Unprecedented Phthalocyanines Bearing Eight Di-butylamino Peripheral Substituents: Synthesis, Spectroscopy, and Structure

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• 作者：Yuxiang Chen ; Wei Cao ; Kang Wang ; Jianzhuang Jiang
• 刊名：Inorganic Chemistry
• 出版年：2015
• 出版时间：October 19, 2015
• 年：2015
• 卷：54
• 期：20
• 页码：9962-9967
• 全文大小：341K
• ISSN：1520-510X

文摘

Unprecedented 2,3,9,10,16,17,23,24-octakis(di-butylamino)phthalocyanine compounds M{Pc[N(C₄H₉)₂]₈} (M = 2H, Mg, Cu, Zn) (1鈥?b>4) were prepared and structurally characterized on the basis of single-crystal X-ray diffraction analysis, representing the first structurally characterized alkylamino-substituted phthalocyanine examples. These novel phthalocyanine derivatives have also been characterized by a wide range of spectroscopic methods including MALDI-TOF mass spectra, NMR, electronic absorption, and IR spectroscopy in addition to elemental analysis. Their electrochemistry was also studied by cyclic voltammetry.