively Coupled Plasma Mass Spectrometry.Chinese Journal of Analytical Chemistry,36(7):947-953(in Chinese with English abstract)
Huang GF.1999.Geological characteristics and seeking mineral orientation of Huangshaping style Pb-Zn deposit in southern Hunan.Hunan Geology,18(2-3):84-90,115(in Chinese with English abstract)
Ishihara S.1977.The magnetite-series and ilmenite-series granitic rocks.Mining Geology,27(145):293-305
Jamtveit B,Wogelius RA and Fraser DG.1993.Zonation patterns of skarn garnets:Records of hydrothermal system evolution.Geology,21(2):113-116
Lei ZH,Chen FW,Chen ZH,Xu YM,Gong SQ,Li HQ,Mei YP,Qu WJ and Wang DH.2010.Petrogenetic and metallogenic age determination of the Huangshaping lead-zinc polymetallic deposit and its geological significance.Acta Geoscientica Sinica,31(4):532-540(in Chinese with English abstract)
Li FS,Kang RH,Hu XY,Ma WL,Huang XH,Zeng YH,Tang JB,Zhu X,Qin ZW,Zhang J and He LB.2012.Geological characteristics and ore-search prospect of the Weijia tungsten deposit in Nanling region.Geology in China,39(2):445-457(in Chinese with English abstract)
Li H,Watanabe K and Yonezu K.2014.Zircon morphology,geochronology and trace element geochemistry of the granites from the Huangshaping polymetallic deposit,South China:Implications for the magmatic evolution and mineralization processes.Ore Geology Reviews,60:14-35
Li XF,Huang C,Wang CZ and Wang LF.2016.Genesis of the Huangshaping W-Mo-Cu-Pb-Zn polymetallic deposit in southeastern Hunan Province,China:Constraints from fluid inclusions,trace elements,and isotopes.Ore Geology Reviews,79:1-25
Linnen RL,Pichavant M,Holtz F and Burgess S.1995.The effect of fO 2on the solubility,diffusion,and speciation of tin in haplogranitic melt at 850℃and 2kbar.Geochimica et Cosmochimica Acta,59(8):1579-1588
Linnen RL,Pichavant M and Holtz F.1996.The combined effects of fO 2and melt composition on SnO2solubility and tin diffusivity in haplogranitic melts.Geochimica et Cosmochimica Acta,60(24):4965-4976
Liu WH.2007.Mineralization mechanism of the Huangshaping lead-zinc polymetallic deposit and its application in ore prospecting.Ph.D.Dissertation.Changsha:Central South University,1-146(in Chinese)
Liu XF,Yuan SD and Wu SH.2012.Re-Os dating of the molybdenite from the Jinchuantang tin-bismuth deposit in Hunan Province and its geological significance.Acta Petrologica Sinica,28(1):39-51(in Chinese with English abstract)
Liu XF,Yuan SD,Shuang Y,Yuan YB,Mi JR and Xuan YS.2014.In situ LA-ICP-MS REE analyses of the skarn garnets from the Jinchuantang tin-bismuth deposit in Hunan Province,and their significance.Acta Petrologica Sinica,30(1):163-177(in Chinese with English abstract)
Ma LY,Lu YF,Qu WJ and Fu JM.2007.Re-Os isotopic chronology of molybdenites in Huangshaping lead-zinc deposit,Southeast Hunan,and its geological implications.Mineral Deposits,26(4):425-431(in Chinese with English abstract)
Mao JW,Guy G,Raimbault L and Shimazaki H.1996a.Manganese skarn in the Shizhuyuan polymetallic tungsten deposit,Hunan,China.Resource Geology,46(255):1-11
Mao JW,Li HY,Shimazaki H,Raimbault L and Guy B.1996b.Geology and metallogeny of the Shizhuyuan skarn-greisen deposit,Hunan Province,China.International Geology Review,38(11):1020-1039
Mao JW,Xie GQ,Guo CL and Chen YC.2007.Large-scale tungsten-tin mineralization in the Nanling region,South China:Metallogenic ages and corresponding geodynamic processes.Acta Petrologica Sinica,23(10):2329-2338(in Chinese with English abstract)
Mao JW,Xie GQ,Guo CL,Yuan SD,Cheng YB and Chen YC.2008.Spatial-temporal distribution of Mesozoic ore deposits in South China and their metallogenic settings.Geological Journal of China Universities,14(4):510-526(in Chinese with English abstract)
Mao JW,Chen MH,Yuan SD and Guo CL.2011.Geological characteristics of the Qinhang(or Shihang)metallogenic belt in South China and spatial-temporal distribution regularity of mineral deposits.Acta Geologica Sinica,85(5):636-658(in Chinese with English abstract)
Mao JW,Cheng YB,Chen MH and Pirajno F.2013.Major types and time-space distribution of Mesozoic ore deposits in South China and their geodynamic settings.Mineralium Deposita,48(3):267-294
McI ntire WL.1963.Trace element partition coefficients:A review of theory and applications to geology.Geochimica et Cosmochimica Acta,27(12):1209-1264
Meinert LD.1992.Skarns and skarn deposits.Geoscience Canada,19(4):145-162
Meinert LD,Hefton KK,Mayes D and Tasiran I.1997.Geology,zonation,and fluid evolution of the Big Gossan Cu-Au skarn deposit,Ertsberg district,Irian Jaya.Economic Geology,92(5):509-534
Meinert LD,Hedenquist JW,Satoh H and Matsuhisa Y.2003.Formation of anhydrous and hydrous skarn in Cu-Au ore deposits by magmatic fluids.Economic Geology,98(1):147-156
Meinert LD,Dipple GM and Nicolescu S.2005.World skarn deposits.Society of Economic Geologists,100:299-336
Menzer G.1926.Die kristallstruktur der granate.Zeitschift fur Kristallographie,63:157-158
Mungall JE.2002.Roasting the mantle:Slab melting and the genesis of major Au and Au-rich Cu deposits.Geology,30(10):915-918
Nicolescu S,Cornell DH,S9dervall U and Odelius H.1998.Secondary ion mass spectrometry analysis of rare earth elements in grandite garnet and other skarn related silicates.European Journal of Mineralogy,10(2):251-260
Peng HJ,Li HY,Pei RF,Zhang CQ,Zhou YM,Tian G,Li JX and Long F.2014.Mineralogical characteristics and metallogeny of the Hongniu-Hongshan copper deposit in Zhongdian area,Yunnan Province,China.Acta Petrologica Sinica,30(1):237-256(in Chinese with English abstract)
Peng HJ,Zhang CQ,Mao JW,Santosh M,Zhou YM and Hou L.2015.Garnets in porphyry-skarn systems:A LA-ICP-MS,fluid inclusion,and stable isotope study of garnets from the Hongniu-Hongshan copper deposit,Zhongdian area,NW Yunnan Province,China.Journal of Asian Earth Sciences,103:229-251
Peng JT,Zhou MF,Hu RZ,Shen NP,Yuan SD,Bi XW,Du AD and Qu WJ.2006.Precise molybdenite Re-Os and mica Ar-Ar dating of the Mesozoic Yaogangxian tungsten deposit,central Nanling district,South China.Mineralium Deposita,41(7):661-669
Reed MJ,Candela PA and Piccoli PM.2000.The distribution of rare earth elements between monzogranitic melt and the aqueous volatile phase in experimental investigations at 800℃and 200MPa.Contributions to Mineralogy and Petrology,140(2):251-262
Shannon RD.1976.Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides.Acta Crystallographica Section A,32(5):751-767
Sillitoe RH.1997.Characteristics and controls of the largest porphyry copper-gold and epithermal gold deposits in the circum-Pacificregion.Australian Journal of Earth Sciences,44(3):373-388
Smith MP,Henderson P,Jeffries TER,Long J and Williams CT.2004.The rare earth elements and uranium in garnets from the Beinn an Dubhaich Aureole,Skye,Scotland,UK:Constraints on processes in a dynamic hydrothermal system.Journal of Petrology,45(3):457-484
Sun WD,Liang HY,Ling MX,Zhan MZ,Ding X,Zhang H,Yang XY,Li YL,Ireland TR,Wei QR and WM.2013.The link between reduced porphyry copper deposits and oxidized magmas.Geochimica et Cosmochimica Acta,103:263-275
Van Westrenen W,Allan NL,Blundy JD,Purton JA and Wood BJ.2000.Atomistic simulation of trace element incorporation into garnets-comparison with experimental garnet-melt partitioning data.Geochimica et Cosmochimica Acta,64(9):1629-1639
Whittaker EJW and Muntus R.1970.Ionic radii for use in geochemistry.Geochimica et Cosmochimica Acta,34(9):945-956
Xie GQ,Mao JW and Zhao HJ.2011.Zircon U-Pb geochronological and Hf isotopic constraints on petrogenesis of Late Mesozoic intrusions in the southeast Hubei Province,Middle-Lower Yangtze River belt(MLYRB),East China.Lithos,125(1-2):693-710
Xie GQ,Mao JW,Zhu QQ,Yao L,Li YH,Li W and Zhao HJ.2015.Geochemical constraints on Cu-Fe and Fe skarn deposits in the Edong district,Middle-Lower Yangtze River metallogenic belt,China.Ore Geology Reviews,64:425-444
Yang JH,Kang LF,Peng JT,Zhong H,Gao JF and Liu L.2018.Insitu elemental and isotopic compositions of apatite and zircon from the Shuikoushan and Xihuashan granitic plutons:Implication for Jurassic granitoid-related Cu-Pb-Zn and W mineralization in the Nanling Range,South China.Ore Geology Reviews,93:382-403
Yao JM,Hua RM and Lin JF.2005.Zircon LA-ICPMS U-Pb dating and geochemical characteristics of Huangshaping granite in Southeast Hunan Province,China.Acta Petrologica Sinica,21(3):688-696(in Chinese with English abstract)
Yao JM,Hua RM,Qu WJ,Qi HW,Lin JF and Du AD.2007.Re-Os isotope dating of molybdenites in the Huangshaping Pb-Zn-W-Mo polymetallic deposit,Hunan Province,South China and its geological significance.Science in China(Series D),50(4):519-526
Yuan SD,Peng JT,Shen NP,Hu RZ and Dai TM.2007.40Ar-39Ar isotopic dating of the Xianghualing Sn-polymetallic orefield in southern Hunan,China and its geological implications.Acta Geologica Sinica,81(2):278-286
Yuan SD,Peng JT,Hu RZ,Li HM,Shen NP and Zhang DL.2008.Aprecise U-Pb age on cassiterite from the Xianghualing tinpolymetallic deposit(Hunan,South China).Mineralium Deposita,43(4):375-382
Yuan SD,Peng JT,Hao S,Li HM,Geng JZ and Zhang DL.2011.In situ LA-MC-ICP-MS and ID-TIMS U-Pb geochronology of cassiterite in the giant Furong tin deposit,Hunan Province,South China:New constraints on the timing of tin-polymetallic mineralization.Ore Geology Reviews,43(1):235-242
Yuan SD,Liu XF,Wang XD,Wu SH,Yuan YB,Li XK and Wang TZ.2012a.Geological characteristics and40Ar-39Ar geochronology of the Hongqiling tin deposit in southern Hunan Province.Acta Petrologica Sinica,28(12):3787-3797(in Chinese with English abstract)
Yuan SD,Zhang DL,Shuang Y,Du AD and Qu WJ.2012b.Re-Os dating of molybdenite from the Xintianling giant tungstenmolybdenum deposit in southern Hunan Province,China and its geological implications.Acta Petrologica Sinica,28(1):27-38(in Chinese with English abstract)
Yuan SD,Mao JW,Cook NJ,Wang XD,Liu XF and Yuan YB.2015.A Late Cretaceous tin metallogenic event in Nanling W-Sn metallogenic province:Constraints from U-Pb,Ar-Ar geochronology at the Jiepailing Sn-Be-F deposit,Hunan,China.Ore Geology Reviews,65:283-293
Yuan SD,Williams-Jones AE,Mao JW,Zhao PL,Yan C and Zhang DL.2018.The origin of the Zhangjialong tungsten deposit,South China:Implication for W-Sn mineralization in large granitebatholiths.Economic Geology,113(5):1191-1208
Yuan YB,Yuan SD,Liu XF,Mi JR,Xuan YS and Zhao PL.2014a.Sulfur isotopic characteristics of the Huangshaping granite and their geological significance in southern Hunan Province.Acta Geologica Sinica,88(12):2437-2442(in Chinese with English abstract)
Yuan YB,Yuan SD,Chen CJ and Huo R.2014b.Zircon U-Pb ages and Hf isotopes of the granitoids in the Huangshaping mining area and their geological significance.Acta Petrologica Sinica,30(1):64-78(in Chinese with English abstract)
Yuan YB.2015.The genetic difference between two metallogenic granites and the ore-forming material source of the Huangshaping deposit in southern Hunan.Master Degree Thesis.Beijing:China University of Geosciences,1-59(in Chinese)
Zhai DG,Liu JJ,Zhang HY,Wang JP,Su L,Yang XA and Wu SH.2014.Origin of oscillatory zoned garnets from the Xieertala Fe-Zn skarn deposit,northern China:In situ LA-ICP-MS evidence.Lithos,190-191:279-291
Zhang ZY,Xie GQ,Zhu QQ,Li W,Han YX and Wang FL.2016.Mineralogical characteristics of skarns of Caojiaba large tungsten deposit in central Hunan Province and their geological significance.Mineral Deposits,35(2):335-348(in Chinese with English abstract)
Zhao B,Li TJ and Li ZP.1983.Experimental study of physico-chemical conditions of the formation of skarns.Geochimica,(3):256-267(in Chinese with English abstract)
Zhao PL,Yuan SD,Mao JW,Santosh M,Li C and Hou KJ.2016.Geochronological and petrogeochemical constraints on the skarn deposits in Tongshanling ore district,southern Hunan Province:Implications for Jurassic Cu and W metallogenic events in South China.Ore Geology Reviews,78:120-137
Zhao PL,Yuan SD and Yuan YB.2016.Zircon LA-MC-ICP-MS U-Pb dating of the Xianglinpu granites from the Weijia tungsten deposit in southern Hunan Province and its implications for the Late Jurassic tungsten metallogenesis in the westernmost Nanling W-Sn metallogenic belt.Geology in China,43(1):120-131(in Chinese with English abstract)
Zhao PL,Yuan SD,Mao JW,Santosh M and Zhang DL.2017.Zircon U-Pb and Hf-O isotopes trace the architecture of polymetallic deposits:A case study of the Jurassic ore-forming porphyries in the Qin-Hang metallogenic belt,China.Lithos,292-293:132-145
Zhao PL,Yuan SD,Mao JW,Yuan YB,Zhao HJ,Zhang DL and Shuang Y.2018.Constraints on the timing and genetic link of the large-scale accumulation of proximal W-Sn-Mo-Bi and distal Pb-ZnAg mineralization of the world-class Dongpo orefield,Nanling Range,South China.Ore Geology Reviews,95:1140-1160
Zhao YM,Lin WW,Bi CG,Li DX and Jiang CJ.1990.China Skarn Deposit.Beijing:Geological Publishing House(in Chinese)
Zhu QQ,Xie GQ,Li W,Zhang F,Wang J,Zhang P and Yu BF.2014.In situ analysis of garnets from the Jingshandian iron skarn deposit,Hubei Province,and its geological implications.Geology in China,41(6):1944-1963(in Chinese with English abstract)
陈小文,伍建柏,息朝庄.2008.湖南黄沙坪铅锌多金属矿床地质特征及成因探讨.国土资源导刊,5(4):45-48
何厚强,王静纯,江元成.2010.湖南黄沙坪铅锌矿区南部铁钨钼铋(锡)多金属矿床成矿地质特征初析.矿产勘查,1(4):323-333
胡明月,何红蓼,詹秀春,樊兴涛,王广,贾泽荣.2008.基体归一定量技术在激光烧蚀-等离子体质谱法锆石原位多元素分析中的应用.分析化学,36(7):947-953
黄革非.1999.湘南地区“黄沙坪式”铅锌矿床地质特征及找矿方向.湖南地质,18(2-3):84-90,115
雷泽恒,陈富文,陈郑辉,许以明,龚述清,李华芹,梅玉萍,屈文俊,王登红.2010.黄沙坪铅锌多金属矿成岩成矿年龄测定及地质意义.地球学报,31(4):532-540
李福顺,康如华,胡绪云,马武良,黄新华,曾永红,唐俊彬,朱贤,秦志伟,赵杰,何立斌.2012.南岭魏家钨矿床地质特征及找矿前景分析.中国地质,39(2):445-457
刘悟辉.2007.黄沙坪铅锌多金属矿床成矿机理及其预测研究.博士学位论文.长沙:中南大学,1-146
刘晓菲,袁顺达,吴胜华.2012.湖南金船塘锡铋矿床辉钼矿Re-Os同位素测年及其地质意义.岩石学报,28(1):39-51
刘晓菲,袁顺达,双燕,原垭斌,弥佳茹,轩一撒.2014.湖南金船塘锡铋矿床石榴子石原位LA-ICP-MS稀土元素分析及其意义.岩石学报,30(1):163-177
马丽艳,路远发,屈文俊,付建明.2007.湖南黄沙坪铅锌多金属矿床的Re-Os同位素等时线年龄及地质意义.矿床地质,26(4):425-431
毛景文,谢桂青,郭春丽,陈毓川.2007.南岭地区大规模钨锡多金属成矿作用:成矿时限及地球动力学背景.岩石学报,23(10):2329-2338
毛景文,谢桂青,郭春丽,袁顺达,程彦博,陈毓川.2008.华南地区中生代主要金属矿床时空分布规律和成矿环境.高校地质学报,14(4):510-526
毛景文,陈懋弘,袁顺达,郭春丽.2011.华南地区钦杭成矿带地质特征和矿床时空分布规律.地质学报,85(5):636-658
彭惠娟,李洪英,裴荣富,张长青,周云满,田广,李建新,龙飞.2014.云南中甸红牛-红山矽卡岩型铜矿床矿物学特征与成矿作用.岩石学报,30(1):237-256
姚军明,华仁民,林锦富.2005.湘东南黄沙坪花岗岩LA-ICPMS锆石U-Pb定年及岩石地球化学特征.岩石学报,21(3):688-696
袁顺达,刘晓菲,王旭东,吴胜华,原垭斌,李雪凯,王铁柱.2012a.湘南红旗岭锡多金属矿床地质特征及Ar-Ar同位素年代学研究.岩石学报,28(12):3787-3797
袁顺达,张东亮,双燕,杜安道,屈文俊.2012b.湘南新田岭大型钨钼矿床辉钼矿Re-Os同位素测年及其地质意义.岩石学报,28(1):27-38
原垭斌,袁顺达,刘晓菲,弥佳茹,轩一撒,赵盼捞.2014a.湘南黄沙坪矿区花岗岩的硫同位素特征及其地质意义.地质学报,88(12):2437-2442
原垭斌,袁顺达,陈长江,霍然.2014b.黄沙坪矿区花岗岩类的锆石U-Pb年龄、Hf同位素组成及其地质意义.岩石学报,30(1):64-78
原垭斌.2015.湘南黄沙坪矿床两类岩体成矿差异性及成矿物质来源研究.硕士学位论文.北京:中国地质大学,1-59
张志远,谢桂青,朱乔乔,李伟,韩颖霄,王凤兰.2016.湘中曹家坝大型钨矿床的主要矽卡岩矿物学特征及其地质意义.矿床地质,35(2):335-348
赵斌,李统锦,李昭平.1983.夕卡岩形成的物理化学条件实验研究.地球化学,(3):256-267
赵盼捞,袁顺达,原垭斌.2016.湘南魏家钨矿区祥林铺岩体锆石LA-MC-ICP-MS U-Pb测年---对南岭西端晚侏罗世钨矿成岩成矿作用的指示.中国地质,43(1):120-131
赵一鸣,林文蔚,毕承思,李大新,蒋崇俊.1990.中国矽卡岩矿床.北京:地质出版社,1-354
朱乔乔,谢桂青,李伟,张帆,王建,张平,于炳飞.2014.湖北金山店大型矽卡岩型铁矿石榴子石原位微区分析及其地质意义.中国地质,41(6):1944-1963
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