The isothermal section of the Tb-Fe-Ga temary system at 773K

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• 作者：M.OuyangJ.Q.LiD.C.LiuF.S.LiuW.Q.Ao
• 会议时间：2008-11-01
• 关键词：稀土化合物 ; 金相图 ; X射线衍射 ; 等温截面 ; 三元体系
• 作者单位：M.Ouyang,J.Q.Li,F.S.Liu,W.Q.Ao(School of Materials Science and Engineering,Shenzhen University and Shenzhen Key Laboratory of Special Functional Materials,Shenzhen 518060,P.R China)D.C.Liu(School of Materials Science and ngineering,Shenzhen University and Shenzhen Key Laboratory of Special Functional Materials,Shenzhen 518060,P.R China)
• 母体文献：第十四届全国相图会议暨国际相图与材料设计研讨会论文集
• 会议名称：第十四届全国相图会议暨国际相图与材料设计研讨会
• 会议地点：长沙
• 主办单位：中国物理学会
• 语种：chi

摘要

The isothermal section of the phase diagram of the Tb-Fe-Ga ternary system at 773 K was investigated by X-ray powder diffraction analysis.Fourteen binary compounds,TbFe2,TbFe3,Tb6Fe23,a-Tb2Fe17,Tb5Ga3,Tb3Ga2,TbGa,Tb3Ga5,ThGa2,a-TbGa3,a-Fe3Ga,a-Fe6Ga5,Fe3Ga4 and FeGa3,have been confirmed and six ternary compounds,TbFe0.32Ga1.68,TbFe2.4Ga0.6,Tb4FeGa12,Tb2FeGa8,TbFe6Ga6 and ThFe5Ga7,were found in this ternary system at 773 K.The structures of theses compounds were determined by Rietveld refinement method.The compound TbFe0.32Ga1.68 is InNi2-type structure(space group P63/mmc)with a=0.43727(2)and C=0.72930(4)nm.The compound TbFe2.4Ga0.6 belongs to CeNi3-type structure(space group P63/mmc)with a-0.51877(9)and C=1.6621(4)nm.The compound Tb4FeGa12 is U4Re7Si6-type structure(space group Im 3m)with a=0.85576(4)nm.The compound Tb2FeGas is H02CoGa8-type structure(space group P4mmm)with a=0.4259(4)and C=1.1 1 356(8)nm.The compound TbFe6Ga6 is ScFe6Ga6-type structure(space group Immm)with a=0.85551(4),b=0.86826(5)and C=0.50717(3)nm.The compound TbFejGa7 is ThMn12-type structure(space group 14/mmm)with a=0.86779(8)and C=O.50923(5)nm.The isothermal section of this ternary system at 773 K consists of 23 single-phase regions,42 two-phase regions and 22 three-phase regions.The solid solutions this temaly system is formed by substitution of Ga for Fe.The maximum solid solubilities of Ga in ThFe2,ThFe3 and Th2Fe17 are 19.6,8.0,and 37.5 at% respectively.The homogeneity ranges for the other compounds are small.