A revisit of strain-rate frequency superposition of dense colloidal suspensions under oscillatory shears

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• 作者：Jun-jie Li 李俊杰 ; Xuan Cheng 程璇 ; Ying Zhang 张颖…
• 关键词：Key wordsstrain ; rate frequency superposition ; medium amplitude oscillatory shear ; linear viscoelasticity ; fractional Maxwell model
• 刊名：Journal of Central South University
• 出版年：2016
• 出版时间：August 2016
• 年：2016
• 卷：23
• 期：8
• 页码：1873-1882
• 全文大小：1,492 KB
• 刊物类别：Engineering
• 刊物主题：Engineering, general
  Metallic Materials
  Chinese Library of Science
  
• 出版者：Central South University, co-published with Springer
• ISSN：2227-5223
• 卷排序：23

文摘

Strain-rate frequency superposition (SRFS) is often employed to probe the low-frequency behavior of soft solids under oscillatory shear in anticipated linear response. However, physical interpretation of an apparently well-overlapped master curve generated by SRFS has to combine with nonlinear analysis techniques such as Fourier transform rheology and stress decomposition method. The benefit of SRFS is discarded when some inconsistencies of the shifted master curves with the canonical linear response are observed. In this work, instead of evaluating the SRFS in full master curves, two criteria were proposed to decompose the original SRFS data and to delete the bad experimental data. Application to Carabopol suspensions indicates that good master curves could be constructed based upon the modified data and the high-frequency deviations often observed in original SRFS master curves are eliminated. The modified SRFS data also enable a better quantitative description and the evaluation of the apparent structural relaxation time by the two-mode fractional Maxwell model.