Sensitive Room-Temperature H2S Gas Sensors Employing SnO2 Quantum Wire/Reduced Graphene Oxide Nanocomposites

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• 作者：Zhilong Song ; Zeru Wei ; Baocun Wang ; Zhen Luo ; Songman Xu ; Wenkai Zhang ; Haoxiong Yu ; Min Li ; Zhao Huang ; Jianfeng Zang ; Fei Yi ; Huan Liu
• 刊名：Chemistry of Materials
• 出版年：2016
• 出版时间：February 23, 2016
• 年：2016
• 卷：28
• 期：4
• 页码：1205-1212
• 全文大小：478K
• ISSN：1520-5002

文摘

Metal oxide/graphene nanocomposites are emerging as one of the promising candidate materials for developing high-performance gas sensors. Here, we demonstrate sensitive room-temperature H₂S gas sensors based on SnO₂ quantum wires that are anchored on reduced graphene oxide (rGO) nanosheets. Using a one-step colloidal synthesis strategy, the morphology-related quantum confinement of SnO₂ can be well-controlled by tuning the reaction time, because of the steric hindrance effect of rGO. The as-synthesized SnO₂ quantum wire/rGO nanocomposites are spin-coated onto ceramics substrates without further sintering to construct chemiresistive gas sensors. The optimal sensor response toward 50 ppm of H₂S is 33 in 2 s, and it is fully reversible upon H₂S release at 22 °C. In addition to the excellent gas adsorption of ultrathin SnO₂ quantum wires, the superior sensing performance of SnO₂ quantum wire/rGO nanocomposites can be attributed to the enhanced electron transport resulting from the favorable charge transfer of SnO₂/rGO interfaces and the superb transport capability of rGO. The easy fabrication and room-temperature operation make our sensors highly attractive for ultrasensitive H₂S gas detection with less power consumption.