A Highly Enantioselective Allylic Amination Reaction Using a Commercially Available Chiral Rhodium Catalyst: Resolution of Racemic Allylic Carbonates

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• 作者：Derek C. Vrieze ; Garrett S. Hoge ; Perrine Z. Hoerter ; Jared T. Van Haitsma ; Brian M. Samas
• 刊名：Organic Letters
• 出版年：2009
• 出版时间：July 16, 2009
• 年：2009
• 卷：11
• 期：14
• 页码：3140-3142
• 全文大小：120K
• 年卷期：v.11,no.14(July 16, 2009)
• ISSN：1523-7052

文摘

A novel method for the kinetic resolution of unsymmetrical acyclic allylic carbonates and the concurrent synthesis of enantioenriched secondary amines using a commercially available chiral catalyst is disclosed.