Alloying Strategy in Cu–In–Ga–Se Quantum Dots for High Efficiency Quantum Dot Sensitized Solar Cells

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• 作者：Wenxiang Peng ; Jun Du ; Zhenxiao Pan ; Naoki Nakazawa ; Jiankun Sun ; Zhonglin Du ; Gencai Shen ; Juan Yu ; Jin-Song HuQing Shen ; Xinhua Zhong
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2017
• 出版时间：February 15, 2017
• 年：2017
• 卷：9
• 期：6
• 页码：5328-5336
• 全文大小：635K
• ISSN：1944-8252

文摘

I–III–VI₂ group “green” quantum dots (QDs) are attracting increasing attention in photoelectronic conversion applications. Herein, on the basis of the “simultaneous nucleation and growth” approach, Cu–In–Ga–Se (CIGSe) QDs with light harvesting range of about 1000 nm were synthesized and used as sensitizer to construct quantum dot sensitized solar cells (QDSCs). Inductively coupled plasma atomic emission spectrometry (ICP-AES), wild-angle X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) analyses demonstrate that the Ga element was alloyed in the Cu–In–Se (CISe) host. Ultraviolet photoelectron spectroscopy (UPS) and femtosecond (fs) resolution transient absorption (TA) measurement results indicate that the alloying strategy could optimize the electronic structure in the obtained CIGSe QD material, thus matching well with TiO₂ substrate and favoring the photogenerated electron extraction. Open circuit voltage decay (OCVD) and impedance spectroscopy (IS) tests indicate that the intrinsic recombination in CIGSe QDSCs was well suppressed relative to that in CISe QDSCs. As a result, CIGSe based QDSCs with use of titanium mesh supported mesoporous carbon counter electrode exhibited a champion efficiency of 11.49% (J_sc = 25.01 mA/cm², V_oc = 0.740 V, FF = 0.621) under the irradiation of full one sun in comparison with 9.46% for CISe QDSCs.