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Stability of Biogenic Schwertmannite in Acidic Solution
详细信息   
摘要

Schwertmannites are secondary minerals widespread in acid mine drainages, and their development and transformations are controlled by environmental factors such as temperature, pH, and co-existing ions. In this study, the effects of temperature and ion concentration on the stability and transformation of biogenic and As-containing schwertmannites were investigated. The results showed that the increase of aging temperature favored mineral phase transformations (MPT): for schwertmannites with and without As incubated for 15 weeks, MPT did not take place at 4 , but partially occurred at 40 . In addition, the change of potassium ion concentration resulted in different aging products of schwertmannites: for the biogenic schwertmannites incubated for 15 weeks, the major aging products were goethite and jarosite/goethite at potassium ion concentrations of 0.01 mM and 100 mM, respectively; for the As()-containing schwertmannites incubated for 15 weeks,

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