聚环氧琥珀酸与Ca~(2+)的螯合反应研究

详细信息    查看全文 | 推荐本文 |

英文篇名：Study on chelation reaction between polyepoxysuccinic acid and Ca~(2+) 作者：王印忠 ; 徐旭 ; 李雪 ; 焦春联 ; 李志洁 ; 张连强 ; 尹建华 英文作者：WANG Yin-zhong;XU Xu;LI Xue;JIAO Chun-lian;LI Zhi-jie;ZHANG Lian-qiang;YIN Jian-hua;The Institute of Seawater Desalination and Multipurpose Utilization,SOA(Tianjin); 关键词：聚环氧琥珀酸 ; 螯合反应 ; 影响因素 ; 阻垢机理 英文关键词：polyepoxysuccinic acid;;chelation reaction;;influencing factor;;scale-inhibiting mechanism 中文刊名：HGGS 英文刊名：Industrial Water & Wastewater 机构：国家海洋局天津海水淡化与综合利用研究所; 出版日期：2017-04-28 出版单位：工业用水与废水 年：2017 期：v.48;No.219 基金：2015年中央级公益性科研院所基本科研业务费专项资金项目(K-JBYWF-2015-G07);; 2015年海洋公益性行业科研专项项目(201505021) 语种：中文; 页：HGGS201702015 页数：4 CN：02 ISSN：34-1204/TQ 分类号：74-77

摘要

为考察聚环氧琥珀酸对Ca~(2+)的螯合能力及其影响效果,采用滴定法考察了聚环氧琥珀酸与Ca~(2+)在不同反应条件下发生螯合反应的钙螯合值。单因素试验结果表明,聚环氧琥珀酸的钙螯合值受反应温度的影响较为明显,在5~45℃范围内随温度升高而增大,在45~65℃范围内随温度上升而减小。但在溶液初始pH值为6.5~9.5的条件下,钙螯合值受溶液初始pH值的影响较小。通过正交试验获得的最大钙螯合值为124.5 mg/g,对应的螯合官能团最大利用率仅为54.4%,而剩余的螯合官能团可能为PESA的致晶格畸变作用和分散作用提供了物质基础。
        To investigate the chelation reaction between polyepoxysuccinic acid and Ca~(2+)as well as its influencing factors, the calcium chelation values of the said chelation reaction under different conditions were investigated using titration. The results of the single factor test showed that, the calcium chelation value of polyepoxysuccinic acid was significantly affected by reaction temperature. When the reaction temperature changed from 5-45 ℃, the chelation value increased with the temperature increasing, however, when it changed from 45-65 ℃, the higher the temperature was, the lower the value would be. Under the condition that the initial pH value of the solution was 6.5-9.5, the calcium chelation value was slightly affected by initial pH value. The maximum calcium chelation value got from orthogonal test was 124.5 mg/g, and the maximum utilization ratio of the corresponding chelating functional groups was only 54.4%. Thereafter, the remaining chelating functional groups might provide material basis for attice distortion and dispersion of PESA.

引文

[1]李晓梅.绿色阻垢剂聚环氧琥珀酸的阻垢机理的研究[J].广州化工,2011,39(7):90-92.
    [2]康永.聚环氧琥珀酸阻垢机理及研究趋势[J].精细化工原料及中间体,2012,(6):22-24.
    [3]张锐,王姣龙.绿色阻垢剂的最新研究进展[J].工业用水与废水,2015,46(6):6-8.
    [4]雷武,王风云,夏明珠,等.绿色阻垢剂聚环氧琥珀酸的合成与阻垢机理初探[J].化工学报,2006,57(9):2207-2213.
    [5]全国化学标准化技术委员会.分析实验室用水规格和试验方法:GB/T 6682—2008[S].北京:中国标准出版社,2008.
    [6]蔡士杰.绿色水处理剂聚环氧琥珀酸物化性能指标及表征技术[D].北京:北京化工大学,2004.
    [7]石文艳,吕志敏,王风云,等.聚环氧琥珀酸及丙烯酸共聚物阻垢机理的分子动力学模拟[J].化学通报,2011,74(7):651-658.
    [8]黄茂福.化学助剂分析与应用手册[M].北京:中国纺织出版社,2001.