Detailed Multi-dimensional Study of Pollutant Formation in a Methane Diffusion Flame

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• 作者：Rory F. D. Monaghan ; R氓bi Tahir ; Alberto Cuoci ; Gilles Bourque ; Marc F眉ri ; Robert L. Gordon ; Tiziano Faravelli ; Alessio Frassoldati ; Henry J. Curran
• 刊名：Energy & Fuels
• 出版年：2012
• 出版时间：March 15, 2012
• 年：2012
• 卷：26
• 期：3
• 页码：1598-1611
• 全文大小：803K
• 年卷期：v.26,no.3(March 15, 2012)
• ISSN：1520-5029

文摘

This paper describes a method to produce chemical reactor networks (CRNs) consisting of large numbers of perfectly stirred reactors (PSRs) from computational fluid dynamics (CFD) simulations to predict pollutant emissions from combustion systems accurately, flexibly, and efficiently using detailed kinetic schemes and the kinetic post-processor (KPP) developed at Politecnico di Milano. Benefits of the method described here include its applicability to a wide range of combustion systems, its ability to predict emissions of a variety of pollutant species, and its speed. CFD and CFD鈥揅RN simulation results of the Sandia D piloted methane鈥揳ir diffusion round-jet flame are successfully validated against experimental data for axial velocity, mixture fraction, temperature, and speciation, including CO and NO mass fractions. A CRN consisting of a large number of PSRs is found to be required to simulate the system accurately, while ensuring independence of the solution from CRN size. The results of CFD鈥揅RN analysis for a 1114 PSR network are used to study the pathways (thermal, prompt, N₂O, and NO₂) by which NO and NO₂, the constituents of NO_x, are formed in the flame. Results of CFD鈥揅RN analysis show that NO is produced in the high-temperature (T > 1850 K) flame brush by a combination of the prompt, N₂O, and thermal pathways and in the intermediate-temperature (1000 < T < 1600 K) post-flame region by a reversal of the NO₂ pathway. NO is consumed in the fuel-rich (mixture fraction, f > 0.43) region, where a low O atom concentration encourages a reversal of the prompt pathway (i.e., NO reburning), and in low-temperature (T < 1000 K) regions by the NO₂ pathway, which oxidizes NO to NO₂. Rate of production analysis, performed using CHEMKIN PRO at specified locations throughout the flame, shows that the trends of NO production and consumption observed in these simulations agree with expected and published results. Finally, the study predicts that, of the total NO_x produced by the Sandia D flame, 47% is due to the prompt pathway, 32% is due to the N₂O pathway, and 21% is due to the thermal pathway. As future steps in this work, the CFD鈥揅RN method will be adapted and used to predict and study emissions from a range of more complex combustion systems.