Synthesis of Mono-, Di-, and Trinuclear Rhodium Diphosphine Complexes Containing Light-Harvesting Fluorene Backbones

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• 作者：Yuko Matsusaka ; Shoji Shitaya ; Kotohiro NomuraAkiko Inagaki
• 刊名：Inorganic Chemistry
• 出版年：2017
• 出版时间：February 6, 2017
• 年：2017
• 卷：56
• 期：3
• 页码：1027-1030
• 全文大小：347K
• ISSN：1520-510X

文摘

Syntheses and structural determination of rhodium complexes ligated by diphosphines containing light-harvesting fluorene backbones are presented. In these rhodium complexes, the rhodium center is surrounded by a light-absorbing diphosphine unit. The presence of Rh–Rh bonding interactions is suggested by density functional theory studies.