Water-Induced Phase Transition in Cyclohexane/n-Hexanol/Triton X-100 Mixtures at a Molar Composition of 1/16/74 Studied by NMR

详细信息    查看全文

• 作者：Mario E. Flores ; Francisco Martínez ; Andrés F. OleaToshimichi Shibue ; Natsuhiko Sugimura ; Hiroyuki Nishide ; Ignacio Moreno-Villoslada
• 刊名：Journal of Physical Chemistry B
• 出版年：2017
• 出版时间：February 2, 2017
• 年：2017
• 卷：121
• 期：4
• 页码：876-882
• 全文大小：384K
• ISSN：1520-5207

文摘

Molecular aggregation in a mixture of Triton X-100/n-hexanol/cyclohexane at a molar ratio of 1/16/74 is studied upon addition of small amounts of water. The composition of organic components has been chosen at a ratio n-hexanol/cyclohexane where a well-formed hydrogen bond network has been described. The ratio Triton X-100/n-hexanol has been chosen to afford a stoichiometry of ethylene oxide (EO) residues/n-hexanol of 1/2. At these conditions the addition of water consecutively produces the appearance of three defined phases: a clear solution, a lamellar phase, and a microemulsion. The two corresponding transitions occur at water/EO/n-hexanol molar ratios of 2/1/2 (clear to lamella), and 3/1/2 (lamella to microemulsion), while phase separation occurs at a molar ratio of 4/1/2, highlighting the important role of stoichiometry. Molecular dynamics measured by ¹H NMR techniques, such as DOSY, and calculations of T₁ and T₂ relaxation times allow distinguishing the transition between the different phases and justifying their structure. Molecular assembly in the three phases is organized around hydrogen bond networks in which the hydroxyl groups of both TX-100 and n-hexanol, ethylene oxide groups of TX-100, and water participate. 1D ¹H NMR spectral changes correlate with the different characteristics of the different phases. As the main characteristics of the lamellar phase we find a very restricted mobility of the molecules involved, and water chemical shifts in 1D ¹H NMR spectra of around 5.0 ppm, higher than that of bulk water appearing at 4.7 ppm.