Located in the western part of the Minxian County-Lixian County metallogenic belt, West Qinling Mountains, the Zhaishang gold deposit is a recently discovered large-sized Carlin-type disseminated gold deposit. Examination of ores by optical microscope, electron microprobe and X-ray surface scanning has revealed that the ore deposit is quite complex in mineralogy. Dissolution of ferruginous limestone in the host rocks and sulfidation of the dissolved iron by H2S introduced by ore fluids were not only the most important depositional mechanism for visible gold grains but also the advantageous conditions for gold enrichment in the Zhaishang gold deposit.