The nondestructive analysis techniques of Proton Induced X-ray Emission (PIXE), X-ray Diffraction (XRD), Laser Raman Spectroscopy (LRS) and Scanning Electron Microscopy (SEM) were applied to analyze the chemical composition and mineral structure of serpentine jade from Luchuan, Guangxi. Raman characteristic bands of antigorite located at 229, 376, 457, 686 and 1 046 cm^-1 while that of chrysotile occurred at 228, 345, 386, 624, 690 and 1 102 cm^-1. Therefore, the Raman spectroscopy can be used to identify chrysotile and antigorite of the serpentine minerals of Luchuan jade.