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Boron- and magnesium-rich marine brines at the origin of giant unco
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  • journal_title:Geology
  • Contributor:Julien Mercadier ; Antonin Richard ; Michel Cathelineau
  • Publisher:Geological Society of America
  • Date:2012-
  • Format:text/html
  • Language:en
  • Identifier:10.1130/G32509.1
  • journal_abbrev:Geology
  • issn:0091-7613
  • volume:40
  • issue:3
  • firstpage:231
  • section:Articles
摘要

In giant unconformity-related U deposits from the Athabasca Basin (Canada), the origin of the ore fluids and the source of elements typically associated with U ore, such as Mg and B, are highly controversial. This paper presents a petrographic and boron isotopic study of Mg-tourmalines (dravites) coeval with U oxides and of primary tourmalines from basement rocks. The heavy B isotopic compositions of dravites (δ11B = 19.6‰–36.5‰) contrast with the light composition of basement tourmalines (δ11B = –8.1‰–3.3‰) and clearly show that most of the B was brought to the ore system by basinal brines of marine origin. Because the latter are also typically Mg-rich, a similar origin for Mg is proposed. These results support the idea that marine-derived brines were the only fluids involved in the formation of the deposits, and therefore challenge the previous models in which the B and Mg were leached from sedimentary and/or basement rocks, or carried by a basement-derived fluid.

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